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Gayake and Desai  Smart Construction and

Smart Construction and Sustainable Cities (2024) 2:7


https://doi.org/10.1007/s44268-024-00031-9 Sustainable Cities

RESEARCH Open Access

Multi‑criteria decision making tool


for sustainable concrete production using
waste polyethylene terephthalate bottle cap
aggregates
Sudhir Bhaskarrao Gayake1,2*   and Atul K. Desai1

Abstract
The widespread use of concrete has raised concerns about the consumption of its raw materials. To address this issue,
researchers are actively exploring alternative waste materials to reduce the environmental impact of the construc-
tion industry. With this objective current study aims to investigate potential use of waste polyethylene terephthalate
(PET) bottle cap aggregates on the characteristics of concrete, both in its fresh and hardened states. Three variations
of modified waste PET aggregates (PETA): full (F), half (H), and quarter (Q), with the aim of evaluating their suitability
as replacements for conventional coarse aggregates (CCA) was examined. The research assesses the effects of dif-
ferent PETA proportions (3%, 5%, and 8%) on concrete workability, compressive strength, splitting tensile strength,
and flexural strength. The findings reveal that PETA-F and PETA-H adversely affect workability, primarily due to their
larger surface area and difficulty in achieving homogeneous blending with other ingredients. In contrast, PETA-
Q exhibits superior workability. The use of PETA-Q results in reduced compressive strength due to its smaller size
and limited load-bearing capacity. Notably, PETA-H demonstrates improved compressive strength after 28 days. Inter-
estingly, PETA-Q shows enhancements in splitting tensile and flexural strength, making it the top-performing alterna-
tive for fresh and hardened concrete properties. Overall, this research indicates that PETA-Q is most suitable for sus-
tainable concrete production. Furthermore, the application of a multi-criteria decision-making tool validates our
findings and determines that a 5% replacement of CCA with PETA is optimal, as higher replacements result in strength
reduction. The utilization of PETA not only minimizes CCA consumption but also contributes to the development
of eco-friendly, sustainable concrete. This study underscores the potential of environmentally conscious concrete
and encourages the adoption of sustainable solutions for plastic waste management.
Keywords Polyethylene terephthalate, Concrete properties, Waste utilization, Analytical hierarchy process, Decision
making

1 Introduction
Concrete, as a fundamental construction material for
infrastructure development, wields substantial poten-
*Correspondence: tial for environmental impact. It ranks among the most
Sudhir Bhaskarrao Gayake extensively employed man-made substances on a global
gayakesudhirst@sanjivani.org.in
1
Department of Civil Engineering, Sardar Vallabhbhai National Institute scale, prompting growing concerns about the over con-
of Technology, Surat 395007, India sumption of raw materials in concrete manufacturing.
2
Department of Structural Engineering, Sanjivani College of Engineering, Comprising two pivotal constituents - an inert filler and
Savitribai Phule Pune University, Kopargaon 423603, India
a binding agent - concrete forms a chemically interlinked,

© The Author(s) 2024. Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which
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licence, visit http://creativecommons.org/licenses/by/4.0/.
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 2 of 17

rigid structure. Cement serves as the critical binding bottles has led to a surge in demand, consequently mak-
component, while coarse and fine aggregates provide ing their waste management a pressing concern [6].
the load-bearing strength. The worldwide construction In recent years, several experiments have explored
industry is actively investigating alternative materials for the replacement of natural aggregates in cementitious
concrete to mitigate reliance on conventional raw materi- composites with waste plastic aggregates. These experi-
als, given concrete’s diverse applications and adaptability. ments encompass various approaches, such as shredding
Recent research has demonstrated promising outcomes and altering the geometric characteristics of heated and
in employing polyethylene plastic waste as a feasible sub- melted PET plastic. Incorporating these waste plastics
stitute for traditional aggregates in concrete [1, 2]. in construction projects significantly reduces the density
Annually, the global production of non-recyclable plas- and overall weight of the resultant concrete structures
tic waste amounts to millions of tons, with the major- [7]. Reusing waste plastics in construction is regarded
ity ending up in landfills or contaminating the world’s as one of the most efficient disposal methods among the
oceans. In the context of India, plastic consumption has multitude of recycling management strategies. The inte-
experienced a substantial upswing, rising from 6,800 gration of used PET bottles as filler materials in concrete
kilo tonnes in 2010 to approximately 20,898 kilo tonnes offers opportunities for recycling these waste materials.
in 2021. This signifies a remarkable 2.28-fold increase in Many studies have explored the application of PET bottle
consumption between 2010 and 2016, as illustrated in fibers as structural concrete reinforcements, albeit at the
Fig. 1 [3]. cost of a reduction in primary strength and a concurrent
The adoption of plastic recycling entails energy con- improvement in flexibility [8].
sumption, thereby contributing to heightened envi- Numerous experimental investigations, employing
ronmental pollution on land, in the oceans, and in the life cycle assessment techniques [9, 10], have evaluated
atmosphere. The increased production of single-use concrete incorporating varying proportions of pow-
plastic items and the management of waste disposal have dered PET, indicating that a 5% substitution yielded the
emerged as significant global environmental challenges. most improved strength [11, 12]. These investigations
Plastics are classified into two primary categories based have also addressed performance, optimization [13], and
on polymer properties: thermosetting plastics and ther- chemical surface treatment of PET fibers, revealing their
moplastics [4]. Among them, PET (polyethylene tereph- role in enhancing concrete properties [14]. Notably, the
thalate) polymer stands out for its extensive application alteration of PET waste shape allows precise size match-
in packaging, including bottled drinking water, and vari- ing with natural sand, with an increase in PET aggregate
ous products due to its durable semi-crystalline nature, content leading to a decrease in mortar consistency [15].
exceptional mechanical strength, and robust resistance The use of PET waste and recycled materials has become
to hydrolysis, chemicals, and solvents, along with com- increasingly prevalent in lightweight mortars and light-
mendable tensile strength [5]. The ease of utilizing PET weight concrete [16, 17]. The geometric attributes of PET

