HYDROCARBON

Hydrocarbon
1. Match the column :- 4. Match the column :-
Column-I Column-II
Column-I Column-II
(Reactants) (Product)
(a) Aromatic (p)
(a) CaC2 + H2O (p) CaC2
(b) CaO + C (q) H2 (b) Anti aromatic (q)
(c) HC CH + Na (r) CH4
(d) CH3COOH + NaOH (s) C2H2 (c) Non-aromatic (r)
+ CaO
(1) a – q, b – p, c – r, d–s
(2) a – p, b – q, c – s, d–r (s)
(3) a – s, b – p, c – q, d–r
(4) a – p, b – q, c – r, d–s N
H H
2. Match the column :-
Column-I Column-II
(Reaction) (Product)
(1) a – q, b – p, c – r,s
(a) HC CH + H2O → (p) Benzene
(b) HC CH + (q) Ammonia (2) a – p, b – q, c – r,s

Hg 2 /H (3) a – r, b – q, c – p,s
H 2O →
(c) HC CH + NaNH2 → (r) No reaction (4) a – p,s, b – q, c – r
(d) HC CH
Red hot
→ (s) Acetaldehyde
Fe tube 5. Match the column :-
(1) a – q, b – p, c – r, d – s
Column-I Column-II
(2) a – r, b – s, c – q, d – p
(3) a – q, b – p, c – s, d – r (Reaction) (Product)
(4) a – p, b – q, c – r, d – s (a) CH3 (p) CH2–Cl
3. Match the column :-
+Cl2
Column-I Column-II
(Type of (b) (q)
(Reaction) CH3 CH3
reaction)
(a) + Cl2 AlCl3
→ (p) Free radical +Cl2 H3C
addition

(b) + Cl2 (q) Free radical

(c) CH3 (r) CH3
substitution
(excess)
+CH3–Cl Cl

(c) CH4 + Br2

h
→ (r) Electrophilic
addition
(d) + HCl (s) Electrophilic
substitution (1) a – q, b – p, c – r

(1) a – p, b – q, c – s, d – r (2) a – r, b – p, c – q
(2) a – q, b – p, c – s, d – r
(3) a – q, b – r, c – p
(3) a – p, b – q, c – r, d – s
(4) a – s, b – p, c – q, d – r (4) a – p, b – q, c – r
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6. Match the column-I with column-II :- 8. Match the column-I with column-II :-

Column-I Column-II
Column-I Column-II
(a) Lindlar's (p) Na/liq. NH3 (Reaction) (Product)
catalyst
(a) CH4 + O2 (p) (CH3)3C – OH
(b) Birch catalyst (q) H2/Pd-CaCO3
Mo2 O3
∆
→
(c) Baeyer's (r) HBr/(PhCO)2O2
Reagent (b) 2CH3CH3 + 3O2 (q) HCHO + H2O
(d) Kharasch (s) Dil. KMnO4/273K (CH3COO)2 Mn
∆
→
effect
(c) (CH3)3CH (r) CO + 3H2
(1) a – q, b – p, c – r, d – s
KMnO 4
Oxidation
→
(2) a – p, b – q, c – s, d – r
(d) CH4 + H2O (s) 2CH3COOH
(3) a – q, b – p, c – s, d – r
Ni
→ + 2H2O
(4) a – p, b – q, c – r, d – s ∆

(1) a – q, b – p, c – r, d – s
7. Match the column-I with column-II :-

(2) a – r, b – s, c – p, d – r
Column-I Column-II
(Reaction) (Product)
(3) a – q, b – s, c – p, d – r
(a) 2CH3CH2Br (p)
2Na
dry ether
→ (4) a – p, b – q, c – r, d – s
(b) (q) CH3CH2CH2CH3
CH3COO Na 9. Match the column-I with column-II :-
CaO NaOH
∆
→
Column-I Column-II
(c) CH3(CH2)4CH3 (r) 2CH3OH
V2 O5
→ (Reaction) (Type of
773K,
10 − 20 atm reaction)
(d) 2CH4 + O2 (s) CH4 (a) HC CH
H2
→ (p) Pyrolysis
Cu/523K Pd
100 atm
→
(1) a – q, b – p, c – r, d – s (b) Anhydrous
→ (q) Reduction
AlCl3 HCl

