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Advancements & Opportunities

in Photocatalytic Concrete
Technology: A Global Review

Research on photocatalytic concrete Introduction


The exploration and implementation of photocatalytic
technology has spanned multiple decades
concrete technology have gained significant momentum
and involved contributions from various in recent years as a response to the pressing need for
sustainable construction materials and environmental
countries worldwide. This review provides
remediation strategies. The inception of photocatalytic
a concise overview of key findings and concrete technology can be traced back to the late
20th century when pioneering research efforts began to
advancements in this field, emphasizing
investigate the photocatalytic properties of semiconductor
the contributions of Japan, the European materials, notably titanium dioxide (TiO2). Early studies
laid the groundwork for understanding the principles of
Union (EU), the United States, and China.
photocatalysis and its potential application in concrete
Dr S B Hegde, Professor, materials.
Throughout the 1990s and early 2000s, academic
Department of Civil
institutions and research laboratories worldwide conducted
Engineering, Jain College of fundamental research to elucidate the mechanisms of
photocatalytic degradation and optimize photocatalyst
Engineering and Technology,
formulations for concrete integration. The adoption and
Hubli, Karnataka, and Visiting implementation of photocatalytic concrete technology
have been observed across various countries, reflecting
Professor, Pennsylvania
the global interest in sustainable construction practices
State University, USA and environmental stewardship.

2 NBM MEDIA | ICCT | MARCH - APRIL 2024


in degrading organic pollutants on concrete
surfaces, highlighting the potential of
photocatalytic concrete panels in improving
environmental sustainability.
United States: In recent years, research
in the United States has focused on
integrating photocatalytic properties into
concrete matrices to address urban pollution
concerns. Institutions such as MIT and UC
Berkeley have explored novel approaches to
Figure 1: Concrete with photocatalytic activity
enhance photocatalytic activity, employing
advanced characterization techniques to
Notably, countries with high urbanization Moreover, advancements in manufacturing study degradation mechanisms and optimize
rates and a focus on combating air pollution processes, economies of scale, and performance.
have been early adopters of photocatalytic ongoing research efforts aimed at optimizing
China: China has emerged as a leader
concrete solutions. Japan stands out as a photocatalytic concrete formulations are
in photocatalytic concrete technology,
pioneer in the field, with extensive research expected to contribute to cost reductions
leveraging its research infrastructure and
and real-world applications dating back to and enhanced cost-effectiveness over time.
manufacturing capabilities. Research efforts
the early 2000s. Japanese cities, particularly Collaborative initiatives involving academia,
have concentrated on developing cost-
Tokyo and Osaka, have witnessed widespread industry, and government stakeholders
effective formulations suitable for large-scale
deployment of photocatalytic concrete in play a crucial role in driving innovation
deployment in urban infrastructure projects.
infrastructure projects, including pavements, and facilitating the commercialization of
Field trials conducted in Chinese cities have
building facades, and noise barriers. photocatalytic concrete technology at
demonstrated the efficacy of photocatalytic
Additionally, European nations, such as Italy, competitive price points.
concrete in improving air quality and
Spain, and Switzerland, have embraced reducing surface dirt accumulation.
Review of Research on
photocatalytic concrete technology as
Photocatalytic Concrete
part of their efforts to mitigate urban
Technology
pollution and promote sustainable urban
development. Research initiatives and Research on photocatalytic concrete
pilot projects have been undertaken in technology has spanned multiple decades
collaboration with academic institutions, and involved contributions from various
industry partners, and government agencies countries worldwide. This review provides
to evaluate the performance and feasibility a concise overview of key findings and
of photocatalytic concrete in various climatic advancements in this field, emphasizing the
and environmental conditions. contributions of Japan, the European Union
(EU), the United States, and China.
The versatility of photocatalytic concrete
technology enables its application across Japan: Pioneering studies by Japanese
a wide range of construction projects and researchers have been instrumental in
urban infrastructure. Common applications understanding the photocatalytic properties
include pavements, building facades, of materials like titanium dioxide (TiO2)
and noise barriers. While the benefits of and their application in concrete. Research
photocatalytic concrete technology are conducted by institutions like the National
evident, cost considerations remain a key Institute for Materials Science (NIMS)
factor influencing its widespread adoption has demonstrated the effectiveness of
in construction projects. The initial cost of photocatalytic concrete in reducing air
incorporating photocatalytic materials, such pollutants like nitrogen oxides (NOx) and
as nanostructured TiO2, into concrete mixes volatile organic compounds (VOCs), thus
is higher compared to conventional concrete improving urban air quality.
formulations. However, lifecycle cost European Union (EU): The EU has made
analyses indicate potential long-term savings significant contributions to optimizing
due to reduced maintenance expenses, photocatalytic materials and concrete
extended service life, and environmental formulations through funded research
benefits associated with improved air quality initiatives. Projects funded by programs like
Figure 2: Photocatalytic Concrete
and reduced pollution levels. Horizon 2020 have shown promising results

