SEC: INSR_*CO-SC Date: 04-06-22

Time: 3 Hrs Max. Marks: 186

04-06-22_INSR.IIT_STAR CO-SC (MODEL-B)_JEE ADV_WAT-48_SYLLABUS
PHYSICS: PRESENT WEEK (80%): Current Electricity: Electric current
density drift velocity mobility, Ohm's law ohmic non-ohmic
conductors, resistance, resistivity and conductivity, colour coding of
resistors, series and parallel combination of resistors, Temperature
dependence of resistance & resistivity, Internal resistance of a cell,
emf and terminal potential difference combination of resistors in
series, parallel, Heating effect of current (fuse, bulb etc..)
(EXCLUDING: circuit problems for finding equivalent resistance),
PREVIOUS WEEK (20%): Refraction at curved surface ,Lenses and
combination of lenses
CHEMISTRY: PRESENT WEEK (80%): Alkyl halides: Preparation and Reactions
of alkyl halides, Mechanism of Nucleophilic Substitution reactions
(SN1, SN2 ), Mechanism of Nucleophilic Substitution reactions (SNi
and NGP), Polyhalogen compounds NCERT(Exclude haloform
reaction)
PREVIOUS WEEK (20%): Colour, Magnetic properties,
Catalytic properties, alloy and interstitial compounds
formation, oxides and oxoanions of metals, Preparation &
Properties of Potassium permanganate, Preparation &
Properties of Potassium dichromate

MATHEMATICS: PRESENT WEEK (80%): Definite Integration: Definite Integration,

Fundamental theorem of integral calculus, Properties of Definite
integrals, Limit as a sum,
PREVIOUS WEEK (20%): Revision Of Ellipse, Hyperbola &
Parabola
Narayana IIT Academy 04-06-22_INSR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-48_Q’P
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. When phenyl magnesium bromide reacts with tert - butanol, the product would be
A) Benzene B) phenol
C) ter - butyl benzene D) ter – butyl phenyl ether
20. Compounds (A), C8 H 9 Br , gives a white precipitate when warmed with alcoholic

AgNO 3 . Oxidation of (A) gives an acid (B), C8 H 9 O 4 .(B) easily from anhydride on

heating identify the compound (A).

A) B) C) D)
21. Identify products of the given reactions :

Reaction-1 
CH3CO2 Na
 Product
CH3CO2 H

Reaction-2 
CH3CO2 Na
 Product
CH3CO2 H

+ enantiomer
A)

enantiomer

B)

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Narayana IIT Academy 04-06-22_INSR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-48_Q’P

single product is obtained in both the reactions

C)

single product obtained in both the reactions

D)
22. What is the principal product of the following reaction ?

A) B) C) D)
23. What are reactant X and product Y in the following sequence of reactions ?

Reactant X Product Y

A)

B)

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Narayana IIT Academy 04-06-22_INSR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-48_Q’P

C)

D)
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
24. Which of the following substrates (reactants) give t-butyl bromide as major product
with HBr ?

A) B) C) D)
25.

Which is (are) correct statement(s) regarding above sequences ?

A)
B) Demercuration step (ii) to product ‘P’ takes place through free radical mechanism

C) Product ‘P’ is
D) X to Y takes place through E2 mechanism

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Narayana IIT Academy 04-06-22_INSR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-48_Q’P
26. Aryl halides are less reactive towards nucleophilic substitution reaction as compared
to alkyl halides due to
A) The formation of less stable carbonium ion
B) Resonance stabilization
C) Longer carbon-halogen bond
D) sp2 hybridized carbon attached to the halogen
27. Rate of SN2 will be negligible in :

Br

A) B) C) D)
28.

Product (A) and (B) are :

A) A = cis B) A = trans C) B = trans D) B = cis
29. The correct order of rate of S1 N is :
Cl

A) B)

C) D)
30. The correct statement(s) is / are
A) In manganate and permanganate , the   bonding takes place by overlap of p-
orbitals of oxygen and d-orbitals of manganese
B) Manganate and permanganate ions are paramagnetic
C) Manganate ion is green in colour and permanganate ion is purple in colour
D)Manganate and permanganate ions are tetrahedral
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Narayana IIT Academy 04-06-22_INSR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-48_Q’P
31. Which of the following statement(s) is/are correct when a mixture of NaCl and K 2Cr2O7
is gently warmed with conc .H 2 SO4
A) An deep red vapour is formed
B) Vapours when passes into NaOH solution gives a yellow solution of Na2CrO4
C) Some Chlorine gas is evolved
D) Chromyl chloride is formed
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32. Total number of products formed upon monochlorination of 2- methyl

butane(including Stereo isomers)

33. The total number of alkenes possible by dehydrobromination of 3-bromo-3-

isopropylhexane using alcoholic KOH is

34. In the following monobromination reaction, the number of possible chiral products is

(1.0 mole)

(enantiomerically pure)

35. Consider a titration of potassium dichromate solution with acidified Mohr’s salt

solution using diphenylamine as indicator. The number of moles of Mohr’s salt

required per mole of dichromate is_____

36. In order to oxidise a mixture of one mole of each of FeC2O4 , Fe2  C2O4 3 , FeSO4 and

Fe2  SO4 3 in acidic medium , the number of moles KMnO4 required is

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Sec: INSR.IIT_*CO SC(MODEL-B) WAT-48 Date: 04.06.22
Time: 3HRS 2016_P1 Max. Marks: 186
KEY SHEET
PHYSICS
1 C 2 A 3 C 4 B 5 C

6 ABCD 7 AD 8 ABD 9 ABC 10 ABC

11 ABD 12 AC 13 ABD 14 2 15 6

16 8 17 8 18 5

CHEMISTRY
19 A 20 D 21 A 22 C 23 B

24 ABC 25 BCD 26 BD 27 BC 28 BD

29 ABD 30 ACD 31 ABCD 32 6 33 5

34 5 35 6 36 2

MATHEMATICS
37 A 38 D 39 C 40 A 41 D

42 ABCD 43 AB 44 ABCD 45 BC 46 AB

47 ABC 48 ABC 49 BCD 50 2 51 6

52 8 53 1 54 3
 CHEMISTRY
19. Grignard reagent reacts with protonating solvents to form alkanes
20. O – Phthalic acid forms anhydride
21. Reaction -1 is SN2 Reaction -2 is NGP
22. SN2reaction Occurs through inversion s
23. Alchols protection by TsCl is retention and the subsequent SN2 reaction is inversion
24. ABC(Conceptual)
25. KEY: BCD

26. Conceptual
27. Aryl and Bridge head halides do not undergo SN reactions
28. E2 reaction is anti-elimination

36.

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