Professional Documents
Culture Documents
2.petrophysics RGE - 2011
2.petrophysics RGE - 2011
Introduction - Definitions
Structure and properties of porous materials
porosity
specific surface area
formation resistivity factor
permeability
compressibility
Statics of fluids in porous media
saturations
wettability
capillary pressure
electrical properties
© IFP Energies nouvelles
• pore geometry
• fluid distribution
• wettability
• saturation history
• applied forces equilibrium
Capillary Number, Ca = µV / σ
ratio of viscous to capillary forces
© IFP Energies nouvelles
mixed-wet or fractionally-wet
© IFP Energies nouvelles
But most of the reservoirs are not strongly « water-wet » nor « oil-
wet ». Thus the « wetting » and « non-wetting » fluids cannot be
defined.
By convention!
Drainage: Decrease of the water saturation
Imbibition: Increase of the water saturation
Drainage:
oil displacement by water
oil-wet sand
Imbibition:
oil displacement by water
water-wet sand
© IFP Energies nouvelles
Craig, 1971
Petrophysics, RGE, O. Vizika
IMMISCIBLE FLOW REL PERM
STEADY-STATE CONDITIONS
∆P1
Fluid 1 Fluid 1
Q1
Q2 Fluid 2 Fluid 2
∆P2 L
K1 A ∆P1
Q1 = K1, K2 effective permeabilities
µ1 L
Kr1=K1/K
K 2 A ∆P2
© IFP Energies nouvelles
Q2 = relative permeabilities
µ2 L Kr2=K2/K
Base permeability
• Kair
• Kwater
• Koil @ Swi
Kr = ƒ(contact angle)
© IFP Energies nouvelles
Water-wet Oil-wet
Native-state Restored-state
Water-oil Kr Gas-oil Kr
1
0,9
0,8 Kro
0,7
0,6
Krw end point
Kr
0,5
Cross point
0,4
0,3
0,2 Krw
0,1
Swi Sor
0
0 0,2 0,4 0,6 0,8 1
© IFP Energies nouvelles
Sw
Kro
0,1
Kr
0,01
0,001 Krw
Swi Sor
0,0001
Sw
© IFP Energies nouvelles
0,1
Kro
0,01
S o − Sor 1 − Sw − S or
Son = =
1 − S wi − S or 1 − S wi − Sor
0,001
Son
© IFP Energies nouvelles
K ro = K ro −end − point ⋅ S on
Son =normalized oil saturation no
So =oil saturation
Sw =water saturation
Swi =irreducible water saturation no =Corey exponent
Sor =residual oil saturation
Petrophysics, RGE, O. Vizika
CHARACTERISTICS OF WATER-OIL REL PERMS
Krw vs normalized saturation
0,1 1
1
0,1
Krw
0,01
nw=4
0,001
0,0001
Swn
S w − S wi K rw = K rw − end − point ⋅ S wn
nw
S wn =
© IFP Energies nouvelles
1 − S wi − S or
nw =Corey exponent
Corey exponents
1
0,9
0,8
0,7
Krw
0,6
no=3 Krw
Kr
0,5
Kro
0,4
Kro
0,3 no=4
nw=3
0,2
0,1 nw=5
© IFP Energies nouvelles
0
0 0,2 0,4 0,6 0,8 1
Swn
Water-wet 2 to 4 5 to 8
Intermediate-wet 3 to 6 3 to 5
© IFP Energies nouvelles
Oil-wet 6 to 8 2 to 3
Wettability issues
• intermediate wettability
• need for appropriate representation in lab tests
• tests at reservoir P,T with reservoir fluids
• Steady state
• Centrifuge
© IFP Energies nouvelles
Steady-State
∆P1
Fluid 1 Fluid 1
Q1
Q2 Fluid 2 Fluid 2
∆P2
KK r1 A ∆P1
Q1 =
µ1 L
KK r 2 A ∆P2
© IFP Energies nouvelles
Q2 =
µ2 L
Petrophysics, RGE, O. Vizika