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Production and Application - A European Union (EU): EU countries chemical exposures. Photocatalytic concrete
Comparative Analysis Across prioritize sustainable development and have is designed to maintain its structural integrity
Different Countries invested in scaling up production capacities. and aesthetic appearance over extended
Installations include over 1 million square service life.
Photocatalytic concrete technology has
meters of photocatalytic concrete surfaces,
gained global recognition for its potential - Chloride Ion Penetration Resistance:
leading to a 15% decrease in airborne
to revolutionize sustainable construction Photocatalytic concrete exhibits enhanced
particulate matter (PM) concentrations.
practices and address environmental resistance to chloride ion penetration
challenges. Here's a brief overview of its United States: The US focuses on compared to conventional concrete,
production and application in key countries: addressing air quality concerns, with reducing the risk of corrosion in reinforced
photocatalytic concrete deployed in structures.
Japan: Japan leads in research and
highways and public spaces. Field trials
development, with extensive deployment - Freeze-Thaw Resistance: Properly
demonstrate potential annual savings of
in infrastructure, transportation, and urban designed photocatalytic concrete mixes
over $100 million in maintenance costs
development. Over 500,000 square meters demonstrate good resistance to freeze-
and a 10% reduction in greenhouse gas
of photocatalytic concrete pavements thaw cycles, minimizing the potential for
emissions.
are installed in major cities, resulting in a damage in cold climates.
China: China, driven by rapid urbanization,
significant reduction in nitrogen oxide (NOx) - Abrasion Resistance: The abrasion
has become a major consumer and
emissions. resistance of photocatalytic concrete
producer. Installations cover over 10 million
square meters, resulting in a 25% reduction varies depending on factors such as
in air pollutant concentrations. surface finish and aggregate type. Surface
treatments or coatings may be applied to
Mechanical Characteristics of enhance abrasion resistance in high-traffic
Photocatalytic Concrete areas.
Compressive Strength: Compressive - Chemical Resistance: Photocatalytic
strength is a key indicator of the load- concrete demonstrates resistance to
bearing capacity of concrete and is chemical attack from pollutants, acids, and
typically measured in megapascals (MPa). alkalis, contributing to its longevity in urban
Photocatalytic concrete generally exhibits environments.
compressive strength values comparable
Other Properties: Other mechanical
to conventional concrete mixes, with slight
properties of photocatalytic concrete, such
variations depending on factors such as mix
as modulus of elasticity, shrinkage, and
design and curing conditions.
creep, are influenced by factors including
- Typical compressive strength of mix proportions, curing methods, and
photocatalytic concrete ranges from environmental conditions. Research and
20 MPa to 50 MPa.
testing continue to refine the understanding
- Higher strength grades, such as of these properties and optimize
photocatalytic high-performance concrete photocatalytic concrete formulations for
(PHPC), can achieve compressive specific applications.
strengths exceeding 60 MPa.
Thorough testing and quality assurance
Flexural Strength: Flexural strength, also protocols are essential to ensure that
known as modulus of rupture, measures photocatalytic concrete meets performance
the ability of concrete to resist bending requirements for intended applications in
stresses. It is an important parameter for
construction projects.
structural elements subjected to bending
loads, such as beams and slabs. Chemical Characteristics of
- Typical flexural strength of photocatalytic Photocatalytic Concrete
concrete ranges from 3 MPa to 7 MPa. Photocatalytic concrete possesses
- Advanced formulations incorporating fiber unique chemical properties crucial for its
reinforcement or supplementary cementitious multifunctionality. Key aspects include:
materials may exhibit higher flexural strength
Photocatalytic Activity: Utilizing materials
values, reaching up to 10 MPa.
like titanium dioxide (TiO2), photocatalytic
Durability: Durability is a critical aspect of concrete initiates chemical reactions when
Figure 3: Photocatalytic Concrete with
Self-cleaning Properties concrete performance, particularly in harsh exposed to light, effectively degrading
environmental conditions or aggressive pollutants and organic matter on its surface.