Fig. 1 Plastic consumption annually from year 1990 to 2021 [3]


Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 3 of 17

fibers have a negligible impact on concrete workability, Numerous studies have assessed the properties of
while the use of thinner-diameter fibers enhances work- concrete incorporating PET-aggregates through experi-
ability [18]. Furthermore, studies incorporating 10% recy- mentation. Typically, raw PET obtained from recycling
cled PET granules as a replacement for fine aggregate programs has been manipulated or heated, and then
have demonstrated improvements in concrete properties, shaped artificially using a specific mechanism or post-
especially up to approximately 10% volumetric replace- processing method. This, in turn, consumes energy and
ment [19–22]. utilizes a minor amount of natural resources, contribut-
The incorporation of PET-aggregates in concrete, in ing to pollution. The fundamental purpose and innova-
any form, invariably leads to a reduction in compressive tion of this study are to evaluate the benefits of using
strength. However, the compressive strength develop- raw PET waste as a coarse aggregate in concrete, facili-
ment of concrete containing various PET-aggregates tating a sustainable construction process in the context
exhibits behavior akin to that of conventional concrete. of modern infrastructure development and smart cit-
No discernible differences in the mechanism of flex- ies. Replacement percentages of conventional coarse
ural failure were observed when PET waste concrete aggregates (CCA) with PET aggregates were set at 3%,
was used for monolithic and hybrid beams [23, 24]. The 5%, and 8% without any preheat treatment or shredding.
utilization of PET bottle shredding material as a substi- PET waste in the form of full bottle caps was adopted
tute for fine aggregate yielded improved workability and as a replacement for CCA, capitalizing on the natural
strength at lower replacement percentages. Neverthe- shape of the bottle cap body and configuring it into half
less, an increase in the percentage of replacement corre- and quarter shapes. Additionally, the Analytical Hierar-
lated with a decrease in strength [25–27]. The inclusion chy Process (AHP), a Multi-Criteria Decision Making
of Bakelite waste in concrete represents a sustainable (MCDM) tool, is employed to recommend the most suit-
approach to waste management and promotes the use able concrete mix based on strength properties. Analytic
of environmentally friendly construction materials. Hierarchy Process (AHP) is often favored over other
However, as the replacement ratio for coarse aggregate Multi-Criteria Decision-Making (MCDM) tools due to
increases, the mechanical properties of the concrete its flexibility in structuring decision problems hierarchi-
deteriorate [28, 29]. cally, ease of use through pairwise comparisons ability to
In the contemporary world, decision-making is of handle both quantitative and qualitative criteria, trans-
paramount importance for achieving optimal outcomes parency in decision-making, and widespread acceptance
while balancing conflicting criteria to attain specific and application across various applications. The find-
objectives. To tackle this challenge, advanced techniques ings aim to provide a more sustainable material for the
such as Multi-Criteria Decision Making (MCDM) tools production of environmentally friendly concrete with
have been developed, leading to a paradigm shift in civil minimal alteration of waste and a reduction in post-pro-
engineering applications [30]. These tools facilitate the cessing treatment, thereby mitigating land and water pol-
evaluation of performance by considering technologi- lution. The management of these substantial quantities
cal, economic, and environmental factors. The objective of plastic waste, however, presents a significant environ-
of incorporating MCDM tools in civil engineering is to mental challenge.
advocate for a sustainable approach to material design in
the construction sector. These tools play a pivotal role in
determining concrete mixtures by considering various 2 Experimental program
inputs and selecting the most suitable alternative through 2.1 Mixture materials
different MCDM methods. The final decision-making Portland pozolana cement (PPC) of 43 grade, the most
process hinges on the alternatives presented [31]. Some common cementitious component for concrete, has been
studies introduce an intelligent multi-criteria decision- employed in the design. For concrete making, 20mm-
making model to handle complex construction scenarios, sized quarry stones are employed as conventional coarse
incorporating expert judgments. It proposes a decision aggregates (CCA) together with natural river sand as fine
hierarchy for method selection and demonstrates the aggregate (FA). Before being used in the concrete mix,
models feasibility, providing a valuable tool for decision- the material was first cleaned to eliminate presence of
making in underground construction [32]. Also a deci- any dirt. Prior test such as specific gravity, water absorp-
sion-making method for identifying optimal risk-control tion capacity was measured using Indian standard tech-
schemes for excavation engineering projects utilizing niques using IS 2386 (Part IV) – 1963 and IS 1489 (Part
the fuzzy VIKOR method and triangular fuzzy sets was I)-1991 [34, 35].
implemented based on engineering experience and envi- Table 1 represents physical properties of raw materials
ronmental factors [33]. used for mix design of concrete.
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 4 of 17

