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04 Mixtures KCi C
04 Mixtures KCi C
Solutions Dilute,
Concentrated,
Mixtures & Saturated
Suspensions
Importance
Separating of Water as a
Solvent
Mixtures
Flotation &
Sedimentation
Separation
Filtration
Chromatography Techniques
Evaporation
Crystallisation
Magnetic Distillation
Attraction
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What is a Mixture?
®
Overall, the description above is partly true, For now, ball-like “particles” will be our
but is simplified, and not the full story. model of matter.
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Mixtures Around Us
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We Use the Earth’s Resources
®
b) what is a mixture?
3.
a) What is a “resource”?
b) What is a “natural” resource? Give an example.
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Solutions & Suspensions
®
If you mix a solid substance with a liquid, one Chalk Dust won’t Dissolve
of 2 things is likely to happen... either it If you mix some chalk dust (or similar solid)
“dissolves” in the liquid, or it does not. with water, no matter how much you stir, it
will not dissolve.
Salt Dissolves in Water
If you add solid salt to water and stir to mix When
stirred, the
them together, the salt seems to disappear. chalk will
NOT cloudy, white
When dissolve suspension
stirred,
the salt
dissolves Clear
solution
This is a “suspension”.
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® Solutions, Suspensions
& the Particle Model
keep it simple science
Solutions Suspensions
Particles Particles Particles Particles
in a solid in a liquid in a solid in a liquid
If the solid is “soluble” in this liquid it will If this solid is “insoluble” in this liquid it will
dissolve to form a solution. not dissolve, but may mix to form a
suspension.
The lump of solid material
completely comes apart and its The solid particles are still in
particles are mixed evenly among “clumps”. They may be too
the particles of liquid. small to see, but they are not
evenly spread in the liquid.
The different particles cling to each other so
the particles of solid cannot fall to the bottom, The “clumps” will eventually
but stay spread throughout the mixture. settle to the bottom.
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Solute, Solvent, Solution ®
Your blood is mostly made of water. It circulates “Cell Membrane” on The cell is filled with
around your body carrying vital chemicals to your the outside contains a jelly-like water
brain and other body organs. Many of these the cell , and controls solution called
chemicals, such as food nutrients, are carried what goes in or out. “cytoplasm”.
dissolved in your blood.
In the Environment
Water is also important as a solvent in the environment of living things.
Plants need many minerals so they can grow and be healthy. They get these minerals from
the soil by absorbing them through their roots. The minerals must be dissolved in the water
in the soil, so the plants can absorb them.
Most of the aquatic plants and animals (aquatic = living in water) have to breathe oxygen,
just as we do. The difference is that they breathe the oxygen that is dissolved in water.
Water is the vital solvent of life.
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Water is the Solvent When you wash your hands, or have a shower, or
in the Oceans wash the dishes, or do the laundry you are
Most of the water on Earth is in the oceans relying on water to dissolve the dirt and wash it
and has salt and many other minerals away.
dissolved in it. To help it clean better,
you use soap or
All the salt has been dissolved detergents which break
out of the rocks and soil by up insoluble greasy dirt
rainwater seeping through over so it is carried away
many millions of years. This has suspended in the
not only created the salty water.
oceans, but is important in the
weathering of rocks and soil In many industrial
formation on land. processes, water is
used as a solvent so
important chemicals
Human Uses of Solvent Water can be easily pumped through pipes, or mixed
Water is important as a solvent in many with each other.
situations in everyday life, in the workplace,
and in industries. Water is the solvent in Whether you drink it, wash with it or swim in it,
many medicines, in tea, coffee and milk. water is the number one solvent and natural
resource for our society and for all living things.
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®
b) solvent.
c) solution.
b) concentrated?
c) saturated?
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®
If you had a mixture of dry sand and Sieves are commonly used in many industries to separate
pebbles, how would you separate the sand substances with different grain sizes.
from the stones?
