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Hempadur 15557 Base Msds
Hempadur 15557 Base Msds
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : metal industry, ships and shipyards.
Ready-for-use mixture : 15553 = 15557 3 vol. / 98021 1 vol.15554 = 15557 3 vol. / 98024 1 vol.
Identified uses : Industrial applications, Professional applications, Used by spraying.
1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Hempel Paints (Saudi Arabia) W.L.L. Hempel Paints (Qatar) W.L.L.
P.O. Box 1077, Dammam 31431 Block 212, Street 16, Salwa Industrial Area The Regional Poison Control Center, Dammam
Kingdom of Saudi Arabia P.O. Box 3484, Doha, State of Qatar (DPCC) Tel.: +966 55 388 0087 (24 hrs)
Tel.: +966 3 8471616 Tel: +974 44 55 9000
HAAD Poison and Drug Information Center
Hempel Paints (Saudi Arabia) W.L.L. Hempel Paints (Kuwait) K.S.C.C. Tel.: 800-424 (7:00 - 15:00 Sunday - Thursday)
P.O. Box 6783, Jeddah 21452 P.O. Box 3400, Safat 13034, Kuwait
Kingdom of Saudi Arabia Tel.: +965 4813366 / 808828 See Section 4 of the safety data sheet (first aid
Tel.: + 966 12 257 4567 measures).
Hempel Paints (Abu Dhabi) L.L.C.
Hempel Paints (Emirates) L.L.C. Plot No 37, Sector M-15,
Interchange 8, Al Dhaid Road, Mussafah Industrial Area,
Plot 698/G, Saja’a Area, P.O. Box 47006, Abu Dhabi,
P.O. Box 2000, Sharjah, United Arab Emirates
United Arab Emirates Tel: +971 2 555 2279
Tel: +971 6 531 0140
hempelae@eim.ae Hempel (Oman) L.L.C.
Ghala Industrial Area, Besides Komatsu,
Hempel Paints (Bahrain) S.P.C. Building No 1280, Way No 5217
P.O.. Box 997, Manama P.O. Box 1260, PC 112, Muscat
Kingdom of Bahrain Sultanate of Oman
Tel.: +973 17 728 668 Tel: +968 24592759
3.2 Mixtures
Product/ingredient name Identifiers % GHS Classification
middle molecular epoxy resin MMW 25068-38-6 ≥10 - ≤25 SKIN CORROSION/IRRITATION - Category 2
700-1200 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
xylene 1330-20-7 ≥5 - ≤10 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
Methylstyrenated phenol 68512-30-1 ≥5 - ≤10 SKIN CORROSION/IRRITATION - Category 2
SKIN SENSITIZATION - Category 1B
AQUATIC HAZARD (LONG-TERM) - Category 3
butan-1-ol 71-36-3 ≥3 - ≤5 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
trizinc bis(orthophosphate) 7779-90-0 ≥3 - ≤5 AQUATIC HAZARD (ACUTE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 1
n-butyl acetate 123-86-4 ≥1 - ≤3 FLAMMABLE LIQUIDS - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
Solvent naphtha (petroleum), light 64742-95-6 ≥1 - ≤3 FLAMMABLE LIQUIDS - Category 3
arom. SKIN CORROSION/IRRITATION - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ASPIRATION HAZARD - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 2
ethylbenzene 100-41-4 ≥1 - ≤3 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
- Category 2
ASPIRATION HAZARD - Category 1
1,2,4-trimethylbenzene 95-63-6 ≥1 - ≤2.8 FLAMMABLE LIQUIDS - Category 3
Version: 0.05 Page: 2/11
Safety Data Sheet
Hempadur 15557 Base
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
xylene EU OEL (Europe, 1/2022). [xylene, mixed isomers] Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
solvent naphtha (petroleum), light arom. EU OEL (Europe).
TWA: 120 mg/m³ 8 hours. Form: Tentativ
TWA: 25 ppm 8 hours. Form: Tentativ
n-butyl acetate EU OEL (Europe, 1/2022).
STEL: 150 ppm 15 minutes.
STEL: 723 mg/m³ 15 minutes.
TWA: 241 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
ethylbenzene EU OEL (Europe, 1/2022). Absorbed through skin.