(2) a – q, b – s, c – p, d – r
(c) 773K
→ (r) Free radical
substitution
(3) a – q, b – p, c – s, d – r
(d) CH3CH3
Cl2
→ (s) Isomerisation
(4) a – p, b – q, c – r, d – s h

(1) a – q, b – s, c – p, d – r
(2) a – p, b – q, c – s, d – r
(3) a – q, b – p, c – s, d – r
(4) a – p, b – q, c – r, d – s

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10. Match the column-I with column-II :- 12. Match the column-I with column-II :-

Column-I Column-II Column-I Column-II

(Reaction) (Product) (a) 2,8-Dimethyl-3,6- (p) 41 & 1

decadiene
(a) CH3–C C–CH3 (p) CH3 CH3
C=C (b) 1,3,5,7-octatetraene (q) 23 & 1
H2
Pd/C
→ H H (c) 2-n-propylpent-1-ene (r) 17 & 4
(d) 4-ethyl-2,6- (s) 33 & 2
(b) CH3–C C–CH3 (q)
dimethyldec-4-ene
CH3 – C C Na
Na /liq.NH3
→ (1) a – s, b – p, c – r, d – q
(2) a – s, b – r, c – q, d – p
(c) CH3–C C–CH3 (r) CH3CH2CH2CH3
(3) a – r, b – p, c – s, d – q
H 2 /Pd − C
→ (4) a – q, b – s, c – r, d – p
Quinoline

13. Match the column-I with column-II :-

(d) CH3 –C CH (s) CH3 H
Na /liq.NH3
C=C Column-I Column-II
→ H CH3
(a) CH – CH = CH (p) Hydrogenation
3 2
(1) a – s, b – r, c – q, d – p
H
→
(2) a – p, b – s, c – r, d – q H2 O

CH3– CH – CH3
(3) a – r, b – s, c – p, d – q
OH
(4) a – p, b – q, c – r, d – s
(b) CH – CH = CH (q) Hydration
3 2
11. Match the column-I with column-II :-
HBr
R 2 O2
→
Column-I Column-II
(Compound) (Boiling point) CH3 – CH2 – CH2 – Br

(a) 2-Methyl propane (p) 309.1 K (c) CH – CH = CH (r) Halogenation

3 2

Br2
(b) Pentane (q) 282.5 K CCl 4
→

(c) 2-Methyl butane (r) 261 K

Br
(d) 2,2-Dimethylpropane (s) 300.9 K CH3– CH – CH2– Br

(1) a – r, b – p, c – s, d – q
(d) CH = CH (s) Hydrohalogenation
2 2
(2) a – q, b – r, c – s, d – p
H2
Pd
→ CH3 – CH3
(3) a – r, b – s, c – q, d – p
(1) a – s, b – r, c – q, d – p
(4) a – s, b – r, c – q, d – p
(2) a – q, b – s, c – r, d – p
(3) a – r, b – s, c – p, d – q
(4) a – p, b – q, c – r, d – s

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14. Given below are two statements: 16. Given below are two statements:

Statement-I : Alkenes decolourise KMnO4 Statement-I : Peroxide effect is not observed in

solution. addition of HCl & HI

Statement-II : Alkenes undergo addition Statement-II : HCl bond is stronger than HBr
reactions, which are mainly nucleophilic addition bond and H – I bond is weaker than H – Br
reactions.
bond.
In the light of the above statements, choose the
In the light of the above statements, choose the
most appropriate answer from the options given
most appropriate answer from the options given
below:
below:
(1) Statement-I and Statement-II are correct.
(1) Both Statement-I and Statement-II are
(2) Both Statement-I and II are incorrect.
correct.
(3) Statement-I is correct but Statement-II is

incorrect. (2) Statement-I is correct but Statement-II is

(4) Statement-I is incorrect but Statement-II is incorrect.

