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Safal 2.0
Amines
1. Hybridisation of nitrogen in amino group is: 8. Primary, secondary and tertiary amines can be
(1) sp (2) dsp2 separated by using:
(3) sp3 (4) None of these (1) Iodoform
(2) Ethyl bromide
(3) Benzene sulphonyl chloride
2. C3H9N represents (4) Tollen's reagent
(1) Primary amine (2) Secondary amine
(3) Tertiary amine (4) All of these 9. For carbylamine reaction, we need hot alcoholic
KOH and:
NaOBr
(1) Any primary amine and chloroform
3. Reaction CH3CONH2   gives : (2) Chloroform and silver powder
(1) CH3Br (2) CH4 (3) A primary amine and an alkyl halide
(4) A monoalkylamine and trichloromethane
(3) CH3OBr (4) CH3NH2
10. A primary amine can be converted to an alcohol by
4. Which among the given amides will give ethylamine the action of
on reaction with sodium hypobromide? (1) Alkali (2) Nitrous acid
(1) Butanamide (2) Propanamide (3) Reducing agent (4) Oxidising agent
(3) Acetamide (4) None of these
11. An organic compound A with molecular formula
C3H5N hydrolysis forms an acid which reduces
5. Which of the following reactions does not yield on Fehling's solution The compound can be
amine? (1) Ethanenitrile (2) Ethyl carbylamine
(1) R  X  NH3   (3) Methoxyethane (4) Propanenitrile

(2) R  CH  NOH   H   NaNO2 /H  Cu 2  CN 2

Na
C3H5OH 12. C6 H5 NH 2   X  

H
(3) R  CN  H 2O  H O/H 
Y 
2
 Z; Z is :
(4) R  CONH2  4 H 
LiAlH4
 (1) C6H5 – NH – CH3
(2) C6H5 – COOH
(3) C6H5 – CH2NH2
6. Which one of the following on reduction with lithium
(4) C6H5 – CH2 – COOH
aluminium hydride yields a secondary amine?
(1) Methyl isocyanide 13. Which of the following compounds will not undergo
(2) Acetamide azo coupling reaction with benzene diazonium
(3) Methyl cyanide chloride?
(4) Nitroethane
(1) Aniline (2) Phenol
7. The correct order of boiling points of the following (3) Anisole (4) Nitrobenzene
isomeric amines is:
ArB2 Cl 
Cu/HCl
C4H9NH2, (C2H5)2NH, C2H5N(CH3)2 14.  ArCl  N2  CuCl
(1) C2H5N(CH3)2 > (C2H5)2NH > C4H9NH2
Above reaction is known as:
(2) (C2H5)2NH > C2H5N(CH3)2 > C4H9NH2
(1) Sandmeyer reaction
(3) C4H9NH2 > (C2H5)2 NH > C2H5N(CH3)2
(2) Gatterman reaction
(4) None of these
(3) Etard chloride
(4) Carbylamine reaction
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18. The correct sequence of reaction to be performed to

15. convert benzene into m-bromoaniline is:
(1) Nitration, reduction, bromination
(2) Bromination, nitration, reduction
The product ‘S’ in the above sequence of reactions is:
(3) Nitration, bromination, reduction
(1) 2, 4, 6-Tribromofluorobenzene (4) Reduction, nitration, bromination
(2) Fluorobenzene
(3) p-Bromofluorobenzene NaNO  HCl CuCN H  /H O
19. C6 H5 NH 2 
2

 A  B 
2
C
(4) Tribromobenzene 273K Boil
The compound ‘C’ in the above reaction is:
16. Azo-dyes are prepared from: (1) C6H5CN (2) C6H5CH3
(3) C6H5COOH (4) C6H5CH2NH2
(1) Aniline (2) Salicylic acid
(3) Benzaldehyde (4) Chlorobenzene 20. Consider the following compounds:
(i) p-Methyl aniline
17. Benzenediazonium chloride reacts with phenol to (ii) N, N-dimethylaniline
give p-hydroxy azobenzene, an orange dye. This (iii) N-ethyl aniline
reaction is known as: (iv) N-ethyl-N-methyl aniline
(1) Coupling reaction The compounds which do not form diazonium salt
(2) Carbylamine reaction with ice-cold NaNO2 and HCl are:
(3) Gattermann reaction (1) (i), (ii) and (iii) (2) (ii), (iii) and (iv)
(4) Hinsberg's reaction (3) (i), (iii) and (iv) (4) (ii) and (iv)
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Answer Key
1. (3) 11. (2)
2. (4) 12. (2)

3. (4) 13. (4)

4. (2) 14. (2)

15. (1)
5. (3)
16. (1)
6. (1)
17. (1)
7. (3)
18. (3)
8. (3)
19. (3)
9. (1)
20. (2)
10. (2)

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