SESSION 2019-20

PRE-NURTURE COURSE
TARGET : NSEJS
RACE #5-B CHEMISTRY
SECTION - I 4. A vessel of uniform cross-section of length 500 as
shown figure is divided in two parts by a weightless &
1. Which of the following graphs represent Boyle's law : frictionless piston one part contains 5 moles of N2 (g)
and other part contains 2 moles of H2(g) & 1 mole of
He (g) gaseous mixture at the same temperature
PV and pressure.
P
(1) (2)
V P

N2 H2& He

PV PV
(3) (4)
What is the length of N2 compartment ?
V P (Assume volume of piston to be negligible)
(1) 187.5 cm (2) 300 cm
2. What conclusions would you draw from the following
(3) 312.5 cm (4) None of these
graphs :
5. If Pd v/s P (where P denotes pressure in atm and d
denotes density in gm/L) is plotted for H 2 gas (ideal
P V gas) at a particular t emperatu re. If

é d ù
ê dP ( Pd ) ú = 10, then the temperature will
ë û P =8.21atm
be
0 K(–273.15°C) T 0 K(–273.15°C) T (1) 40 K (2) 400 K
(3) 20 K (4) none
6. Two closed vessel A and B of equal volume containing
(1) As the temperature is reduced, the volume as
air at pressure P1 and temperature T1 are connected
well as pressure increase.
to each other through a narrow open tube. If the
(2) As the temperature is reduced, the volume temperature of one is now maintained at T1 and other
becomes zero and the pressure reaches infinity. at T2 (where T1 > T2) then that what will be the final
(3) As the temperature is reduced, the volume as pressure ?
well as the pressure decrease. T1 2P1 T2
(1) (2)
(4) A point is reached where theoretically, the 2P1 T2 T1 + T2
volume as well as the pressure become zero.
3. On the surface of the earth at 1 atm pressure, a 2P1 T2 2P1
(3) (4)
balloon filled with H2 gas occupies 500 mL. This T1 - T2 T1 + T2
volume 5/6 of its maximum capacity. The balloon 7. A balloon containing 1 mole air at 1 atm initially is
is left in air. It starts rising . The height above which filled further with air till pressure increases to 4 atm.
the balloon will burst if temperature of the The initial diameter of the balloon is 1 m and the
atmosphere remains constant and the pressure pressure at each stage is proportion to diameter of
decreases 1 mm for every 100 cm rise of height is : the balloon. How many no. of moles of air added to
change the pressure from 1 atm to 4 atm :
(1) 120 m (2) 136.67 m
(1) 80 (2) 257 (3) 255 (4) 256
(3) 126.67 m (4) 100 m

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 PRE-NURTURE COURSE TARGET : NSEJS
8. What is the mass of H2O present in air in 10 litre 13. Which one of the following V, T plots represents the
closed vessel with 80% relative humidity at 1 atm behaviour of one mole of an ideal gas at one
and 300 K ? Given : Vapour pressure of H 2O is 30 atm?
torr at 300 K.
(1) 0.23 gm (2) 0.36 gm 38.8 L 28.8 L
V(L) 373 K V(L) 373 K
(3) 2.3 gm (4) 3.6 gm
22.4 L 20.4 L
9. Equation of Boyle's Law is (1) 273 K (2) 273 K
T(K) T(K)
dP dV dP dV
(1) =- (2) =
P V P V
30.6 L 14.2 L
2 2 2
V(L) 373 K V(L) 373 K
d P dV d P d V
(3) =- (4) =- 22.4 L 22.4 L
P dT P dT (3) 273 K (4) 273 K
T(K) T(K)
10. In a separate bulbs containing ideal gases A and B
respectively, the density of A is twice that of B while
14. Positive deviation from ideal behaviour takes place
Mol. wt. of gas A is half that of gas B. At the same
because of.
temperature pressure ratio PA PB will be
(1) molecular interaction between atoms and
(1) 1/4 (2) 1/2
PV
(3) 4 (4) 1 >1
nRT
11. A cylinder contains acetylene gas at 27°C and 4.05
M Pa. The pressure in the cylinder after half the PV
(2) molecular interation between atoms and <1
mass of gas is used up and temperature has fallen to nRT
12°C will be : PV
(1) 4.05 M Pa (2) 2.025 M Pa (3) finite size of atoms and >1
nRT
(3) 3.84 M Pa (4) 1.92 M Pa
12. Match the entries in column I with entries in Column PV
II and then pick out correct options. (4) finite size of atoms and <1
nRT
Column I Column II
Paragraph for Question 16 & 17

1 X and Y are two volatile liquids with molar weights

(a) vs P for ideal gas (w) of 10g mol–1 and 40g mol–1 respectively. Two cotton
V2
plugs, one soaked in X and the other soaked in Y,
at constant T and n. are simultaneously placed at the ends of a tube of
length L = 24 cm, as shown in the figure. The tube
1 is filled with an inert gas at 1 atmosphere pressure
(b) V vs for ideal gas at (x) and a temperature of 300K. Vapours of X and Y
T
react to form a product which is first observed at a
constant P and n distance d cm from the plug soaked in X. Take X
and Y to have equal molecular diameters and assume
ideal behaviour for the inert gas and the two vapours.
(c) log P vs log V for ideal (y)
L = 24 cm
gas at constant T and n.

