19.01.23 SR - Star Co-Sc (Model-A&b) Jee Main Gtm-12 Key & Sol

Sec: SR.
IIT_*CO-SC(MODEL-A&B) GTM-12 Date: 19-01-23

Time: 3 HRS JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 4 2 2 3 4 4 4 5 3
6 3 7 3 8 3 9 1 10 2
11 3 12 3 13 3 14 3 15 4
16 4 17 3 18 1 19 2 20 4
21 392 22 8 23 30 24 750 25 2
26 14 27 1 28 400 29 15 30 5
CHEMISTRY
31 1 32 1 33 1 34 3 35 2
36 2 37 3 38 4 39 1 40 2
41 4 42 3 43 2 44 4 45 1
46 2 47 4 48 1 49 1 50 3
51 25 52 87 53 2 54 2 55 2
56 22 57 5 58 8 59 3 60 3
MATHEMATICS
61 4 62 2 63 3 64 4 65 2
66 1 67 3 68 4 69 1 70 2
71 4 72 1 73 2 74 2 75 4
76 2 77 3 78 2 79 1 80 4
81 57 82 17 83 13 84 99 85 9
86 12 87 5 88 6 89 56 90 104
Narayana IIT Academy 19-01-23_SR.IIT_*CO-SC(MODEL-A&B)_JEE-MAIN_GTM-12_KEY&SOL
SOLUTIONS
PHYSICS
1.       sin    Dimensionless
 1 sin       D.L.
 

2. r  3tiˆ  5t 3 ˆj  7 k

d2r
 30t ˆj
dt 2

d2r
At t  1   30 ˆj
dt 2
3. F   a 2  103  10  104  20  20
F  400
4.
a
 m2  m1  g
 m2  m1 
g

   L  l   l  g
L 
L L
2 L 4 x
x4
5. Using mv  2 mk
1
u 2  0.2  90  30 m / s
0.2
1
v 2  0.2  40  20 m / s
0.2
20  30
a  10 m / s 2
1
u 2
s  45 m
2a
1 1
6. t and g 
g  R  h 2
t1 g R2
 
t2 g  R  h 2
t1 4 R
   h  3200 km
t2 6  R  h 
SR.IIT_*CO-SC Page NO: 2

1
7. Apply Bernoulli’s theorem between Piston and hole PA   gh  P0   ve2
2
Assuming there is no atmospheric pressure on piston
5  105 1
 103  10  10  1.01  105   103  ve2
 2
ve  17.8 m / s
8. vrms  T
vrms  300 K , vrms f  2vrmsi
14 1
T f  1200 K , Ti  300 K , n  
28 2
1 5R
Q  nCv T    900
2 2
Q  9360 J
9.
3d d
x y  d  x y 
4 4
A 0
 C0
d
E 3d 3Ed
V  Ex    Ey   E  x  y
k 4 4k
 3d d 
V  E   
 4k 4 
  3d  dk  Qd  3  k 
V  
0  4k  A 0  4k 
Q A 0  4k  4kC0
C  
V d  3  k  k  3
10.
 8m 
e 
Fy e  E 
 
e 
ay    8m / s 2
m m m
sx  u xt
1 2  t

1
t  sec
2
1
v y  u y  a yt  vy  0  8 
2
vy  4 m / s
vy 4
tan    2    tan 1  2 

vx 2
11. Statement 1 - R  80 
R1  R2  R3  R4  20 
20
In parallel Req   5
4
Statement 2
v2
Pth 
R
P1  R2  2
    (where P is power)
P2  R1  3
12. FM  CD   BIleff
 
