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Chemistry - Units and Measurement
Chemistry - Units and Measurement
Table of Contents
Essential Knowledge................................................................................................................ 87
Self-Help.................................................................................................................................. 94
Let’s Check .............................................................................................................................. 94
Let’s Analyze ........................................................................................................................... 95
In a Nutshell ............................................................................................................................ 95
Keywords Index....................................................................................................................... 95
References .............................................................................................................................. 95
Big Picture in Focus: ULO2c ........................................................................................................... 97
Metalanguage ......................................................................................................................... 97
Essential Knowledge................................................................................................................ 97
Self-Help................................................................................................................................ 112
Let’s Check ............................................................................................................................ 112
Let’s Analyze ......................................................................................................................... 112
In a Nutshell .......................................................................................................................... 112
Keywords Index..................................................................................................................... 113
References ............................................................................................................................ 113
Big Picture in Focus: ULO2d ........................................................................................................ 114
Metalanguage ....................................................................................................................... 114
Essential Knowledge.............................................................................................................. 115
Self-Help................................................................................................................................ 127
Let’s Check ............................................................................................................................ 127
Let’s Analyze ......................................................................................................................... 127
In a Nutshell .......................................................................................................................... 128
Keywords Index..................................................................................................................... 128
References ............................................................................................................................ 128
Course Schedule ................................................................................................................... 131
Big Picture 3 ................................................................................................................................. 132
Big Picture in Focus: ULO3a ......................................................................................................... 132
Metalanguage ....................................................................................................................... 132
Essential Knowledge.............................................................................................................. 134
Self-Help................................................................................................................................ 140
Let’s Check ............................................................................................................................ 140
Let’s Analyze ......................................................................................................................... 140
In a Nutshell .......................................................................................................................... 141
College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
Self-Help................................................................................................................................ 205
Let’s Check ............................................................................................................................ 205
Let’s Analyze ......................................................................................................................... 206
In a Nutshell .......................................................................................................................... 206
Keywords Index..................................................................................................................... 207
References ............................................................................................................................ 207
Big Picture in Focus: ULO4c ......................................................................................................... 209
Metalanguage ....................................................................................................................... 209
Essential Knowledge ............................................................................................................. 210
Self-Help................................................................................................................................ 220
Let’s Check ............................................................................................................................ 220
Let’s Analyze ......................................................................................................................... 220
In a Nutshell .......................................................................................................................... 221
Keywords Index..................................................................................................................... 222
References ............................................................................................................................ 222
Big Picture in Focus: ULO4d ........................................................................................................ 225
Metalanguage ....................................................................................................................... 225
Essential Knowledge ............................................................................................................. 227
Self-Help................................................................................................................................ 236
Let’s Check ............................................................................................................................ 237
Let’s Analyze ......................................................................................................................... 237
In a Nutshell .......................................................................................................................... 238
Keywords Index..................................................................................................................... 238
References ............................................................................................................................ 238
Course Schedule ................................................................................................................... 239
College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
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College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
Assessment Task Submission Submission of assessment tasks shall be on 3rd, 5th, 7th
and 9th week of the term. The assessment paper shall
be attached with a cover page indicating the title of the
assessment task (if the task is performance), the
name of the course coordinator, date of submission and
name of the student. All submissions should be done
through Blackboard. It is also expected that you already
paid your tuition and other fees before the submission of
the assessment task.
Penalties for Late The score for an assessment item submitted after the
Assignments/Assessments designated time on the due date, without an approved
extension of time, will be reduced by 5% of the possible
maximum score for that assessment item for each day or
part day that the assessment item is late.
Return of Assignments/ Assessment tasks will be returned to you two (2) weeks
Assessments after the submission. This will be returned by email or via
Blackboard portal.
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College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
Re-marking of Assessment Papers You should request in writing addressed to the program
and Appeal coordinator your intention to appeal or contest the score
given to an assessment task. The letter should explicitly
explain the reasons/points to contest the grade. The
program coordinator shall communicate with the
students on the approval and disapproval of the
request.
3
College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
GSTC
Ronadora E. Deala, RPsy, RPm, RGC, LPT
ronadora_deala@umindanao.edu.ph
09212122846
Silvino P. Josol
gstcmain@umindanao.edu.ph
09060757721
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College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
CC’s Voice: Hello engineer in the making! Welcome to this course BCHE 111/L:
Chemistry for Engineers. This course deals with core concepts of
chemistry which are important in the practice of engineering profession
which includes generation of energy, the chemistry of engineering
materials, the chemistry of the environment and a special topic specific
to an engineering field of expertise.
CO CO stands for Course Outcomes. These are the skills that students are
expected to demonstrate at the end of the course to pass the subject. The
following are the COs of BCHE 111/L:
CO 1. Demonstrate understanding of chemistry in relation to the
generation of energy, the chemical principles and concepts of structures
and bonding of common engineering materials, and the chemical
processes that take place in the environment.
