Sec: OSR.

IIT_*CO-SC GTA-8(P1) Date: 25-04-24

Time: 3HRS 2023_P1 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 BC 2 BCD 3 ABCD 4 B 5 C
6 B 7 C 8 10 9 3 10 13
11 24 12 8 13 5 14 C 15 D
16 A 17 B

PHYSICS
18 ABC 19 ABCD 20 BC 21 C 22 A

23 B 24 D 25 5 26 4 27 8

28 3 29 8 30 5 31 A 32 B

33 A 34 B

CHEMISTRY
35 BC 36 CD 37 AD 38 C 39 A

40 B 41 B 42 7 43 6 44 9

45 5 46 3 47 4 48 A 49 B

50 C 51 D
Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
SOLUTIONS
MATHS
1.  2
   
det A  2 I  0  det A  2 I det A  2 I  0 
As A contains rational entries, det  A    
2 I  det A  2 I  0
So characteristics equation of A is A  2 I 2  0
2

A2 n  2n I 2 , A2 n 1  2n A & A  2 .
2. As sum of coefficients of x 2 , y 2 and z 2 is zero so the planes are perpendicular
1
Clearly x  y  z satisfies the equation. So l  m  n  .
3
yz z2 y2
3. If OA  x, OB  y, OC  z. p  q    2 &   2 .
y2  z2 y z
4. P  0   0  a0  0
Now a1 x  a2 x 2  .  x a1  a2 x .  1 So a1  1 .
5. Maximum value of A is 398 .
1
6. a2  2 so an  2n  2. an2  an21  2
an21
1 1
As an  2 so  1
an2 4
Hence 2  an2  an21  3
putting n  2, 3, ,75 and adding 148  a75
2
 1  222
144  149  a75
2
 223  225 So 12  a75  15
7. Sum (required) 
12

 i  112  i   12  0  1 .  11  1  2  3 ..  12   870

i 1
8. Note that the left-hand side of the equation can be written as
x  x 2  2m  1  m  x 2  2m  1  x 2  2m  1  5
Then,  x  m  1  x 2  2m  1  5
Now, if the equation has an integer root, we have
 x  m  1, x2  2m  1  1,5 ,  1, 5 ,  5,1 ,  5, 1
We have four cases,
(i) x  m  1  1 and x 2  2m  1  5 .
Then, x 2  2m  1  2  x  m  1  7 .
Hence, x 2  2 x  4  0 , which has no integer roots.
(ii) x  m  1  1 and x 2  2m  1  5 . Then, x 2  2 x  10  0 , which has no real roots.
(iii) x  m  1  5 and x 2  2m  1  1 . Then x 2  2 x  8  0 , which gives x  2, 4 and , m  2,8
respectively.
(iv) x  m  1  5 and x 2  2m  1  1 . Then x 2  2 x  14  0 , which has no real roots.
9. a  2, b  6, c  3, d  4

SR.IIT_*CO-SC Page NO: 2

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
13
10. 
sin 1  sin 2 x  cos 4 x 
14

3 3

cos 1  sin 2 x  cos 4 x  
14
1 1
11. We split into cases on the integer k   x 2  y 2  . Note that x  y  k but x 2  y 2  ( x  y ) 2  k 2
2 2
and x  y  1 , which forces k  2 .
2 2

 2 2
If k  0 , the region defined by 0  x 2  y 2  1 and x  y  0 is the diameter from  ,  to
 2 2 
 2 2
  ,  , which has length 2 .
 2 2 
If k  1 , the region 1  x 2  y 2  2 and x  y  1 consists of two segments, which is the chord on
2
 2
x  y  2 minus the chord on x  y  1 . The former has length 2 ( 2)  
2 2 2 2
  6 , and the
2

 2 
2
 2
latter has length 2 1     2 . So the total length here is 6  2 .
2

 2 
If k  2 , the region 2  x  y 2  3 and x  y  1 is the chord on x 2  y 2  3 , which has length
2

2 ( 3) 2  ( 2) 2  2 .
Our final answer is 2   
6  2 2  4 6  2 .
 n   n 
12. H  n   5 1  2  3      52 1  2  3    2    so. On. ([.] G.I.F)
 5  5  
2
n
Using sandwich theorem, we can show lim n 8.
H n
ac
13. The given condition is equivalent to b  .
1  ac
a  tan , b  tan , c  tan ,
  
where tan  tan     and  ,  ,     ,  , so we have
 2 2
2 2 3 2 2 3
A  2  2   
a  1 b  1 c  1 tan   1 tan      1 tan   1
2 2 2 2

