WTA-23 Q.Paper

Sri Chaitanya IIT Academy.,India.
 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant

ICON Central Office - Madhapur - Hyderabad
Sec: Jr.C-120 2020_P2 Date: 10-01-23
Time:09.00PM to 12.00PM WTA-23 Max. Marks:198
10-01-2023_Jr.C-120
Jee-Adv (2020-P2)_WTA-23_Weekend Test Syllabus
MATHEMATICS : Tangents & Normals,Errors& Approximations (Complete)
PHYSICS : Thermodynamics: upto Different thermodynamics process

including polytropic process
CHEMISTRY T-1 : Group 13: upto Diborane

CHEMISTRY T-2 : Polymers (Complete)
Name of the Student: ___________________ H.T. NO:

Sri Chaitanya IIT Academy 10-01-2023_Jr.C-120_Jee-Adv(2020-P2)_WTA-23 Q.Paper
JEE-ADVANCE-2020-P2-Model
Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 198
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 6) Questions With Integer Answer Type 3 -1 6 18
Questions with Multiple Correct
Sec – II(Q.N : 7 – 12) 4 -2 6 24
Choice +1 partial marks
Questions with Numerical Value
Sec – III(Q.N : 13 – 18) 4 0 6 24
Answer Type
Total 18 66
CHEMISTRY:
Sec – II(Q.N : 25 – 30) 4 -2 6 24
Sec – III(Q.N : 31 – 36) 4 0 6 24
Answer Type
Total 18 66
MATHEMATICS:
Sec – II(Q.N : 43 – 48) 4 -2 6 24
Sec – III(Q.N : 49 – 54) 4 0 6 24
Answer Type
Total 18 66
Sec:Jr.C-120 Space for rough work Page 2

PHYSICS Max Marks: 66
SECTION-I
(INTEGER ANSWER TYPE)
• This section contains SIX (06) questions.
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual Numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 If the question is unanswered;
Negative Marks : -1 In all other cases
1. A 1000kg piston encloses 32g of oxygen gas at a temperature of 270 C in a vertical
cylinder of base area of 4m 2 . The air pressure outside is 1  105 Pa . The axis of the
cylinder is vertical, and the piston can move in it without friction. If heat to be transferred
574kilo joule
to the gas to raise the piston by 20cm is where N is an integer. Then ‘N’
N
 25 
is equal to.  R  J / mol / K 
 3 
2. Figure shows variation of internal energy (U) with the pressure (P) of 2.0 mole gas in
cyclic process abcda. The temperature of gas at c and d are 300 K and 500 K. Heat
absorbed in the process is 400 R ln X . Find the value of X .
U
a d
b c
P0 2P0 P

3. If 50 cal of heat is supplied to the system containing 2 mol of an ideal monatomic gas, the
rise in temperature in K is  R  2 cal/mol  K 
P0
Monoatomic
gas
4. A thermodynamic system is taken from an initial state i with internal energy U i  100 J to
the final state f along two different paths iaf and ibf, as schematically shown in the figure.
The work done by the system along the paths af, ib and bf are Waf  200 J , Wib  50 J
and Wbf  100 J respectively. The heat supplied to the system along the path
iaf , ib and bf are Qiaf , Qib and Qbf respectively. If the internal energy of the system
in the state b is U b  200 J and Qiaf  500 J , the ratio Qbf / Qib is
a f
b
i

5. A sample of ideal gas is expanded to twice its original volume of 1 m3 in a quasi-static

process for which P  V 2 with   3  105 Pa/m 6 as shown in Fig. Work done by the
expanding gas is x times 100000. Find x.
i l1
3
1m3 2m V
6. If for hydrogen C p  Cv  m and for nitrogen C p  Cv  n , where C p
and Cv refer to specific heats per unit mass respectively at constant pressure and constant
volume, (molecular weight of hydrogen = 2 and molecular weight of nitrogen = 14) Find
ratio m / n
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
•This section contains SIX (06) questions.
•Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
•For each question, choose the option(s) corresponding to (all) the correct answer(s).
•Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If only (all) the correct option(s) is(are) chosen; Partial Marks +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct;
Partial Marks: +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: -2 In all other cases.

