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2024 04 14 JM 25A ONLINE - PMD 1353112 2024 04 16 19 44
2024 04 14 JM 25A ONLINE - PMD 1353112 2024 04 16 19 44
1. A particle projected from the ground has maximum height 20 m and horizontal range
40 m. Its angle of projection with the horizontal is tan–1 k where k =
(A) 1 / 2 (B) 2 (C) 4 (D) 1 / 4
1. (B) k = tan = 4H / R = 80 / 40 = 2.
2. A 100 kg man sits on a 25 kg chair supported by a rope passing over a smooth fixed
pulley. The man exerts 450 N force on the chair downwards while pulling on the rope.
g = 10 ms–2. The acceleration upward is
(A) 0.45 ms–2 (B) zero (C) 2 ms–2 (D) 4.5 ms–2
PRERNA CLASSES
3. Blocks A (5 kg) and B (3 kg) rest on a rough horizontal surface in contact. The friction
coefficient with ground of A is 0.4 and of B is 0.5. A horizontal force of 75 N acts on A
pushing it towards B. The normal contact force between A and B is
(A) 55 N (B) 30 N (C) 37.5 N (D) 0 N
4. A 5000 kg truck moves at 10 ms–1 along a circular road of radius 20 m banked at 37º
with the horizontal. g = 10 ms–2. Frictional force acting on truck is
(A) 6 kN (B) 8 kN (C) 10 kN (D) 12 kN
5. Balls A, B, C of masses m, m, M respectively are placed in the same line some distance
apart on a smooth horizontal surface. A is given velocity u towards B. All collisions are
perfectly elastic. The number of collisions between the balls is nL if M < m and nG if
M > m. Then (2nL + nG) =
(A) 9 (B) 8 (C) 7 (D) 6
5. (C) After first, A at rest. After second, C moves forward. B also forward if m > M
i.e. nL = 2. If m < M, B reverses direction and comes to rest on collision with A.
nG = 3.
6. (C) By CAM about lowest point, (2Eo Icm) = (2E Iicor). E / Eo = Icm / Iicor = 2 / 7.
7. A uniform hollow cylinder has inner & outer radii 10 cm & 30 cm. The radius of a
uniform thin cylindrical shell of equal mass and same moment of inertia is nearly
(A) 20 cm (B) 17.5 cm (C) 15 cm (D) 22.5 cm
8. Imagine a light planet revolving around a massive star in a circular orbit of radius R with
period of revolution T. If the gravitational force of attraction between planet and star is
inversely proportional to R3, then T is proportional to
(A) R3 (B) R2 (C) R1.5 (D) R0.5
9. A uniform rod of length L, density is being pulled on a smooth horizontal floor with
acceleration a. The stress at the transverse cross-section at rod midpoint is µLa where
µ=
(A) 1 / 2 (B) 1 (C) 1 / 4 (D) 3 / 4
10. Bodies A & B, in mass ratio 1 : 4, are suspended from two separate springs with spring
constants in ratio 4 : 1. Both bodies oscillate vertically with ratio of maximum velocities
1 : 2. Then, ratio of amplitude of vibration of A to that of B is
(A) 1 : 4 (B) 4 : 1 (C) 1 : 2 (D) 1 : 8
12. A rectangular block of mass m, CSA A floats in a liquid of density . If given a small
vertical displacement from equilibrium, it oscillates with a time period (nm / Ag)
where n =
PRERNA CLASSES
13. A wood cube of side 10 cm, floats at the interface between oil and water, with its lower
face 2 cm below the interface. Oil extends 4 cm above the cube’s upper face. Density of
the oil is 0.6 gm cm-3. Mass of the block is
(A) 0.68 kg (B) 0.92 kg (C) 0.80 kg (D) 0.70 kg
13. (B) Mg = 8 × 102 × waterg + 2 × 102 × oilg M = 920 gram = 0.92 kg.
14. A vessel of CSA A filled with a liquid to height H has a hole of CSA a (<< A) at the
bottom. The time taken to empty the vessel is
(A) (2AH / ag) (B) (2A2H / a2g) (C) (A2H / 2a2g) (D) (AH / 2ag)
15. A horizontal pipeline carries water in a streamline flow. At a point along the tube where
the CSA is 10–2 m2, the water speed is 2 ms–1 and pressure is 8000 Pa. The water
pressure at another point where the CSA is 0.5 × 10–2 m2 is
(A) 4000 Pa (B) 1000 Pa (C) 2000 Pa (D) 3000 Pa
16. (D) h = 2S / gr, WST = S · 2r · h = 4S2 / g. PEinc = mg · hcm = (r2h) g · ½ h
= 2S2 / g. H = WST – PEinc = 2S2 / g or n = 4.