Table 1 Physical Properties of raw materials Figure 2 shows the geometry of modified PETA used in
Test Description Type of Material
the experimentation according to shape alterations. Here
the post processing, per-heating or shredding of waste
Cement Sand Coarse PET Aggregates plastic is completely eliminated and the collected PET
Aggregate
bottle cap are directly used by making variation in the
Specific Gravity 3.15 2.62 2.74 1.23 surface configuration of PETA. The detailed work chart
Water absorption - 6.50 2.20 0.35 illustrating the experimental flow is represented in Fig. 3.
Capacity %
2.3 Design mix
Four mixture types with the natural CCA substituted
with PETA by 3%, 5% and 8% were chosen in order to
2.2 Modified PETA evaluate the performance of PET aggregate on the fresh
In this experimentation waste packaged drinking water and harden characteristics of concrete. Due to the differ-
bottle were collected from local restaurants and hotels ence in specific gravity between natural CCA and PETA,
and the bottle caps was segregated from collected waste. the volumetric design technique was adopted. Here, full
The segregated caps were then cleaned and open dried in cap PETA, half cap PETA, and quarter cap PETA con-
an enamel try for 24 h. The full (F) caps were then cut into crete was compared to Normal M25 concrete, which
half (H) and quarter (Q) shape approximately 28mm in served as the controls specimen.
diameter and adopted for experimentation by a replace- In the concrete mix design, each combination had
ment of 3%, 5% and 8% with CCA with varying shapes. the same kind of Portland pozolana cement (PPC) of

Fig. 2 PETA normal and cut shaped configurations a Full, b Half, and c Quarter

Fig. 3 Flow chart of the experimentation work


Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 5 of 17

43 grade and river sand as fine aggregate. Based on the splitting tensile strength was then calculated for
findings of earlier tests on the core raw materials, an each mix blend adopted for experimentation.
experimentation mix design for M25 concrete adopting iii. Flexural strength (FS)-A total of 24 beam speci-
IS10262:2009 [36] was designed and implemented. In mens (100mm × 100mm × 500mm) were cast,
Table 2, the weighted average mix proportions for each cured for 28 days and tested for two-point load and
mix for a concrete volume of one cubic meter are listed. simply supported condition. The necessary fail-
The concrete mix was created with a water cement ratio ure load was then progressively and consistently
of 0.50 and a target strength of 25 MPa at 28 days. The applied at a standard rate. During testing, fracture
proportions of cement, fine aggregate, coarse aggregate, patterns were noted and crack initiation and prop-
and water/cement followed the formula 1:2.09:2.83:0.5 agation were observed visually. The experimental
for the concrete mix design. summarized test findings are presented in Table 3
and its significance is explained in the discussion.
2.4 Test performed

i. Workability- Utilizing the slump cone test method


[37], flow ability of each freshly mixed mixture 3 Results and discussions
was assessed. Concrete was poured into a surface- 3.1 Workability
leveled slump cone during the mixing of various Figure 4 illustrates the results of the slump test con-
concrete blends, and it was then tamped for every ducted on the investigated concrete mixtures. Notably,
interval of concrete filling. The slump value was an increase in the percentage of PETA (Polyethylene
then calculated as the height difference between Terephthalate Aggregates) replacement in the mix cor-
the cone and sample after the cone had been lifted. relates with a reduction in the slump value. This obser-
ii. Compressive (CS) and Splitting tensile strength vation aligns with prior research findings reported by
(STS) - After 28 days of fully immersed water-cur- Edmund et al. [7], Lee et al. [14], and Islam et al. [5]. The
ing, tests for concrete compressive strength and diminished slump is attributed to the sub optimal bond-
splitting tensile strength were conducted. Typical ing between PETA and the concrete matrix, primarily
size molds were used for the experiments as per caused by the smooth surface texture of PETA. Initially,
[38]. Loading was then induced gradually and con- a controlled mixture was meticulously formulated to
stantly at a standard rate until the corresponding achieve a 100 mm slump. However, as the PETA replace-
failure load occurs. The compressive strength and ment percentage rises, both PEAT-F and PETA-H exhibit

