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12 - Thermodynamics
12 - Thermodynamics
Types of Processes - Level I Q4. If an ideal gas undergoes two processes at constant
volumes V and V as shown in the pressure-
1 2
Q1. In thermodynamic processes, which of the following temperature (P-T) diagram, then:
statements is not true?
1. In an adiabatic process the system is insulated from
the surroundings.
2. In an isochoric process the pressure remains constant.
3. In an isothermal process the temperature remains
constant.
4. In an adiabatic process, P V =constant.
γ
3
) is compressed to 1
8
of
its volume adiabatically. If its initial pressure is P0, its
new pressure will be 1. V = V
1 2
1. 8 P0 2. V > V
1 2
2. 16 P0 3. V < V
1 2
4. V ≥ V
3. 6 P0 1 2
1.
2.
Match the following:
column-I column-II
P. Process-I (a) Adiabatic
Q. Process-II (b) Isobaric
R. Process-III (c) Isochoric
S. Process-IV (d) Isothermal
1. P → a , Q → c , R → d , S → b
2. P → c , Q → a , R → d , S → b 3.
3. P → c , Q → d , R → b , S → a
4. P → c , Q → d , R → b , S → a
4.
Page: 1
Recommended MCQs - 118 Questions -
Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q6. Which one of the following processes is reversible? Q11. In the following figures, four curves A, B, C and D,
1. Transfer of heat by radiation are shown. The curves are:
2. Transfer of heat by conduction
3. Isothermal compression
4. Electrical heating of a nichrome wire
27
of its original volume. If γ = , then the rise in
5
1. ( )
L1
1. 64 P L2
L2
2. 32 P 3. L1
3. P/64 2/3
4. ( )
L2
4. 16 P L1
Q10. The initial pressure and volume of a gas are P and Q13. A gas performs the minimum work when it
V, respectively. First, it is expanded isothermally to expands:
volume 4V and then compressed adiabatically to volume 1. Isochorically
V. The final pressure of the gas will be: 2. Isobarically
[Given: γ = 1. 5 ] 3. Adiabatically
1. 1P 3. Isothermally
2. 2P
3. 4P Q14. When a bicycle tyre suddenly bursts, the air inside
4. 8P the tyre expands. This process is:
1. isothermal
2. adiabatic
3. isobaric
4. isochoric
Page: 2
Recommended MCQs - 118 Questions -
Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q15. The pressure and volume of a gas are changed as Q20. A pressure (P) versus volume (V) graph is
shown in the P-V diagram. The temperature of the gas obtained for an ideal gas from state A to State B (as
will: shown in the figure below). Which of the following is
the correct statement?
Types of Processes - Level II Q21. A closed hollow insulated cylinder is filled with
gas at 0°C and also contains an insulated piston of
negligible weight and negligible thickness at the middle
Q16. The pressure and density of a diatomic gas
point. The gas on one side of the piston is heated to
(γ = 7/5) changes adiabatically from (P, d) to (P', d').
100°C. If the piston moves 5 cm, the length of the
Ifd'
d
= 32, then
P'
P
should be hollow cylinder will be:
1. 1/128 1. 13.65 cm
2. 32 2. 27.3 cm
3. 128 3. 38.6 cm
4. None of the above 4. 64.6 cm
Page: 3
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Work Done by a Gas - Level I Q24. One mole of an ideal gas expands at a constant
temperature of 300 K from an initial volume of 10 litres
Q22. The figure shows the P-V diagram of an ideal gas to a final volume of 20 litres. The work done in
undergoing a change of state from A to B. Four different expanding the gas is equal to
paths I, II, III and IV, as shown in the figure, may lead to (R = 8.31 J/mole-K)
the same change of state. 1. 750 joules
2. 1728 joules
3. 1500 joules
4. 3456 joules
1. 4P V 0 0
2. 2P V 0 0
3. P V
1
2
0 0
4. P V0 0
Page: 4
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q27. The pressure-temperature (P-T) graph for two Q30. In an adiabatic process, the graph for work done
processes, A and B, in a system is shown in the figure. versus change of temperature ∆T will be:
If W and W are work done by the gas in process A
1 2
1.
1. W 1 =W2
2. W 1 <W2
2.