CO 2. Conduct experiments in relation to the models and concepts learned
in class.
Let us begin!
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College of Engineering Education
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Telefax: (082)296-1084
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Big Picture 1
Week 1-3: Unit Learning Outcomes (ULO): At the end of the unit, you are
expected to
Metalanguage
In this section, the most essential principles and concepts relevant to the study of
chemical safety to demonstrate ULO1a will be reviewed. Please refer to these
definitions in case you will encounter difficulty in understanding educational concepts.
Essential Knowledge
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College of Engineering Education
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This section points out the importance of taking a measurement, both in the
laboratory and in day–to–day life. Weight, volume, and temperature are examples of
variable measured by chemists.
An example of this is the ruler below. The line measures between 3 &
4. The black lines are the calibration lines. How can this value become more
accurate (closer to the true value)?
1 2 3 4
The ruler reads between 3.5 and 3.6, but the value seems closer to
3.6. It seems reasonable to call it 3.59. The statement below is the fundamental rule
of measurement.
“When recording a reading from a digital measuring device, record all the
digits shown. When recording a reading from a non-digital device, write down
all the digits that are known with certainty plus one that is estimated.”
Significant Figures
Not all of the figures in a value are always “significant”; that is, they are not
always included in the actual measured value.
The following are rules on how to deal with significant digits when rounding
numbers & using scientific notation.
1. Rounding
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College of Engineering Education
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Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
B. Rounding up: If the number just after the last significant figure (or digit)
is greater than 5, the significant figure is rounded up:
54.528 rounded to 4 digits would be 54.53
C. Even/Odd Rule: This is only used occasionally & is one of two ways
that are used in dealing with the number after the last significant figure
being equal to 5. Round the five so the last figure is even. For example,
54.625 rounded to 4 digits would be 54.62
54.635 rounded to 4 digits would be 54.64
Examples:
Round the following measurements. Report the answer with the proper units.
a. 107.77 degrees Celsius to 4 digits Þ 107.8°C
b. 6.53300 grams to 5 digits Þ 6.5330 g
c. 28.6 grams/milliliter to 2 digits Þ 29 g/mL
d. 48.67305 nanometers to 6 digits Þ 48.6730 nm
2. Scientific Notation
Examples:
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College of Engineering Education
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Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
Examples:
Give the number of significant figures in each of the following values:
a. 69.4703 mL Þ 6 significant figures
b. 0.00071 g Þ 2 significant figures; the leading zeros are not important
c. 0.03300 s Þ 4 significant figures; the trailing zeros are important
Fundamental (or base) quantities are the simplest types of quantities and cannot
be reduced further.
Quantity Unit
1. Length, L Meter, m
2. Mass, m, or Weight, W Kilogram, kg
3. Time, t Second, s
4. Temperature, T Kelvin, K
5. Electric current, I Ampere, A
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College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
A system of units is a complete set of units, both fundamental and derived, for all
kinds of quantities.
1. English system
2. Metric system (SI)
Powers (or factors) of ten is used to express very large or very small numbers,
more conveniently, in an abbreviated form. This is done by the use of prefixes (see
Table 3).
Conversions between and within the system of units can be made by use of a very
few conversion factors.
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College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
Conversion factors (cf) are the factors that relate 2 different units of the same
quantity (unit1 and unit2).
Table 3. Table below shows the names, symbols, and numerical values of the
prefixes.
I Length
1 kilometer (km) = 0.6214 mile (mi)
1 meter (m) = 100 centimeter (cm) = 39.37 inches (in) = 3.28 feet (ft)
1 mile (mi) = 5280 feet (ft) = 1760 yards (yd) = 1.6093 km = 1609.3 m
1 inch (in) = 2.54 cm = 25.4 mm
1 yard (yd) = 3 feet (ft) = 0.9146 m
1 feet (ft) = 12 inches (in)
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Telefax: (082)296-1084
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1 angstrom (Å) = 10 – 10 m
II Mass/Weight
1 kilogram (kg) = 2.205 pounds (lb)
1 pound (lb) = 453.6 g = 0.4536 kg
1 pound (lb) = 16 oz
1 oz = 28.35 g
1 metric ton (T) = 1000 kg = 2205 lb
1 US short ton = 907 kg = 2000 lb
1 British long ton = 1016 kg = 2240 lb ;
1 atomic mass unit (u) = 1.6606 x 10 – 27 kg
III Volume
1 liter (L) = 1000 milliliter (mL) = 10 – 3 m3 = 1 dm3
= 1.06 quarts (qt) = 0.0353 cubic ft (ft3)
1 mL = 1 cubic cm (cc or cm3)
1 US gallon (gal) = 3.785 L
1 US gallon (gal) = 4 quarts (qt) = 8 pints (pt)
1 quart (qt) = 32 fluid ounces (fl oz) = 0.946 liter (L)
1 fl. oz. = 29.6 mL
1 ft3 = 28.32 ; 1 m3 = 35.3 ft3
IV Area
1 yd2 = 0.836 m2 ; 1 cm2 = 0.155 in2 ; 1 km2 = 1.196 x 10 6 yd2
1 acre = 4840 yd2 = 4046.556 m2
1 hectare (ha) = 2.471 acres = 10,000 m2
V Energy
1 calorie (cal) = 4.184 joules (J)
1 British Thermal Unit (BTU) = 252 cal = 1055 J
VI Pressure
1 Pascal (Pa) = 1 kg/m•s2 ; 1kPa = 1000 Pa
1 atmosphere (atm) = 760 torr = 760 mm Hg = 101,325 Pa = 14.7 in Hg
Before introducing the base unit used to define mass, consider one important
issue, distinguishing the difference between weight and mass. Weight & mass are
not the same.
