SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-1)

Exam Dt. 30-03-2024

Chemistry

PART - A
ONE OR MORE THAN ONE ANSWER CORRECT:
1. The pressure and density of a diatomic gas  γ=7/5  change from  P1 , d1  to  P2 , d 2  reversibly and
adiabatically. If d 2 /d1 = 32, then the value of P2 /P1 can not be (mass of gas remains same)
a) 32 b) 64 c) 128 d) 256
1.a,b,d

Sol. P1V1 = P2 V2

P P
 1 = 2
d1 d2

P d  7/5
 2 =  2  =  32  = 128
P1  d1 

2. A 2.5 g impure sample containing weak monoacidic base (Molecular weight = 45) is dissolved in
100 ml water and titrated with 0.5 M HCl at 250 C. When 1/5th of the base was neutralized, the pH
was found to be 9 and at equivalent point, the pH of solution is 4.5 (log 2 = 0.3). Identify the correct
statements from the following.
a) K b of base is less than 10 6 .
b) Concentration of salt at equivalent point is 0.25 M.
c) Volume of HCl used at equivalent point is 100 ml.
d) Mass percentage of base in given sample is 80%.
2.b,c

Sol. BOH + H+ 

 B+ + H 2O
a mole b mole 0
1 a a
 At th run a 0
5 5 5
 At Equivalent point =0 =0 a mole

B 
Now, for 1/5th reaction, POH = P Kb + log  
 BOH 
a/5
or, 14  9  = P K b + log
4a/5
 P K b = 5.6  K b = 2.5  106
1

At equivalent point: P H  7  P K b + log C
2

1
Or, 4.5=7   5.6 + log C   C = 0.25 M
2
Now, n HCl used = n B+ formed

Or,
V  0.5
=
100 + V   0.25  V = 100 ml
HCl
1000 1000
Finally, n BOH takes = n HCl used for equivalent point
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-1)
Exam Dt. 30-03-2024
w 100  0.5
Or, =  w = 2.25 gm
45 1000
2.25
 Percentage purity of base =  100 = 90%
2.5

3. Consider the following statements:

If the Vander Walls parameters of two gases are given as:
a (atm L2 mol 2 ) b ( L mol1 )
Gas x: 6.5 0.056
Gas y: 8.0 0.011
Then
1: Vc  x  < Vc  y 
2: Pc  x  < Pc  y 
3: Tc  x  < Tc  y 
Select incorrect relation
a) 1 alone b) 1 and 2 c) 1, 2 and 3 d) 2 and 3
3.a,b,c

Sol. Pc Vc = RTc
a
Vc = 3b, Pc =
27b 2
8a
Tc =
27Rb

4. Incorrect order of rate of Electrophilic substitution reaction is

O
H H
N O N O
NH

NH

p q r s
a)q> p > s > r b) q > p > r > s c) p > q > r > s d) p > q > s > r
4.b,c,d

Sol. e density on benzene ring  rate of E.A.S.

5. Find out incorrect order for heat of combustion of these compounds.

X Y  Z
a) X > Y > Z b) Z > Y > X c) Y > Z > X d) Z > X > Y
5.a,b,d

1
Sol. Stability 
H.O.C
Stability order is X > Z > Y
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-1)
Exam Dt. 30-03-2024
6. The correct statement(s) regarding diborane  B2 H 6  is / are:
a) Maximum six hydrogen atoms can lie in a plane
b) Maximum six atoms can lie in a plane.
c) Bridging Hb  B  H b bond is stronger than terminal B  H t bond
d) Terminal Ht  B  H bond angle is greater than bridging H  B   H bond angle.
t b b
6.b,c,d

Sol.

a) Maximum 4H atoms can lie in a plane.

b) Maximum 6-atom can lie in a plane.
c) Bond strength  B    H b    B    B  H t 
 H > H B
 H

d) H t  B t  
b b 
7. Which of the following properties of the elements of group – II (alkaline earth metals) increase(s)
with increasing atomic number?
a) Stability of carbonates b) Solubility of hydroxides
c) Reactivity with water d) First ionization energy
7.a,b,c

Sol. Factual

8.  I3 . This reaction is set-up in aqueous medium we start with 1 mole I2 and 0.5 mole I
I2 + I  
in 1 L flask. After equilibrium is reached excess of AgNO3 gave 0.25 mole of yellow
precipitate.Equilibrium constant is_________.
a) 1.33 b) 2.66 c) 2.00 d) 3.00
8.a

Sol. I2 + I 
 I3
Initial 1 0.5 0
At eq. (1 – x) (0.5 – x) x
AgNO3 + I    Agl 
0.5  x = 0.25
x = 0.25
 I3  0.25
Kc = = = 1.33
 I2  I  0.75  0.25


9.  3Cu  NO3  2 + 2NO + 4H2 O,

In 3Cu + 8HNO3 
What is the equivalent mass of HNO3? The molecular mass of HNO3 = M amu
M 3M 4
a) M b) c) d) M
3 4 3
9.d
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-1)
Exam Dt. 30-03-2024

