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12th 1 Mark Questions
12th 1 Mark Questions
1 marker Questions
Std : 12th Sub : Chemistry
Q. 4. Define : ethers
Organic compounds characterized by an oxygen atom bonded to alkyl groups 𝑅 − 𝑂 − 𝑅
Q. 5. Alkyl halides
When one or more hydrogen of alkane are replaced by halogen group.
+ 2𝑁𝑎 + −2𝑁𝑎𝐶𝑙
Q. 15. Write the name of reagent used during conversion of acetaldehyde to acetaldehyde
cynohydrin.
Hydrogen cyanide (HCN)
Q. 16. Write the name of nanostructure material used in tyres to increase their life.
Carbon black
applied to living tissues such as wounds, cuts, ulcers and diseases skin surfaces.
Examples : furacine , soframicine, Dettol
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i. A free expansion means expansion against zero opposing force such expansion
occurs in a vacuum.
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ii. When the gas expands in a vacuum there is no opposing force, that is 𝜌𝑒𝑥𝑡 = 0 the
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Q. 48. Why nobelium is the only element actenoid with +2 oxidation state.
i. The electronic configuration of nobelium (𝑁𝑜) is [𝑅𝑛]5𝑓 14 6𝑑 0 7𝑠 2 .
ii. After losing 2 electrons (𝑁𝑜) forms 𝑁𝑜 2+ ion, which is stable due to completely
filled 5𝑓-orbitals.
iii. Such extra stability due to completely filled orbital is not acquired by any other
actenoid in their +2 oxidation state.
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Hence, nobelium is the only actenoid with a +2 oxidation state.
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electrons due to the presence of electrons in the inner shells is called the shielding
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effect.
ii. As a result of the shielding effect, the effective nuclear charge experienced by the
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Q. 50. Iron shows +2 and +3 oxidation states. Write the electronic configuration. Which
more stable & why?
i. Electronic configuration of 𝐹𝑒 2+ ∶ 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 3𝑑 6
ii. Electronic configuration of 𝐹𝑒 3+ ∶ 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 3𝑑 5
iii. 𝐹𝑒 3+ is more stable than 𝐹𝑒 2+ . This is due to the presence of half filled ‘𝑑’ orbital
in 𝐹𝑒 3+ .
Q. 54. In medicines :
a) 𝑃𝑡 complex, cisplatin is used in the treatment of cancer.
b) 𝐸𝐷𝑇𝐴 is used for the treatement of lead poisoning.
Q. 55. A complex with co-ordination no. four has a tetrahedral or square planner structure.
Q. 56. Stereoisomers which are non-superimposable mirror images of each other and rotate the
plane of plane polarised light through the same angle but in opposite directions are known
as enantiomers or enatiomorphs.
Q. 57. Optical activity is the property of certain organic substances to rotate the plane of plane
polarized light towards the right (clockwise) or toward the left (anticlockwise).
𝐶𝐻2 𝐶𝑙
𝐶𝐻2 𝐶𝑁
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+𝐾𝐶𝑁 Δ
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(𝑎𝑙𝑐.) → + 𝐾𝐶𝑙
𝐵𝑒𝑛𝑧𝑦𝑙 𝑐𝑦𝑎𝑛𝑖𝑑𝑒
Q. 59. 𝐶𝐻3 𝐶𝐻2 𝑂𝐻 + 𝐻𝐶𝑙 𝐺𝑟𝑜𝑜𝑣𝑒 ′ 𝑠 𝐶𝐻3 𝐶𝐻2 𝐶𝑙 𝐴𝑙𝑐. 𝐾𝐶𝑁 Δ 𝐶𝐻3 𝐶𝐻2 𝐶𝑁
𝐸𝑡ℎ𝑎𝑛𝑜𝑙 → 𝐶ℎ𝑙𝑜𝑟𝑜𝑒𝑡ℎ𝑎𝑛𝑒 → 𝑝𝑟𝑜𝑝𝑎𝑛𝑒
𝑝𝑟𝑜𝑐𝑒𝑠𝑠 −𝐻2 𝑂
𝑛𝑖𝑡𝑟𝑖𝑙𝑒
Q. 61. 𝑁𝐻2
𝑁2+ 𝐶𝑙 − 𝐶𝑙
𝐴𝑛𝑖𝑙𝑖𝑛𝑒
𝐶ℎ𝑙𝑜𝑟𝑜𝑏𝑒𝑛𝑧𝑒𝑛𝑒
Q. 62. 𝐶𝐻3 − 𝐶𝐻 = 𝐶𝐻2 + 𝐻𝐵𝑟 𝑃𝑒𝑟𝑜𝑥𝑖𝑑𝑒 𝐶𝐻3 − 𝐶𝐻2 𝐵𝑟 + 𝐴𝑔 − 𝑂 − 𝑁 = 𝑂 →
𝑝𝑟𝑜𝑝𝑒𝑛𝑒 → 1−𝐵𝑟𝑜𝑚𝑜𝑝𝑟𝑜𝑝𝑎𝑛𝑒 𝑆𝑖𝑙𝑣𝑒𝑟
𝑛𝑖𝑡𝑟𝑖𝑡𝑒
𝐵𝑟
|
Q. 63. 𝐶𝐻3 − 𝐶 − 𝐶𝐻3 + 𝐾𝑂𝐻 →
| (𝑎𝑙𝑐.)
