SR MPC(CIO&CAO) Date: 24-01-2023

Time: 3 Hrs GTM-20 Max. Marks: 300

24.01.23_SR MPC(CIO& CAO) _JEE MAIN MODEL _GTM-20_QP _AN_FINAL

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.

1. Time for 20 oscillations of a pendulum in three attempts are measured as t1  39.6s ,

t2  39.9s and t3  39.5s respectively. Then the accuracy of the measurement is
1)  0.1s 2)  0.2s 3)  0.3s 4)  0.5s

2. Two solid hemispheres of radii R and R/2 with centers O and O' respectively as shown in
figure. The density of bigger hemisphere is ρ and that of smaller hemisphere is 2ρ .
Taking center of bigger hemisphere is at origin and the distance between centers of two
hemispheres OO' is R/10 find co-ordinates of center of mass of the system.
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O'
R
O
X
R/2 R
O O'=
10

  R 21R    R 21R   R 7R    R 7R 
1)  ,  2)  ,  3)  ,  4)  , 
 50 80   30 80   50 16   30 16 
3. The figure shows the variations of potential energy of a particle as a function of x . The
x  coordinate of the region in the figure.. It has been assumed that potential energy
depends on x . For all other values of x , U is zero. i.e., for x  10 and x >15;U=0

If total mechanical energy of the particle is 25 J, then it can be found in region.

1) 10  x  5 and 6  x  15 2) 10  x  0 and 6  x  10
3) 5  x  6 4) 10  x  10

4. A uniform thin rod of mass m and length R is placed normally on surface of earth as
shown. The mass of earth is M and its radius is R. Then the magnitude of gravitational
force exerted by earth on the rod is

GMm GMm 4GMm GMm

1) 2) 2 3) 2 4)
2R 2
4R 9R 8R 2
5. The rate of flow of a liquid through a capillary tube of radius r is V when the pressure
difference across the two ends of the capillary is P. If pressure difference is increased by
3P and radius r is reduced to r/2, then the rate of flow becomes

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1) V/8 2) V/4 3) V/2 4) V/9

6. 3 moles of an ideal gas with constant volume heat capacity CV undergo an isobaric
expansion by certain volume. The ratio of the work done in the process to heat supplied
is
4R 3R 4R 3R
1) 2) 3) 4)
CV  3R CV  4R CV  4 R CV  3R
7. A sealed cubical container with volume ‘V’ contains 20 particles each of mass ‘m’ and
having various speeds. Two particles have speed ‘v’, three particles have speed 2v, five
particles have speed 3v, four particles have speed 4v, three particles have speed 5v, two
particles have speed 6v and one has speed 7v. Pressure exerted by these particles on the
walls of container is ‘P’. Then ‘PV’ is nearly
2
8 2 2 2
1) 106 mv 2) mv 3) 51mv 4) 20 mv
3
8. When infrared-rays falls on substance it gets heated up because.
1. The rays vibrates only electrons in the substance
2. The rays vibrates only atoms in the substance
3. The rays vibrates not only electrons but also atoms (or) molecules of the substance.
4. The rays vibrates only the nuclei of atoms.
9. A particle of mass M at rest decays into two particles of masses m1 and m2 having
nonzero velocities. The ratio of the de Broglie wavelengths of the particle 1 / 2 is
1) m1 / m2 2) m2 / m1 3) 1 4) m2 / m2
10. Choose the correct graph representing the variation of intensity with wavelength of
X-rays coming from a Coolidge’s X-ray tube

1) 2)

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3) 4)

11. A potential barrier V volts exists across a P – N junction. The thickness of the depletion
region is ‘d’. An electron with velocity ‘ v ’ approaches P – N junction from N – side.
The velocity of the electron immediately after crossing the junction is
2Ve 2Ve 2Ve
1) v 2  2) v2  3) v 4)
m m m
12. Two large black plane surfaces are maintained at constant temperatures T1 and T2
(T1> T2). Two thin black plates are placed between the two surfaces and in parallel to
these. After some time, steady conditions are obtained. By what factor   is the steady
heat flow reduced due to the presence of black plates ?

