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Indian Journal of Engineering & Materials Sciences

Vol. 22, August 2015, pp. 473-481

Performance of self-compacting geopolymer concrete containing different


mineral admixtures
T G Ushaaa, R Anuradhab* & G S Venkatasubramanic
a
Karpagam University, Coimbatore 641 021, India
b
Department of Civil Engineering, SNS College of Technology, Coimbatore 636 035, India
c
Paavai Engineering College, Rasipuram 637 018, India

Received 14 August 2014; accepted 2 January 2015

Self-compacting geopolymer concrete is an innovative concrete that does not require vibration for placing and
compaction. It is able to flow under its own weight, completely filling formwork and achieving full compaction, even in the
presence of congested reinforcement. In this paper fly ash was replaced by different mineral admixtures, which reduces the
cost of self compacting geopolymer concrete especially if the mineral admixtures are waste or industrial by-product. This
paper presents an experimental investigation on strength aspects like compressive, flexural and split tensile strength of self
compacting geopolymer concrete containing different mineral admixtures and workability tests for different mineral
admixtures (slump, L-box, U-box and T50) are carried out. The methodology adopted is that mineral admixtures GGBFS and
silica fume are replaced by 10%, 20%, 30% and 5%, 10% and 15% respectively for fly ash and performance is measured
and compared. The influence of mineral admixtures on the workability, compressive strength, splitting tensile strength and
flexural strength of self-compacting concrete is investigated. It is observed that when mineral admixtures used in self-
compacting geopolymer concrete, only 6% of super-plasticizer necessary to achieve a given fluidity. From this view point, a
cost effective self-compacting concrete design can be obtained.

Keywords: Self-compacting geopolymer concrete, Fly ash, Silica fume, Ground granulated blast furnace slag

Self-compacting concrete is a complex system that is compacting geopolymer concrete3. One alternative to
usually proportioned with one or more additions and reduce the cost of self-compacting concrete is the use
one or more chemical admixtures. A key factor for a of additions. Due to the better engineering and
successful formulation is a clear understanding of performance properties, additions such as silica fume,
the role of the various constituents in the mix and fly ash, and ground granulated blast-furnace slag are
their effects on the fresh and hardened properties1. normally included in the production of high-strength
Successful self-compacting concrete must have high and high-performance concrete4. The most often
fluidity (for flow under self-weight), high segregation used fillers increasing viscosity of self-compacting
resistance (to maintain uniformity during flow) concrete mixtures are fly ash, glass filler, limestone
and sufficient passing ability so that it can flow powder, silica fume and quartzite filler. More
through and around reinforcement without blocking recently, environmental arguments began to prevail,
or segregating2. The longer curing time improves in particular the need to decrease the overall CO2
the geopolymerisation process resulting in higher production related to the use of cement in concrete1.
compressive strength. Increase in compressive Fly ash5, ground granulated blast furnace slag and
strength was observed with increase in curing time. silica fume4 were the most frequently applied in self
The compressive strength was highest when the compacting concrete. The incorporation of mineral
specimens were cured for a period of 96 h however; admixtures also eliminates the need for viscosity-
the increase in strength after 48 h was not significant. enhancing chemical admixtures. The lower water
Compressive strength of concrete increased with the content of the concrete leads to higher durability,
increase in curing temperature from 60°C to 70°C in addition to better mechanical integrity of the
however an increase in the curing temperature beyond structure. It is also known that some mineral
70°C decreased the compressive strength of self admixtures may improve rheological properties and
———————
reduce thermally-induced cracking of concrete due
*Corresponding author (E-mail: anuradhastalin@gmail.com) to the reduction in the overall heat of hydration and
474 INDIAN J. ENG. MATER. SCI., AUGUST 2015