 2cos 2  2cos2      3cos 2

   
 2cos 2  1  2cos 2      1  3cos 2
 cos  cos  2  2   3cos   2sin  2    sin  3cos 2
2

2
 1  10 10
 

Let x  sin . Then we have A  2 x  3 1  x  3x  2 x  3  3  x     .
2 2

3 3 3
1
Equality holds if any only if sin  2     1 and sin  , from which we deduce
3
 2 2
 a, b, c    , 2,  .
 2 4 

SR.IIT_*CO-SC Page NO: 3

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
14. Use (2a ) 2  (3b) 2  12ab  c 2  0
  2a  3b  c  2a  3b  c   0
15. Conceptual

16. (P) lim x 1 

x2 f t   t
dt  lim x 1
   
f x2  x2  2 x2 f  x2  2 x2
1 ( x  1) 2
1

 lim x 1
2x  f  x   x   lim
2 2
   
f x2  x2  2 x2 f  x2  2 x 2
4
2  x  1
x 1
1
n
 n
4 1 
(Q) lim n (1  4)  lim n  1 
n n

 2 
 41/ n 1   1  41/ n 1  
 lim   1
lim 
n 
 n  n 2 1/ n   n 4
 2 
e e   
 e2 2
2x
(R) f  x   lim n tan 1  nx   x; x  0

 n 1  1
lim  f  x   1  lim x  1  1 (S) lim   r   lim 1  r   0
x0 x 0 n 
 r 1 2  n  2 
17. (A) 2sinx,sin2x & 2cosx are in A.P., hence sin2x  sinx  cosx
Now, let sinx  cosx  t , then sin2 x  t 2  1 , then the above equation gives t 2  t  1  0 or
1 5
t  sinx  cosx 
2
 c   c
(B) Let C be the sides angles, then angles will be  , , 
3 3 3 3 3
 c    
   c  c  , hence angles are , ,
3 3 2 6 3 2
a b c a b c
Now     
   1 3 2
sin sin sin
6 2 2
  
Hence angles are , ,
6 3 2
a b c a b c
Now    
  
sin sin sin 1 3 2
6 2 2
(C) Let AB  a, BC  3a, CA  3a & AD  3 3a
a 2  27 a 2  BD 2 a 2  9a 2  BD 2
Now cosA  cosC  0   0
3 3a 2 3 3a 2
BD
BD 2  20a 2   20  2 5
AB
2a 2 c 2 8a 2c 2
(D) a  c  2b & b 2  2 2  (a  c) 2  2 2
a c a c
(a  c) 2
 (a  c)2  2ac(a  c) 2  8a 2 c 2  0  2, 4
ac
a
But gives a  c , hence taking 2 a 2  4ac  c 2  0   3 2.
c

SR.IIT_*CO-SC Page NO: 4

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
PHYSICS
  ˆ ˆ
    ˆ ˆ 
18. a0   2 g i  g j  FB  V  a0  g   2 Vg  i  j 
   
    ˆ ˆ
 ˆ
Fnet  FB  mg  2 Vg  i  j    0Vg j
 
 2  ˆ ˆ
 ˆ   
anet  g  i  j   g j arelative  anet  a0
0  
T
19. Most probable velocity Vmp
M
T T
From graph, V1  V2  1  2
M1 M 2
1 2
20. Applying Bernaullis theorem from the frame of car. Pin  0  Pout  v
2
Again  Pin  Pout   (0.4)2    1.6  t
1 2 1 1.25  40  40  0.16
  v  0.16  4 107 1.6t    t t  2.5 m
2 2 1.60  4  107
3 grsin 4 4l
21. aQ  aP  gsin  r 
l 3 9
    
22.  
aB  a A    rB , A   rB , A  5 j  4 i  3 j  12i  16 j 
2


aB along y-axis should be zero.
4
 11  3  0     rad / s 2
3
80
aB   4  12  i   im / s 2
3
 MR 2
23. dT   dm  r 2sin  T  TA  1  cos 
2 2

24. Given 10VSD  9MSD

1MSD
Least count   0.1 mm
10
As ' 0 ' of V.S. lies before ' 0 ' of M.S.
Zero error   10  6 L.C.
 4  0.01 cm  0.04 cm
Reading  4.1 cm  2  LC
 4.1 cm  2  0.01 cm  4.12 cm
True diameter  Reading - Zero error  4.12   0.04  cm  4.16 cm
ml 2  2k k  2  5k 
25.      l      
12  12 4  m