WATER-OIL Kr: MEASUREMENT METHODS
• STEADY-STATE
Advantages
Shortcomings
∆P1
Fluid 1 Fluid 1
Q1
nw Non uniform saturation
Q2 w
Fluid 2 Fluid 2
∆P2
∆P1
Fluid 1 Fluid 1
Q1
Solution 1
Q2 Fluid 2 Fluid 2
∆P2
© IFP Energies nouvelles
Unsteady-state method
∆P Oil
Vnr
oil
water
Swi
Q
Water
Vr
•Welge Kro/Krw
© IFP Energies nouvelles
Advantages
• Fast
• Representativity of flow in the reservoir
• Reservoir conditions (P,T)
Shortcomings
• Calculations not straightforward
• Strong assumptions for analytical calculations
•homogeneous samples
•Pc=0
• Narrow range of saturations (only after BT)
To overcome shortcomings
© IFP Energies nouvelles
UNSTEADY-STATE
40
Fluid production
35
30
Cumulative oil volume (cm3)
25 Pressure drop
200
V oil exp
20
V oil mod
180
15
160
10 140
Overall pressure drop (mbar)
5
120
Saturation profiles
100
0 0.9 DP exp
0 50 100 150 80200 250 300 350 400 450 500
Time (mn)
DP mod
0.8
60
40 0.7
Swj@40mn
20 0.6
Swj@80mn
Swj@120mn
0 0.5 Swj@160mn
0 50 100 150 200 250 300 350 400 450 500 Swj@200 mn
Sw
0.4 calc80
calc120
calc160
0.3
calc200
0.2
0.1
0
0 5 10 15 20 25 30
35
Pressure drop
Cumulative oil volume (cm3)
30
25 V oil exp
180
O mod new15
20
160
Overall pressure drop (mbar)
15 140
Saturation profiles
10 120
100
5
80
DP exp
0
0 50 100 150 200 250 300 350 400 450 500
DP mod new15
0.9
60
Time (mn)
0.8
40
0.7
20 Swj@40mn
Swj@80mn
0.6
0 Swj@120mn
0 50 100 150 200 250 300 350 400 450 500 Swj@160mn
calc40 new15
0.4 calc80 new15
calc120 new15
calc160 new15
© IFP Energies nouvelles
0.3
calc200 new15
0.2
0.1
0
0 5 10 15 20 25 30
0.15 1.00
krw new
Pcow old 0.90
krow new
Pcow new
krw old
0.1
0.80 krow old
Water-oil capillary pressure (bar)
0.70
0.05
0.60
Kr
0.50
0
0 0.2 0.4 0.6 0.8 1
0.40
-0.05
0.30
0.20
-0.1
© IFP Energies nouvelles
0.10
0.00
-0.15 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90
Water saturation Sw
• CENTRIFUGE
Advantages
• Fast
• One speed step sufficient
• Stable displacement
• Kro over wide saturation range
Shortcomings
• Calculations not straightforward
• Strong assumptions
• Kr of only the produced phase (Kro)
• Plugs only @ T but not P (representative wettability?)
© IFP Energies nouvelles
1,E-04
krw RT4
1,E-05
kro RT4
krw RT5
1,E-06
RRTÇ kro RT5
© IFP Energies nouvelles
1,E-07
1,E-08
Sg
0 Sgc SgM 1
© IFP Energies nouvelles
Depends on:
• Pore size distribution, aspect ratio, connectivity
• Displacement mechanism
•higher for pressure depletion than for gas
injection
© IFP Energies nouvelles
•Unsteady-state gasfloods
•Core Plugs or Composite cores
•End effects - local saturation measurements
•Room or reservoir conditions (refined oil & inert gas
or reservoir oil and gas)
•Centrifuge
© IFP Energies nouvelles
1 − S g − S wi − Sor
Son = K ro = S on n o
1 − S wi − Sor
S g − S gc
S gn = K rg = S gn n g
1 − S wi − Sor − S gc
Bardon, 1980
Petrophysics, RGE, O. Vizika