17. A rain drop starts falling from a height of 2H (negligible compared to earth radius) and
acquires terminal velocity by the time it reaches the ground. In the upper half and the
lower half journey of the drop, the ratio of the work done by gravitational forces is n : 1
while the ratio of the time of fall is k : 1.
(A) n = 1, k > 1 (B) n = 1, k < 1 (C) n > 1, k = 1 (D) n < 1, k = 1
PRERNA CLASSES
17. (A) Wmg = (mgh / 2) in both halves, so n = 1. Time of fall lesser as speed increases in
lower half, so k > 1.
18. A bimetallic strip made of two identical dimensions copper & brass strips (with coefficients
of linear expansion c & b) is heated. The temperature rises by T and the strip forms
an arc of radius R. Then R is proportional to
(A) | b – c |–1 T (B) | b – c |–1 T–1 (C) | b – c | T (D) | b – c | T–1
19. The temperature of a hot liquid in a container of negligible heat capacity falls at the rate
of 3 oC min–1 just before it begins to solidify. The temperature then remains constant for
30 minutes by which time the liquid has all solidified. The ratio of specific latent heat of
fusion to the specific heat capacity of the liquid (in oC) is
(A) 90 (B) 10 (C) 1 (D) 0.1
20. One end of a uniform rod of length L is in boiling water while its other end is in melting
ice. A point P on the rod is maintained at a constant 800 ºC. The mass rate of steam
production equals the mass rate of ice melting. If specific latent heat of steam is 7 times
the specific latent heat of ice, the distance of P from the steam chamber must be
(A) L / 7 (B) L / 9 (C) L / 10 (D) L / 12
23. A rectangular surface of area 8 cm × 4 cm of a black body at 127 °C emits energy at rate
P. If the length and width of the surface are each halved and the temperature made
327 °C, the rate of energy emission will become
(A) 3P / 8 (B) 81P / 16 (C) 9P / 16 (D) 81P / 64
24. The sun radiates thermal radiation with maximum intensity at wavelength 0.50 µm. If the
sun cools down to a temperature where it emits only 81% of its present power, the
maximum intensity will then be emitted at wavelength
(A) 0.45 µm (B) 0.47 µm (C) 0.53 µm (D) 0.56 µm
24. (C) As m T–1 and P T4, 2 = (100 / 81)¼ · 0.50 µm (3.162 / 3) · 0.50 µm
= 0.527 µm.
25. Hydrogen molecules at 200 K have the same rms speed as oxygen molecules at
(A) 527 oC (B) 1327 oC (C) 2127 oC (D) 2927 oC
Me
D H
26. H
E2
Product . The predominant product is
H I
Me Me Me
Br H
H H
H Br
H Br
27.
Br H
I II
CH3 CH3
II. CH3CH2Cl + CH3 C O CH3 C OCH2CH3
CH3 CH3
OH OH
(A) CH3 CH CH CH2 (B) CH3 CH CH CH
Cl OCH3 Cl OCH3
OH O
(C) CH3 CH CH CH2 (D) CH3 CH CHCH2OCH3
OCH3 OCH3
PRERNA CLASSES
O O
29. (D)
CH3 CH CH CH2 OCH3 CH3 CH CH CH2
Cl Cl OCH3
O
CH3 CH CH CH2
OCH3
Best L.G.
30. (A) Br
CH2 NH2
CH2 NH3
EtOH
Br
Br
+
NaOMe + +
31. (D) CH2 Cl
MeOHSN1
CH2 CH2 CH2
O O O O
OMe OMe OMe
H OMe
H
CH2 O CH2
CH2 O O
PRERNA CLASSES
O
Me
Tauto Tauto
OMe
OMe
MeO CH3
O CH3 O
OMe
OMe OMe
O
(A) (B)
O O O
OMe
OH
HO
(A) (B) (C) OH (D)
OH
O O H O H
OH OH
33. (B) Ring
H+ expansion
H
HBr
(C) CH3 – S – CH = CH2 (D) O2N – CH = CH2 HBr
CCl4 CCl4
O O
(A) O C (B) O C
O
(C) O C (D) All of these
36. (C) Metamer have different number of C atoms on either side of functional group.