STEL: 884 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 442 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. Be sure to use an approved/certified respirator or equivalent.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.
10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Irritant Rabbit - -
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
Methylstyrenated phenol Eyes - Mild irritant Rabbit - -
Skin - Irritant Rabbit - -
titanium dioxide Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
butan-1-ol Eyes - Severe irritant Rabbit - 24 hours 2 milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 milligrams
solvent naphtha (petroleum), light Eyes - Mild irritant Rabbit - 24 hours 100 microliters
arom.
n-butyl acetate Eyes - Mild irritant Rabbit - -
Respiratory - Mild irritant Rabbit - -
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
ethylbenzene Eyes - Mild irritant Rabbit - -
Respiratory - Mild irritant Rabbit - -
Skin - Mild irritant Rabbit - 24 hours 15 milligrams
zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
Skin - Mild irritant Rabbit - 24 hours 500 milligrams
Sensitizer
Product/ingredient name Route of exposure Species Result
middle molecular epoxy resin MMW skin Guinea pig Sensitizing
700-1200
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of exposure Target organs
butan-1-ol Category 3 Respiratory tract irritation
Category 3 Narcotic effects
n-butyl acetate Category 3 Narcotic effects
Solvent naphtha (petroleum), light arom. Category 3 Respiratory tract irritation
Category 3 Narcotic effects
1,2,4-trimethylbenzene Category 3 Respiratory tract irritation
toluene Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
ethylbenzene Category 2 - hearing organs
toluene Category 2 - -
Aspiration hazard
Product/ingredient name Result
Solvent naphtha (petroleum), light arom. ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Sensitization : Contains middle molecular epoxy resin MMW 700-1200, Methylstyrenated phenol. May produce an
allergic reaction.
Other information : No additional known significant effects or critical hazards.
12.1 Toxicity
Do not allow to enter drains or watercourses. Toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
middle molecular epoxy resin MMW Acute EC50 >100 mg/l Daphnia 48 hours
700-1200
Acute LC50 >100 mg/l Fish 96 hours
Methylstyrenated phenol Acute EC50 15 mg/l Algae 72 hours
Acute EC50 14 - 51 mg/l Daphnia 48 hours
Acute EC50 25.8 mg/l Fish 96 hours
titanium dioxide Acute LC50 >100 mg/l Daphnia 48 hours
Acute LC50 >100 mg/l Fish 96 hours
butan-1-ol Acute EC50 1328 mg/l Daphnia 96 hours
Acute LC50 1.376 mg/l Fish 96 hours
solvent naphtha (petroleum), light Acute EC50 19 mg/l Algae - Pseudokirchneriella subcapitata 96 hours
arom. (green algae)
Acute EC50 6.14 mg/l Daphnia - Daphnia magna 48 hours
Acute LC50 9.22 mg/l Fish - Oncorhynchus mykiss (rainbow 96 hours
trout)
trizinc bis(orthophosphate) Acute EC50 0.8 mg/l Algae 72 hours
Acute EC50 2.44 mg/l Daphnia 48 hours
n-butyl acetate Acute EC50 648 mg/l Algae 72 hours
Acute EC50 44 mg/l Daphnia 48 hours
ethylbenzene Chronic NOEC <1000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours
zinc oxide EC50 0.413 mg/l Daphnia 48 hours
LC50 0.1169 mg/l Fish 96 hours
Acute EC50 0.17 mg/l Algae - Pseudokirchneriella subcapitata 72 hours
- Exponential growth phase
Acute EC50 1 mg/l Daphnia - Pseudokirchneriella 48 hours
subcapitata - Exponential growth phase
Acute LC50 24600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours
Chronic EC50 0.136 mg/l Algae 72 hours
Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN no. Proper shipping name Transport hazard class(es) PG* Env* Additional information
IMDG UN1263 PAINT. (trizinc bis(orthophosphate)) 3 III Yes. The marine pollutant
Class mark is not required
when transported in
sizes of ≤5 L or ≤5 kg.
Emergency schedules
F-E, S-E
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
TOXIC TO REPRODUCTION - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
AQUATIC HAZARD (ACUTE) - Category 2 Calculation method
AQUATIC HAZARD (LONG-TERM) - Category 2 Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.