1 1 1
1)   2)   3)   1 4)  
2 3 4
13. A thin metallic spherical shell contains a charge Q on its surface. A point charge q1 is
placed at the center of the shell, and another chargeq2 is placed outside the shell. All
the three charges are positive. Then the force on charge q1 is

1) Toward right 2) Toward left 3) Zero 4) None of these

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Q
14. Let   r   r be the charge density distribution for a solid sphere of radius R and
 R4
charge Q. For a point p inside the sphere at distance r1 from the centre of the sphere, the
magnitude of electric field is
Q Q r1 2 Qr12
1) 0 2) 3) 4)
4   0 r12 4  0 R 4 3 0 R 4
15. Three uncharged capacitors of capacities C1 , C2 and C3 are connected as shown in the
figure to one another and the points A, B and C are at potentials V1 ,V2 and V3
respectively. Then the potential at O will be

V1C1  V2C2  V3C3 V  V2  V3 V1 V2  V3  VV

1 2V3
1) 2) 3) 4)
C1  C2  C3 C1  C2  C3 C1  C2  C3  C1C2 C3
16. A charged particle of specific charge (charge / mass)  is released from origin at time
 
t  0 with velocity v  v0 i  j in uniform magnetic field B  B0 i . Coordinates of the
 

particle at time t  are
B0
 v0 2v0 v0   v0   2v0 v0   v0 2v0 
1)  , ,  2)  ,0,0  3)  0, ,  4)  ,0, 
 2 B0  B0 B0   2 B0   B0 2 B0   B0 B0 
17. A short bar magnet placed in a horizontal plane has its axis aligned along the magnetic
north-south direction. Null points are found on the axis of the magnet at 14 cm from the
centre of the magnet. The earth’s magnetic field at the place is 0.36 G and the angle of
dip is zero. What is the total magnetic field on the normal bisector of the magnet at the
same distance as the null-point (i.e.14 cm) from the centre of the magnet?
(At null points, field due to a magnet is equal and opposite to the horizontal component
of earth’s magnetic field)
1) 0.54G 2) 0.8G 3) 0.64G 4) 0.74G

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18. Two concentric circular coils, one of small radius r1 and the other of large radius r2 ,
such that r1  r2 , are placed co-axially with centres coinciding. Obtain the mutual
inductance of the arrangement.
 0  r2  0  r1 2  0 r 2
 0  r1 2
1) 2) 3) 4)
2 r2 2 r2 2 r2 r2
19. In the circuit given in the figure, VC  50V and R  50 . The values of C and VR are

1) 3.3 mF , 60 V 2) 10 4  F , 98 V 3) 52  F , 9 8 V 4) 2  F , 60 V
20. The objective of a telescope has a focal length of 100cm. When the final image is
formed at the least distance of distinct vision (25 cm), the distance between the lenses is
105 cm, then
(a) The focal length of the eyepiece is 6.25 cm. and
(b) The magnifying power of the telescope is 20.
1) Only statement (a) is correct.
2) Only statement (b) is correct.
3) Both the statements (a) and (b) are correct.
4) Both the statements (a) and (b) are wrong.

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. A point moves in a circular path with a constant angular acceleration of 2 rad s-1 starting
1
form rest. After s , the angle between the velocity and acceleration of the point will be
2
1
tan 1 . Then find value of ‘n’
n

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22. In figure if   0.1 is the coefficient of friction between the wedge and the horizontal
surface, then for what maximum value of m (in kg), the wedge remains at rest
[Take M = 18kg and   450 ]

23. Two particles P1 and P2 of equal masses situated at (0, 0) and (10, 0) respectively at t = 0
moving with constant velocities moving in opposite direction collided head on at point
(4, 0) after time t0 . If the coefficient of restitution is 1. Then what is the x-co-ordinate of
centre of mass of the two particles at t = 2 t0 .
24. A uniform solid sphere of radius R is placed on a rough horizontal surface and given a
linear velocity v0 and an angular velocity ω0 as shown. If the angular velocity and the
linear velocity both become zero simultaneously, then xv 0  2ω 0 R , then x is_____.

25. A block of wood of relative density 0.5 is placed 10 m inside a vessel containing water.
The vessel is accelerated upward with an acceleration of 10m /s 2 . If the block is
released at some instant then the time (in sec) taken by the block to reach the surface of
water from that instant is (consider g  10m /s 2 )

26. There is no friction between surface and block. If system is slightly displaced and
released, it executes S.H.M., spring constant of the spring is K and co-efficient of
friction between the blocks is  . Maximum amplitude of oscillation so that upper block
 mg
does not slip on the lower block is  th en  is
K

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2m

5m

27. The carrier frequency of a transmitter is provided by a tank circuit of a coil of inductance

50  H and a capacitance of 202 nF. It is modulated by an audio signal of 12 kHz. The


upper side band frequency (in kHz) is nearly _____

28. A battery of emf 10V and internal resistance 3 is connected to a resistor. If the current
in the circuit is 0.5A, what is the resistance (in ohms) of the resistor?
29. A parallel beam of monochromatic light of wavelength 450nm passes through a long slit
of width 0.2mm. The angular divergence in which most of the light is diffracted, is
1.5  P  10 3 rad , then the value of ‘P’ is

30. A SONAR system fixed in a submarine at rest operates at a frequency 40.0 kHz. An
enemy submarine moves towards the SONAR with a speed of 360 km h–1. Then the
frequency received by stationary submarine approximately is (In kHz) (Take the speed
of sound in water to be 1450 ms–1).