3. W 1 >W2
4. W 1 =-W 2
Page: 5
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q32. 0.04 mole of an ideal monatomic gas is allowed to Q34. One mole of an ideal gas at an initial temperature
expand adiabatically so that its temperature changes of T K does 6R joules of work adiabatically. If the ratio
from 800 K to 500 K. The work done during expansion of specific heats of this gas at constant pressure and at
is nearly equal to constant volume is 5/3, the final temperature of the gas
will be:
1. (T + 2.4)K
2. (T – 2.4)K
3. (T + 4)K
4. (T – 4)K
1. 129.6 J
2. −129.6 J
3. 149.6 J
4. −149.6 J
2.
15
P0 V0
2
13 P0 V0
3. 2
3 P 0 V0
4. 2
1. (P A − PB )(VB − VA )
2. 1
2
(PB − PA )(VB + VA )
3. 1
2
(PB − PA )(VB − VA )
4. 1
(PB + PA )(VB − VA )
1. 6P 0 V0
2
2. 5P 0 V0
3. 3P 0 V0
4. 2P 0 V0
Page: 6
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Molar Specific Heat - Level I Q41. If n moles of an ideal gas is heated at a constant
pressure from 50°C to 100°C, the increase in the internal
Q37. An ideal gas goes from A to B via two processes, l energy Cp
of the gas will be:
and ll, as shown. If ΔU and ΔU are the changes in (
1 2 = γ and R = gas constant)
Cv
2.
100 nR
γ−1
50 nγR
3. γ−1
25 nγR
4. γ−1
1. ΔU > ΔU 1 2
2. ΔU < ΔU 1 2
3. ΔU = ΔU 1 2
4. ΔU ≤ ΔU 1 2
2
P(V2 − V1 )
1. 12 J 3. 3
2
P(V1 − V2 )
2. 24 J 4.
7
P(V1 − V2 )
2
3. 36 J
4. 0 J Q43. If the ratio of specific heat of a gas at constant
pressure to that at constant volume is γ, the change in
Q39. The incorrect relation is: internal energy of a mass of gas, when the volume
(where symbols have their usual meanings) changes from V to 2V at constant pressure, P is
γR
1. C P =
γ−1
1. R/(γ − 1)
2. C − C
P V = R
2. PV
Pf Vf −Pi Vi 3. PV /(γ − 1)
3. ΔU = 1−γ
4. PV(γ − 1)
4. C V =
R
γ−1
1. 100 J 2.
3
2. 225 J 5
3. 400 J 3. 3
4. 450 J 4. 5
Page: 7
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q45. The pressure in a monoatomic gas increases Q49. The volume (V) of a monatomic gas varies with its
linearly from 4 atm to 8 atm when its volume increases temperature (T), as shown in the graph. The ratio of
from 0.2 m to 0.5 m . The increase in internal energy
3 3
work done by the gas to the heat absorbed by it when
will be- it undergoes a change from state A to state B will be:
1. 480 kJ
2. 550 kJ
3. 200 kJ
4. 100 kJ
4. 235. 5°C
5
2.
2
1. T 4
3
0
Q51. A monoatomic gas is supplied with the heat Q very
2. 2T 0
slowly, keeping the pressure constant. The work done by
T0 the gas will be
3. 2
1. Q 2
4.
5 3
T0
2.
3
3
Q
5
is 4. 1
Q
5
1. Infinite
2. Zero
3. Negative
4. Remains constant
Page: 8
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q52. The variation of molar heat capacity at constant Q55. Under isothermal conditions, the volumes of ideal
volume C with temperature T for a monatomic gas is:
V gas A and actual gas B grow from V to 2 V. The increase
in internal energy:
1. will be the same in both A and B.
2. will be zero in both the gases.
3. of B will be more than that of A.
4. of A will be more than that of B.
3.