SR.IIT_*CO-SC Page NO: 5

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
 /2 2  1  2  R g
26. f  2    1  2  Rg  sin d   2  1  2  R g  a  4
 0  2 R

d v2
27. 2Tsin  dN   Rd ( is linear mass density of belt)
2 R
 Td  dN   v 2 d
  
  
 so total normal force   2 dNcos   2 Tcos d   v 2  2 cos d
  
2 2 2
 N  8 newton

 
28. Since    , the upper block will move faster than the middle block and hence force of friction
4 2
on upper block is towards left
 g
 f  mg  a A  leftward
4 4
3 1
 3m  mg   mg
f  g aB  4 4   g leftwards
2 2 m
2
g 3 3L 1  3  L
a A/ B   g   g    g t2  t   3s
4 4 8 2 4  g

29. Acceleration of particle with respect box is along perpendicular to inclined plane
vmin  gcos37  AB  CD  AC   8  2  3  3  8 m / s

SR.IIT_*CO-SC Page NO: 6

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
30. A system of pullies is massless,  net 0  0

T1 R  T3  3R   T2  2 R   0
T1  3T3  2T2
8mg  T1  8m  R 
T1  8m  g  R 
Similarly,
T3  2m  g  3R  #  3
T2  m  g  2 R  #  3
Substituting (2), (3), (4) in (1)
8m  g  R   6m  g  3R   2m  g  2 R 
12 g 120
12 g  30 R  R    4 m 2
30 30
1 VdT 3dV dT
30.  P  tan   3   
T TdV V T
3
lnV  lnT  C  TV  constant
3

This is polytropic process with x  1  3  x  2

 25 
2 
nR 50
W T1  T2    3   1   J
x 1 3 9
 25
2 
3
(Q) ΔU  nCV ΔT    1  25 J
5 
 3  1
 
 5R  25 125
(R) ΔQP  nCP ΔT   2    ΔT  5  1  J
 2  3 3
( S )ΔU  25 J for any polytropic co-efficient i.e., for any value of '  '.
3a 2
32. Pt   s
2V 3
3V
  rel
V 3
(Q) 0   2 
x a 2
V rel 3V
(R) t  
x 2x

SR.IIT_*CO-SC Page NO: 7

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
d 3V  1   dx  3V  3V  3 3
    2    
2   0 
dt 2  x   dt  2 x  2  4
3V 3V  a  5a
(S) x  a  t a  
2 2  4V  8
1 1  3x  3  5a 
2
25 3
A  b  h    x       
2 2  2  4 8 256
m
33. A) If 1  0  m1  0
m2
v
Then v2 f  0 and v1 f  v1i  1i  1
v1 f
m1
When    m1  
m2
v1 f
Then v2 f  2v1i and v1 f  v1i   1 Correct graph is (B)
v1i
B) From above discussion, the answer is -1
m v
C) When 1   , 2 f  2
m2 v1i
v m
D) 2 f  0 if m2 is massive  when 1  0
v1i m2
v2 f m
 2 if m2 is light  when 1 is large
v1i m2
34. U  4( x  1) 2 ( x  2) 2
dU
 4  2  x  1 ( x  2) 2  2( x  1)2  x  2  
dx
dU
Or,  8  x  1 x  2   x  2  x  1  8  x  1 x  2  2 x  3
dx
dU
Force on the particle is F    8  x  1 x  2  2 x  3
dx
dU
Force (i.e., ) is zero at x  1, 2,1.5 m . These are positions of equilibrium. Nature of the
dx
d 2U
equilibrium can be ascertained by finding or just by plotting the graph of U versus x .
dx 2

A) From (ii), the force on the particle is negative at x  1 m . If it is released at x  1 m , it will

move in the negative x direction.
B) If the particle is released at x  1 m , it will remain in unstable equilibrium.

SR.IIT_*CO-SC Page NO: 8

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
C) Force F  8  x  1 x  2  2 x  3
When the particle is displaced Δx from its equilibrium position at x  1.5 m (so that its co-ordinate
is 1.5  Δx) , the force on it is
F  8 1.5  Δx  11.5  Δx  2  3  2Δx  3
 8  0.5  Δx  Δx  0.5  2Δx 
  
 8 Δx 2  0.52  2Δx   16Δx Δx 2  0.52 
If Δx  0.5 , then Δx  0.5  0.5
2 2 2

Or, F  16Δx  0.52   4Δx

 ma  4Δx  a  4Δx  m  1 kg 
 Motion is SHM and   4  2
D) It is same as (C)

