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Liquid Solution
Liquid Solution
® 1
7. AB2 is 10% dissociated in water to A2+ and
LIQUID SOLUTION
1. When 9.45 g of ClCH2COOH is added to 500 mL B–. The boiling point of a 10.0 molal aqueous
solution of AB2 is _______oC. (Round off to the
of water, its freezing point drops by 0.5°C. The
dissociation constant of ClCH2COOH is Nearest Integer).
[Given : Molal elevation constant of water
x × 10–3. The value of x is ________.
Kb = 0.5 K kg mol–1 boiling point of pure water
(Rounded off to the nearest integer)
= 100oC]
Kf(H O) = 1.86K kgmol-1
2 8. At 363 K, the vapour pressure of A is 21 kPa
2. C6H6 freezes at 5.5°C. The temperature at which and that of B is 18 kPa. One mole of A and
a solution 10 g of C4H10 in 200 g of C6H6 freeze 2 moles of B are mixed. Assuming that this
is _______ °C. (The molal freezing point solution is ideal, the vapour pressure of the
depression constant of C6H6 is 5.12°C/m.) mixture is ________ kPa. (Round of to the
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12. A solute a dimerizes in water. The boiling point 18. Of the following four aqueous solutions, total
of a 2 molar solution of A is 100.52ºC. The number of those solutions whose freezing point
percentage association of A is.____. is lower than that of 0.10 M C2H5OH is
(Round off to the Nearest integer) ________ (Integer answer)
[Use : Kb for water = 0.52 K kg mol–1 (i) 0.10 M Ba3(PO4)2
Boiling point of water = 100°C] (ii) 0.10 M Na2SO4
13. Which one of the following 0.06 M aqueous (iii) 0.10 M KCl
solutions has lowest freezing point ? (iv) 0.10 M Li3PO4
(1) Al2(SO4)3 (2) C6H12O6 19. 83 g of ethylene glycol dissolved in 625 g of
(3) KI (4) K2SO4 water. The freezing point of the solution is
14. CO2 gas is bubbled through water during a soft _______K. (Nearest integer)
drink manufacturing process at 298 K. If CO2 [Use : Molal Freezing point depression constant
exerts a partial pressure of 0.835 bar then x m of water = 1.86 K kg mol–1]
mol of CO2 would dissolve in 0.9 L of water. Freezing Point of water = 273 K
The value of x is ________ . Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u]
(Nearest integer)
20. 1 kg of 0.75 molal aqueous solution of sucrose
(Henry's law constant for CO 2 at 298 K is can be cooled up to –4°C before freezing. The
1.67 × 10 3 bar) amount of ice (in g) that will be separated out is
15. When 3.00 g of a substance 'X' is dissolved in ________ . (Nearest integer)
100 g of CCl4, it raises the boiling point by [Given : Kf(H2O) = 1.86 K kg mol–1]
0.60 K. The molar mass of the substance 'X' is 21. 40 g of glucose (Molar mass = 180) is mixed
–1
________ g mol . (Nearest integer). with 200 mL of water. The freezing point of
[Given Kb for CCl4 is 5.0 K kg mol–1] solution is _____ K. (Nearest integer)
16. 1.46 g of a biopolymer dissolved in a 100 mL [Given : Kf = 1.86 K kg mol–1 ; Density of
water at 300 K exerted an osmotic pressure of water = 1.00 g cm–3; Freezing point of
2.42 × 10–3 bar. water = 273.15 K]
22. Which one of the following 0.10 M aqueous
The molar mass of the biopolymer is _____
solutions will exhibit the largest freezing point
× 104 g mol–1.
depression ?
(Round off to the Nearest Integer)
(1) hydrazine (2) glucose
[Use : R = 0.083 L bar mol–1 K–1]
(3) glycine (4) KHSO4
17. When 400 mL of 0.2M H2SO4 solution is mixed
23. 1.22 g of an organic acid is separately dissolved
with 600 mL of 0.1 M NaOH solution, the
in 100 g of benzene (Kb = 2.6 K kg mol–1) and
increase in temperature of the final solution is 100 g of acetone (Kb = 1.7 K kg mol–1). The
_____ × 10–2 K. (Round off to the nearest acid is known to dimerize in benzene but
integer). remain as a monomer in acetone. The boiling
[Use : H+ (aq) + OH–(aq) H2O : point of the solution in acetone increases by
H = – 57.1 kJ mol–1] 0.17°C. The increase in boiling point of solution
Specific heat of H2O = 4.18 J K–1 g–1 in benzene in °C is x × 10–2. The value of x is
density of H2O = 1.0 g cm–3 _______.(Nearest integer)
Assume no change in volume of solution on [Atomic mass : C = 12.0, H = 1.0, O= 16.0]
mixing.