increase the workability and long-term properties of review of the effect of different SPs on slag and fly
concrete6. One of the most important differences ash based geopolymers8.
between self-compacting concrete and conventional The use of optimum level of palm oil fuel ash
concrete is the incorporation of mineral admixture. (POFA), ground granulated blast furnace slag
Since cement is one of the most expensive (GGBS) and low calcium fly ash (FA) with
components of concrete, reducing the cement content manufactured sand (M -sand) to produce
is one of the economical solutions. Besides these geopolymer mortar. Eleven mixtures were prepared
economical benefits, the use of by products or waste with varying binder contents with the POFA content
materials reduces environmental pollution. varying between 25% and 100%; the other constituent
The influence of different superplasticizer dosage materials such as fine aggregate and water were kept
on compressive strength and micro-structure constant. All the specimens were cured in
characteristics of interfacial transition zone (ITZ) oven for 24 h at 65°C and thereafter kept in room
prepared with fly ash based self-compacting temperature (about 26-29°C) before testing for the
geopolymer concrete (SCGC). The correlations compressive strength. The highest compressive
between compressive strength development and strength of about 66 MPa was achieved for the mortar
microstructure of interfacial transition zone were containing 30% of POFA and 70% of GGBS with a
also investigated. Concrete specimens were prepared total binder content of 460 kg/m3 . The increase in the
with different superplasticizer (SP) dosage namely POFA content beyond 30% reduces the compressive
3%, 4%, 5%, 6% and 7% and cured at 70°C strength. The density reduction after 3 days was found
for duration of 48 h. Field emission scanning electron negligible9. The influence of high-calcium fly ash
microscope (FESEM) observations revealed that (HCFA) on selected properties of fresh and hardened
improved performance of concrete was found when self-compacting concrete and high performance self-
the compressive strength increased through formation compacting concrete. HCFA was used as an additive
of dense ITZ between the aggregate and binder matrix for concrete (up to 30%) or as a main constituent in
at higher SP dosage. There are good correlations cement. Studies have confirmed the possibility of
between compressive strength and micro-structure HCFA use in self-compacting concrete, while
characteristics of interfacial transition zone. The maintaining the assumed workability of fresh concrete
FESEM analysis revealed that relatively a loose and and compressive strength of hardened concrete.
porous interfacial zone was found between the binder HCFA should be processed by grinding, and its
and aggregate for low SP dosage and theses loose and amount in the mixture should not be higher than
porous ITZ decreased the performance of concrete by 30% of the cement's mass. Cements that contain
lowering the compressive strength; however, a dense HCFA as the main component can be used in both
ITZ was found between the aggregate and binder normal and high performance self-compacting
matrix for higher SP dosage that enhanced the concrete. Studies have also confirmed the possibility
concrete performance by increasing the compressive of the use of high-ash, multi-component cements
strength7. Geopolymer is a novel engineering binder containing HCFA (CEM X – “CEM V/A (S-W)”) for
with lower environmental impacts (CO2 emission, the new generation of concrete10.
embodied energy and global warming potential) than In this study, it is aimed to investigate the effect of
ordinary Portland cement (OPC). Geopolymers can be fly ash, silica fume, and ground granulated blast
synthesized from mixing high alkaline activators by furnace slag as mineral admixtures on the fresh and
industrial by-products such as fly ash and slag as the
hardened properties of self-compacting geopolymer
aluminosilicate source materials. Superplasticizers
concrete. Fresh concrete tests such as slump-flow,
(SPs) are one of the common used admixtures
L-box, T500, U-box and hardened concrete tests such
added to conventional OPC concrete to improve its
as compressive strength, split tensile strength, flexural
workability, rheology and mechanical properties. SPs
strength were conducted.
are intended for use with OPC paste, mortar and
concrete. The suppliers of SP do not intend them to be
used in geopolymer mixes since SPs are attacked by Experimental Procedure
alkaline solutions and degrade rapidly. However, Materials
some SPs can be used with geopolymer with limited Locally available river sand conforming to grading
effectiveness. This study presents a state of the art zone II of IS: 383-1970 was used and crushed stones
USHAA et al.: SELF-COMPACTING GEOPOLYMER CONCRETE 475