+5
Sol.  +5  +2
3Cu + 8HNO3   3Cu  NO3  + 2NO + 4H 2O
 
change in 0 state = 5  2  3
Now,
 8 HNO3 accept = 2  3 electrons
6 3
1 HNO3 accept = = electrons = n factor
8 4
M 4M
Hence, Equivalent weight = =
nf 3

10. The reaction given below is an example of

MeO NO 2 NO 2

NaOEt
 

a) E 2  elimination b) E1  elimination c)syn  elimination d) E1CB  elimination

10.d

MeO NO 2 MeO NO 2 NO 2

H H NaOEt
Sol. 
E1CB


Carbanion
 Stable 

COMPREHENSION:
A monoatomic ideal gas of two moles is taken through a cyclic reversible process starting from A as
V V
shown in figure. The volume ratios are B = 2 and D = 4.
VA VA

If the temperature TA at A is 270C, then answer the following questions.

 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-1)
Exam Dt. 30-03-2024

11. What is the temperature of gas at B?

a) 500 K b) 600 K c) 300 K d) 700 K
11.b

VA V
Sol. = B
TA TB

12. Calculate heat absorbed or evolved in the cyclic process.

a) 1200 cal b) 3000 cal c) 2500 cal d) 4000 cal
12.a
VC V
Sol. q = q AB + q BC + q C D + q DA = nCP  + nRTln + nCv  + nRTln A
VB VD
13. The process from B  C is
a) Adiabatic b) Isothermal c) Isochoric d)Isoentropic
13.b

Sol. At constant temperature process is isothermal.

COMPREHENSION:
A terpene that is contained in the oil of citronella is   farnesene. Refer to the structure to
  farnesene to answer the following questions.
2

1 4

14. What reaction conditions could be used to produce acetone from   farnesene?
a) H2SO4 and heat b)HBr
c) O3 and  CH 3  2 S d) dil. acid and cold conditions
14.c
Sol. On ozonolysis   farnesene give Acetone.
15. If   farnesene is reacted with an excesHBr, what would be the product?
Br
Br

a) b) Br Br
Br
Br Br
Br
Br
Br Br
Br

c) d) Br
Br Br
Br
Br
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-1)
Exam Dt. 30-03-2024
15.b

Br
2

Sol. 3 Exces
 
of HBr Br Br

1 4
Br

16. In the reaction of   farnesene with excess HBr, which double bond would be slowest to react?
a)The bond labelled 1 b) The bond labelled 2
c) The bond labelled 3 d)The bond labelled 4
16.d

Sol. At double bond labelled 4, Relatively less stable carbocation is formed during its reaction with HBr.

PART-B
MATCH THE MATRIX

1. Match the following as per the complete reaction shown by reactant in Column – I with respect to
that in Column - II
Column – I
A) 100 ml of 0.3 M H 2C2 O4 solution
B)50 ml of 0.6 M KHC2O4 solution
C) 50 ml of 0.6 M –HCl solution
D) 100 ml of 0.2 M H3PO4 solution
1.A  Q,S; B  P,Q,R,S; C  P,R; D  S
Column – II
P) 100 ml of 0.3 M –KOH solution
Q) 120 ml of 0.1 M KMnO4 solution in the
presence of H2SO4
R) 60 ml of 0.1 M KMnO4 solution in the
presence of H2SO4
S) 100 ml of 0.6 M – KOH solution

Sol.
Column – I Column – II
A) 100  0.3  2 = 60 for Q, S P) 100  0.3  1 = 30
B) 50 × 0.6  1 = 30 for P, S Q) 120  0.1  5 = 60
50 × 0.6  2 = 60 for Q, R
C) 50 × 0.6  1 = 30 for P, R R) 60  0.1  5 = 30
D) 100  0.2  3 = 60 for S S) 100  0.6  1 = 60

2. Match the following

Column – I Column – II
A) XeF5 P) d-orbital with zero nodal plane is used in hybridisation
B) PBr4 Q) Non-axial d-orbital is used in hybridisation
C) IOF3 R) Planar species
D) NH 2 S) Bond angle 1090 28' or less than 1090 28'
2.A  P,Q,R; B  S; C  P,S; D  R.
 SOLUTIONS FOR SENIORS RESHUFFLING FULL TEST (PAP-1)
Exam Dt. 30-03-2024

Sol.

 
sp3d3  hybridisation s + p x + p y + p z + d x 2  y2 + d z2 + d xy , d-orbital with zero nodal plane  d z2 
and non-axial d-orbital  d xy  used in hybridisation.
Planar.
Bond angle, 720

Hybridisation sp3  s + p x + p y + p z 
b)
Non – planar species
Bond angle 1090 28'

c) Hybridisation sp3d  s + p x + p y + p z + d z2 
d-orbital with zero nodal plane  d z2  used
Non – planar
Bond angle < 900
d)

Hybridisation sp3
Planar
Bond angle < 1090 28'