in Photocatalytic Concrete Technology: A Global Review
Research on photocatalytic concrete Introduction
The exploration and implementation of photocatalytic technology has spanned multiple decades concrete technology have gained significant momentum and involved contributions from various in recent years as a response to the pressing need for sustainable construction materials and environmental countries worldwide. This review provides remediation strategies. The inception of photocatalytic a concise overview of key findings and concrete technology can be traced back to the late 20th century when pioneering research efforts began to advancements in this field, emphasizing investigate the photocatalytic properties of semiconductor the contributions of Japan, the European materials, notably titanium dioxide (TiO2). Early studies laid the groundwork for understanding the principles of Union (EU), the United States, and China. photocatalysis and its potential application in concrete Dr S B Hegde, Professor, materials. Throughout the 1990s and early 2000s, academic Department of Civil institutions and research laboratories worldwide conducted Engineering, Jain College of fundamental research to elucidate the mechanisms of photocatalytic degradation and optimize photocatalyst Engineering and Technology, formulations for concrete integration. The adoption and Hubli, Karnataka, and Visiting implementation of photocatalytic concrete technology have been observed across various countries, reflecting Professor, Pennsylvania the global interest in sustainable construction practices State University, USA and environmental stewardship.
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in degrading organic pollutants on concrete surfaces, highlighting the potential of photocatalytic concrete panels in improving environmental sustainability. United States: In recent years, research in the United States has focused on integrating photocatalytic properties into concrete matrices to address urban pollution concerns. Institutions such as MIT and UC Berkeley have explored novel approaches to Figure 1: Concrete with photocatalytic activity enhance photocatalytic activity, employing advanced characterization techniques to Notably, countries with high urbanization Moreover, advancements in manufacturing study degradation mechanisms and optimize rates and a focus on combating air pollution processes, economies of scale, and performance. have been early adopters of photocatalytic ongoing research efforts aimed at optimizing China: China has emerged as a leader concrete solutions. Japan stands out as a photocatalytic concrete formulations are in photocatalytic concrete technology, pioneer in the field, with extensive research expected to contribute to cost reductions leveraging its research infrastructure and and real-world applications dating back to and enhanced cost-effectiveness over time. manufacturing capabilities. Research efforts the early 2000s. Japanese cities, particularly Collaborative initiatives involving academia, have concentrated on developing cost- Tokyo and Osaka, have witnessed widespread industry, and government stakeholders effective formulations suitable for large-scale deployment of photocatalytic concrete in play a crucial role in driving innovation deployment in urban infrastructure projects. infrastructure projects, including pavements, and facilitating the commercialization of Field trials conducted in Chinese cities have building facades, and noise barriers. photocatalytic concrete technology at demonstrated the efficacy of photocatalytic Additionally, European nations, such as Italy, competitive price points. concrete in improving air quality and Spain, and Switzerland, have embraced reducing surface dirt accumulation. Review of Research on photocatalytic concrete technology as Photocatalytic Concrete part of their efforts to mitigate urban Technology pollution and promote sustainable urban development. Research initiatives and Research on photocatalytic concrete pilot projects have been undertaken in technology has spanned multiple decades collaboration with academic institutions, and involved contributions from various industry partners, and government agencies countries worldwide. This review provides to evaluate the performance and feasibility a concise overview of key findings and of photocatalytic concrete in various climatic advancements in this field, emphasizing the and environmental conditions. contributions of Japan, the European Union (EU), the United States, and China. The versatility of photocatalytic concrete technology enables its application across Japan: Pioneering studies by Japanese a wide range of construction projects and researchers have been instrumental in urban infrastructure. Common applications understanding the photocatalytic properties include pavements, building facades, of materials like titanium dioxide (TiO2) and noise barriers. While the benefits of and their application in concrete. Research photocatalytic concrete technology are conducted by institutions like the National evident, cost considerations remain a key Institute for Materials Science (NIMS) factor influencing its widespread adoption has demonstrated the effectiveness of in construction projects. The initial cost of photocatalytic concrete in reducing air incorporating photocatalytic materials, such pollutants like nitrogen oxides (NOx) and as nanostructured TiO2, into concrete mixes volatile organic compounds (VOCs), thus is higher compared to conventional concrete improving urban air quality. formulations. However, lifecycle cost European Union (EU): The EU has made analyses indicate potential long-term savings significant contributions to optimizing due to reduced maintenance expenses, photocatalytic materials and concrete extended service life, and environmental formulations through funded research benefits associated with improved air quality initiatives. Projects funded by programs like Figure 2: Photocatalytic Concrete and reduced pollution levels. Horizon 2020 have shown promising results