 0.5  10   5sin 60  102  0.216 N
13.
0 I
B1 
2R
0 IR 2 1  I  B B 8
B2    0  1  1 

2 R 2  3R 
2 3/2 8  2R  8 B2 1
14.
8  10  3 2
 80  103
Rp
R p  800 
160 2  80  103  RS  0.32 
Rs

I
15.  area  force
C
I
 36  104  7.2  109
C
7.2  109  3  108 6  101
I 
36  109  10 103
6  101 W w
I 3
 I  6  102 2  0.06 2
10 m cm
  1 1 
16. P  2   1  2     (For this formula refer to NCERT Part-2, Chapter-9, Page no.328,
f  R1 R2 
solved example 8)
( 1 is refractive index of lens and 2 is of surrounding medium)
 1 1 
1.25  1.5  2    
 0.2 0.4 
1.25  0.08 4
 1.5  2   2 
0.6 3
1 2 1 2
17. mv1  4  mv2  9
2 2
v1 2

v2 3
1
18. Remaining 
8
3t1/2  15 min
t1/2  5 min
Vout R
19.   out
Vin Rin
100  10  103
Vout  3
 103  1 V
10
20. Given
FM broadcast
Modulating frequency = 20 k Hz = f
frequency deviation f
Deviation ratio= 
modulating frequency f
 frequency deviation f  f  10
 20 kHz  10  200 kHz
 Bandwidth  2  f  f 
 2  20  200  kHz  440 kHz
u 19.6
21. ta    2s
g 9.8
2hmax
tda  16  2 s 
g
16  9.8 392
 hmax  
2 5

22.
 x2 
dm   .dx  0 1  2 
  

 x3 
0   x  2  dx   
2 4
X cm 
 x dm  0     2 42  3

 dm 0  1  x2  dx    2 8
2 3
0
  3
23.
Strain = F/AY
2  5
2
mv 2
mg  20 
 R 
6
0.5  30  105
AY 3  10  10 11
24. W  nRT  150 J

 f  8 
Q   1 nr T    1150  750 J
2  2 
25. U  4 1  cos 4 x 
dU
F   4   sin 4 x  4  16sin  4 x 
dx
For small 
sin  
F  64 x
a  64 x / m  16 x
 2  16
2 
T 
 2
2
V 2202 V 2 2202  10 
26. R1    484 , R2    480  
P 100 P 60  6
220
I
10
484  484 
6
P1  I R1  14.06 W
2
27. Just after closing the switch S, inductor behaves like an open circuit.
6
I  1A
24

28. After 10 sec.
u = –80 cm
f = –100 cm
1 1 1
 
v u f
v  400 cm
29. vu  f 2 (by Newton’s formula)
f 2  225  f = 15 cm
 1 T2
30. t  2 g 2
g 4 
g 2T  g 1 1 mm
    2. 
g T  g 100  0.5 10 cm
g 5

g 100
CHEMISTRY
31.
32. Across a period metallic character decreases

33. G   H  T  S
 Entropy of liquid is more than solid
 on melting the entropy increases and G becomes more negative and hence it becomes easier to
reduce metal
34. In Clark’s method lime water is used
Ca  HCO3 2  2Ca  OH 2  2CaCO3  2 H 2O
Mg  HCO3 2  2Ca  OH 2  2CaCO3  Mg  OH 2  2 H 2O
35. Alloy of Li and Mg is used to make armour plates and not aircraft plates.
Calcium plays important roles in neuromuscular function, interneuronal transmission and cell
membrane integrity
36. P4  8 SOCl2  4 PCl3  4SO2  2S2Cl2
37. I 2  10 HNO3 conc   2 HIO3  10 NO2  4 H 2O
Sm 2  electron  60 

Eu 3  electron  60 
38.  (not isoelectronic)
Tb 2  electron  63 

Tm 4  electron  65 
39. 2 KMnO4  16 HCl  2MnCl2  2 KCl  8H 2O  Cl2
HCl gets oxidised by KMnO4 into Cl2

