Marksupp Learning App Nitesh Devnani

Marksupp Learning App Nitesh Devnani

HALOALKANES AND HALOARENES

Marksupp Learning App Nitesh Devnani

 HALOALKANES

Marksupp Learning App Nitesh Devnani

Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
NUCLEOPHILIC SUBSTITUTION

Marksupp Learning App Nitesh Devnani

Characteristics of SN1 reaction:

● RDS is carbocation formation.

● Rate is directly proportional to stability of carbocation.
● Rearrangement possible
● Rate = k[R-L]¹
● First order reaction
● Unimolecular
● Polar protic solvent is preferred.

Marksupp Learning App Nitesh Devnani

Marksupp Learning App Nitesh Devnani
Characteristics of SN2 reaction:

● Rate = k[R-L]¹[ Nu ]¹
● Second order reaction
● Bimolecular
● Polar aprotic solvent is preferred.

● Rate of reaction is inversely proportional to steric crowding

Marksupp Learning App Nitesh Devnani

Marksupp Learning App Nitesh Devnani
METHODS OF PREPARATION

Marksupp Learning App Nitesh Devnani

Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
CHEMICAL PROPERTIES

1) Reaction with Aqueous KOH

Marksupp Learning App Nitesh Devnani

2) Reaction with moist Ag2O

Marksupp Learning App Nitesh Devnani

3) Reaction with NaCN/KCN

4) Reaction with AgCN

Marksupp Learning App Nitesh Devnani

5) Reaction with NaNO2/KNO2

6) Reaction with AgNO2

Marksupp Learning App Nitesh Devnani

7) Williamson ether synthesis

Marksupp Learning App Nitesh Devnani

Elimination Reactions

Marksupp Learning App Nitesh Devnani

E1 reaction

Characteristics of E1 reaction:
● RDS is carbocation formation.
● Rate is directly proportional to stability of carbocation.
● Rearrangement possible
● Rate = k[R-L]¹
● First order reaction
● High temperature are preferred.
● Saytzeff product dominates

Marksupp Learning App Nitesh Devnani

E2 reaction

Characteristics of E2 reaction:
● Single step process.
● rate=k[base][R-L]
● Order=2
● Rate is proportional to stability of transition state

Marksupp Learning App Nitesh Devnani

Marksupp Learning App Nitesh Devnani
HALOARENES

Marksupp Learning App Nitesh Devnani

Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani
Marksupp Learning App Nitesh Devnani