1 Cotton wool d Cotton wool

(d) V vs for ideal gas at (z) soaked in X soaked in Y
P2 Initial formation of
the product

constant T and n.
(1) a–y, b–z, c–w, d–x (2) a–w, b–x, c–y, d–z 15. The value of d in cm (shown in the figure), as
(3) a–z, b–w, c–y, d–x (4) a–x, b–y, c–z, d–w estimated from Graham's law, is -
(1) 8 (2) 12 (3) 16 (4) 20

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 PRE-NURTURE COURSE TARGET : NSEJS
16. The experimetnal value of d is found to be smaller 20. Assuming that O2 molecule is spherical in shape with
than the estimate obtained using Graham's law. This radius 2 Å, the percentage of the volume of O2
is due to - molecules to the total volume of gas at S.T.P. is :
(1) Larger mean free path for X as compared to (1) 0.09 % (2) 0.9 %
that of Y
(3) 0.009 % (4) 0.045 %
(2) Larger mean free path for Y as compared to
that of X
SECTION - II
(3) Increased collision frequency of Y with the inert
gas as compared to that of X with the inert gas 21. 11 moles N2 and 12 moles of H2 mixture reacted in
20 litre vessel at 800 K. After equilibrium was
(4) Increased collision frequency of X with the inert
reached, 6 mole of H2 was present. 3.58 litre of
gas as compared to that of Y with the inert gas
liquid water is injected in equilibrium mixture and
17. Two closed bulbs of equal volume(V) containing an ideal
resultant gaseous mixture suddenly cooled to 300
gas initially at pressure pi and temperature T1 are
K. What is the final pressure of gaseous mixture?
connected through a narrow tube of negligible volume
Assume (i) all NH3 dissolved in water (ii) no change in
as shown in the figure below. The temperature of one
volume of liquid (iii) no reaction of N2 and H2 at 300
of the bulbs is then raised to T2. The final pressure
K (iv) Vapour pressure of water to be negligible :
pf is :-

N2 :11 moles T = 300 K ; P = ?

T1 T1 T1 T2 T=800K N2,H2
pi,V pi,V Þ pf,V pf,V H2 :12 moles V=20L NH3(aq) solution
Initial condition

22. A manometer attached to a flask contains NH3 gas

æ TT ö æ TT ö have no difference in mercury level initially as shown
(1) 2pi ç 1 2 ÷ (2) pi ç 1 2 ÷
è T1 + T2 ø è T1 + T2 ø in diagram. After the sparking into the flask, it have
difference of 19 cm in mercury level in two columns.
Calculate % dissociation of ammonia.
æ T1 ö æ T2 ö
(3) 2pi ç ÷ (4) 2pi ç ÷
è T1 + T2 ø è T1 + T2 ø
Patm=760 mm
18. The best vaccum so far attained in laboratory is 10 –

10
mm of Hg. The number of molecules of gas remain NH3
per cm3 at 20°C in this vaccum is : gas
(1) 3.29 × 104 molecules
(2) 3.29 × 105 molecules
(3) 3.29 × 106 molecules
(4) 3.29 × 107 molecules 23. A 10 liter container consist of 1 mole of gas at 300
19. 3
A 0.5 dm flask contains gas A and 1 dm flask 3 K. It is connected to another container having volume
contains gas B at the same temperature. If density 40 liter and is initially at 300 K. The nozzle connecting
of A = 3 g/dm3 and that of B = 1.5 g/dm3 and the two containers is opened for a long time and once
molar mass of A = 1/2 of B, the ratio of pressure the movement of gas stopped, the larger container
exerted by gases is : was heated to a temperature of 600 K. Calculate
(1) Moles and pressure of gas in both the containers
PA PA
(1) P = 2 (2) P = 1 before heating.
B B (2) Moles and pressure in two containers after
heating.
PA PA (Assume that initially the larger container is
(3) P = 4 (4) P = 3
B B completely evacuated.)

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 PRE-NURTURE COURSE TARGET : NSEJS
24. The figure shows initial conditions of a uniform [Assume that temperature remains constant.]
cylinder with frictionless pistons A and B held in shown (1) Pressure developed in each compartment in fi-
position by mechanical stoppers. nal state.
Mechanical stoppers (2) What will be the final position of piston A (with
respect to far left end of container)
A B
(3) What will be the final position of piston B (with
respect to far left end of container)
25 m 35 m 40 m 25. V.D. of a container containing A was found to be 20.
He(g) Ar(g) Ne(g) Now the container is heated due to which A changes
T = 300 K
P = 10 atm P = 30/7 atm P = 5/2 atm according to reaction

nA ¾¾
® An
Comp - I Comp - II Comp - III

If the mechanical stoppers holding piston A and B as After the end of reaction the vapour density was found
shown in figure are removed. to be 40 and it is known that 66.6% of A is con-
verted into product then find the value of n.

-3348337
•

↳amaezBBMmmmm
ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 2,3 3,4 3 1,2 1 2 3 1 1 3 4 1 3 3 3 4 4 3 3 1

21. 22.5 atm 22.25% 23. (a) 0.492 atm (b) 0.821 atm
24. (a) 5 atm (b) 50 m (c) 80 m 25. n = 4

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