CHEMISTRY MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. NO2 gas is obtained by heating
1) NH4NO2 2) NH4NO3 3) LiNO3 4) NaNO3
32. Last line of the Lyman series of H-atom has frequency v1 , last line of Lyman series of

He ion has frequency v2 and 1st line of Lyman series of He ion has frequency v3 , then
1) 4v1  v2  v3 2) v1  4v2  v3 3) v2  v3  v1 4) v2  v1  v3

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33. 25ml solution containing mixture of Na2CO3 and NaOH required 20 ml of 1N HCl for
the end point using phenolphthalein. In a separate titration, 25 ml of the same mixture
required 25ml of same HCl for methyl orange end point. Ratio of moles of Na2CO3 and
NaOH taken in initial mixture
1) 1 : 1 2) 1 : 2 3) 2 : 1 4) 1 : 3
34. Which one of the following species is planar and non-polar with two lone pairs of
electrons on the central atom?
1) ClF3 2) XeF5 3) PCl5 4) BrF5
35. Match the following
List – I List – II
P) Ni (CO)4 1) Octahedral, paramagnetic
Q) [Ni(CN)4]2- 2) Square planar, diamagnetic
R) [Ni(NH3)6]2+ 3) Tetrahedral, diamagnetic
S) [NiCl4]2- 4) Tetrahedral, paramagnetic
P Q R S P Q R S
(1) 2 1 3 4 (2) 3 2 1 4
(3) 4 3 1 2 (4) 1 3 4 2

36. Relatively strongest oxidizing agent among the following is

1) VO2 2) MnO4 3) Cr2O72 4) VO2
37. The standard electrode potential for the following reaction is +1.33 V. What is potential
at pH=2.0?
Cr2O72 (aq,1M )  14 H  (aq)  6e   2Cr 3 (aq,1M )  7 H 2O(l )
1) +1.82V 2) +1.99 V 3) +1.61 V 4) +1.05V
38. During the preparation of acetanilide from aniline, the addition of excess acetic
anhydride and prolonged heating should be avoided because
1) it is oxidized 2) it is reduced
3) diacetyl derivate is formed 4) triacetyl derivative is formed

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39. When a 20 mL of 0.08 M weak base BOH is titrated with 0.08M HCl, the pH of the
solution at the end point is 5. What will be the pOH if 10 mL of 0.04 M NaOH is added
to the resulting solution?
1) 5.40 2) 5.88 3) 4.92 4) 6.88
40. In the process of extraction of gold, O
Roasted gold ore CN   H2O   X   OH  2

 X   Zn 
 Y   Au ;
 2
1) X   Au  CN  2  , Y   Zn  CN  4 
 4
3) X   Au  CN  2  , Y   Zn  CN  6 
Identify the complexes  X  and Y  .
3 2
2) X   Au  CN  4  , Y   Zn  CN  4 
 2
4) X   Au  CN  4  , Y   Zn  CN  4 

41. Which of the following statement is incorrect?

1) Ionization energy of an element is equal in magnitude but opposite in sign to the
electron gain enthalpy of the cation of that element.
2) ‘F’ has the highest Electronegativity out of all the elements in the long form of
periodic table.
3) In any period, the atomic radius of the noble gas is lowest.
4) The second ionization energy of sulphur is less than that of chlorine.
42. Match List-1 with List-II and select the correct answer using the codes given below the
lists:
List-I List-II
P) Benzene + Toluene 1) formation of azeotropic mixture
Chloroform + non-ideal solution with positive
Q) 2)
acetone(propanone) deviation from Raoult’s law
R) Ethanol + Acetone 3) ideal solution
S) HCl + water 4) Hmix  0