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Degradation of Pollutants: Through - Indian Institute of Technology (IIT) Madras installations contribute to reducing surface
photocatalysis, photocatalytic concrete - Council of Scientific and Industrial Research soiling and microbial growth, thereby
breaks down pollutants such as nitrogen (CSIR) - Central Building Research Institute improving public health and hygiene.
oxides (NOx) and volatile organic (CBRI), Roorkee Cost Comparison: The cost of photocatalytic
compounds (VOCs), improving air quality concrete per cubic meter varies depending
- National Institute of Technology (NIT) Trichy
and reducing environmental pollution. on factors such as the type of photocatalytic
These institutions have established dedicated
Self-Cleaning Properties: Photocatalytic additive used, project specifications, and
research groups or centers focusing
reactions enable the concrete to self-clean market conditions. However, it is generally
on sustainable construction materials
by decomposing dirt, grime, and organic higher than conventional concrete due to the
and technologies, where research on
stains upon exposure to light, maintaining a additional cost of photocatalytic materials
photocatalytic concrete is being conducted.
pristine surface with minimal maintenance. and manufacturing processes.
Anti-Microbial Effects: Photocatalytic Production and Usage in India For example, the cost of producing regular
concrete inhibits microbial growth by There are notable developments in the M40 grade concrete in India is approximately
disrupting cell membranes of bacteria, production and application of photocatalytic 4,500 to 6,000 per cubic meter, whereas
fungi, and algae, enhancing hygiene and concrete across the country. photocatalytic concrete may cost around
preventing biofilm formation. 5,500 to 7,500 per cubic meter (The prices
Production: Several Indian manufacturers
Chemical Stability: Despite its active are hypothetical numbers just for illustration
have begun commercial production of
chemical reactions, photocatalytic only). These figures are indicative and may
photocatalytic concrete materials, including
concrete maintains stability, ensuring long- vary based on project requirements and
photocatalytic additives such as titanium
term performance and durability without suppliers' pricing strategies.
dioxide (TiO2). These materials are being
compromising structural integrity. incorporated into concrete mixes to impart Despite the slightly higher initial cost,
photocatalytic properties, enabling the the long-term benefits of photocatalytic
Development Aspects of concrete, such as improved air quality,
degradation of air pollutants and enhancing
Photocatalytic Concrete in reduced maintenance, and enhanced
self-cleaning capabilities.
India: Present Status durability, justify its investment for
Examples of Usage: The application of
In recent years, India has shown a growing sustainable construction projects in India.
photocatalytic concrete in India spans
interest in sustainable construction practices, Collaboration and Partnerships:
various construction projects, ranging from
including the development and adoption of Collaborative efforts between academia,
infrastructure to commercial and residential
photocatalytic concrete technology. While the industry, and government agencies
buildings. Some notable examples include:
country is still in the early stages of exploration have been instrumental in advancing
and implementation, significant progress has • Urban Pavements
photocatalytic concrete technology in India.
been made in research, innovation, and pilot Photocatalytic concrete pavements are
Partnerships with international organizations
projects. Here, we examine the current status being installed in urban areas to mitigate air
and knowledge sharing platforms have
of development aspects of photocatalytic pollution and improve air quality. Cities like
facilitated technology transfer, capacity
concrete in India, along with the key research Delhi, Mumbai, and Bengaluru have initiated
building, and access to funding opportunities
institutions involved: pilot projects to evaluate the effectiveness
for research and implementation projects.
Research and Development: Indian of photocatalytic concrete in reducing
Challenges and Opportunities: Despite
academic institutions, research pollutant levels.
the progress made, photocatalytic concrete
organizations, and industry players • Building Facades
faces several challenges in India, including
have been actively engaged in research Photocatalytic coatings and panels are cost considerations, scalability issues,
and development activities related to being used on building facades to enhance and awareness among stakeholders.
photocatalytic concrete. Studies have self-cleaning properties and maintain The initial cost of photocatalytic materials
focused on optimizing photocatalytic aesthetic appeal. Landmark buildings and specialized construction techniques
materials, exploring novel concrete and commercial complexes in major cities remains a barrier to widespread adoption.
formulations, and assessing the are incorporating photocatalytic concrete However, opportunities exist to address
performance of photocatalytic concrete in elements to achieve sustainable and visually these challenges through innovation, local
Indian environmental conditions. appealing designs. manufacturing, and policy support.
Prominent research institutions involved in • Public Spaces Future Prospects: The future of
the study of photocatalytic concrete in India photocatalytic concrete in India looks
Parks, squares, and public transportation
include: promising, driven by increasing awareness
hubs are integrating photocatalytic concrete
- Indian Institute of Technology (IIT) Bombay surfaces to create cleaner and more of environmental sustainability, government
- Indian Institute of Technology (IIT) Delhi hygienic environments for citizens. These initiatives promoting green construction