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Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
Weight measures the effect the gravity (attraction from another body) on an object. It
is related to mass (since it acts on it), yet weight varies from one planet & star to
another, because different objects pose different gravitational (attractive) forces on
the same mass. Therefore, the weight of an object will vary depending on where it is.
Volume, as used, is the amount of space occupied by matter. The most common
instruments or equipment for measuring volume of liquids are the graduated
cylinder, volumetric flask, burette, pipette, and syringe.
DENSITY
Alternate forms:
!
𝑉= "
or 𝑚 = 𝜌𝑉
The density of water at 4°C is 1.0000 g/mL or 1.0000 g/cm3 or 1000.00 kg/m3 or
62.4 lb/ft3.
Densities for liquids and solids are usually represented in terms of g/mL or
g/cm3. The density of gases, however, is expressed in terms of g/L.
The specific gravity (sp gr) of a substance is the ratio of the density of that substance
to the density of another substance, usually water at 4°C. The specific gravity tells us
how many times as heavy a liquid, a solid, or a gas is as compared to the reference
material. Since the density of water at 4°C is 1.00 g/mL, the specific gravity of a solid
or liquid is the same as its density in g/ml without the units.
𝑑𝑒𝑛𝑠𝑖𝑡𝑦 𝑜𝑓 𝑠𝑎𝑚𝑝𝑙𝑒
𝑆. 𝐺. 𝑜𝑓 𝑠𝑎𝑚𝑝𝑙𝑒 =
𝑑𝑒𝑛𝑠𝑖𝑡𝑦 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟
Alternate form:
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Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
When an insoluble solid object is dropped into water, it will sink or float,
depending on its density. If the object is less dense than water, it will float, displacing
a mass of water equal to the mass of the object. If the object is more dense than
water, it will sink, displacing a volume of water equal to the volume of the object.
This information can be utilized to determine the volume (and density) of irregularly
shaped objects.
TEMPERATURE SCALES
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scale in the United States outside the laboratory, defines the normal freezing &
boiling points of water to be exactly 32°F & 212°F, respectively.
Absolute Scales
T° R = T°F + 460 TK = T° C + 273
Self-Help: You can also refer to the sources below to help you
further understand the lesson.
Serway, R. (2014). Physics for Scientist and Engineers with Modern Physics (9th
ed) Australia: Cengage Learning.
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College of Engineering Education
2nd Floor, BE Building
Matina Campus, Davao City
Telefax: (082)296-1084
Phone No.: (082)300-5456/300-0647 Local 133
Let’s Check
For #s 1-3, round the following measurements. Report the answer with the proper
units.
1. 7.8177 rounded to the nearest tenth
2. 1.0643 rounded to the nearest hundredth
3. 3.8781 rounded to the nearest thousandth
4. Write 13.378162 correct to 4 significant digits.
5. Write 75.378212 correct to 3 significant digits/figures.
Let’s Analyze
Express the following numbers in scientific notation. (Note: When expressing
numbers in scientific notation, it is preferable to keep the value between 1 and 10 as
was done in the previous three cases.)
1. 1,181,995
2. 10,279,191
3. 873,490,238
4. 2,348,992,374
5. 49,810,823,012
In a Nutshell
1. Convert 312 oC to oR.
2. Convert 2.5 meters to yards.
3. Convert 4 liters to cm3.
4. Convert 149 cm2 to in2.
5. Convert 510 oR to K.
Keywords Index
Dimension Units
Conversion Factor Scientific Notation
References
Masterton, W. et al. (2018). Chemistry for Engineering Students (Philippine Edition).
Quezon City, Philippines: C&E Publishing, Inc.
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