7. An ideal gas is taken from state 1 to state 2 trough optional path A, B, C & D as shown in
P – V diagram. Let Q, W and U represent the heat supplied, work done & internal energy
of the gas respectively. Then
P
2
B
A C
1 D
 0,0 V
A) QB  WB  QC  WC B) QA  QD  WA  WD
C) W A  WB  WC  WD D) Q A  QB  QC  QD
8. C P is always greater than CV due to the fact that
A) No work is being done on heating the gas at constant volume
B) When a gas absorbs heat at constant pressure its volume must change so as do some
external work
C) The internal energy is a function of temperature only for an ideal gas
D) For the same rise of temperature, the internal energy of a gas changes by a smaller
amount constant volume than at constant pressure.
9. In the arrangement shown in Fig. gas is thermally insulated. An ideal gas is filled in the
cylinder having pressure P0   atmospheric pressure Pa  . The spring of force constant K
is initially unstretched. The piston of mass m and area S is frictionless. In equilibrium, the
piston rises up by distance x0 , then

m,S
P0
Kx0 mg
A) Final pressure of the gas is Pa  
S S
1 2
B) Work done by the gas is Kx0  mgx0
2
1 2
C) Decrease in internal energy of the gas is Kx0  mgx0  Pa Sx0
2
D) All of the above
10. A closed vessel contains a mixture of two diatomic gases A and B. Molar mass of A is 16
times that of B and mass of gas A contained in the vessel is 2 times of B. Which of the
following statements are correct?
A) Average kinetic energy per molecule of A is equal to that of B.
B) Root-mean-square value of translational velocity of B is four times that of A.
C) Pressure exerted by B is eight times of that exerted by A.
D) Number of molecules of B, in the cylinder, is eight times that of A.

11. An ideal gas undergoes the cyclic process shown in a graph below:
a
b
T1
Pressure (P)
T2
d c
Va Vd Vb Ve
Volume (V)
A) T1  T2 B) T1  T2
C) VaVc  VbVd D) VaVb  VcVd
12. One mole of a monoatomic ideal gas undergoes a cyclic process as shown in the figure
(where V is the volume and T is the temperature). Which of the statements is correct
T
II
I III
IV
A) Process I is an isochoric process

B) In process II, gas absorbs heat
C) In process IV, gas releases heat
D) Processes I and III are not isobaric

SECTION – III
(NUMERICAL VALUE TYPE)
• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
Numeric keypad in the place designated to enter the answer. If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered;
Zero Marks: 0 In all other cases..
13. When an ideal diatomic gas is heated at constant pressure, the fraction of heat energy
supplied which is used in doing work to maintain pressure constant is
14. In a cyclic process shown in the figure an ideal gas is adiabatically taken from B to A, the
work done on the gas during the process B  A is 30 J, when the gas is taken from
A  B the heat absorbed by the gas is 20J . The magnitude of change in internal energy
of the gas in the process A  B is:
A
P
20J
30J
B
15. A cylinder of ideal gas is closed by an 8 kg movable piston area 60 cm 2   as shown in
Fig. Atmospheric pressure is 100 kPa. When the gas is heated from 300 C to 1000 C ,
the piston rises by 20 cm. The piston is then fixed in its placed and the gas is cooled back
to 300 C . Let Q1 be the heat added to the gas in the heating process and Q2 the
heat lost during cooling. Then the value of 
 Q1  Q2  will be [answer the nearest
integer]
Piston
Gas

16. A thin tube of uniform cross-section is sealed at both ends. It lies horizontally, the middle
5 cm containing mercury and the two equal ends containing air at the same pressure p .
When the tube is held at an angle of 600 with the vertical direction, the length of the air
column above and below the mercury column are 46 cm and 44.5 cm respectively.
Calculate the pressure p in centimetre of mercury. (The temperature of the system is kept
at 300 C ).
17. A cylindrical chamber A of uniform cross section is divided into two parts X and Y by a
movable piston P which can slide without friction inside the chamber. Initially part X
contains 1 mol of a monoatomic gas and Y contains 2 mol of a diatomic gas, and the
volumes of X and Y are in the ratio 1:2 with both parts X and Y being at the same
temperature T. Assuming the gases to be ideal, magnitude of the work W=nT will be
done in moving the piston slowly to the position where the ratio of the volumes of X and
Y is 2:1. Write n  ln 2  0.70, R  8.3
P P'
A
X Y
18. Carbon monoxide is carried around a closed cyclic process abc in which bc is an
isothermal process, as shown in Fig. The gas absorbs 7000 J of heat as its temperature is
increased from 300 K to 1000 K in going from a to b . The magnitude of heat ejected by
the gas during the process ca is
b
P2
c
P1
a
V1 V2

CHEMISTRY Max Marks: 66

SECTION-I
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
19. Hybridization of Boron in B2 H 6 is SP x . Value of x is
20. Al4C3  H 2O  A  Al  OH 3 total number of 1090 bond angles in A is

21. H 3 BO3  x Oxidation number of B in x is
Cl
(CH 2 CH C CH 2 ) n
22. Synthetic rubber such as Neoprene obtained from
chloroprene which having x number of  bonds , y number of  bonds and z number of
lone pairs then x  y  z is
23. How many of the following are thermoplastic polymers
Polystyrene, Teflon, Neoprene, Buna-S, PVC, Dacron, Bakelite, Dextrin, Terylene
24. Number of lone pair of electrons present in melamine.