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® 3
SOLUTION 3. Official Ans. by NTA (375)
1. Official Ans. by NTA (36) Sol. Tb = iKbm
+
Sol. ClCH2COOH ClCH2COO + H = (1 + 4) × 0.52 × 1
i = 1 + (2 –1) = 3.4 × 0.52 × 1 = 1.768
i=1+
Tb = 1.768 + 373.15 = 374.918 K
Tf = ikfm
= 375K
9.45
0.5 1 1.86 94.5 Hence answer is (375)
500
4. Official Ans. by NTA (3)
1000
5 1.28 Sol. = 0.75, n = 2
1
3.72 3.72 i = 1 – + n = 1 – 0.75 + 2 × 0.75 = 1.75
32
Tb = ikbm
93
ClCH2COOH ClCH2 COO + H
+ or, 2.5 = 1.75 × 0.52 × m
Kf 5.12 C / m 2
= 24
(2 15 10 3 )
10g : Solute is non dissociative
= 23.82
200 g C6H6 P = 0.18 torr = 18 × 10–2 torr.
Tf = kf × m
Sol.(2) SO2 + NaOH NaHSO3
10
9.2 10 –
T T 5.12 58 mol
f
0
f
'
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6. Official Ans by NTA (2) 9. Official Ans. by NTA (25)
12.2 Sol. P = KH · x
0 – (–0.93) = i × 1.86 × 1000
122 100 n O2
3 4 3
or, 20 × 10 = (8 × 10 × 10 ) ×
0.93 n O2 n water
i 0.5
1.86
1 nO2 nO
1 1 1 or, 2
i = 1 1 1 1 1 4000 n O2 n water n water
n 2 n
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® 5
12. Official Ans. by NTA (100) 16. Official Ans. by NTA (15)
Sol. = CRT ; = osmotic pressure
Sol. Tb = Tb – Tb0
C = molarity
100.52 – 100 T = Temperature of solution
let the molar mass be M gm / mol
= 0.52ºC
2.42 × 10–3 bar
1.46g
i = 1
2 Mgm / mol 0.083 bar
=
300K
Tb = i Kb × m 0.1 mol K
M = 15.02 × 104 g/mol
17. Official Ans. by NTA (2)
0.52 = 1 0.52 2
2 ALLEN Ans. (82)
400 0.2
=1 Sol. n H 2 0.16
1000
So, percentage association = 100%. 600 0.1
n OH – 0.06 (L.R)
13. Official Ans. by NTA (1) 1000
Now, heat liberated from reaction
Sol. Tf – Tf' = i Kf.m = heat gained by solutions
For minimum Tf' or, 0.06 × 57.1 × 103
= (1000 × 1.0) × 4 .18 × T
'i' should be maximum. T = 0.8196 K
Al2(SO4)3 i=5 = 81.96 ×10–2 K 82 × 10–2 K
C6H12O6 i=1 18. Official Ans. by NTA (4)
Sol. As 0.1 M C2H5OH is non-dissociative and rest
KI i=2
all salt given are electrolyte so in each case
K2SO4 i=3 effective molarity > 0.1 so each will have lower
14. Official Ans. by NTA (25) freezing point.
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20. Official Ans. by NTA (518) 23. Official Ans. by NTA (13)
Sol. Let mass of water initially present = x gm Sol. With benzene as solvent
Tb = i Kb m
Mass of sucrose = (1000 - x) gm
1 1.22 / Mw
Tb 2.6 …(1)
1000 x
moles of sucrose =
2 100 /1000
342
With Acetone as solvent
1000 x Tb = i Kb m
0.75 = 342 x 1000 x 1.22 / Mw
x 1000 342 0.75 0.17 = 11.7 …(2)
1000 100 /1000
(1) / (2)
256.5 x = 106 – 1000x
1 1.22 / M w
2.6
x = 795.86 gm Tb 2 100 /1000
0.17 1.22 / Mw
1 1.7
moles of sucrose = 0.5969 100 /1000
40
mol
180 10
Sol. molality molal
0.2Kg 9
10
Tf Tf Tf ' 1.86
9
10
Tf ' 27315 1.86
9
= 271.08 K
271 K (nearest-integer)
KHSO4