of nominal size 12.5 mm conforming to IS 383-1970 (W/G’s) ratio by mass for all the mixes was
was used. The specific gravity of coarse aggregate maintained at 0.33 and the total powder content was
was 2.77. The maximum size of the coarse aggregate fixed at 450 kg/m3. To obtain the required workability
was restricted to avoid the blocking effect in characteristics of SCGC, a water content of 12% and
self-compacting concrete. The amount of coarse superplasticizer dosage of 6% by mass for the binder
aggregates in self-compacting concrete mixtures is were used. Based on the above discussions mix
much lower than in traditional vibrated concrete. On proportions have been arrived for Fresh SCGC as
the other hand, they contain a high amount of fine shown in Table 2.
fillers and/or additives to increase the viscosity. In Seven mixes with different replacements of mineral
this way, the stability of the mix is maintained, admixtures were prepared and examined to quantify
bleeding is reduced, and separation of coarser the properties of self-compacting geopolymer
aggregates is avoided6. The specific gravity of sand concrete. Table 3 presents the composition of self-
was 2.65. Besides this the byproducts, flyash was compacting geopolymer concrete mixtures. The
obtained from Salem Thermal Power Plant, India, mineral admixtures GGBFS and silica fume are
silica fume from Meridian Science and Technologies, replaced by 10%, 20%, 30% and 5%, 10%, 15%,
ground granulated blast furnace slag from Agni Steel respectively for fly ash by mass. The water/
Plant, Erode, Tamilnadu, India. In general, the geopolymer solids mass ratio (w/G) was selected as
approach of minimizing free water content to 0.3313. Many different test methods have been
enhance stability can result in self-compacting developed in attempts to characterize the properties of
concrete mixtures with a low yield stress and self-compacting concrete. So far no single method or
moderate-to-high viscosity levels. The low water combination of methods has achieved universal
content requires a relatively high dosage of high range approval and most of them have their adherents.
water reducers to obtain the required deformability Similarly no single method has been found which
especially with the lower binder contents11. A new characterizes all the relevant workability aspects
generation based polycarboxylic ether was used. so each mix design should be tested by more than one
In terms of effectiveness polycarboxylic ether is test method in order to obtain different workability
higher compared to other bases and it also works parameters13. The total powder content was varied as
at low dosages than other types of superplasticizers. 400 kg/m3, 450 kg/m3, 500 kg/m3 as iterative values
The pH of superplasticizer was greater than 6. and finally is fixed as 450 kg/m3. A polycarboxylate-
The characteristic properties and mineralogical based high range water reducing admixture was used
composition of these three mineral admixtures are along with these mixes, apart from the control mix.
given in Table 1. Some design guidelines have been prepared from the
acceptable test methods14. The workability related
Mix proportions fresh properties for molarity of 8M, 10M, 12M, and
The mix design in the case of self-compacting 14M of SCGC were assessed through slump flow,
geopolymer concrete is inverse to that of conventional T50cm Slump flow, V-funnel, L-box and U-Box test
concrete. The design is made by the help of EFNARC methods. Based on the results taken from workability
guidelines12. For this study, proportions of water and tests the optimized molarity is chosen for SCGC.
solids for various molarities like 8M, 10M, 12M and
14M are taken. The water to geopolymer solids Example molarity calculation
Table 1 – Properties of mineral admixtures The solids must be dissolved in water to make a
solution with the required concentration. The
Component (%) Fly ash Silica fume Slag cement concentration of sodium hydroxide solution can vary
Chemical composition (%) in different molar. The mass of NaOH solids in a
SiO2 40 97.1 10-19 solution varies depending on the concentration of the
Magnesium oxide (MgO) 4 0.0 11 solution. For instance, NaOH solution with a
Al2O3 26 0.4 1-3
concentration of 12 molar consist of 12×40 = 480 g of
NaOH solids per litre of water, were 40 is the
Loss on ignition (LOI) 2.0 1.7 1.2
molecular weight of NaOH. It may be noted that the
Fe2O3 6.0 0.3 22-30 mass of water is the major component in both the
Calcium oxide (CaO) 15 0.3 40-52 alkaline solutions. The mass of NaOH solids was
476 INDIAN J. ENG. MATER. SCI., AUGUST 2015

Table 2 – Mix proportions for fresh SCGC


3 3
Mix Fly ash (kg/m ) FA (kg/m ) CA (kg/m3 ) NaOH(kg/m3) Na2SiO3(kg/m3) W/G SP Extra water
8M 450 850 1000 57 143 0.33 6% 12%
10M 450 850 1000 57 143 0.33 6% 12%
12M 450 850 1000 57 143 0.33 6% 12%
14M 450 850 1000 57 143 0.33 6% 12%

Table 3 – Mixture proportions for self-compacting geopolymer concrete (kg/m3)


