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Exams 3rd Sec الجمهوريه
Exams 3rd Sec الجمهوريه
50 We can obtain an explosive sub- a ethyl hydrogen sulphate / di- reduction of ketone produces
18 c
stance from benzene through the methyl ether / ethene secondary alcohol.
following steps ……… ethylene glycol is dihydric
b ethyl hydrogen sulphate / dieth- 19 c reacts with two moles of
a Alkaline hydrolysis / chlorina- yl ether / ethene
tion / nitration methanol
c ethyl hydrogen sulphate / 20 a ketone, acid & tertiary alcohol
b Nitration / alkaline hydrolysis / ethene / dimethyl ether can’t be oxidized
chlorination
١٢
21 c largest [H+] most acidic
d dimethyl ether /ethyl hydrogen
..لن يخرج عنه االمتحان c Chlorination / alkaline hydroly- sulphate / ethene
(aromatic acid)
alcohol & ether are isomers
sis / nitration
41 لمتعة
The تحولتhydrocarbon
aliphatic معنا المذاكرةderiv- d Chlorination / alkaline hydroly-
22 a (have same general formula
CnH2n+2O)
ative which contains the group 60 Ammonolysis of methyl propa-
الخصوصى الدرس تغنيك عن
(> CH – OH),
trated strong
reacts
الخارجى
mineral
with concen-
والكتاب
acid to pre-
pare asymmetric alkene, so the
روشتة تفوق sis / alkylation
tion / nitration b ethyl hydrogen sulphate / dieth- 69 The molecular mass of each of both carbinol are primary oxi- 64 a
CH3CH2COOCH3+H 2O/H
17 d CH3CH2COOH + CH3OH
yl ether / ethene methanol and oxygen gas equals dized into carboxyl group
b Nitration / alkaline hydrolysis / 32 g/mole Although that, metha- reduction of ketone produces 65 b
propene is asymmetric alkene
c ethyl hydrogen sulphate / 18 c obeys markwnikoff’s rule
chlorination nol is a liquid while oxygen is a secondary alcohol.
ethene / dimethyl ether phenol has acidic character
c Chlorination / alkaline hydroly- gas because…….. ethylene glycol is dihydric 66 a
d dimethyl ether /ethyl hydrogen (can react with KOH)
19 c reacts with two moles of
sis / nitration reacts easily with the indicator
sulphate / ethene a All bonds in methanol are methanol of acidified Cr6+ (can be oxi-
d Chlorination / alkaline hydroly- single while oxygen contains 67 a
20 a ketone, acid & tertiary alcohol dized), primary alcohol can be
sis / alkylation double bond oxidized while others not.
60 Ammonolysis of methyl propa- can’t be oxidized
noate ester gives ….. largest [H+] most acidic 68 a Carboxyl group (acid) is re-
b Methanol contains pi bonds 21 c duced into alcohol (-OH)
51 A and B are from the hydroxyl or- (aromatic acid)
a CH3CH2CONH2 + CH3OH while all bonds in oxygen are alcohol & ether are isomers 69 d methanol can form hydrogen
ganic compounds. 22 a bond while oxygen can’t.
sigma bonds (have same general formula
- Which of the following sentenc- b CH3CONH2 + CH3CH2OH CnH2n+2O) presence of benzene ring in-
c Methanol contains methyl 70 c
es is correct? ………. creases acidic character.
c CH3CH2COOH + CH3OH group which able to form hy- (a) violet, (b) forming ester , (c)
23 d reduction of carbonyl group (C=O)
OH OH d CH3COOH + CH3CH2OH drogen bonds effervesce & (d) no reaction of fructose & reduction of formyl
71 d
C2H5ONa +H 2O C2H5OH group (-CHO) of glucose.
d Methanol contains hydroxyl 24 b CH 3COOH
CH3COOC2H5 All of them benzoate ester ex-
61 Both of phenol and methanol are group which able to form hy- 72 a
CH3-CBr(CH3)-CH3 alkaline hydrolysis cept (a) phenyl ethanoate.
A B similar in reacting with ……….. drogen bonds 25 d
CH3-C(CH3)(OH)-CH3
Reacts
More Easy with red
Change a zinc methyl & ethyl alcohol form
Choice acidity oxidation bromine FeCl3 into 26 b primary
violet
in UV b sodium hydroxide first member of alkene is
a 27 d
A A A A c potassium C2H4 ,alkyne is C2H2 – ester
HCOOCH3
b B B B B
d hydrogen chloride hydrolysis of methyl benzoate
28 c in acidic medium forms benzoic
22 The general formula for a com-
pound RCH2OH is similar to the
general formula for a compound
……….