𝐶𝐻3
𝑇𝑒𝑟𝑡−𝐵𝑢𝑡𝑦𝑙−𝑏𝑟𝑜𝑚𝑖𝑑𝑒
𝐻
|
𝐶𝐻3 − 𝐶 = 𝐶𝐻2 + 𝐻𝐵𝑟 𝑃𝑒𝑟𝑜𝑥𝑖𝑑𝑒 𝐶𝐻3 − 𝐶 − 𝐶𝐻2 𝐵𝑟
| → |
𝐶𝐻3 𝐶𝐻3
𝐼𝑠𝑜𝑏𝑢𝑡𝑒𝑛𝑒 𝐼𝑠𝑜𝑏𝑢𝑡𝑦𝑙 𝑏𝑟𝑜𝑚𝑖𝑑𝑒
Q. 66. Write the structure of optically active alcohol having molecular formula 𝑪𝟒 𝑯𝟏𝟎 𝑶.
𝐶𝐻2 − 𝐶𝐻3
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𝐶𝐻3 − 𝐶 − 𝐻 butan-2-ol
|
𝑂𝐻
𝐶𝑦𝑐𝑙𝑜ℎ𝑒𝑥 − 2 − 𝑒𝑛 − 1 − 𝑜𝑙
Q. 69. 𝐻𝑂 𝐶𝐻3
Q. 74. Arrange the following in increasing order of boiling points formaldehyde, ethane,
methyl alcohol.
Ethane < Formaldehyde < Methyl alcohol.
Q. 75. Write the reaction of p-toluene sulphonyl chloride and diethyl amine.
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Q. 77. Why are primary aliphatic amines stronger base than ammonia.
This is due to the presence of an alkyl group that reverts electron releasing inductive effect
(+1 effect)
Q. 79. Arrange the following amines in an increasing order of boiling points 𝒏-propyl
amine, ethylmethyl amine, trimethyl amine.
Trimethylamine (3°) < ethylmethyl amine (2°) < 𝑛-propylamine (1°)
Q. 83. Define :
a) Nanoscience
Nano science is the study of phenomena and manipulation of materials of atomic,
molecular and macromolecular scales where properties differ significantly from those
at a large scale.
b) Nanotechnology
Nanotechnology is the design, characterization, production and application of
structures, devices and systems by controlling shape and size at nanometer scale.
c) Nanomaterial
The nanomaterial is a material having structural component with at least one
dimension in the nanometer scale i.e. 1 – 100 nm.
d) Nanochemistry
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designing and synthesis of materials of nanoscale with different sizes and shape,
structure and composition and their organization into functional architectures.
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Q. 84. Which nanomaterial us used for sunscreen lotion and what are uses of it?
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Sunscreen lotions contain nanoparticles of zinc oxide (𝑍𝑛𝑂) and titanium dioxide
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(𝑇𝑖𝑂2 ) . These chemicals protect the skin against harmful UV (ultraviolet) rays by
absorbing or reflecting the light. Hence sunscreen lotions prevent the skin from damage.
Q. 87. Why all collisions between reactant and molecules do not lead to chemical reaction.
All collisions of reactant molecules do not lead to chemical reaction because the colliding
molecules need to possess certain energy which is greater than the activation energy E
and a proper orientation.
is 3.011 × 1023.
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𝐶9 𝐻8 𝑂4
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Q. 95. Arrange the halogen acids (𝑯𝑿) in increasing order of acidic strength.
Acidic strength of halogen acids increases in the order of 𝐻𝐼 > 𝐻𝐵𝑟 > 𝐻𝐶𝑙 > 𝐻𝐹.