1) P  3, 4; Q 1; R 1; S 1, 2 2) P  3, 4; Q 1; R 1, 2; S 1

3) P 1; Q  3, 4; R 1; S 1,2 4) P 1; Q  3, 4; R 1,2; S 1

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43. True statements for Tyndal effect
1) It is observed when diameter of dispersed particles is not much smaller than wave
length of light used
2) The refractive indices of dispersed phase and dispersion medium differ greatly in
magnitude, it is observed
3) Tyndal effect is more for lyophobic sols generally than lyophillic sols
4) All of these
44. The incorrect statement related to thin layer chromatography is
1) The relative adsorption and separation of each component of the mixture is expressed
in terms of its retardation factor.
2) A type of liquid –liquid chromatography
3) The spots of amino acids are identified by spraying with ninhydrin solution
4) The spots of some colourless compounds are identified by using with Iodine.
45. The correct order of acidic strength of the following is
COOH COOH COOH COOH

NO2
P) Q) R) S)
NO2

NO2

1) P>Q>R>S 2) Q>S>R>P 3) S>Q>R>P 4) Q>R>S>P

Zn / HCl
46. Given that C2 H 5  X  C2 H 6  HX , Here ‘X’ can not be
1) F 2) Cl 3) Br 4) I
47.
OH
OH

OH

This conversion can be carried out by

1) H 2 SO4 /  , NaBH 4 2) NaIO4 , H  /  3) HIO4 , NaBH 4 4) H  / , Zn  Hg  .HCl

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48. Which of the following products will be formed on addition of water to but-1-yne in
acidic medium, in the presence of Hg 2 ions as a catalyst

O O

1) CH 2  CH 2  CH 2  C  H 2) CH 3  CH 2  C  CH 3
O O O

3) CH 3  CH 2  C  OH  CO2 4) CH 3  C  OH  H  C  H

49. The major product of the following reaction is :

1) 2) 3) 4)

50. Among the following which one takes more than 3 minutes time to give red precipitate
on boiling with the mixture CH3COOH   CH3COO 2 Cu ?
1) D-Glucose 2) D-Fructose 3) Maltose 4) both 1&2
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

51. Number of chiral centres in chloramphenicol is/are

52. The sum of the number of  bonds and lone pairs in the final product of the following
reaction is

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53. An organic molecule has 5C = C bonds (heat of hydrogenation for one C = C bond is
28.8k J / mol) and the experimental value for heat of hydrogenation is 99 k J /mol of
compound. The magnitude of resonance energy in k J /mol of compound is
54. Chlorine water on cooling to 00 C deposits greenish yellow crystals of Cl2 . XH 2O .
What is the value of X?
55. How many moles of dilute HNO3 can be reduced by 4 moles of zinc?
56. Under the same reaction conditions initial concentration of 1.386 mol dm 3 of a
substance becomes half in 40 sec and 20 sec through first order and zero order kinetics
k 
respectively. Ratio  0  of the rate constants for first order k1  and zero order k0  of
 k1 
the reaction is
57. Density of vapours of a substance of molar mass 18 gm/mole at 1atm pressure and 500K
100
is 0.36 kgm-3. Compressibility factor for the vapour is Z, then the value of is
Z

Take R  0.082 L atm mole1K 1 

58. The volume (in ml) of 10 volume H2O2 solution that decolourises 200 ml of 1N KMnO4
solution in acidic medium is
59. An element crystalises in FCC lattice having edge length 400 pm. The maximum
diameter in pm which can be placed in interstitial sites without disturbing the structure is

60. Assuming H 0 and S 0 do not change with temperature the boiling point of liquid A (in
K) as per the thermodynamics data given below is
Thermodynamics A (liq) A (gas)
H 0  kJ / mol  -130 -100

S 0 JK 1 mol 1
  100 200
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MATHS Max. Marks : 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3)
and (4) for the answer, out of which ONLY ONE option can be correct.
Marking scheme : +4 for correct answer, 0 if not attempted and -1 if not correct.

tan x x x
  3 
61. The number of distinct real roots of x tan x x  0 in the internal  ,  is
2 2 
x x tan x

1) 1 2) 2 3) 3 4) 
21000
1
62. The lowest integer which is greater than  1  1000  is
 2 

1) 2 2) 4 3) 21000 4) 3

63. If nP  504 and nCr  84 then the value of n  r is

r
1) 9 2) 3 3) 12 4) 15
99
 x 
64. If f  x    x    x   2 
then the value of  f  3   is
n 1  1  nx   

(where  k  and k denote the greatest integers and fractional part functions of k
respectively)
1) 17 2) 73 3) 100 4) 1
45
 15 1

65. The number of irrational terms in the expansion of  4  7 
10 is
 

1) 41 2) 5 3) 45 4) 40
66. The negation of the statement “If I become a teacher, then I will open a school” is
1) I will become a teacher and I will not open a school
2) either I will not become a teacher or I will not open a school
3) neither I will become a teacher nor I will open a school
4) I will not become a teacher or I will open a school