a R–O–R b R – O – Ar
١٣
..لن يخرج عنه االمتحان c Ar – O – Ar :إشراف d Ar – OH
b
primary alcohol
secondary alcohol
شحاتة
d
أشرف الشناوى سامى
carbonic acid
hol. b
c
formic acid with methyl alcohol
c (A) is 2 – Bromopropane, (B) Iso- acetic acid with ethyl alcohol
a methyl b ethyl
propyl alcohol, (C) is Acetone c aldehyde d formic acid with ethyl alcohol
d (A) is Ethyl chloride, (B) is ethyl 17 Complete oxidation of ethylene c propyl d butyl
alcohol, (C) is Acetic acid d ketone glycol gives ……… 35 Formic acid can be obtained from
27 Which group of the following com- acetic acid by ………
a 2-hydroxyacetic acid
2 The pair of the following from 10 Methanol can be obtained from pounds its first member starts by a Neutralization / dry distillation /
which its first member starts by ethanol by …………
b ethanal two carbon atoms? ……… rapid quenching / hydration
three carbon atoms is ………….. a Dehydration / hydrogenation /
b Neutralization / dry distillation /
halogenation / alkaline hydrolysis c ethanoic acid a Alkenes – Alkynes – Cycloalkanes
a aldehydes / ketones halogenation /alkaline hydroly-
b Dehydration / addition of HBr /
d oxalic acid b Alkenes – Ketones – Esters c Neutralization / dry distillation /
b esters / ketones alkaline hydrolysis
rapid quenching / alkaline hy-
c ketones / cycloalkanes c Oxidation / neutralization / dry
18 What happens on adding one c Alkynes – Esters – Aldehydes drolysis / oxidation
d cycloalkanes / esters distillation / rapid quenching mole of hydrogen to one mole of
d Oxidation / neutralization / dry
d Neutralization / dry distillation /
ketone?… d Alkenes – Alkynes – Esters
halogenation / alkaline hydroly-
3 A, B and C are 3 compounds: on distillation / halogenation / alka-
a No reaction happens
sis / oxidation
adding (A) to the compound (C) line hydrolysis
28 Sodium benzoate can be obtained
a food flavor is produced, and on
b Reacts forming primary alcohol by all the following methods ex- 36 Primary alcohol its molar mass is
adding sodium hydroxide to (B) 11 What is the structural formula of cept……….. 60 g/mole is oxidized into ………..
or (C) a reaction occurs while on the organic compound (X) which c Reacts forming secondary alcohol while its isomer is oxidized into
adding it to (A) no reaction oc- is produced from the following a Acidity test for benzoic acid by
…….(C=12,O=16,H=1)
curs, then the three compounds reaction : d Reacts forming tertiary alcohol sodium bicarbonate
o a propanoic acid – acetone
are ………… 140 C b Neutralization of benzoic acid
CH3CH2OSO3H + CH3CH2OH X + H2SO4
by caustic soda b propanal – acetaldehyde
a A: acid, B: alcohol, C: phenol 19 The opposite structure is pro-
c c ethanoic acid – propanone
a CH3CH2OH duced at 140oC from a reaction of hydrolysis of methyl benzoate
b A: alcohol, B: phenol, C: acid in acidic medium d acetic acid - acetamide
b CH2CH2 ………..
c A: phenol, B: alcohol, C : acid H d Alkaline hydrolysis of methyl
c CH3CH2OCH2CH3 H C O CH3 benzoate in presence of sodi-
d A: acid, B: phenol, C: alcohol 37 Which of the following is pro-
um hydroxide duced on performing the follow-
d CH3CH2CH2CH2OH H C O CH3
ing processes on sucrose with
H 29 What is the product of reacting
4 Primary alcohol can be obtained hydrogen chloride with the ther- the following arrangement :
12 What happens on heating chro- ( acidic hydrolysis – fermenta-
from secondary alcohol by …….. mic acid with methanol in water a 4 molecules of methanol mometric substance which used
in cold areas? …….. tion – dehydration – hydrogena-
a Dehydration / catalytic hydration bath?...... b 2 molecules of ethanol
tion)? ……
b Dehydration / addition of HBr / a The color of the solution con- c 1 molecule of ethylene glycol a Chlorine gas a Ethene b Ethane
alkaline hydrolysis verted into orange and metha- with 2 molecules of methanol
c Dehydration / halogenation / al- noic acid is formed b Ethanol c d Methane
d 2 molecules of ethylene glycol Ethyne
kaline hydrolysis b The color of the solution con-
c Ethyl chloride
d Dehydration / hydrogenation / ha- verted into green and metha-
logenation / alkaline hydrolysis noic acid is formed 20 Acidified potassium perman- 38 On adding hydrogen bromide
ganate is used to differentiate d Methyl chloride HBr to propene then hydrolyze
c The color of the solution con- between all the following ex- the product in alkaline medium
5 Iron III chloride solution with faint verted into orange and metha- cept…………. …… gives the same product of …….. of
yellow color is added to each of : nal is formed a 1 – propanol / 2 – propanol 30 If B is benzoic acid so, A will be propene.
OH OH d The color of the solution con- …………… acid.
verted into green and metha-
b 1 – butanol / 2 – methyl – 2 – a oxidation b halogenation
Acid basicity