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Production and Application - A European Union (EU): EU countries chemical exposures. Photocatalytic concrete Comparative Analysis Across prioritize sustainable development and have is designed to maintain its structural integrity Different Countries invested in scaling up production capacities. and aesthetic appearance over extended Installations include over 1 million square service life. Photocatalytic concrete technology has meters of photocatalytic concrete surfaces, gained global recognition for its potential - Chloride Ion Penetration Resistance: leading to a 15% decrease in airborne to revolutionize sustainable construction Photocatalytic concrete exhibits enhanced particulate matter (PM) concentrations. practices and address environmental resistance to chloride ion penetration challenges. Here's a brief overview of its United States: The US focuses on compared to conventional concrete, production and application in key countries: addressing air quality concerns, with reducing the risk of corrosion in reinforced photocatalytic concrete deployed in structures. Japan: Japan leads in research and highways and public spaces. Field trials development, with extensive deployment - Freeze-Thaw Resistance: Properly demonstrate potential annual savings of in infrastructure, transportation, and urban designed photocatalytic concrete mixes over $100 million in maintenance costs development. Over 500,000 square meters demonstrate good resistance to freeze- and a 10% reduction in greenhouse gas of photocatalytic concrete pavements thaw cycles, minimizing the potential for emissions. are installed in major cities, resulting in a damage in cold climates. China: China, driven by rapid urbanization, significant reduction in nitrogen oxide (NOx) - Abrasion Resistance: The abrasion has become a major consumer and emissions. resistance of photocatalytic concrete producer. Installations cover over 10 million square meters, resulting in a 25% reduction varies depending on factors such as in air pollutant concentrations. surface finish and aggregate type. Surface treatments or coatings may be applied to Mechanical Characteristics of enhance abrasion resistance in high-traffic Photocatalytic Concrete areas. Compressive Strength: Compressive - Chemical Resistance: Photocatalytic strength is a key indicator of the load- concrete demonstrates resistance to bearing capacity of concrete and is chemical attack from pollutants, acids, and typically measured in megapascals (MPa). alkalis, contributing to its longevity in urban Photocatalytic concrete generally exhibits environments. compressive strength values comparable Other Properties: Other mechanical to conventional concrete mixes, with slight properties of photocatalytic concrete, such variations depending on factors such as mix as modulus of elasticity, shrinkage, and design and curing conditions. creep, are influenced by factors including - Typical compressive strength of mix proportions, curing methods, and photocatalytic concrete ranges from environmental conditions. Research and 20 MPa to 50 MPa. testing continue to refine the understanding - Higher strength grades, such as of these properties and optimize photocatalytic high-performance concrete photocatalytic concrete formulations for (PHPC), can achieve compressive specific applications. strengths exceeding 60 MPa. Thorough testing and quality assurance Flexural Strength: Flexural strength, also protocols are essential to ensure that known as modulus of rupture, measures photocatalytic concrete meets performance the ability of concrete to resist bending requirements for intended applications in stresses. It is an important parameter for construction projects. structural elements subjected to bending loads, such as beams and slabs. Chemical Characteristics of - Typical flexural strength of photocatalytic Photocatalytic Concrete concrete ranges from 3 MPa to 7 MPa. Photocatalytic concrete possesses - Advanced formulations incorporating fiber unique chemical properties crucial for its reinforcement or supplementary cementitious multifunctionality. Key aspects include: materials may exhibit higher flexural strength Photocatalytic Activity: Utilizing materials values, reaching up to 10 MPa. like titanium dioxide (TiO2), photocatalytic Durability: Durability is a critical aspect of concrete initiates chemical reactions when Figure 3: Photocatalytic Concrete with Self-cleaning Properties concrete performance, particularly in harsh exposed to light, effectively degrading environmental conditions or aggressive pollutants and organic matter on its surface.