40. Ni  CO 4 Hybridisation sp 3
2
 Ni  CN 4  Hybridisation dsp 2
3
Co  CN   Hybridisation d 2 sp 3
 6
3
Co  F   Hybridisation sp 3d 2
 6
1483 2000 K 
41. 
N 2  O2  2 NO
(Endothermic and feasible at high temperature)
42.
CH3
CH3
Br NO2
CH3 CH3 CH3

43. A) , B) , C) , D) , E)
 NO2 is strongly deactivating
–Br – deactivating
CH 3 –activating group
D<B<E<A<C
O OH

Conc.HI
 
Zn



44.
45.
NH2 NH2 NH2
NH2 NO2
 

HNO
3
H SO
2 4 + +
NO2
NO2
2% 47% 51%
Due to formation of anilinium ion in acidic medium meta product is also obtained in significant
amount
46. Neoprene is elastomer
Nylon-6, 6 is fiber
PVC is thermoplastic
Novolac is thermosetting
47. Some drugs do not bind to active sites. These bind to different site of enzyme called allosteric sites.
48 Theory based
Thin layer chromoatography (TLC) is another type of adsorption chromatography, which involve
sepration of substance of a mixture ovel a thin layer of an adsorbent coated on glass plate. A thin layer
(about 0.2 mm thick) of an adsorbent (silica gel) or (Alumina) in spread overa glass plate of suitable
size. Hence Assertion (A) is correct and Reason (R) is correct explanation of (A)
49.
50.
51. H 2 SO4  2 NaOH  Na2 SO4  2 H 2O

0.4 mol 0.2 mol -
0.3 mol - 0.1 mol
0.1
Molarity of Na2 SO4 is  0.025 M
4
52. a  4  108 cm , d  9.03g / ml
ZM
d
N Aa3
9.03  6.02  10 23  64  10 24
M  86.97
4
53.
h

2mK
h2
K
2m 2
h2 43.9  1068
K 
2m 2 2  9.1  1031  10.89  1020
K  2.215  1018
Eabs  Ereq  K
Eabs K 2.215  1018
 1  1  2.0166
Ereq Ereq 13.6  1.602  1019

54. YA  0.5  YB  0.5
PA  PA0 X A
PA0  2
55. 2 NO  O2  2 NO
2 1 -
2-2x 1-x 2x
1.2 0.6 0.8
2
 0.8 
 
Kp   2.6   1.925
2
 1.2   0.6 
   
 2.6   2.6 
56. V  22.78 ml , T  280 K
Ptotal  759 mm Hg
PN 2  759  14.2  744.8 mm Hg
744.8  22.78
nN 2   0.00097
760  1000  0.082  280
WNitrogen  0.02716
0.02716
%N   1000  21.728
0.125
57. IO4  H 2O2  IO3  O2
58. K  Ae Ea / RT
 Ea
ln k   ln A
RT
Ea 20
Slope  
R 5
Ea  4 R  8 Cal / mol
1
X
59.  KP n
m
x 1
log  log p  log k
m n
60. Internal energy, volume enthalpy are state variable

MATHS
61. S  T  5, 4,3

1 1
62. a  2
2 2
1 1 1
b  2  2 1 2 2
   
1 1 5
ab  1  1  
  6 6
 5   5
x2     2  x   2    1
 6   6
6 x  17 x  7  0
2
7 1
x   , x   are the roots
3 2
Both are real and negative.
63. Given that AT  A, BT   B
    B 
T 4 T
(1) C T  A4  B 4  A4  A4  B 4  C
(2) C  AB  BA
C T   AB  BA    AB    BA   BT AT  AT BT   BA  AB  C
T T T
(3) C  B5  A5
   B   A 
T 5 T 5 T
C T  B 5  A5   B 5  A5
(4) C  AB  BA
C T   AB  BA    AB    BA    BA  AB  C
T T T
 Option C is not true.
64. f  0   3    4  14
 f  0  7    c
f 1  a  b  c  3 …(i)
f  3  9a  3b  c  4 …(ii)
f  2   4a  2b  c   …(iii)
(i) – (iii)
4
ab  put in equation (i)
5
4
7  3
5
6  24 .   4