4. 1. 6 J
2. 12 J
Q53. The molar heat capacity in case of a diatomic gas 3. 18 J
Q 4. 24 J
if it does a work of when heat Q is supplied to it is:
4
1. 2
5
R Q58. Two cylinders, A and B, of equal capacity are
2. R
5 connected to each other via a stopcock. A contains gas at
2
a standard temperature and pressure. B is completely
3. R 10
3
evacuated. The entire system is thermally insulated. If
4. R
6
the stopcock is suddenly opened, then the change in
7
internal energy of the gas is:
Q54. Which of the following is true for the molar heat 1. 0
capacity of an ideal gas? 2. 5 J
1. It cannot be negative. 3. 1 J
2. It has only two values (C and C ). 4. 3 J
P V
Page: 9
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q59. We consider a thermodynamic system. If ∆U Q64. 1 kg of gas does 20 kJ of work and receives 16 kJ
represents the increase in its internal energy and W the of heat when it is expanded between two states. The
work done by the system, which of the following second kind of expansion can be found between the
statements is true? same initial and final states, which requires a heat input
1. ∆U = –W in an isothermal process of 9 kJ. The work done by the gas in the second
2. ∆U = W in an isothermal process expansion will be:
3. ∆U = –W in an adiabatic process 1. 32 kJ
4. ∆U = W in an adiabatic process 2. 5 kJ
3. -4 kJ
Q60. The latent heat of vaporisation of water is 2240 4. 13 kJ
J/gm. If the work done in the process of expansion of 1 g
is 168 J, then the increase in internal energy is: Q65. If a gas undergoes the change in its
1. 2408 J thermodynamic state from A to B via two different
2. 2240 J paths, as shown in the given pressure (P) versus volume
3. 2072 J (V) graph, then:
4. 1904 J
4. Q 1 + W1 = Q2 + W2
Q67. The work done by an ideal diatomic gas in its
sudden expansion is 20 J. The change in the internal
energy of the gas will be:
Q63. An ideal monoatomic gas (γ = ) absorbs 50 1. 20 J
5
Page: 10
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
γ−1
(T2 − T1 )
2. nR
γ−1
(T1 − T2 )
3. nR(T1 – T2)
4. Zero
1. 380 J
Q70. Find out the total heat given to diatomic gas in the 2. 500 J
process A→B→C : (B→C is isothermal) 3. 460 J
4. 300 J
2. P V + 2P V ln 2
1
2
0 0 0 0 Q74. If ΔQ and ΔW represent the heat supplied to the
3. P V + 2P V ln 2
5 system and the work done on the system, respectively,
0 0 0 0
2
then the first law of thermodynamics can be written as:
4. 3P V + 2P V ln 2
0 0 0 0
1. ΔQ = ΔU + ΔW
2. ΔQ = ΔU – ΔW
Q71. A unit mass of a liquid with volume V1 is 3. ΔQ = ΔW – ΔU
completely changed into a gas of volume V2 at a 4. ΔQ = –ΔU – ΔW
constant external pressure P and temperature T. If the where ΔU is the internal energy.
latent heat of evaporation for the given mass is L, then
the increase in the internal energy of the system is Q75. In the case of free expansion, when a sample of gas
1. Zero expands suddenly, the change in internal energy of the
2. P (V − V ) 2 1
gas will be:
3. L − P (V − V ) 2 1
1. Positive
4. L 2. Negative
3. Zero
4. May be positive or negative
Page: 11
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q76. An ideal gas is enclosed in an insulated cylinder. Q80. An ideal gas is taken through the process as shown
The piston is frictionless and attached to an ideal spring. in the figure. Then:
When the gas is heated, then:
Page: 12
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
1. 1000 J
2. zero
3. –2000 J
4. 2000 J
1. P V0 0
2. 2P V 0 0
Q85. In the cyclic process shown in the pressure-volume
3.
P0 V 0
2
P2 −P1
1. π( 2
)
2
V2 −V1
2. π( 2
)
3. π
4
(P2 − P1 )(V2 − V1 )
1. 10 J 4. Zero
2. 5J
3. 15 J
4. 20 J
Page: 13
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q86. ABCA is a cyclic process. Its P-V graph would be Q87. Which one of the following is correct for one
complete cycle of a thermodynamic process on a gas as
shown in the P-V diagram?
1. ΔE int = 0, Q < 0
2. ΔE int = 0, Q > 0
4. Δ E int
< 0, Q > 0
1.
Q88. An ideal gas is taken through the cycle
A → B → C → A as shown in figure below. If the net
2.