O OH
37. (C)
H Anit aromatic
Stable H unstable
NO2
39. What is the molar solubility of Mn(OH)2 (Ksp = 4.5 × 10–14) in a buffer solution
containing equal amounts of NH4+ and NH3 (Kb = 1.8 × 10–5) ?
(A) 3.0 × 10–5 (B) 1.38 × 10–4 (C) 1.38 × 10–2 (D) 7.3 × 10–6
K sp 10 11
40. (B) [OH ] 10 4
Mg
2
10 3
41. The ratio of excluded volume or non-compressible volume of gas and actual volume of
gas molecule is :
(A) 2 (B) 4 (C) 3 (D) 0.5
PRERNA CLASSES
4
41. (B) Excluded volume for two molecules r 3 .... (i)
3
3
4 r
Volume of one molecule
3 2
r 3
... (ii)
6
From eq. (i) & (ii)
Excluded volume for one molecule = 4 × Volume of one molecule
42. Which of the following gases will have the same rate of effusion under identical condition ?
(i) CO (ii) CO 2 (iii) N2 O (iv) C2H 4 (v) C3H 8
(A) CO, CO2, C2H4 (B) CO2, C2H4, N2O
(C) C3H8, N2O, CO2 (D) CO, N2O, C2H4, C3H8
42. (C) Rate of effusion is directly proportional to the molecular weight of gas. Hence
C3H8, N2O, CO2 have same molecular weight, so they will effuse at the same rate.
45. (A) H + B HB
0.1 0.1 0 Initial
0.08 0.08 0.02 Equibrium
At equilibrium = Kc = 3.125.
46. Bromine is added drop-wise to a 0.01 M solution of SO2. All sulphur dioxide is oxidised
to sulphate (VI). excess of bromine is removed. Then which of the following balanced
reactions represent the redox change ?
(A) 2SO2(aq) + Br2(aq) SO42–(aq) + 2Br–(aq)
(B) SO2(aq) + 2H2O(l) + Br2(aq) SO42–(aq) + 2Br–(aq) + 4H+(aq)
(C) H2O(l) + SO2(aq) + Br2(aq) SO42–(aq) + 2Br–(aq) + 2H+(aq)
(D) 2SO2(aq) + 3Br2(aq) + 4H2O(l) 2SO42–(aq) + 6Br–(aq) + 8H+(aq)
47. 15 mL sample of a solution of 0.04 M Sn2+ and X M Fe2+. Both ions are easily oxidized
by Cr2O72– in acidic solution and the redox products are Sn4+, Fe3+ and Cr3+. If 20 mL
of 0.1250 M Cr2O72– is required for oxidation, what is X ?
(A) 0.80 (B) 0.46 (C) 0.92 (D) 0.60
48. (B) Hydrated AlCl3remains in ionic form and is less soluble in organic solvents while
AlCl3 is covalent.
49. (C) In CO, when an electron is removed, it belongs to 2s orbital hence its bond order
increases to 3.5 whereas in CO, N2 and N2+ bond order is 3.3 and 2.5 respectively.
50. Two elements ‘X' and 'Y' contain only one electron in the outer level. Element 'X' is
reactive and loses electron easily while element 'Y' is relatively unreactive and non-
corrosive. The element 'X' and 'Y' are respectively.
PRERNA CLASSES
50. (C) Alkali metal and coinage elements, both have valence electron one, elements of
same group I ( A and B).
Alkali metals are highly reactive while coinage elements are very less reactive.
= 3n2 + 4n + 1.
55. If (x2 / a2) + (y2 / b2) = 1 (a > b) and x2 – y2 = c2 cut at right angles, then
(A) a2 + b2 = 2c2 (B) b2 – a2 = 2c2 (C) a2 – b2 = 2c2 (D) a2b2 = 2c2
55. (C) mellipse = – b2x / a2y, mhyperbola = x / y. At right angles if mellipse · mhyperbola
= – 1 i.e. x2 / a2 = y2 / b2. From ellipse, x2 = a2 / 2, y2 = b2 / 2 and putting in
hyperbola, a2 – b2 = 2c2.
56. (A) If midpoint (h, k), chord is hx – ky = h2 – k2 which coincides with tangent
x – my = a / m if ah2 / k = h2 – k2 i.e. k3 = h2 (k – a). Thus curve is y3 = x2 (y – a).
57. (C) g1 (258) = 96, g2 (258) = 42, g3 (258) = 24, g4 (258) = 18, g5 (258) = 16.
PRERNA CLASSES
n = 5.
