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Note # 12

Mass Transfer
April - 2005

Basic Concept
Ir. Mohammad Fahrurrozi, M.Sc., Ph.D.

Berbagai Satuan untuk Konsentrasi

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Notasi untuk Fluks pada Sistem Biner

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Hukum Ficks

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Prediction of Diffusivity Coefficient

• We often have to do mass transfer calculation

where DAB data is not available
• Prediction method (even it is rough) will be useful

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Diffusivity for Gas Phase

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Liquid Diffusivity

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Fluxes
Mass Flux:
ni =  i v i

Molar Flux:
N i = Ci v i

Diffusion Flux:
ji =  i (v i − v )
Relative to mass
average velocity v
J i = Ci (v i − v )

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Diffusion Flux:
j *i = i (vi − v* )
Relative to molar
average velocity v*
J i = Ci (vi − v* )
*

Fick’s law:
J i = −CD AB x A
*

x A
N Az = x A (N Az + N BZ ) − C.DAB .
z
diffusive part
Convective part

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Diffusion in a Gas Film

X= yAg
x

x yA0

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Reaksi Heterogen

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dN Az
N Az .S z − N Az .S z + z = 0 − =0
dz
Boundary Conditions:

at z = 0  xA = xA0

at z =   xA = 0 (instantaneous reaction)

Perhitungan selanjutnya tergantung target perhitungan.

•Cukup menghitung fluks molar ?
•Juga menghitung profile konsentrasi ?

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Perhitungan Fluks Molar

dN Az N Az = Konstant = N A0 = N A
− =0
dz

N Az = x A (N Az + N A2 z ) − C.DA− A2
dx A
dz

Dari stoikiometri:
1
N A2 z = − N Az
2
 N  dx
N Az = x A  N Az − Az  − C.DA− A 2 A
 2  dz

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C.DA− A2 dx A 
0
dx A
N Az = − N Az  dz = −C.DA− A 2
x
1 − A dz 0  x
xA0 1 − A
2 2

 
 1 
N Az = 2C.DA− A2 ln  
 1 − x A0 
 
 2 

 
2C.DA− A2  1 
N Az = ln  
  1 − x A0 
 
 2 

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Bagaimana Kalau yang Diperlukan adalah profile

konsentrasi ?

C.DA− A2 dx A
N Az = −
x
1 − A dz
2

dx A  x 
N Az z = −C.DA− A2  =2.C.DA− A2 . ln 1 − A  + C
x
1− A  2 
2

at z =   xA = 0
 0
N Az  = 2.C.D A− A 2 . ln 1 −  + C N Az = C
 2

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 x 
N Az z = 2.C.DA− A 2 . ln 1 − A  + N Az
 2 

 x 
N Az z = 2.C.DA− A 2 . ln 1 − A  + N Az
 2 

  x A0  z   x 
2C.DA− A2 ln 1 − 1 −  = 2.C.DA− A2 . ln 1 − A 
  2     2 

 z
 1− 
 x A0     x 
1 −  = 1 − A 
 2   2 

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Homogeneous Reaction

Liquid film

Gas
Bubble

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Bila diabaikan faktor kelengkungan:

z=

Film Cairan
− rA = k .C A
CA0
z=0

Rate of In. – Rate of Out. – Rate of Reaction = 0

N Az .S z − N Az .S z + z − k .C A .S .z = 0

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dN Az
− − k .C A = 0
dz
Hukum Fick dapat dituliskan:
dC A
N Az = C AV * − DAB
dz
Bila baik CA maupun V* sama-sama kecil, maka
bagian konveksi dapat diabaikan terhadap diffusi.

dC A d 2C A k
N Az  − DAB − .C A = 0
dz dz 2 DAB

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Non-Dimensional Equation:
Kecepatan pelarutan A?

d 2 A k . 2  =
z =
CA
− . A = 0  C A0
d 2 DAB

 A = C1. sinh (m. ) + C2 . cosh (m. )

k
m= .
DAB

Boundary conditions?
One case: at z = 0 CA = CA0 and at z =  CA = 0

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Derive expression
for flux at the
surface. Assume the
film is stagnant

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