correct. (3) Statement-I is incorrect but Statement-II is

15. Given below are two statements: correct.

Statement-I : Ozonolysis of alkenes involves the (4) Statement-I and II both are incorrect.

addition of ozone molecule to alkene to form 17. Given below are two statements:
ozonide and then cleavage of the ozonide by Zn-
Statement-I : Cis-But-2-ene has less dipole
H2O to smaller molecules.
moment than trans-but-2-ene.
Statement-II : Ozonolysis reaction is highly
Statement-II : R–C C–R' reacts with H2 in
useful in detecting the position of double bond in
presence of Na/liq. NH3 to form cis-alkene.
alkenes or in other unsaturated compounds.

In the light of the above statements, choose the In the light of the above statements, choose the

most appropriate answer from the options given most appropriate answer from the options given

below: below:

(1) Both Statement-I and Statement-II both are
correct.
(2) Statement-I and II both are incorrect.
(3) Statement-I is wrong but Statement-II is correct.
(4) Statement-I is correct but Statement-II is wrong.
(1) Statement-I is correct but Statement-II is
incorrect.
(2) Statement-I is incorrect but Statement-II is
correct.
(3) Statement-I and Statement-II are correct.
(4) Both Statement-I and II are incorrect.

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18. Given below are two statements:
Statement-I : Dihydrogen gas adds to alkenes
and alkynes in the presence of finely divided
catalyst like platinum, palladium or Nickel to form
alkanes.
Statement-II : Metals adsorb dihydrogen gas on
their surfaces and activate the hydrogen-
hydrogen bond.
In the light of the above statements, choose the
most appropriate answer from the options given
below:
(1) Both statements-I and II are correct.
(2) Both Statement-I and II are incorrect
(3) Statement-I is correct but Statement-II is
incorrect.
(4) Statement-I is incorrect but Statement-II is
correct.
19. Given below are two statements:
Statement-I : Sodium metal reacts with Ethyne
and form sodium acetylide with liberation of
nascent oxygen gas.
Statement-II : Alkynes are more acidic than
alcohols.
In the light of the above statements, choose the
most appropriate answer from the options given
below:
(1) Statements-I and II both are incorrect.
(2) Statement-I is correct but Statement-II is
incorrect.
(3) Statement-I is incorrect but Statement-II is
correct.
(4) Statement-I and II both are correct
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20. Given below are two statements:
Statement-I : Ethyne is formed from
dibromoethane by using alcoholic KOH followed
by NaNH2.
Statement-II : Ethyne is formed from geminal
dibromo ethane by using one equivalent of
alcoholic KOH.
In the light of the above statements, choose the
most appropriate answer from the options given
below:
(1) Statement-I and Statement-II both are correct.
(2) Statement-I and II both are incorrect.
(3) Statement-I is correct but Statement-II is incorrect.
(4) Statement-I is incorrect but Statement-II is
correct.
21. Given below are two statements:
Statement-I : Hydrogenation of alkenes and
alkynes with platinum and palladium catalyse the
reaction at room temperature but nickel catalyst
requires high temperature and pressure.
Statement-II : Alkyl halides on reduction with
zinc and dilute HCl give alkene.
In the light of the above statements, choose the
most appropriate answer from the options given
below:
(1) Statement-I and II both are incorrect.
(2) Statement-I and Statement-II both are correct.
(3) Statement-I is correct but Statement-II is
incorrect.
(4) Statement-I is incorrect but Statement-II is
correct.
22. Given below are two statements: 24. Given below are two statements:

Statement-I : Alkyl halides on treatment with Statement-I : Naphthalene balls are used in

toilets and for preservation of clothes.

sodium metal in moist ether gives higher alkane.
Statement-II : Naphthalene balls are immiscible
Statement-II : Wurtz reaction is used for the
with water but are readily miscible with organic
preparation of higher alkanes containing even
solvents.
number of carbon atoms. In the light of the above statements, choose the

In the light of the above statements, choose the most appropriate answer from the options given

most appropriate answer from the options given below:

(1) Statement-I is correct but Statement-II is

below:
incorrect.
(1) Statement-I and Statement-II both are correct.
(2) Statement-I is incorrect but Statement-II is
(2) Statement-I and II both are incorrect.
correct.

