E-CAPS: 04A (Chemistry) CF &Second Step for JEE (Main & Advancedi

CF & Second Step for JEE (Main & Advanced) JEEIAdv.)

E-CAPS-04A : CHEMISTRY
(Engineering-Classroom Assessment Practice Sheet)

Topics covered: lntroduction: Three states of maler, Classification of solids: (0) Characteristic properties, (i) Differeno
:
between crystalline and amorphous solids, (i) Classification of crystalline solids; Structure of solids (i) Basic definitions
(ü) Types of unit cels, Seven crystal systems and Bravais lattice, Calculation of effective number of particles in a unit cal
Elements of symmetry in cube :(i) Centre of symmetry. (i) Plane of symmetry. (ii) Axis of symmetry, Close packed structufes
(0) 1-D close packing, (ü) 2-D close packing, (ii) 3-D close packing. (AAA. type packing). ABAB....ype packing

) hexagonal close packing, (i) Cubic close packing and voids, Packing efficiency. Radius ratio in ionic solids :r+/r- in voids
Density, Coordination number

Choose the correct answer : O-A

1. Which of the following statements islare false? -B

(A) It is the anisotropic nature of amorphous solids

that all the bonds are of equal strength
(B) Entropy of a crystaline solid is higher than that
of an amorphous solid
(C) Amorphous solids have sharp melting point Answer the following questions using the above
figure.
(D) Amorphous solids can become crystaline on
slow heating (annealing) 3 particles along one of C3 axis are removed
If all

then resultant particles of B will be

2. and Column-ll contain four entries
Column-
each. Entries of Column-l are to be matched with (A) 3 (B) 4
some entries of Column-Il. One or more than one
(C) 2 (D) 1

entries of Column- may have the matching with

the same entries of Column-ll. 4. If allparticles along one of C2 axis are removed
then formula of compound is
Column Column-I
(A) AB (B) AB
(Bravais Lattice(s)] [Crystal system]
(C) AeBs (D) AzB7
i. Primitive, face centered, (p)Cubic

body centered,
5. The shaded area in the figure represents

end centered (A) Rectangular plane of symmetry

i. Primitive, face centered, (9) Orthorhombic (B) Diagonal plane of symmetry

body centered
(C) No plane of symmetry
ii. Primitive, body centered () Hexagonal
(D) Six fold axis of symmetry
v. Primitive only (s) Tetragonal
metal crystallizes in two cubic phases i.e.,
fcC
(A) i(p), il(s), ilq), iv(c) (B) i(), i(p), ifs), iv(q) 6. A
are 3.5 A and 3.0 A
and bcc whose unit cell lengths
(C) i(9). ikp), i(s), iv(¢) (D) i(s), i(p), i(), iv(a)
respectively. Which are not correct regarding
Uie

Paragraph for Q. (3 to 5) ratio of their densities?

Apart from interfacial angles another important feature (B) 2.04
(A) 3.12
s elements of symmetry. Crystals have plane of
symmetry, axis of symmetry and centre of symmetry. (C) 1.26 (D) 0.72

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CF & Second Step for JEE (Main & Advanced) E-CAPS: 04A (Chemistry)

7 The percentage packing efficiency of the (C) Rhombohedral–CaCO3

two-dimensional arrangement of sphere for plane
ABCDEF shown below is
(D) Tetragonal - CaSO:
11. An element with molar mass 40 g/mol
crystallises
into an unit cell having edge length 4.05 A.
If its

density is 2 g/cm, then nature of unit cell is

(A) SC (B) HCP
(C) BCC (D) FCC
12. Select the correct statement(s) with respect to
classification of crystalline solids
(A) Non-polar molecular solids are soft and non
(A) 90.64% (B) 74.05% conductors of electricity
(C)68.02% (D) 78.54% (B) lonic solids are conductors of electricity in
Solid state as wellas in molten state
Which among the following statements is/are
INCORRECT? (C) Not all the covalent solids are non-conductor
(A) Amorphous solids do not have a regular of electricity
(D) In metallic solids, constituent particles are
crystal system
positive ions in a sea of
(B) Carborundum is an example of molecular
solids delocalised electrons
13. Lithium borohydride crystallizes in ar
(C) Graphite follows triclinic crystal system
orthorhombic system with 4 molecules per unit
(D) Total number of atoms per unit cell in end face
cell. The unit cell dimensions are a = 6.8 À, b= 4.4
centered unit cell is 2
and c =7.2 Å. If the molar mass is 21.76, then
Å

9 Consider the given statements and select the the density of crystals is X g/cm. What is value of
correct option
100X?
Statement :For BCC and FCC unit cell, a is 2/2r
I

14. A crystal is made of particle X, Y and Z. X forms

4r fcc packing, Y occupies all octahedral voids of X
and V3 respectively
and Z occupies all tetrahedral voids of X, if all the
Statement Il : Packing fractiön in HCP is 0.74 particles along one body diagonal are removed
(A) Statement and Il both are true
I
then the formula of the crystal would be of the form
XaYbZo. What is value of a + b+ c? (a, b, c are
(B) Both statements and Ill are false
I

whole numbers)
(C) Statement I is false and statement Il is true
15. A crystal is made of particles A and B. A forms
(D) Statement I is true and statement Il is false
FCC packing and B occupies all the octahedral
10. Column I includes type of void or crystal system
and column Il contains respective examples. The voids. the particles from one of the body
If all

incorrect match among the following is diagonal plane are removed, then the formula of
(A) Cubic void -B203 the crystal would be of ABy. What is the value
(B) Octahedral Void -NaCIht of x + y?

ANSWERS
1. (A, B, C) 2. (C) 3. (A) 4. (C) 5. (B)

(A, B, D) 7. (A) 8. (B, C) 9. (C)

6. 10. (A)

(A, C, D) 13. (67) 14. (17)15.

11. (C)12. (02)

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