  sin  x  1
 x  1
 x 1
   sin 2  1 x  1

65. fx   cos 2 x 1  x  1
1 x 1

  sin  x  1
 x 1
 x 1
f  x  is discontinuous at x  1 and x  1
f  x   x e    f   x   e    2 x  1 x  1
x 1 x x 1 x
66.
 1 
f  x  is increasing in   , 1
 2 
67. f  x   tan  sin x  cos x 
1
cos x  sin x
f  x  t 0
 sin x  cos 2  1
3
 x
4
X 0 3 
4
f  x 
 tan 1 2 
4 4
 f  x  max  tan 1 2


 f  x  min   4 

 1 
sum  tan 1 2   cos 1 
4 3 4
68. x  2 2 cos t sin 2t
dx 2 2 cos 3t

dt sin 2t
y  t   2 2 sin t sin 2t
dy 2 2 sin 3t dy
   tan 3t
dt sin 2t dx
dy 
 1 at t 
dx 4
2
d y 3 
2
 sec3 3t. sin 2t  3 at t 
dx 2 2 4
2
 dy 
1  
  dx   1  1   2
d2y 3 3
2
dx

x
dt
69. In  x   
t 
n
0
2
5
Applying integral by parts
x
  x
 
t  n 1
In  x    2   n t2  5
 0
.2t 2
 t 5
   0
x
x t2
In  x    2n  dt
x t  
n n 1
2
5 0
2
5
In  x 
x
 2n 
t x 2
 5  5
dt
 x  5 t  5
2 n 2 n 1
0
x
In  x    2n I n  x   10 n I n1  x 
x 
n
2
5
x
10 n I n1  x   1  2n  I n  x  
x 
n
2
5
Put n  5
70.
Required area is
0 ln 2
  
ln x  e 2
  1dx   2e x
 1 dx  1  e  ln 2
e e2 0
1
dy 1  x 1  2
71.  2 y 
dx x  1  x 1
dy
 Py  Q
dx
1
 x 1  2
I.F.  e 
P dx
 
 x 1
1
1
 x 1  2  x 1 
y     dx
 x 1  x 1
 x  2 log e x  1  C
 1 
Curve passes through  2, 
 3

5
 C  2 log e 3 
3
At x  8 ,
7 y  8   19  6 log e 3
72. Equation of circle passing through  0,  2  and  0, 2  is
 
x2  y 2  4   x  0 ,    R 
Dividing by x we get

x2  y 2  4   0
x
Differentiation with respect to x
 dy 
x  2 x  2 y.    x 2  y 2  4 
 dx 
x2
dy

 2 xy.  x 2  y 2  4  0
dx

73.
C :  x  2  y2  1
2
Equation of chord AB : 2 x  3
3
AM 
2
1
Area of triangle OAB   2 AM  OM 
2
3 3
 sq. units
4
x2 y 2
74. H : 2  2 1
a b
Foci : S  ae, 0  , S   ae, 0 
Foot of directrix of parabola is  ae, 0 
Focus of parabola is  ae, 0 
Now, semi latus rectum of parabola  SS   2ae
 2b 2 
Given, 4ae  e  
 a 
 b 2  2a 2 …(1)

Given, 2 2,  2 2 lies on H 
1 1 1
 2
 2  …(2)
a b 8
From (1) and (2)

 b2  a 2 e2  1 
 e 3
 Equation of parabola is y 2  8 3 x
x 1 y  2 z  3 x  26 y  18 z  28
75. Given, L1 :   and L2 :   are coplanar
 1 2 2 3 
27 20 31
  1 2 0
2 3 
Now, normal plane P, which contains L1 and L2
iˆ ˆj kˆ
 3 1 2
2 3 3
 3iˆ  13 ˆj  11kˆ
 Equation of required plane P :
 0, 4, 5 does not lie on plane P.
76. Normal of plane P :
iˆ ˆj kˆ
 2 1 3  4iˆ  ˆj  3kˆ
1 2 2
Equation of plane P which passes through  2, 2,  2  is 4 x  y  3 z  12  0
Now, A  3, 0, 0  , B  0, 12, 0  , C  0, 0, 4 
   3,   12,   4
 p        13
Now, volume of tetrahedron OABC
1   