In a flour mill, wheat grains are cracked open by heavy
You could possibly pick out all the stones rollers to release the powdery flour inside. Then the husk
one-by-one with your fingers, but a quick of the wheat seeds needs to be removed. This is done by
sieving. Flour falls through a fine mesh sieve, but the seed
and easy way is to use a sieve.
husks are too big and are trapped on the mesh.
Sieving might work, but a lot of the sawdust grains If the solid settles to the bottom to form a “sediment”,
may be the same size as sand grains, and will sneak the process is called “sedimentation”; if it floats it is
through the sieve with the sand. “flotation”.
Try this! Note that this will NOT work for dissolved solids in a
Drop the mixture into a solution. The solid particles in a solution are
beaker of water, stir it, intimately mixed in with the solvent particles and they
then let it stand. cling to each other so that the solid will never
Water
separate.
The sawdust floats.
The sand sinks. Sedimentation is the process by which mud and sand
settle to the bottom of lakes and seas. (More on that
Scoop the sawdust off the top and dry it. Carefully in a later topic!)
pour off the water, collect the sand and dry it. Mission
accomplished! Sedimentation is important in sewerage treatment.
After primary treatment, the solid “sludge” is allowed
Difference in Properties? to settle to the bottom of a “sedimentation pond”. The
Firstly, neither the sand nor the sawdust dissolve in clear water can then be released into the
water, so they form a suspension. The separation then environment, or treated further and re-cycled.
occurs because of differences in density.
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Centrifuging ®
1.
a) Give an example of using a sieve in the kitchen.
2. Imagine that a solid has been mixed with a liquid and allowed to stand.
a) Describe what will happen if the solid is soluble in the liquid.
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Filtration
®
Filtration can be used to separate a suspension mixture. It WILL NOT separate the parts of a solution.
For some suspensions, like sand in water, the
solid will rapidly settle to the bottom and form What property difference allows separation?
a sediment.
Grain size!
Suspensions containing very fine solids may
take days to settle. In this case it may be better Although the grains of the suspended solid
to filter the mixture. may seem very small, they are very much
larger than the particles of the liquid.
Suspension
mixture The filter paper has microscopic channels
and holes between its fibres, and the
Filtration particles of liquid can easily flow through.
funnel The solid grains are much larger, and are
and caught in the filter paper.
filter paper
Filtration is really the same as sieving.
at a different size scale.
Condenser
Flask The condenser is
containing solution a tube within a
to be separated. tube.
The solution boils, Cold water flows
and the solvent through the
evaporates. outer tube and
cools the hot
As the vapour vapour flowing
passes through the in the central
condenser, it is tube.
cooled so that it
condenses back to The vapour
liquid. condenses, and
This hose brings cooling pure, liquid
The solute remains solvent flows out
in the flask. water from a tap
the end.
1.
a) What sort of solid-liquid mixtures CAN be separated by filtration?
e) If you had a mixture of dirty (suspended), salty (dissolved) water and you
filtered it:
i) what would be collected in the filter paper?
ii) what would pass through?
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®
Useful chemical
The soluble impurities mostly stay in solution
Soluble impurity because they are not so concentrated and do
not crystallise.
Insoluble impurity
This is how chemicals for laboratories or for
Some of the impurities do not dissolve. medicines can be made 99.999% pure.
These can be removed by filtration.
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Separating Mixtures to Obtain Resources
Most of the substances around us (land, sea, air and living things) are mixtures.
To obtain the many resources we need, we often have to separate
® the things we want from the mixtures in which they occur.
keep it simple science The following are just a few examples.
Water is usually pumped into a large To make ethanol, corn starch or cane sugar is first fermented.
reservoir where it stays long enough for This process is basically the same as the making of beer or
wine. The fermented “brew” contains 15% ethanol.
some of the “dirt” to settle to the
Distillation is used to separate almost pure ethanol from the
bottom as a sediment. water mixture.
The water may then be pumped through Ethanol factory among the
huge filters to trap any remaining corn-fields, USA.
suspended solids, so it is clear and
clean for human uses.
KCiC.04 Separating Mixtures Slide 27
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Evaporation
Salt is separated from sea water by evaporation.