58. If f (x) = 0 for rational x, f (x) = x for irrational x, g(x) = x for rational x, g(x) = 0 for
irrational x; then f – g is
(A) one-one, onto (B) one-one, into
(C) many-one, onto (D) many-one, into
58. (A) h(x) = f (x) – g(x) = – x for rational x, h(x) = x for irrational x.Clearly h is one-one,
onto.
59. Let L1 = Lim x 0 sec–1 (x / sin x) and L2 = Lim x 0 sec–1 (sin x / x).
(A) L1 & L2 both exist (B) L1 exists, L2 does not exist
(C) L1 does not exist, L2 exists (D) L1 & L2 both do not exist
59. (B) For x 0, x / sin x 1 & x > sin x. L1 = sec–1 1+ = 0 while L2 = sec–1 1–
which does not exist.
60. (B) Lim x 0 (tan x – x) / x = 0 while cos (x–1) is a finite quantity for non-zero x.
L = 0.
61. (B) f (1–) = ln 3, f (1+) = – sin 1 i.e. i. is true. f (x) = ln (2 + x) for 0 < x < 1,
f (x) = – sin x for 1 < x < ( / 2). f (x) = 0 is not possible for 0 < x < / 2 i.e.
iv. is true.
62. Let f (x) = x, x 1 and f (x) = x2 + bx + c, x > 1. If f ’(x) exists finitely for all real x, then
PRERNA CLASSES
(A) b = – 1, c = 1 (B) b = 1, c = – 1
(C) b = – 1, c is any real (D) c = 1, b is any real
63. Let f (x) = sin x; g(x) = x2 and h(x) = ln x. If p(x) = h(f (g(x))), then p”(x) =
(A) 2 cosec3 x (B) 2 cot x2 – 4x2 cosec2 x2
(C) 2x cot x2 (D) – cosec2 x
63. (B) p(x) = ln (sin x2), p’(x) = 2x cot x2 and p”(x) = 2 cot x2 – 4x2 cosec2 x2.
64. The derivative of cos–1 ((2 cos x – 3 sin x) / 13) + sin–1 ((2 sin x + 3 cos x) / 13) with
respect to (1 + x2) is
(A) 2 (B) 2 (1 + x2)
(C) (2 / x) (1 + x2) (D) 2x / (1 + x2)
65. If f ’(x) = sin (x / 2) + cos (x / 2), then, at x = 1, (d / dx) (f (x2024)) =
(A) 0 (B) 1012 (C) 2024 (D) – 2024
66. (C) du / dx = 2x sin x2 while dv / dx = 3x2 cos x3. du / dv = (2 / 3x) sin x2 · sec x3.
67. (C) y’ = (2 / cos t) (– ae– t 2 + bet 2) or (1 – x2) (y’)2 = 2 (y2 – 4ab).
(1 – x2) 2y’ y” – 2x (y’)2 = 4yy’ or (1 – x2) y” – xy’ = 2y.
69. The volume of a spherical balloon is increasing at 40 cm3 s–1. The rate of change of its
surface area in cm2 s–1 at the instant its radius is 8 cm, is
(A) 2.5 (B) 5 (C) 10 (D) 20
69. (C) As 40 = dV / dt = 4r2 (dr / dt), dS / dt = 8r (dr / dt) = 40 (2 / r)= 80 / 8 = 10.
73. If x, y, z R such that x2 + y2 + z2 = 1 and w= x2 + 2y2 + 3z2, then w [a, b] where
(a + 3b) =
(A) 11 (B) 10 (C) 8 (D) 7
73. (B) w = 1 + (y2 + 2z2) 1 with least value when y = z = 0. w = 3 – (y2 – 2x2) 3 with
greatest value when x = y = 0. As a = 1, b = 3, a + 3b = 10.
PRERNA CLASSES
74. If | (sin2 x + 2p2)1 / 2 – (2p2 – 1 – cos2 x)1 / 2 | k p, x R; then the minimum value of
k2 is
(A) 1 (B) 2 (C) 3 (D) 5
74. (B) By 2p2 – 1 – cos2 x = t2, sin2 x + 2p2 = t2 + 2. k | (t2 + 2)½ – t | where t 0.
As f (t) = (t2 + 2)½ – t is a decreasing function, f (t) f (0) = 2 for all t.
Thus minimum value of k2 = 2.
75. Let M be maximum and m be minimum value of f (x) = (a – a–1 – x) (4 – 3x2), a > 0. The
least value of (M – m) is
(A) 4 / 9 (B) 8 / 9 (C) 16 / 9 (D) 32 / 9