Mix proportion Fly ash Silica GGBFS FA CA NaOH Na2Sio3 W/G SP Extra water
(kg/m3 ) Fume (kg/m3) (kg/m3) (kg/m3) (kg/m3) (kg/m3)
M1 (0% GGBFS &SF) 450 - 0 850 1000 57 143 0.33 6% 12%
M2 (10% GGBFS) 405 - 45 850 1000 57 143 0.33 6% 12%
M3 (20% GGBFS) 360 - 90 850 1000 57 143 0.33 6% 12%
M4 (30% GGBFS) 270 - 135 850 1000 57 143 0.33 6% 12%
M5 (5% SF) 427.5 22.5 - 850 1000 57 143 0.33 6% 12%
M6 (10% SF) 405 45 - 850 1000 57 143 0.33 6% 12%
M7 (15% SF) 382.5 67.5 - 850 1000 57 143 0.33 6% 12%

measured as 361 g/kg of NaOH solution with a The flexural strength studies were carried out in
concentration of 12 molar. prisms of size 100 mm × 100 mm × 500 mm. For
each mixture of fly ash, silica fume, ground
Alkaline liquid granulated blast furnace slag 36 number of specimens
Generally alkaline liquids are prepared by mixing were casted and tested for compressive, split and
of sodium hydroxide solution and sodium silicate at flexure. Before these strength studies the slump flow,
the room temperature. When the solutions mixed L-box, U-box, V-funnel, T50 were done to study the
together the both solution start to react with each workability properties of self-compacting concrete
other there polymerization process take place. It to access the filling ability and passing ability and
liberate large amount of heat so it is recommended to to fix the molarity. The slump flow test was used
leave it for about 20 min thus the alkaline liquid is to evaluate the flow ability of self-compacting
ready as binding agent. geopolymer concrete in terms of mean spread
Preparation of fresh SCGC diameter. The minimum value of self compacting
For the production of fresh SCGC, fine powdered geopolymer concrete to be 650 mm and a maximum
materials (i.e., fly ash, and fine aggregate) were firstly of 800 mm for a fresh self-compacting concrete.
placed in a pan mixer and blended manually. During the slump flow test, the time required to reach
Afterwards, the coarse aggregate in saturated surface 50 cm diameter of slump flow is measured (T50). The
dry condition was added to the mixer and mixed V-funnel (Fig. 1) test is used to determine the filling
mechanically for about 2.5 min. At the end of this dry ability of the concrete. The time taken for the concrete
mixing, a well-shacked premixed liquid mixture, to flow down is noted in seconds. The slump-flow test
containing alkaline solution, superplasticizer, and extra judges the capability of concrete to deform under its
water, was added in the mixer. This duration was not own weight against the friction of the surface with no
less than 3 min. The freshly prepared concrete mix was external restraint present. Because of the viscous
then assessed for the essential workability tests required nature of some self-compacting concrete mixtures, the
for characterizing SCC. Slump flow, V-funnel, and L- slump-flow measurements were carried out. At the
box tests were performed for this purpose. same time, the slump-flow time (T50) was measured
when the concrete was slumping until it reached
Casting, curing and testing 50 cm of flow. The V-funnel and L-box tests were
Compressive strength studies were carried out on performed according to the procedure given by
cube moulds of 150 mm × 150 mm × 150 mm, while European Federation Committee.
cylindrical moulds of size 150 mm × 300 mm were The maximum time that can be taken by a self-
used for the determination of split tensile strength. compacting geopolymer concrete mix in V-funnel is
USHAA et al.: SELF-COMPACTING GEOPOLYMER CONCRETE 477

Fig. 1 – V-funnel apparatus, L-box, T50 slump test and U-box


10 s. In the L-box test, the test was started by
removing the control gate at once to allow the flow of
self-compacting concrete through the horizontal
obstruction in the box and then the ratio of h2/h1 were
determined, if the concrete flows freely as water, at
rest it will be horizontal and therefore the ration
will be equal to unity. The minimum acceptable value
is to be 0.812. The U-box test method is used to
measure the filling ability of self-compacting
concrete. The height of the concrete in both the Fig. 2 – Slump flow test for various molarity
compartments is measured and this test gives a direct for periods of 14 and 28 days. After casting, the
measurement of filling ability. The difference in specimens were kept in heat for 48 h then the
height h1-h2 is the filling height. If the concrete flows specimens were kept in the ambient temperature till
freely as water, at rest it will be horizontal. The the test was conducted.
acceptable value of filling height is 30 mm maximum
as suggested by European standards. The strength Results and Discussion
studies were carried out at both 7th and 28th day for In this study, fresh and hardened properties of self-
these mix proportions. Figures 2-6 show the values compacting geopolymer concrete were investigated
of fresh properties of different molarities and Fig. 7 by using waste materials (silica fume, and blast
shows the compressive strength for various molarity. furnace slag) at different replacement rates for fly ash.
Based on these results molarity is fixed to 12 and self The ability of such studies is done according to
compacting geopolymer concrete mix proportions are appropriate criteria given by European standards.
shown in Table 3. Tables 4-6 show the mechanical In the present study, such properties of self-
strength obtained for different mixes. Curing compacting concrete produced with fly ash, silica
methodology used is ambient curing which was done fume and blast furnace slag were investigated based
478 INDIAN J. ENG. MATER. SCI., AUGUST 2015