Table 2 Mix proportion details ingredients


Mix Type Quantity of Ingredient PETA Shape Water/
3 3
Cement
Cement (kg/m ) Fine Coarse Aggregate (kg/m ) PET Aggregate (Approximately Nos.) ratio
Aggregate
(kg/m3) 3% 5% 8% 3% 5% 8%

CCA​ 383.2 800.94 1087.7 1087.7 1087.7 -- -- -- -- 0.50


PEAT-F 383.2 800.94 1055.0 1033.3 1000.6 2331 3886 6217 Full 0.50
PETA-H 383.2 800.94 1055.0 1033.3 1000.6 4662 7772 12,434 Half 0.50
PETA-Q 383.2 800.94 1055.0 1033.3 1000.6 9324 15,544 24,468 Quarter 0.50

Table 3 Summarized test results at 28-day strength


Test Results for % Compressive Strength (MPa) Split Tensile Strength (MPa) Flexural Strength (MPa)
PETA/ Shapes
3% 5% 8% 3% 5% 8% 3% 5% 8%

CCA​ 23.420 23.420 23.420 2.724 2.720 2.720 2.250 2.250 2.250
PETA-F 24.550 26.074 24.160 2.632 2.795 2.590 2.020 2.120 1.960
PETA-H 30.203 33.190 28.270 2.789 3.065 2.611 3.335 3.665 3.130
PETA-Q 28.527 31.348 26.780 3.059 3.325 2.840 4.096 4.452 3.803
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 6 of 17

Fig. 4 Observed slump variation for PETA concrete

a declining slump. This decrease in workability can be in compressive strength when compared to the control
ascribed to the larger diameter of PEAT-F and PETA-H specimens and other combinations. These outcomes
aggregates and their inability to blend effectively with align with the experimental results reported by Bamig-
the other concrete matrix constituents. It becomes evi- boye et al. [4], Islam et al. [5], and Edmund et al. [7]. The
dent that an escalation in the surface area of PETA leads decrease in strength can be ascribed to the relatively
to a commensurate decrease in workability. Interestingly, smaller size of PETA particles within the concrete, which
the slump value for PETA-Q remains nearly identical to fails to effectively contribute to load shearing, conse-
that of the controlled concrete, signifying excellent work- quently leading to early concrete crushing. The variation
ability. This congruence with results obtained by Bamig- in compressive strength of the designed PETA-modified
boye et al. [4] suggests that the shape of PETA-Q closely concrete mixes is graphically illustrated in Fig. 5. Regard-
matches that of the natural aggregate, thereby contribut- ing splitting tensile strength, a negative correlation with
ing to its favorable workability. Consequently, a smaller the surface area of PETA is observed, coupled with a
PETA surface area is associated with improved concrete marginal increase in response to changes in the shape of
flow, as evidenced in this study. PETA. This relationship is depicted in Fig. 6. The finer
surface texture and expanded surface area of PETA,
3.2 Compressive and splitting tensile strengths which result in sub optimal bonding at the interface and
The evaluation of concrete quality places significant the accumulation of free water, have also been identified
emphasis on its compressive strength, a pivotal and as factors contributing to the decline in tensile strength.
fundamental parameter. The results of the tests, as These observations align with the findings of Bamigboye
summarized in Table 3, indicate that the replacement et al. [4] and Islam et al. [16].
of Conventional Coarse Aggregates (CCA) with Poly- In comparison to the controlled mixture, PETA-Q
ethylene Terephthalate Aggregates (PETA) leads to an (Quarter PETA) exhibited a remarkable improvement in
enhancement in both compressive strength and splitting strength, ranging from 16 to 22%. After 28 days of cur-
tensile strength, but only up to a 5% substitution level. ing, PETA-Q achieved a peak strength of 3.325 MPa.
This observation concurs with the findings of Umasabor In this context, the smaller size and shape of PETA-Q
and Daniel. After a curing period of 28 days, it is note- particles serve as fibrous materials within the concrete
worthy that H-PA (Hybrid PETA Aggregates) exhibited mixture, augmenting its splitting behavior. A visual rep-
the highest compressive strength, reaching 31.348 MPa. resentation of the cylindrical specimen following the test
This superior performance is attributed to the efficient is presented in Fig. 7. Unlike PETA-Q and PETA-H (Half
packing of PEAT-F (Full PETA) and PETA-H (Half PETA) PETA), no indications of sudden, brittle concrete failure
in conjunction with CCA within the concrete matrix. In were observed, suggesting an enhancement in the dura-
contrast, PETA-Q (Quarter PETA) displayed a decrease bility of the fractured concrete. These observations align
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 7 of 17