V  OA. OB  OC  24
6

 
77. For angle to be acute u . v  0
 a  log e b   12  6a  log e b   0
2
 b 1
Let log e b  t  t  0 as b  1
y  at 2  6at  12 and y  0 ,  t  0
 a 

78.
OP
 tan150  OA  OP cot150
OA
OP
 tan 450  OP  OC
OC
Now, OP  OA2  82
 OP 2   OP  cot 2 150  64
2
 OP 2 
32
3

2 3 
1 P  A  B 1
79. P  A | B   
7 P  B 7
7
 P  B 
9
2 P  A  B 2
P  B | A   
5 P  A 5
5
 P  A 
8
Now, P  A  B   1  P  A  B   P  B 
5
 1  P  A  P  A  B  
6
P  A  B   1 P  A  B
 
1
 1  P  A  P  B   P  A  B  
18
 Both (S1) and (S2) are true.
80. p  Ramesh listens to music
~ q  He is in village
r  s  Saturday or Sunday
p   ~ q    r  s 
2 3
81. 4
C2  , 6 ,  6C3  are in A.P.
6 8
5
 2   3  12
2
12 12
 or   2   
5 5
72 144 504
d   
5 25 25
2d
 50  2  57

82. b
C3  C2  168
8
b  b  1 b  2  g  g  1  8  7  6  3  2
b  3 g  17
83. Ellipse is
x2 y 2
2

4
1, e 
1
2
; S  0 2  
Chord of contact is
x

2 2 2 y
1

2 4

x
 1
2 1 y  
solving with ellipse
2 2
 y  0, 2  x  2, 1
  Q   2, 0
P  1, 2
  SP    SQ   13
2 2
84. 1  1  2  2  1  2
49 49 98
m  1, n  98
m  n  99
x
85. y2  
2
1
y  mx 
8m
This tangent pass through  2, 0 
1
m i.e. one tangent is x  4 y  2  0
4
17 r  9
6  1 2 2 2 23 210 
86.  10 
 11 10    ....  
312 3 3 39 38 3 
6 10  611  1 
  
312 311  6  1 
 212.l ; m.n  12
87. tan   5 tan 2 tan   5  tan 2
tan 3  5
n 
  ; tan   5
3 3
1 z
88. z 2  z .2  z 1
z 2  z  z 3  1  z   or  2
 
n
 n  1      2
n
Least number of n is 6.

89.
 2   X 2 P  X     XP  X   
2 56
100
100  2  56
 sin 6 x  sin 4 x sin 4 x  sin 2 x sin 2 x 

2
90. I  60      dx
0  sin x sin x sin x 

2
I  60   2 cos 5 x  2 cos 3 x  2 cos x  dx
0
 /2
2 2 
I  60  sin 5 x  sin 3 x  2sin x   104
5 3 0



19.01.23 SR - Star Co-Sc (Model-A&b) Jee Main Gtm-12 Key & Sol

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IIT_*CO-SC(MODEL-A&B) GTM-12 Date: 19-01-23

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24. W  nRT  150 J

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32. Across a period metallic character decreases

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CH3 CH3 CH3

51. H 2 SO4  2 NaOH  Na2 SO4  2 H 2O

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60. Internal energy, volume enthalpy are state variable

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61. S  T  5, 4,3

 Option C is not true.

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72. Equation of circle passing through  0,  2  and  0, 2  is

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 sin 6 x  sin 4 x sin 4 x  sin 2 x sin 2 x 

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