on fresh concrete tests, specifically workability tests, had more superplasticizer dosage to provide same
and strength studies. slump flow than other mixtures and have shown good
slump-flow values15.
Fresh properties
T50 times as indicators of viscosity of highly
The slump flow values for self-compacting
flowable concrete mixes. Lower time indicates greater
geopolymer concrete with fly ash, silica fume and
flowability. The T50 was influenced by the dosage of
blast furnace slag immediately after the mixing
water and super plasticizer. The volume of coarse
process are presented in Table 5. In terms of slump
aggregate, a good flow ability with increasing fly ash,
flow, all self-compacting concrete mixtures exhibited
silica fume and blast furnace slag content till 30% is
satisfactory slump flows in the range of 660–690 mm,
observed, afterward flow time increases but with
which is an indication of a good deformability. Higher
some bleeding and segregation. Good relationship
replacement levels have shown better slump values
exists between slump flow and T50 for various mixtures
which can be inferred from Table 5. Also it can be
of self-compacting geopolymer concrete which can be
seen that blast furnace slag series have shown better
inferred from Figs 8 and 9. The root mean square
slump. When fly ash is replaced by mineral
value to be highly satisfied for all these relations.
admixtures, a lower dosage of super plasticizer
6% is required to maintain the flow. Fly ash series V-funnel test was performed to assess the
flowabilty and stability of the self-compacting
concrete. For self-compacting concrete a flow time
of 10 s is considered appropriate. The inverted cone
shape restricts flow, and prolonged flow time may
Table 4 – Limitations specified by European standards
Test methods Units Minimum Maximum
Slump flow mm 650 800
T50 s 0 7
L-box h2/h1 0.8 1
Fig. 3 – T50cm slump flow tests for various molarity V-funnel s 0 10
U-box h2-h1 0 30

Fig. 6 – U-box tests for various molarity


Fig. 4 – V-funnel tests for various molarity

Fig. 5 – L-box tests for various molarity Fig. 7 – Compressive strength for various molarity
USHAA et al.: SELF-COMPACTING GEOPOLYMER CONCRETE 479

Table 5 – Fresh properties of self compacting mixes

Water/ Slump V-funnel U-box L-box T50


Mixture no
powder (mm) (s) (h2-h1) mm (h2/h1) (s)
M1-Fly ash-100% 0.33 650 14 0.87 0.88 4.5
M2-Silica fume -5% 0.33 660 12 0.93 0.94 5
M3-Silica fume -10% 0.33 670 11.5 0.96 0.96 5.5
M4-Silica fume -15% 0.33 680 105 0.95 0.95 6.5
M5-GGBFS -10% 0.33 660 9.3 26 0.89 5.9
M6-GGBFS -20% 0.33 680 9.5 29 0.92 5.6
M7-GGBFS -30% 0.33 690 11 30 0.96 4.7

Table 6 – Compressive strength of replacement of fly ash by silica Table 8 – Flexural Strength of replacement of Fly ash by Silica
fume and slag mixes fume and Blast furnace slag mixes
Compressive strength, MPa Flexural strength, MPa
Mix Mix
14 days 28 days 14 days 28 days
M1 (0% replacement by GGBFS & SF) 32.89 34.67 M1 (0% replacement by GGBFS&SF) 3.86 4.2
M2 (10% replacement by GGBFS) 32.44 35.92 M2 (10% replacement by GGBFS) 3.71 4.43
M3 (20% replacement by GGBFS) 32 36.26 M3 (20% replacement by GGBFS) 3.5 4.63
M4 (30% replacement by GGBFS) 31.11 38.55 M4 (30% replacement by GGBFS) 3.26 4.82
M5 (5% replacement by SF) 33.33 36 M5 (5% replacement by SF) 4.1 4.28
M6 (10% replacement by SF ) 35.56 37.38 M6 (10% replacement by SF) 4.4 4.6
M7 (15% replacement by SF ) 33.78 35.56 M7 (15% replacement by SF) 4.2 4.3