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Degradation of Pollutants: Through - Indian Institute of Technology (IIT) Madras installations contribute to reducing surface photocatalysis, photocatalytic concrete - Council of Scientific and Industrial Research soiling and microbial growth, thereby breaks down pollutants such as nitrogen (CSIR) - Central Building Research Institute improving public health and hygiene. oxides (NOx) and volatile organic (CBRI), Roorkee Cost Comparison: The cost of photocatalytic compounds (VOCs), improving air quality concrete per cubic meter varies depending - National Institute of Technology (NIT) Trichy and reducing environmental pollution. on factors such as the type of photocatalytic These institutions have established dedicated Self-Cleaning Properties: Photocatalytic additive used, project specifications, and research groups or centers focusing reactions enable the concrete to self-clean market conditions. However, it is generally on sustainable construction materials by decomposing dirt, grime, and organic higher than conventional concrete due to the and technologies, where research on stains upon exposure to light, maintaining a additional cost of photocatalytic materials photocatalytic concrete is being conducted. pristine surface with minimal maintenance. and manufacturing processes. Anti-Microbial Effects: Photocatalytic Production and Usage in India For example, the cost of producing regular concrete inhibits microbial growth by There are notable developments in the M40 grade concrete in India is approximately disrupting cell membranes of bacteria, production and application of photocatalytic 4,500 to 6,000 per cubic meter, whereas fungi, and algae, enhancing hygiene and concrete across the country. photocatalytic concrete may cost around preventing biofilm formation. 5,500 to 7,500 per cubic meter (The prices Production: Several Indian manufacturers Chemical Stability: Despite its active are hypothetical numbers just for illustration have begun commercial production of chemical reactions, photocatalytic only). These figures are indicative and may photocatalytic concrete materials, including concrete maintains stability, ensuring long- vary based on project requirements and photocatalytic additives such as titanium term performance and durability without suppliers' pricing strategies. dioxide (TiO2). These materials are being compromising structural integrity. incorporated into concrete mixes to impart Despite the slightly higher initial cost, photocatalytic properties, enabling the the long-term benefits of photocatalytic Development Aspects of concrete, such as improved air quality, degradation of air pollutants and enhancing Photocatalytic Concrete in reduced maintenance, and enhanced self-cleaning capabilities. India: Present Status durability, justify its investment for Examples of Usage: The application of In recent years, India has shown a growing sustainable construction projects in India. photocatalytic concrete in India spans interest in sustainable construction practices, Collaboration and Partnerships: various construction projects, ranging from including the development and adoption of Collaborative efforts between academia, infrastructure to commercial and residential photocatalytic concrete technology. While the industry, and government agencies buildings. Some notable examples include: country is still in the early stages of exploration have been instrumental in advancing and implementation, significant progress has • Urban Pavements photocatalytic concrete technology in India. been made in research, innovation, and pilot Photocatalytic concrete pavements are Partnerships with international organizations projects. Here, we examine the current status being installed in urban areas to mitigate air and knowledge sharing platforms have of development aspects of photocatalytic pollution and improve air quality. Cities like facilitated technology transfer, capacity concrete in India, along with the key research Delhi, Mumbai, and Bengaluru have initiated building, and access to funding opportunities institutions involved: pilot projects to evaluate the effectiveness for research and implementation projects. Research and Development: Indian of photocatalytic concrete in reducing Challenges and Opportunities: Despite academic institutions, research pollutant levels. the progress made, photocatalytic concrete organizations, and industry players • Building Facades faces several challenges in India, including have been actively engaged in research Photocatalytic coatings and panels are cost considerations, scalability issues, and development activities related to being used on building facades to enhance and awareness among stakeholders. photocatalytic concrete. Studies have self-cleaning properties and maintain The initial cost of photocatalytic materials focused on optimizing photocatalytic aesthetic appeal. Landmark buildings and specialized construction techniques materials, exploring novel concrete and commercial complexes in major cities remains a barrier to widespread adoption. formulations, and assessing the are incorporating photocatalytic concrete However, opportunities exist to address performance of photocatalytic concrete in elements to achieve sustainable and visually these challenges through innovation, local Indian environmental conditions. appealing designs. manufacturing, and policy support. Prominent research institutions involved in • Public Spaces Future Prospects: The future of the study of photocatalytic concrete in India photocatalytic concrete in India looks Parks, squares, and public transportation include: promising, driven by increasing awareness hubs are integrating photocatalytic concrete - Indian Institute of Technology (IIT) Bombay surfaces to create cleaner and more of environmental sustainability, government - Indian Institute of Technology (IIT) Delhi hygienic environments for citizens. These initiatives promoting green construction