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dy  6 
67. If y  x  is solution of  x  1  xy  1; y  0   1 then y   is equal to
dx  5 
1) 7 2) 3 3) 5 4) –5
68. For two data sets, each of size 5, the variances are given to be 4 and 5 and the
corresponding means are given to be 2 and 4 respectively. The variance of the combined
data set is
5 11 13
1) 2) 3) 6 4)
2 2 2

2
 a  b sin  
69. If a  0, b  0 then the value of  log  a  b sin   d is equal to


2

a  b 
1) 0 2)  log   3) log   4) log  ab 
b 2 a 2

70. If a fair die is thrown three times then the mean of the random variable associated with
number of sixes of the distribution is
5 1 5 1
1) 2) 3) 4)
12 4 28 2
10
1
71. If k is the sum of 5th and 7th terms in the expansion of  x   then the least value of k is
 x

1) 210 2) 2 3) 420 4) 420 2

72. If a tangent to the ellipse 9 x 2  16 y 2  144 meets the tangents at the extremities of its major
axis at P, Q and the circle with PQ as a diameter passes through two fixed points A and
B on the major axis and C is one end of minor axis of the ellipse then area of ABC is

1) 12 sq.units 2) 6 7 sq.units 3) 3 7 sq. units 4) 24 sq. units

 x 2  1
73. If g :  2, 2  R, where f  x   x3  tan x    is an odd function, then the value of
 p 

parameter p, where    denotes G.I.F. is

1) 5  p  5 2) p  5 3) p  5 4) p  5

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74. Let y  f  x  be defined parametrically as y  t 2  t t and x  2t  t , t  R . Then f  x 
1) is discontinuous for two values of x
2) is differentiable at x  0
3) is discontinuous at x  0 4) is non differentiable at x  1
75. If sin 270  p, then the value of 1  sin 36 0 is
p
1) p 2) 3) 1  p 2 4) 2  2 p 2
2
76. The line x  3 y  2  0 bisects the angle between a pair of straight lines of which one has the
equation x  7 y  5  0. The equation of other line is
1) 3x  3 y 1  0 2) x  3 y  2  0 3) 5x  5 y  3  0 4) 5x  3 y  3  0
77. If a and b are two vectors such that a  1, b  4 and a.b  2. when c   2a  b   3b , angle

between b and c is
  3 5
1) 2) 3) 4)
3 6 4 6

78. If the tangent at any point  4m2 ,8m3  of x3  y 2  0 is a normal to the curve x3  y 2  0 then

values of m are
2 1 9 2
1)  2)  3)  4) 
9 3 2 3
79. Height of the cylinder of maximum volume that can be inscribed in a sphere of radius ' a '
is
2a a 2a a
1) 2) 3) 4)
3 3 3 3

8x  4x  2x  1
, x0
80. If f  x    x2 is continuous at x  0, then the value of  is
e x sin x   x    ln 4  , x  0


1) 4 log e2 2) 2 log e2 3) log e2 4) 3log 2e

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The important thing in life is not the triumph but the struggle.
CODE-E
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.

81. The equation of the radical axis of the two circles represented by the equations z  2  3

and z  2  3i  4 on the complex plane is ax  by 1  0 then the value of a  b is

199 n
82. If nC  4.nC  7.nC  10.nC  .....  n  1 terms  602  2  then the value of is equal to
0 1 2 3 4

83. Let a, b, c be three real numbers such that a  b  c  0 and a 2  b2  c2  2 then the value at
a4  b4  c 4 is
3
84. The probability of a shooter hitting a target is . The minimum number of times must he
4
fire so that the probability of hitting the target at least once is more than 0.99 is

85. The slope of tangent at  x, y  to a curve y  f  x  passing through  1,  is given
4  
y y
by  cos 2   then the value of 8  f  e  is equal to
x x
15 th th
86. If in the expansion of 1  x  , the coefficients of  2 r  3  and  r  1 terms are equal,
then the value of r is
   1
87. If sum of all solutions of the equation 8cos x  cos   x  cos   x     1 in 0,   is k
6 
 6  2 

then k is
1 1 1
88. The points A  2  x, 2, 2  , B  2, 2  y, 2  , C  2, 2, 2  z  and D 1,1,1 are coplanar, then   
x y z
x 1 y 1 2  z
89. The lines   and y  x  0  x  z   are coplanar for  
2 3 1

 a b 
90. If the vectors a , b , c satisfy the condition a  c  b  c then  b  a  .  c  
 2 

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The important thing in life is not the triumph but the struggle.