(3) Statement-I is correct but Statement-II is incorrect. (3) Statement-I and Statement-II are correct.

(4) Statement-I is incorrect but Statement-II is (4) Statement-I and Statement-II are incorrect.

correct. 25. Given below are two statements:

23. Given below are two statements: Statement-I : P–H3C–C6H5–NO2 is more

reactive than P–O2N–C6H5–NO2 towards

Statement-I : is aromatic compound
electrophile.
–
Statement-II : There are 12 e having Statement-II : –CH3 is ortho/para directing

complete delocalisation. group while –NO2 is meta directing group.

In the light of the above statements, choose the In the light of the above statements, choose the
most appropriate answer from the options given most appropriate answer from the options given

below: below:

(1) Statement-I is incorrect but Statement-II is (1) Both Statement-I and Statement-II are

correct.
correct.
(2) Statement-I and Statement-II are incorrect.
(2) Statement-I is correct but Statement-II is
(3) Statement-I is incorrect but Statement-II is
incorrect.
correct.
(3) Statement-I and Statement-II are correct.
(4) Statement-I is correct but Statement-II is
(4) Both Statement-I and II are incorrect.
incorrect.

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26. Given below are two statements:
Statement-I : Ozonolysis of o-xylene (1,2-
dimethyl benzene gives three products. The result
supports kekule structure of benzene.
Statement-II : Benzene have 6 e in cycle and
— solids.
have cyclic delocalisation.
In the light of the above statements, choose the
most appropriate answer from the options given
below:
(1) Statement-I is correct but Statement-II is
incorrect.
(2) Statement-I is incorrect but Statement-II is
correct.
(3) Statement-I and Statement-II are incorrect.
(4) Both Statement-I and Statement-II
correct.
27. In given statements which is/are correct :-
(A) Cis & Trans isomers have same structure but
have different configuration (arrangement of
atoms or groups)
(B) Cis-2-butene has more boiling point than
trans-2-butene.
(C) Trans-2-butene has more dipole moment than
cis-2-butene.
(D) Geometrical isomerism is also shown by
alkenes of the types XY C = C XZ and XY
C = C ZW.
(1) A, B, C & D (2) Only A, B
(3) Only A, B & C (4) Only A, B & D
28. Which of the following statements is/are
incorrect :-
(A) In alkenes first three members are gases, the
next 14 are liquid & the higher ones are
(B) Except ethene all other alkenes are colourless
& odourless.
(C) Straight chain alkenes have higher boiling
point than isomeric branched chain
compounds.
(D) Generally alkenes are soluble in water &
insoluble in non polar solvents.
(1) A, B & C only
(2) Only D
are (3) B & D only
(4) B, C & D only
29. Given below are two statements; one is labelled
as Assertion (A) and the other is labelled as
Reason(R) .
Assertion: If benzene is treated with 1-
chloropropane in presence of anhydrous AlCl3,
Isopropyl benzene is major product not n-propyl
benzene.
Reason : Reaction occurs via rearrangement of
carbocation.
In the light of the above statements, choose the
most appropriate answer from the options
given below :
(1) Both (A) and (R) are correct but (R) is not the
correct explanation of (A).
(2) Both (A) and (R) are correct and (R) is the
correct explanation of (A).
(3) (A) is correct but (R) is not correct.
(4) (A) is not correct but (R) is correct.

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 2 4 3 2 3 2 3 1 3 1 2 2 3 1
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29
Ans. 1 4 1 1 3 3 4 2 3 1 4 4 2 2

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