SECTION – II
25. How many of the following reactions produce H 2

A) NaBH 4  I 2 B) B  KOH
C) B2 H 6  2 NH 3 D) 2 Al  2 NaOH  6 H 2O
26. Al  OH 3  x Al2O3  y H 2O value of x & y are
A) 1,3 B) 2,3 C) 2,6 D) 3,4

27. The crystalline form of borax has
2
A) Tetra nuclear  B4O5  OH 4  -unit
B) All boron atoms in the same plane
C) Equal number of SP 2 and SP3 hybridized boron atoms

D) One terminal hydroxide per boron atom
28. Which of the following is incorrect statement?
A) Natural rubber is a linear polymer of cis - 2-methyl 1, 3 - butadiene.
B) Low density polythene is branched polymer
C) Low density polythene is abtained by the polymerization of ethane in the presence of
Ziegler – Natta catalyst
D) In the presence of an organic peroxides, alkenes and their derivatives undergo step
growth polymerization through free radical mechanism.

29. Which of the following are correctly matched?
A) Terylene 
O O
O CH2 CH2 C O C
n
B) PMMA 
C) PHBV 
O O
O O
O
D) Gutta-percha 
30. Which of the following are step growth co-polymers?

A) Buna-S rubber B) Dacron
C) Glypothal D) Nylon 6

SECTION – III
TWO decimal places.
31. Sum of  bonds + π bonds in inorganic benzene is
32. In Di borane molecule how many bonding electrons are ----?
33. B  H 2O  B2O3  H 2 2 mole of Boron release how many litre of H 2 gas
34. Formation of polyethylene from calcium carbide as below
CaC2 + 2H 2O  Ca  OH  2 + C 2H 2 C2H 2 + H 2  C2H 4
nC 2 H 4  ( CH 2  CH 2 )n The amount of polyethylene (in kg) obtained

from 3.2 kg of CaC 2
π
35. In the determination of M n by osmotic pressure experiment along y-axis and
c
concentration along x-axis graph, y – intercept is equal to 3  104 atm / gm / lit at 270C .
Number average molecular weight of the polymer is X  10 1 what is the X value.

36. Enthalpy of polymerization of Ethylene as represented by a
Reaction nCH 2  CH 2  ( CH 2  CH 2 ) n is -100 KJ / mole. Given
bond enthalpy of C=C is 600 KJ / mole . Enthalpy of
C - C bond (in KJ / mole) will be

MATHEMATICS Max Marks: 66
SECTION-I
Full Marks: +3 If ONLY the correct integer is entered;
Zero Marks: 0 If the question is unanswered;
Negative Marks: -1 In all other cases
37. The number of tangents to the curve y 2  2 x 3  4 y  8  0 which pass through 1, 2  is
3
38. If the sub-normal at any point on y  a1 n x n is of constant length, then the value of is
n
39. If the curves ay  x 2  7 and x3  y intersect orthogonally then the value of a is

40. If A is the area formed by the positive x  axis , and the normal and tangent to the circle
A
 
x2  y 2  4 at 1, 3 then the value of
3

41. Find the number of tangents to the curve y  cos  x  y   sin  x  y  ,  2  x  2 that
are perpendicular to the line 2 x  y  3 .
42. If the normal to the curve y  f  x  at x  0 is 3x  y  3  0 then the value of
x2 1
lim is  then k is
      
x 0 f x 2  5 f 4 x 2  4 f 7 x 2 k

SECTION – II
43. Equation of a line which is tangent to both the curves
y  x 2  1 and y = - x 2 is
1 1
A) y  2 x  B) y  2 x 
2 2
1 1
C) y   2 x  D) y   2 x 
2 2
44. If LT , L N , LST and LSN denote the lengths of tangent, normal, Sub-tangent and sub-
normal respectively of a curve y  f  x  at a point P  2009, 2010  on it. Then
LST 2010 LT LSN
A) = B)  constant
2010 LSN LN LST
2
2009  L  LN  LST
C) 1  LST LSN D)  T  
2010  LT - L N  LSN
45. Let the parabolas y  x 2  ax  b and y  x  c  x  touch each other at the point 1, 0  .
Then
A) a  3 B) b  2 C) c  2 D) b  c  3
46. The equation of the tangents to the curve y  x 4 from the point  2, 0  are given by
A) y  0 B) y  1  5  x  1
4096 2048  8 32 80  2
C) y   x  D) y   x 
81 27  3 243 81  3

47. Which of the following options is/are correct?
A) The approximate value of 49.02 is 7.0014
B) The approximate value of f  2.01 when f  x   4 x 2  5 x  2 is 28.21
C) If the height of a cylinder is equal to the radius. If an error of 2% made in the height,
then the percentage error in its volume is 6%
D) The period of oscillation, T of a pendulum of length of length, l at a place of
l
acceleration due to gravity is given T  2 . If the calculated length is 0.992 times
g
the actual length and if the value assume for g is 1.002 times the actual value. The
relative error in the computed value of T is -0.005
x
48. If tangents are drawn from a point P  2,0  to the curve 1  y2  which meet the
3
curve at A and B, then
 5
A) Acute angle between the tangents is tan 1  
 2 
B) AB  5
5 5
C) Area of PAB 
4
D) PAB is equilateral triangle.