CHEMISTRY
35. Ionic product of D2O 1.35 10 15
 is less than ordinary water 1 1014
D  O bond is stronger than O  H bond so ionization of D 2 O is less than H 2O
The pD value of neutral D2O is 7.43 so if D2O has pD 7.2 which is less than 7.43, D2O
is acidic. For neutral H 2OpH  7 but for D 2 O is 7.43
36. I & II are aromatic.
Basic order IV  III  II  I
37. Addition of Br2 on an alkene is a trans-addition. Q1 is a binary mixture and is optically inactive due
to external compensation. Note that the alkene P formed  MeCH  CHEt  is an unsymmetrical
alkene and hence anti addition of Br2 upon it will not yield meso-product.
38. -186 and -104 are less than 100 C . So they exist as liquids 60 and 10 are greater than
-100 . So they vapourse and do not exist as liquids.
39. C60 soluble in benzene. The remaining statements are incorrect
2a a
40. In version temperature Ti  , Boyle's temperature TB   Ti  2  TB
Rb Rb
8a 2a
Critical temperature TC  , Inversion temperature Ti 
27 Rb Rb
Critical temperature is less than Inversion temperature
Inversion tempature more than critical temperature and Inversion temperature.
41. G  H  TS
G  U  PV  TS
Δ G  Δ U  P Δ V  V Δ P  TΔ S  S Δ T
From the first and second laws, TΔS  ΔU  PΔV
 ΔG  VΔP  SΔT
ΔG
G  H T
ΔT
OR
 G 
G  H T  
 T  P
H G 1  G 
 2  2   
T T T  T  P

SR.IIT_*CO-SC Page NO: 9

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
  G / T  
 
 T  P
  G / T   
H  T 2   
 T  P 
42.  Be(CH)3 n ,  BeH 2 n ,  AlH3 n , Al2  CH3 6 , B2 H6 , Be  BH 4 2 and Al  BH 4 3 contain 3c-2e bonding
 BeCl2 n , Al2Cl6 contain 3c  4e bonding
43. O2 , O 22 , O2 , O3 ions hydrolyse in water liberating oxygen converting into hydroxide ions N 3 gives
NH 3 , C22 gives C2 H 2 , C34 gives propyne by reacing with water.
F , Cl , OH  ,SO 24  and NO3 ions exists in water as hydrated ions
K P1 4P1 4  1 1
44.     K P2  9 K p1
K P2 P2 36 9
45. Given 2  30.4 107 cm 1  108.5  107 cm
let excited state of He be n2 . it comes from n2 to n1 and then n1 to 1 to emit two successive photon
1 1 1  1 1 1 
 R H  Z2  2  2   109678  4  2  2  n1  2
2  1 n1  30.4 10
7
1 n1 
1 1 1 1 1 1
Now  R H 2 z[  2  2   109678  4  2  2
1  2 n 2  108.5 10
7
 2 n2 
n 2  5 thus excited state for He is 5 orbit.
th

46.

47. Each aromatic ring can have three resonating forms.

48 .
49. Mixture I:
End point with phenolphthalein (disappearance of pink colour) corresponds to the neutralisation of
NaOH and half- neutralisation of Na 2 CO3 .
NaOH  HCl  NaCl  H 2O
Na 2 CO3  HCl  NaHCO3  NaCl
End point with Methyl orange (Appearance of Red colour) corresponds to the neutralisation of
NaOH and Na 2 CO3 .

SR.IIT_*CO-SC Page NO: 10

Narayana IIT Academy 25-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-8(P1)_KEY&SOL
NaOH  HCl  NaCl  H 2O
Na 2 CO3  2HCl  2NaCl  CO 2  H 2 O
Volume of HCl required for neutralisation of Na 2 CO3
 2  x  w
1 2  x  w 
Normality of Na 2 CO3 
100
2  x  w  10 2

Molarity of Na 2 CO3   x  w  102

Volume of HCl req. for neutralisation of NaOH
 w   x  w
  2w  x  ml
 2w  x  1
Hence, molarity of NaOH 
100
  2w  x  10 M 2

Mixture II :
End point with phenolphthalein corresponds to half- neutralisation of Na 2 CO3 as
Na 2 CO3  HCl  NaHCO3  NaCl
Volume of HCl req. for complete neutralisation of Na 2 CO3  ' 2y ' ml
1 2y
 Molarity of Na 2 CO3  
2 100
2
 y  10
End point with Methyl orange corresponds to neutralisation of NaHCO3
Hence, volume required for neutralisation of NaHCO3 present initially   z  2 y  ml
 z  2y
 Molarity of NaHCO3    z  2 y   102
100
50. Conceptual
51. Conceptual

SR.IIT_*CO-SC Page NO: 11