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practices, and growing investments in o Collaborative Efforts: Collaborative 2. Li, L., Luo, M., & Huang, H. (2019). infrastructure development. With continued efforts between academia, industry, and Photocatalytic pavement: A promising research, innovation, and collaboration, government agencies are driving progress strategy for improving urban air quality. photocatalytic concrete is poised to play in photocatalytic concrete technology Journal of Environmental Management, a significant role in addressing India's in India. Partnerships with international 231, 1066-1075. urban challenges, including air pollution, organizations and knowledge sharing 3. Nataraja, M. C., Ramegowda, D., & sanitation, and sustainable urbanization. platforms have facilitated technology Rudresh, K. (2016). A comprehensive Conclusion transfer, capacity building, and access review on the development of eco-friendly The development of photocatalytic to funding opportunities for research and photocatalytic concrete. Construction and concrete technology presents a promising implementation projects. Building Materials, 110, 134-146. pathway towards sustainable construction o Future Directions: Looking ahead, 4. NIOSH. (2016). Preventing Silicosis practices and environmental remediation the future of photocatalytic concrete and Deaths in Construction Workers. efforts in India. Despite being in the early in India appears promising. With U.S. Department of Health and Human stages of exploration and implementation, increasing awareness of environmental Services, Centers for Disease Control significant strides have been made in sustainability, government initiatives and Prevention, National Institute for research, innovation, and pilot projects. promoting green construction practices, Occupational Safety and Health. DHHS Key conclusions drawn from the above and growing investments in infrastructure (NIOSH) Publication No. 96-112. discussions include: development, photocatalytic concrete 5. Pacheco-Torgal, F., Aguiar, J. B., Ding, Y., o Growing Interest and Engagement: India is poised to play a significant role in Jalali, S., &Miraldo, S. (2012). Materials has demonstrated a growing interest in creating cleaner, more sustainable urban and products to save the environment. sustainable construction practices, as environments. Springer Science & Business Media. evidenced by the increasing engagement o Continued research, innovation, 6. Rajasekaran, C., Santhanam, M., & of academic institutions, research and collaboration will be essential to Parida, S. (2019). Photocatalytic concrete organizations, and industry players in overcoming challenges and accelerating pavements for sustainable transportation the study of photocatalytic concrete. This the adoption of photocatalytic concrete infrastructure: A review. Transportation trend reflects a broader shift towards technology across India. Research Part D: Transport and environmentally conscious approaches To sum up, while challenges remain, the Environment, 67, 684-696. to infrastructure development. development of photocatalytic concrete in 7. Wu, Z., Oeser, M., & Herrmann, H. (2018). o Research and Innovation: Research India represents a significant step towards Photoactive concrete pavements: An institutions such as the Indian Institutes achieving the goals of sustainability emerging technology for sustainable of Technology (IITs), Council of Scientific and environmental stewardship in the development. Journal of Cleaner and Industrial Research (CSIR) labs, construction sector. Production, 174, 364-377. and National Institutes of Technology By leveraging research, innovation, and (NITs) have established dedicated 8. Yang, Y., Ho, J. C., & Yang, K. H. (2021). collaborative partnerships, India can research groups focusing on sustainable Photocatalytic concrete: Technology, harness the potential of photocatalytic construction materials. challenges, and future prospects. concrete to address pressing urban Construction and Building Materials, 275, o Pilot Projects and Demonstrations: While challenges and pave the way towards a 122143. the scale of deployment is relatively greener, more resilient future. modest compared to other countries, 9. Zhang, Z., Duan, P., Zhang, Y., & Li, J. References several pilot projects and demonstrations (2020). Research progress of nano- 1. Akbarnejad, M. M., Aslani, F., &Nejadi, TiO2 photocatalytic concrete. In IOP showcasing the application of S. (2017). A comprehensive review of Conference Series: Materials Science and photocatalytic concrete have been TiO2-based photocatalytic cementitious Engineering (Vol. 725, No. 1, p. 012005). initiated in India. These projects serve materials: Photocatalytic mechanism, IOP Publishing. as valuable learning experiences fabrication, durability assessment, and and demonstrate the potential of 10. Zhao, Z., & Lin, X. (2018). Photocatalytic challenges. Cement and Concrete photocatalytic concrete in addressing concrete for air purification: A review Composites, 80, 227-241. urban challenges such as air pollution on factors influencing NOx removal and sanitation. performance. Journal of Environmental Management, 206, 749-764.