Fig. 5 Compressive strength variation for PETA modified concrete

Fig. 6 Splitting tensile strength variation for PETA modified concrete

with the findings of Fakhruddin et al. [24] and Aocharoen (Quarter PETA) exhibited an impressive maximum
et al. [27]. strength of 4.452 MPa, nearly double the strength of the
controlled beam. This enhancement can be attributed to
3.3 Flexural strength the smaller size and shape of PETA-Q particles, which
Figure 8 illustrates the flexural behavior of beams sub- function as fibrous materials within the mixture, reduc-
jected to a two-point load system using a Universal Test- ing the propagation of fractures and leading to improved
ing Machine, following 28 days of curing. The experiment bending strength. These findings contradict the results
involved untreated plain M25 grade concrete beam spec- reported by Umasabor and Daniel [11], Islam et al. [16],
imens, measuring 100 mm × 100 mm × 500 mm, without and Fakhruddin et al. [24].
reinforcement. These beams were treated with PETA to When comparing PETA-Q to PETA-H (Half PETA) and
evaluate the bending strength of the concrete. The results PEAT-F (Full PETA), PETA-Q demonstrated a 26% and
presented in Fig. 8 reveal that, after 28 days, PETA-Q 90% increase in flexural strength, respectively. Notably,
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 8 of 17

the flexural strength of PEAT-F was found to be compa- the fracture dispersion pattern induced during testing. It
rable to that of the controlled beam, implying a higher is evident that in the controlled beam, the fracture initi-
likelihood of voids in the concrete, which compromise ates at the center and follows a vertical bending crack,
the cohesion of the matrix. Figure 9 provides a visual while in the PETA-modified concrete beam specimen,
representation of the tested beam specimens, along with the crack moves toward the support as inclined crack.

Fig. 7 Tested specimens for splitting tensile strength a M25 Controlled concrete b Full cap PETA concrete c Half cap PETA concrete and d Quarter
cap PETA concrete

Fig. 8 Flexural strength variation for PETA modified concrete

Fig. 9 Crack initiation and pattern of failure a M25 Controlled concrete b Full cap PETA concrete c Half cap PETA concrete and d Quarter cap PETA
concrete
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 9 of 17

Furthermore, it can be observed that the crack initially the pairwise comparison matrix being equal to 1.
displays a semi-vertical orientation up to one-third of the An excerpt of the pairwise matrix for the compres-
beam’s depth on the tension side before transitioning into sive strength parameter is provided in Table 4 with
a shear fracture-like behavior below the point load. matrix size M = 12.
ii. The geometric mean of each row in the compari-
4 Application of analytical hierarchy process son matrix is computed, and the geometric means
for selecting best concrete mix design of the rows are normalized to ascertain the rela-
The Analytical Hierarchy Process (AHP) is a critical tive normalized weight of each attribute as given in
tool in the selection of the most suitable concrete mix Eqs. 1 and 2.
parameter from a range of available options. Figure 10
M 1/M
illustrates the hierarchical structure of the AHP analysis Geometric mean (GMj ) = [ bij] (1)
used to identify the best mix parameter for PETA con- j=1

crete, considering various criteria and alternatives. These


tools are instrumental in prioritizing available options Weight of each attribute = Wj = GMj /
M
GMj (2)
and facilitating the selection of the optimal decision from
j=1

among the accessible alternatives. The AHP approach iii. Three PETA aggregate shapes were tested for com-
adheres to a hierarchical structure, with the ultimate goal pressive, splitting tensile, and flexural strength
positioned at the top, criteria at the second level, and of concrete, with comparisons made to conven-
alternatives at the lowest level. AHP stands out as the tional concrete strength. By examining the weight
most widely employed mathematical model for resolv- obtained for the compressive strength of concrete,
ing intricate and challenging decision-making problems. it becomes evident that PETA-H holds the highest
These tools excel in determining the highest priority weight (0.10) for the mix, positioning it as the top-
among the offered alternatives. Notably, when conflicts ranking choice for compressive strength.
arise in decision-making, one of the significant advan- iv. Analogous steps from i to iii were executed for
tages of AHP is its ability to rank options while adhering splitting tensile and flexural strength evaluations of
to the defined objectives. PETA concrete in comparison to conventional con-
The following steps were implemented to determine crete. The most suitable alternatives for each test
the weight of the mix for all the combinations tested in are highlighted in Tables 4, 5 and 6, and they are
the experimentation: visually presented in Figs. 11 and 12.
v. Figure 13 displays the maximum weights of alter-
i. In the initial AHP step, a pairwise comparison of natives for all tested mix combinations. The most
the experimental observations for attributes ‘i’ and appropriate mix parameter among the various
‘j’ as detailed in Table 3 is conducted, employing combinations experimented with is ranked, and
the normalization technique. When an attribute PETA-Q emerges as the top choice in the list.
is compared to itself, it is invariably assigned the vi. As depicted in Fig. 13, it is notably evident that
value 1, resulting in the main diagonal elements of the highest weight is attributed to the 5% replace-