Table 7 – Split tensile strength of replacement of fly ash by silica


fume and blast furnace slag mixes
Split tensile strength, MPa
Mix
14 days 28 days
M1 (0% replacement by GGBFS&SF) 3.25 4.2
M2 (10% replacement by GGBFS) 3.11 4.44
M3 (20% replacement by GGBFS) 2.97 4.56
M4 (30% replacement by GGBFS) 2.83 4.62
M5 (5% replacement bySF) 3.51 4.2
M6 (10% replacement bySF) 3.88 4.4
M7 (15% replacement bySF) 3.62 4.38
Fig. 8 – Relationship between slump flow and T50 (s) for silica fume
give some indication of the susceptibility of the mix better the flow of the concrete. The effect of increase
to blocking. Hence, the value obtained from the in the volume of coarse aggregate on the L-box test
experimental investigation is within the limit of indicated a significant decrease of the blocking ratio.
European standards. The increase in coarse aggregate The U-type test was used to assess the self-
causes the increase in V-funnel time. L-box ratio indicates compactability of concrete. If the concrete flows as
the filling and passing ability of each mixture. L-box free as water, at test it will be horizontal, so H1-H2 =
test is more sensitive to blocking. There is a risk of 0. Therefore the nearer this test value, the filling
blocking of the mixture when the L-box blocking height is to zero, better the flow and passing ability of
ratio is below 0.8. The obtained L-box values are the concrete. From the test result of self-compacting
tabulated in Table 5. From Fig. 10, it is also found concrete mix the value obtained for the U-box test is
that the filling capacity was more than 80%. within the limit of European standards.
If the concrete flows as freely as water, at rest it Mechanical properties
will be horizontal, so H2/H1 = 1. Therefore the nearer The compressive, split and flexure studies at
this test value, the ‘blocking ratio’, is to unity, the different ages are shown in the Tables 6-8. When
480 INDIAN J. ENG. MATER. SCI., AUGUST 2015

geopolymer concrete mixtures and the following


conclusions can be drawn from this study:
(i) All the self-compacting geopolymer concrete
mixes had a satisfactory performance in the fresh
state. Among the mineral admixtures considered,
the blast furnace slag series had a good workability
properties compared to silica fume series.
(ii) In general the use of mineral admixtures
improved the performance of self-compacting
concrete in fresh state and also avoided the use of
viscosity modifying admixtures.
(iii) The results of the mechanical properties
Fig 9 – Relationship between slump flow (mm) and T50 (s) for GGBFS (compressive, split and flexure) had shown
significant performance differences and the
higher compressive strength has been obtained for
slag series. Also the increase in replacement
levels has resulted in decrease in strength in
silica fume series. So 30% replacement of slag
levels could be of optimum consideration for
both flowability as well mechanical properties.
(iv) The evaluation of the mixes indicates the more
critical changes in self-compacting concrete occur
when there is an excess mineral admixture, less
fly ash, excess superplasticizer, and excess sand,
excess coarse aggregate.
Fig. 10 – L-box ratio (h2/h1) versus slump flow (mm) (v) The most critical test for evaluating the self-
compared to that of the control mixture with 100% fly compacting concrete loss seems to be slump flow;
ash increasing amounts of mineral admixtures i.e, robustness is assured if the parameters of
generally increases the strength. Thus, it is clear that these tests are satisfied.
the roles of slag and silica fume act as mineral (vi) Optimum water/powder ratio was chosen
admixtures increasing the compressive strength of as 0.33 by weight, the ratio greatly beyond or
slag and silica fume series. But, the blast furnace slag less than this may cause segregation and
series has shown the best performance both at blocking tendency in self-compacting geopolymer
14 days and 28 days at 30% replacements. This concrete mixtures.
is due to the physical nature of better packing and
fineness of it16. Higher replacements of slag also have References
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