GAS-OIL RELATIVE PERMEABILITIES
0. 9
Nc Ç
0. 8
Nc Ç
0. 7
relative permeability
Krg - base Nc
0. 6
Kro - base Nc
Krg - Base Nc * 10
0. 5
Kro - Base Nc * 10
Krg - Base Nc * 100
0. 4 Kro - Base Nc * 100
Krg - Base Nc * 1000
0. 3 Kro - Base Nc * 1000
Krg - Base Nc * 10000
0. 2 Kro - Base Nc * 10000
Krg - Base Nc * 100000
Kro - Base Nc * 100000
© IFP Energies nouvelles
0. 1
0
0 0. 2 0. 4 0. 6 0. 8 1
Gas saturation
Petrophysics, RGE, O. Vizika
Mott, 2001
FLOW OF IMMISCIBLE FLUIDS IN
POROUS MEDIA
Darcy’s law, for two phases, oil and water
Linear displacement in a porous material inclined at an angle a to the horizontal and
with a cross section A:
k w A ⎛ δ Pw ⎞
qw = − ⎜ + ρ w g sin α ⎟ (1)
µ w ⎝ δx ⎠
k o A ⎛ δ Po ⎞
qo = − ⎜ + ρ o g sin α ⎟ (2)
µ o ⎝ δx ⎠
δ qo δS
= −φ A o (5)
δx δt
© IFP Energies nouvelles
So + Sw = 1 (6)
δ
By adding equation 4 and 5 to equation 6 we get: (q + q ) = 0
δx o w
ko A ⎛ µwqw δPc ⎞
Combine the Eqs. (1), (2) and (3) to eliminate Pw and Po qo = − ⎜⎜ − + − ∆ρg sinα ⎟⎟
µο ⎝ kw A δx ⎠
ko A ⎛ δPc ⎞
1+ ⎜ − ∆ρg sin α ⎟
Substitute qw and qo in equation 7: µ o qt ⎝ δx ⎠
fw =
kµ
1+ o w
kw µo
© IFP Energies nouvelles
1
fw =
k µ
1 + ro w
k rw µ o
constant)
© IFP Energies nouvelles
dx qt df w
υ Sw = =
dt Sw A φ dS w Sw
Integrating the Buckley-Leverett Solution for the total time since the start of
injection gives:
t Wi df w
1 df w =
Aφ dS w ∫0
xSw = qt ⋅ dt xSw
or: Aφ dS w Sw
© IFP Energies nouvelles
• Capillary models
•Bundle of capillary tubes
•Ignore interconnected nature of rocks
• Statistical models
•Bundle of capillary tubes distributed randomly
•Unable to model interconnected nature of rocks
• Empirical models
•Empirical relationships describing experimentally
determined Kr
• Network models
© IFP Energies nouvelles
Pc = f ( S w )
Consider the bundle of capillaries concept to calculate rel perms
Distribution of liquid phases within the pore space according to the Pc curve
1
∫
S wt
∫ dS / Pc2
2
dS / P c
=A =B
0 S wt
krwt krnwt 1
∫ dS / P
1
∫ dS / P
2 2
c c
0 0
Pc = f ( S w )
6
10
Slope =1/(DL-2)
1/r (cm-1)
= -3.3
10 5 DL=1.7 = -1.9
DL=1.5
= -1.5
DL=1.34 1
10 4 Pc ∝ DL − 2
R0
S wetting
3
10
© IFP Energies nouvelles
DL : Fractal Dimension of
10
2 the porous structure
-1 0
10 S (w Ph) 10
wetting
Durand, 2000
Petrophysics, RGE, O. Vizika
© IFP Energies nouvelles CLAY CONTAINING SANDSTONE
Durand, 2000
Petrophysics, RGE, O. Vizika
© IFP Energies nouvelles
INTERGRANULAR CLAY STRUCTURES
Durand, 2000
Petrophysics, RGE, O. Vizika
DESCRIPTION OF THE FRACTAL MODEL -
MODELING
Water
Oil
R
Gas 1
R2 R0
Rk = R0 (π / η ) k ln η
© IFP Energies nouvelles
DL = fractal dimension
ln η / π
Nk = η k
Petrophysics, RGE, O. Vizika
Kr CALCULATION WITH THE FRACTAL MODEL
Swi 4−DL
Oil 4−DL
+ Sor K ro = SL 2−DL
− (Swi + Sor ) 2−DL
Gas
[ ]
4
Krg = 1 − SL
1
2−D L
SL = SO + Sw