Fig. 10 Schematic diagram showing hierarchy of AHP


Table 4 Pair-wise matrix for compressive strength property for all mix types
% PETA Compressive 3% 5% 8% Product of Weight
Strength (MPa) the row of the
CCA​ PEAT-F PETA-H PETA-Q CCA​ PEAT-F PETA-H PETA-Q CCA​ PEAT-F PETA-H PETA-Q mix
Gayake and Desai Smart Construction and Sustainable Cities

3% CCA​ 1 0.95 0.78 0.82 1.00 0.90 0.71 0.75 1.00 0.97 0.83 0.87 0.88 0.07
PEAT-F 1.05 1 0.81 0.86 1.05 0.94 0.74 0.78 1.05 1.02 0.87 0.92 0.92 0.08
PETA-H 1.29 1.23 1 1.06 1.29 1.16 0.91 0.96 1.29 1.25 1.07 1.13 1.13 0.09
PETA-Q 1.22 1.16 0.94 1 1.22 1.09 0.86 0.91 1.22 1.18 1.01 1.07 1.07 0.09
(2024) 2:7

5% CCA​ 1.00 0.95 0.78 0.82 1 0.90 0.71 0.75 1.00 0.97 0.83 0.87 0.88 0.07
PEAT-F 1.11 1.06 0.86 0.91 1.11 1 0.79 0.83 1.11 1.08 0.92 0.97 0.97 0.08
PETA-H 1.42 1.35 1.10 1.16 1.42 1.27 1 1.06 1.42 1.37 1.17 1.24 1.24 0.10
PETA-Q 1.34 1.28 1.04 1.10 1.34 1.20 0.94 1 1.34 1.30 1.11 1.17 1.17 0.09
8% CCA​ 1.00 0.95 0.78 0.82 1.00 0.90 0.71 0.75 1 0.97 0.83 0.87 0.88 0.07
PEAT-F 1.03 0.98 0.80 0.85 1.03 0.93 0.73 0.77 1.03 1 0.85 0.90 0.90 0.07
PETA-H 1.21 1.15 0.94 0.99 1.21 1.08 0.85 0.90 1.21 1.17 1 1.06 1.06 0.09
PETA-Q 1.14 1.09 0.89 0.94 1.14 1.03 0.81 0.85 1.14 1.11 0.95 1 1.00 0.08
Sum 13.81 13.17 10.71 11.34 13.81 12.40 9.74 10.32 13.81 13.38 11.44 12.07 12.08
Page 10 of 17
Table 5 Pair-wise matrix for split tensile strength property for all mix types
% PETA Split Tensile 3% 5% 8% Product of Weight
Strength (MPa) the row of the
CCA​ PEAT-F PETA-H PETA-Q CCA​ PEAT-F PETA-H PETA-Q CCA​ PEAT-F PETA-H PETA-Q mix
Gayake and Desai Smart Construction and Sustainable Cities

3% CCA​ 1 1.03 0.98 0.89 1.00 0.97 0.89 0.82 1.00 1.05 1.04 0.96 0.97 0.08
PEAT-F 0.97 1 0.94 0.86 0.97 0.94 0.86 0.79 0.97 1.02 1.01 0.93 0.93 0.08
PETA-H 1.02 1.06 1 0.91 1.03 1.00 0.91 0.84 1.03 1.08 1.07 0.98 0.99 0.08
PETA-Q 1.12 1.16 1.10 1 1.12 1.09 1.00 0.92 1.12 1.18 1.17 1.08 1.09 0.09
(2024) 2:7