SECTION – III
TWO decimal places.
49. There exists a chord of the parabola y  a 2 x 2  5ax  4 which touches the curve
1
y at the point x  2 and is bisected by that point. Find `a ' .
1 x
4 5
50. If the slope of the tangent to the curve 2 x  y3   
 x 2 1  x3 
at the point 1,  1 is t , then find the value of  t  .
[Note :  k  denotes the largest integer less than or equal to k .]
51. The angle of intersection of curves e x cos y sin x  3 sin y e y  1  0 and  
e x cos x sin y  sin x at origin is  . then 7 sin 2    _____ (where . is G.I.F]
 
52. The tangent to the curve y  x3 at the point M meet the curve again at N. Find the ratio
of gradient to the curve at N to the gradient at M.
53. If d denotes the distance between parallel tangents drawn to the curve
  13 
f  x   x  sin x where x   ,  , then find the number of possible values of
 6 6 
d  N  ?
8
54. A tangent is drawn to the curve y  in xy  plane at the point A  x0 , y0  where
x2
x0  2 , and the tangent cuts the x  axis at a point B. Then AB.OB (where O is
origin) is equal to ______

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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant

MATHEMATICS : Tangents & Normals,Errors& Approximations (Complete)

PHYSICS : Thermodynamics: upto Different thermodynamics process

CHEMISTRY T-1 : Group 13: upto Diborane

Name of the Student: ___________________ H.T. NO:

Sec:Jr.C-120 Space for rough work Page 2

1. A 1000kg piston encloses 32g of oxygen gas at a temperature of 270 C in a vertical

Sec:Jr.C-120 Space for rough work Page 3

Sec:Jr.C-120 Space for rough work Page 4

5. A sample of ideal gas is expanded to twice its original volume of 1 m3 in a quasi-static

Sec:Jr.C-120 Space for rough work Page 5

Sec:Jr.C-120 Space for rough work Page 6

Sec:Jr.C-120 Space for rough work Page 7

A) Process I is an isochoric process

Sec:Jr.C-120 Space for rough work Page 8

15. A cylinder of ideal gas is closed by an 8 kg movable piston area 60 cm 2   as shown in

Sec:Jr.C-120 Space for rough work Page 9

Sec:Jr.C-120 Space for rough work Page 10

CHEMISTRY Max Marks: 66

19. Hybridization of Boron in B2 H 6 is SP x . Value of x is

20. Al4C3  H 2O  A  Al  OH 3 total number of 1090 bond angles in A is

chloroprene which having x number of  bonds , y number of  bonds and z number of

lone pairs then x  y  z is

23. How many of the following are thermoplastic polymers

Polystyrene, Teflon, Neoprene, Buna-S, PVC, Dacron, Bakelite, Dextrin, Terylene

24. Number of lone pair of electrons present in melamine.

Sec:Jr.C-120 Space for rough work Page 11

25. How many of the following reactions produce H 2

26. Al  OH 3  x Al2O3  y H 2O value of x & y are

A) 1,3 B) 2,3 C) 2,6 D) 3,4

B) All boron atoms in the same plane

C) Equal number of SP 2 and SP3 hybridized boron atoms

Sec:Jr.C-120 Space for rough work Page 12

30. Which of the following are step growth co-polymers?

Sec:Jr.C-120 Space for rough work Page 13

nC 2 H 4  ( CH 2  CH 2 )n The amount of polyethylene (in kg) obtained

Number average molecular weight of the polymer is X  10 1 what is the X value.

Sec:Jr.C-120 Space for rough work Page 14

39. If the curves ay  x 2  7 and x3  y intersect orthogonally then the value of a is

42. If the normal to the curve y  f  x  at x  0 is 3x  y  3  0 then the value of

Sec:Jr.C-120 Space for rough work Page 15

Sec:Jr.C-120 Space for rough work Page 16

A) The approximate value of 49.02 is 7.0014

B) The approximate value of f  2.01 when f  x   4 x 2  5 x  2 is 28.21

then the percentage error in its volume is 6%

D) The period of oscillation, T of a pendulum of length of length, l at a place of

relative error in the computed value of T is -0.005

curve at A and B, then

D) PAB is equilateral triangle.

Sec:Jr.C-120 Space for rough work Page 17

Sec:Jr.C-120 Space for rough work Page 18

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