3.
1. -10 J
2. -30 J
3. -15 J
4. -20 J
Page: 14
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q90. In the P-V diagram shown, the gas does 5 J of Q93. The Carnot cycle (reversible) of a gas is
work in the isothermal process ab and 4 J in the represented by a pressure-volume curve as shown.
adiabatic process bc. What will be the change in internal Consider the following statements:
energy of the gas in the straight path from c to a? I. Area ABCD = Work done on the gas
II. Area ABCD = Net heat absorbed
III. Change in the internal energy in cycle = 0
Which of the statement(s) given above is/are correct?
1. 9J
2. 1 J
3. 4 J 1. I only
4. 5 J 2. II only
3. II and III
Q91. In a cyclic process, the internal energy of the gas 4. I, II and III
1. Increases
2. Decreases Q94. A cyclic process for 1 mole of an ideal gas is
3. Remains constant shown in the V-T diagram. The work done in AB, BC
4. Becomes zero and CA respectively is:
1. 0,
V1
RT2 ln( ) , R (T1 − T2 )
V2
2. R(T
V1
1 − T2 ), 0, RT1 ln
V2
3. 0,
V2
RT2 ln( ) , R (T1 − T2 )
V1
4. 0,
V2
RT2 ln( ) , R (T2 − T1 )
V1
1. 50 J
2. 20 J
3. 10 J
4. 80 J
Page: 15
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q95. The cyclic process of 2 moles of diatomic gas is Q99. A heat engine operates between the temperatures
shown in the figure. Which of the following statements of 300 K and 500 K. If it extracts 1200 J of heat energy
is correct? from the source, then the maximum amount of work that
can be done by the engine is:
1. 720 J
2. 520 J
3. 480 J
4. 200 J
Q97. A refrigerator whose coefficient of performance is Q103. An ideal gas heat engine operates in a Carnot
5 extracts heat from the cooling chamber at a rate of 250cycle between 227ºC and 127ºC. It absorbs 6 × 104 cals
J per cycle. For refrigeration, the work done per cycle is:
of heat at higher temperatures. The amount of heat
1. 150 J converted to work will be
2. 200 J
1. 4.8 × 104 cals
3. 100 J
4. 50 J 2. 2.4 × 104 cals
3. 1.2 × 104 cals
Q98. The efficiency of an ideal heat engine is less than 4. 6 × 104 cals
100% because of:
1. the presence of friction.
2. the leakage of heat energy.
3. unavailability of the sink at zero kelvin.
4. All of these
Page: 16
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
t1 −t2
t1 +273
2. t1 −t2
t2 +273
3. t1 +t2
4.
t1 +t2
t1 +273
1 to 2 is isothermal,
Heat Engine & Refrigerator - Level II 2 to 3 is adiabatic,
3 to 1 is adiabatic.
Q107. If a refrigerator extracts heat 'a' from the cold Such a process does not exist, because:
reservoir and 'b' is the heat released from the hot a. heat is completely converted to mechanical energy in
reservoir, then the work done on the refrigerant (system) such a process, which is not possible.
is: b. In this process, mechanical energy is completely
1. a + b converted to heat, which is not possible.
2. a − b c. curves representing two adiabatic processes don’t
3. a intersect.
4. b − a d. curves representing an adiabatic process and an
isothermal process don't intersect.
Q108. A reversible engine converts one-sixth of the heat 1. (a, b)
input into work. When the temperature of the sink is 2. (a, c)
reduced by 62°C, the efficiency of the engine is doubled. 3. (b, c)
The temperatures of the source and sink are 4. (c, d)
1. 80°C, 37°C
2. 95°C, 28°C
3. 90°C, 37°C
4. 99°C, 37°C
Page: 17
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Q112. A sink, that is, the system where heat is rejected, Q117. Two Carnot engines x and y are working between
is essential for the conversion of heat into work. From the same source temperature T and the same sink
1
which law does the above inference follow? temperature T . If the temperature of the source in
2
4. Third 1. η = η
x y
2. η < η
x y
Page: 18
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Thermodynamics (Physics) Contact Number: 9667591930 / 8527521718
Answers
Page: 19