5% CCA​ 1.00 1.03 0.98 0.89 1 0.97 0.89 0.82 1.00 1.05 1.04 0.96 0.97 0.08
PEAT-F 1.03 1.06 1.00 0.91 1.03 1 0.91 0.84 1.03 1.08 1.07 0.98 0.99 0.08
PETA-H 1.13 1.16 1.10 1.00 1.13 1.10 1 0.92 1.13 1.18 1.17 1.08 1.09 0.09
PETA-Q 1.22 1.26 1.19 1.09 1.22 1.19 1.08 1 1.22 1.28 1.27 1.17 1.18 0.10
8% CCA​ 1.00 1.03 0.98 0.89 1.00 0.97 0.89 0.82 1 1.05 1.04 0.96 0.97 0.08
PEAT-F 0.95 0.98 0.93 0.85 0.95 0.93 0.84 0.78 0.95 1 0.99 0.91 0.92 0.08
PETA-H 0.96 0.99 0.94 0.85 0.96 0.93 0.85 0.79 0.96 1.01 1 0.92 0.93 0.08
PETA-Q 1.04 1.08 1.02 0.93 1.04 1.02 0.93 0.85 1.04 1.10 1.09 1 1.01 0.08
Sum 12.4 12.8 12.1 11.07 12.4 12.1 11.0 10.19 1245 13.0 12.9 11.92 12.03
Page 11 of 17
Table 6 Pair-wise matrix for flexural strength property for all mix types
% PETA Flexural 3% 5% 8% Product of Weight
Strength the row of the
(MPa) CCA​ PEAT-F PETA-H PETA-Q CCA​ PEAT-F PETA-H PETA-Q CCA​ PEAT-F PETA-H PETA-Q mix
Gayake and Desai Smart Construction and Sustainable Cities

3% CCA​ 1 1.11 0.67 0.55 1.00 1.06 0.61 0.51 1.00 1.15 0.72 0.59 0.80 0.06
PEAT-F 0.90 1 0.61 0.49 0.90 0.95 0.55 0.45 0.90 1.03 0.65 0.53 0.72 0.06
PETA-H 1.48 1.65 1 0.81 1.48 1.57 0.91 0.75 1.48 1.70 1.07 0.88 1.18 0.09
PETA-Q 1.82 2.03 1.23 1 1.82 1.93 1.12 0.92 1.82 2.09 1.31 1.08 1.45 0.12
(2024) 2:7

5% CCA​ 1.00 1.11 0.67 0.55 1 1.06 0.61 0.51 1.00 1.15 0.72 0.59 0.80 0.06
PEAT-F 0.94 1.05 0.64 0.52 0.94 1 0.58 0.48 0.94 1.08 0.68 0.56 0.75 0.06
PETA-H 1.63 1.81 1.10 0.89 1.63 1.73 1 0.82 1.63 1.87 1.17 0.96 1.30 0.10
PETA-Q 1.98 2.20 1.33 1.09 1.98 2.10 1.21 1 1.98 2.27 1.42 1.17 1.58 0.13
8% CCA​ 1.00 1.11 0.67 0.55 1.00 1.06 0.61 0.51 1 1.15 0.72 0.59 0.80 0.06
PEAT-F 0.87 0.97 0.59 0.48 0.87 0.92 0.53 0.44 0.87 1 0.63 0.52 0.69 0.06
PETA-H 1.39 1.55 0.94 0.76 1.39 1.48 0.85 0.70 1.39 1.60 1 0.82 1.11 0.09
PETA-Q 1.69 1.88 1.14 0.93 1.69 1.79 1.04 0.85 1.69 1.94 1.22 1 1.35 0.11
Sum 15.70 17.49 10.59 8.63 15.70 16.67 9.64 7.94 15.70 18.03 11.29 9.29 12.53
Page 12 of 17
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 13 of 17

Fig. 11 Maximum weight of alternatives for a compressive strength and b split tensile strength

ment of Conventional Coarse Aggregates (CCA) strength of PETA-Q is observed from Table 4 and
with PETA. Furthermore, out of the three tests Fig. 11a the weight is equal to 0.096 which is almost
conducted, the maximum weight is observed for equals with 0.10 and therefore concluded as the
PETA-Q and PETA-H types of aggregates. The best suitable shape of PETA.
triangular shape of PETA contributes to effective
particle packing, rendering the concrete denser and
subsequently enhancing its strength. 4.1 Field applications of AHP
vii. Here it is evident that, though the compressive The application of Multi-Criteria Decision-Making
strength of PETA concrete is improved by adding (MCDM) tools can provide significant advantages in the
PETA-H the remaining two strengths have shown process of material selection for concrete production.
improvement using PETA-Q. Here the PETA of These tools enable the consideration of a multitude of
smaller shape acts like and fiber in the matrix factors, encompassing aspects such as strength, sustain-
resisting the crack initiation and thus improve- ability, physical properties, shape and size, and feasibil-
ment in the strength. If the weight for compressive ity, when making informed decisions. In particular, the
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 14 of 17

Fig. 12 Maximum weight of alternatives for flexural strength

Fig. 13 Ranking of most suitable concrete mix

Analytic Hierarchy Process (AHP) offers a systematic PET aggregates, the extent of substitution, and diverse
and structured approach to the comparative assessment mechanical strength properties. By harnessing the capa-
and prioritization of different formulations of PET- bilities of AHP, the primary objective is to discern the
based concrete, with a specific focus on its mechanical most suitable concrete mixture from the available alter-
strength. This comprehensive evaluation involves the natives, taking into account a range of critical factors.
examination of various variables, including the shape of Furthermore, the AHP methodology can be effectively
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 15 of 17

deployed in practical field applications, facilitating the cluded that PETA-Q, with an optimal 5% replacement
simplification of material selection processes and the of CCA, significantly enhances concrete strength and
refinement of material choices for concrete production. is ranked as the most suitable mix.