© IFP Energies nouvelles
"Bundle of Tubes"
8k
L r=
ϕ
or
or
φ, pore size distribution, throat size distribution and pore accessibility (the
must)
© IFP Energies nouvelles
3D pore network : 1
Conceptual 0.8
representation of 0.6
Kr
porous media 0.4
0.2
0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
S
© IFP Energies nouvelles
water-wet solid
spreading oil on water in presence of gas
© IFP Energies nouvelles
Dullien, 1992
Pi2
∑ ij = 0
q α
j
P P Pi1
i3 i for each phase α present in the
pore α
(α α
)α
with q ij = g ij Pi − P j
© IFP Energies nouvelles
P
i4
Rf = f (β ,θW/S )
NW=
GAS
r β
© IFP Energies nouvelles
Perfectly wetting: θ W / S = 0
Oil-wet
pore Throat: β = π/3 Pore: β = π/4
Rf = 31 Rf = 94
Petrophysics, RGE, O. Vizika
MAIN DRAINAGE AND
IMBIBITION MECHANISMS
© IFP Energies nouvelles
Pw PCowIJ=γow
I
.CdIJ
PoI − Pw J > PCowIJ Cpor
P Cd Pw J
I o
e PwI
PoI
g IJ ⎜
= w + w ⎟ C pore = +
⎜g ⎟
⎝ Tmono (lw ) gTfilm (lo ) + gTbulk (lo ) ⎠
o Rm e
PwI
PoJ PoI
Pg PwI
PoI
Pg
PCog
Po I = Pg − PCog IJ > Po J
© IFP Energies nouvelles
Conceptual representation of
the porous structure by a
interconnected 3-D network of
pores and capillaries
roughness
fractal solid surface
(
qijα = gijα Piα − Pjα )
• CALCULATE TOTAL FLOW RATE Qa FOR EACH PHASE IN THE NETWORK
Qα µα L
K rα =
AK∆P
Petrophysics, RGE, O. Vizika
© IFP Energies nouvelles 3 PHASES IN THE PORE NETWORK
Qw µ w L
© IFP Energies nouvelles
K rw =
AK∆P
Qg µ g L
© IFP Energies nouvelles
K rg =
AK∆P
76 Petrophysics, RGE, O. Vizika
© IFP Energies nouvelles Kro CALCULATION
Qo µ o L
K ro =
AK∆P
77 Petrophysics, RGE, O. Vizika
EFFECT OF WETTABILITY (SINGLE POROSITY)
Pc curve
Θ=0°
Θ =60°
Θ =40° Θ =0°
© IFP Energies nouvelles
Θ=0°
Θ =60°
no corner flow
Θ =0° corner
flow
© IFP Energies nouvelles
Θ =40°
Lavoux carbonate
K=1.9 mD, Φ= 23%
Ca pilla ry pre ssure
Stochastic Network
1000
Hg
co de R elative p erm eab ilities
100 1
Pc_Hg [bar]
0.8
10
num e ric a l Kr g
1
0 0.2 0.4
S _Hg 0.4
0.6 0.8 1
e x pe rim e nta l Kr w
0.2
num e ric a l Kr w
© IFP Energies nouvelles
0
0 0.2 0.4 Sg 0.6 0.8 1
Pcow (bar)
10000 AR == 66
AR
wet
water wet 0.1
0.1
wet
oil wet
λ ρ == 11
1000
λ ρ == 22
λ ρ == 22
AR=6
AR=6
AR = 6 0.01
0.01
100
0.01
0.01 0.1
0.1 Sw
Sw 11
IR
11
water
water wet
10 oil wet
oil wet
λλρρ == 1
λλρρ == 2
λλρρ == 2
(bar)
Pcow (bar)
1 AR
AR == 66
0.1
0.1
Sw
Sw
© IFP Energies nouvelles
0.01 0.1 1
Pcow
Multiphase transport
properties
Kr=ƒ (S)
Stochastic
Pc Hg 1
0.8
F&K 0.6
Kr
0.4
0.2
0
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
RI =ƒ (S)
Deterministic
10000
µ-CT
© IFP Energies nouvelles
100
RI
1
0.01 0.1 1
•Characterization of rock
microstructure au µ-scanner
•Calculation and up-scaling
of transport properties
© IFP Energies nouvelles
3 mm
Pc
pores, throats
pores sizes Kr
throats sizes measured
>1µm
connectivity
IR
µ−porosity