5 Conclusions This study underscores the positive impacts of


This experimental study aimed to enhance the perfor- incorporating PETA in concrete, leading to improved
mance of materials and structures while retaining the structural properties, addressing CCA scarcity, and
use of conventional coarse aggregates by integrating mitigating pollution stemming from discarded plastic
discarded PET bottle caps into structural concrete. A bottles through sound waste management practices.
significant impetus behind this investigation was the
promotion of sustainable concrete production and the 6 Limitations and scope for future work
realization of environmental benefits through the effec- The integration of PET waste in concrete production
tive utilization of this waste material. Furthermore, the may not be universally suitable for all types of cement.
study sought to validate the experimental findings by The results of the experimental investigation empha-
employing a multi-criteria decision-making optimiza- size that the replacement of conventional coarse aggre-
tion tool to address conflicting alternatives. The follow- gate with PET aggregates is most effective up to a 5%
ing conclusions are drawn from this research: replacement ratio. Beyond this threshold, a noticeable
decline in the mechanical properties of the concrete is
1. PETA (Polyethylene Terephthalate Aggregates) with observed. It’s worth noting that the tested concrete in
a smaller surface area exhibits workability compara- this study was plain cement concrete, and variations
ble to that of the controlled mix. This enables optimal may arise when dealing with reinforced cement con-
flow and improved compaction, resulting in denser crete (RCC). In light of the limitations identified in this
concrete with enhanced strength properties. PETA- research, the following areas merit consideration for
Q, in particular, maintains a similar slump as the con- future studies.
trolled mix, signifying that a larger surface area and a
higher percentage of PETA have a detrimental effect 1. Further experiments are recommended to explore the
on concrete workability, leading to harsher mixes and generalization of these findings to reinforced cement
reduced strength in the final product. concrete (RCC). This extension of the research can
2. Compressive strength (CS) improves up to a 5% provide insights into the behavior of PET aggregates
replacement of conventional coarse aggregate (CCA). in a more complex and structurally demanding envi-
In this context, PETA-H demonstrates the highest ronment.
CS value of 33.190 MPa. When combined with CCA, 2. The influence of different shapes of PET aggregates
PETA-H offers a mix with improved workability, on the mechanical properties of concrete can be sys-
reduced PETA surface area, and enhanced CS. Since tematically investigated by varying the shapes and
the CS values for PETA-H and PETA-Q are nearly conducting comprehensive tests. This approach can
identical, it can be inferred that PETA-F decreases yield a deeper understanding of how the geometry of
concrete strength by reducing density, aggregate con- PET aggregates impacts concrete performance.
tent, and ultimately resulting in lighter concrete. 3. Exploring the long-term durability of concrete
3. The addition of PETA has a marginal impact on split- incorporating PET aggregates and evaluating the
ting tensile strength (STS) and flexural strength (FS). economic feasibility of this approach for large-scale
In this scenario, PETA-Q outperforms PETA-F and applications are excellent avenues for further inves-
PETA-H. A maximum STS of 3.325 MPa, which is tigation. This area of study can delve into the long-
22.24% higher than the standard concrete cylinder term performance, resilience, and resistance of
after 28 days, was observed. Additionally, the maxi- PET-modified concrete in various environmental
mum FS is approximately double that of CCA con- conditions, providing valuable insights into its poten-
crete, measuring 4.45 MPa. This increase in strength tial for sustainable construction.
is attributed to the fact that smaller PETA shapes
function as fibrous materials, enhancing particle
Abbreviations
packing and overall strength. PET Polyethylene terephthalate
4. The application of a Multi-Criteria Decision-Making PETA Polyethylene terephthalate aggregates
CCA​ Conventional coarse aggregates
(MCDM) tool facilitated the ranking of the most
PETA-F Polyethylene terephthalate aggregates-full shaped
suitable mix type among the tested trial mixes, taking PETA-H Polyethylene terephthalate aggregates-half shaped
into consideration various test parameters. It is con- PETA-Q Polyethylene terephthalate aggregates-quarter shaped
Gayake and Desai Smart Construction and Sustainable Cities (2024) 2:7 Page 16 of 17

MCDM Multi criteria decision making 10. Chandran V, Raj TM, Lakshmanan T, Kumar MS (2015) Influence of differ-
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PPC Portland pozolana cement mance. Int J Eng 28(6 (C)):932–939. https://​doi.​org/​10.​5829/​idosi.​ije.​2015.​
FA Fine aggregates 28.​06c.​14
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Validation, Investigation, Writing - Original Draft. Dr. Atul K. Desai- Writing - ling6​010018
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