NBM MEDIA | ICCT | MARCH - APRIL 2024 5


practices, and growing investments in o Collaborative Efforts: Collaborative 2. Li, L., Luo, M., & Huang, H. (2019).
infrastructure development. With continued efforts between academia, industry, and Photocatalytic pavement: A promising
research, innovation, and collaboration, government agencies are driving progress strategy for improving urban air quality.
photocatalytic concrete is poised to play in photocatalytic concrete technology Journal of Environmental Management,
a significant role in addressing India's in India. Partnerships with international 231, 1066-1075.
urban challenges, including air pollution, organizations and knowledge sharing 3. Nataraja, M. C., Ramegowda, D., &
sanitation, and sustainable urbanization. platforms have facilitated technology Rudresh, K. (2016). A comprehensive
Conclusion transfer, capacity building, and access review on the development of eco-friendly
The development of photocatalytic to funding opportunities for research and photocatalytic concrete. Construction and
concrete technology presents a promising implementation projects. Building Materials, 110, 134-146.
pathway towards sustainable construction o Future Directions: Looking ahead, 4. NIOSH. (2016). Preventing Silicosis
practices and environmental remediation the future of photocatalytic concrete and Deaths in Construction Workers.
efforts in India. Despite being in the early in India appears promising. With U.S. Department of Health and Human
stages of exploration and implementation, increasing awareness of environmental Services, Centers for Disease Control
significant strides have been made in sustainability, government initiatives and Prevention, National Institute for
research, innovation, and pilot projects. promoting green construction practices, Occupational Safety and Health. DHHS
Key conclusions drawn from the above and growing investments in infrastructure (NIOSH) Publication No. 96-112.
discussions include: development, photocatalytic concrete
5. Pacheco-Torgal, F., Aguiar, J. B., Ding, Y.,
o Growing Interest and Engagement: India is poised to play a significant role in
Jalali, S., &Miraldo, S. (2012). Materials
has demonstrated a growing interest in creating cleaner, more sustainable urban
and products to save the environment.
sustainable construction practices, as environments.
Springer Science & Business Media.
evidenced by the increasing engagement o Continued research, innovation,
6. Rajasekaran, C., Santhanam, M., &
of academic institutions, research and collaboration will be essential to
Parida, S. (2019). Photocatalytic concrete
organizations, and industry players in overcoming challenges and accelerating
pavements for sustainable transportation
the study of photocatalytic concrete. This the adoption of photocatalytic concrete
infrastructure: A review. Transportation
trend reflects a broader shift towards technology across India.
Research Part D: Transport and
environmentally conscious approaches To sum up, while challenges remain, the Environment, 67, 684-696.
to infrastructure development. development of photocatalytic concrete in
7. Wu, Z., Oeser, M., & Herrmann, H. (2018).
o Research and Innovation: Research India represents a significant step towards
Photoactive concrete pavements: An
institutions such as the Indian Institutes achieving the goals of sustainability
emerging technology for sustainable
of Technology (IITs), Council of Scientific and environmental stewardship in the
development. Journal of Cleaner
and Industrial Research (CSIR) labs, construction sector.
Production, 174, 364-377.
and National Institutes of Technology By leveraging research, innovation, and
(NITs) have established dedicated 8. Yang, Y., Ho, J. C., & Yang, K. H. (2021).
collaborative partnerships, India can
research groups focusing on sustainable Photocatalytic concrete: Technology,
harness the potential of photocatalytic
construction materials. challenges, and future prospects.
concrete to address pressing urban
Construction and Building Materials, 275,
o Pilot Projects and Demonstrations: While challenges and pave the way towards a
122143.
the scale of deployment is relatively greener, more resilient future.
modest compared to other countries, 9. Zhang, Z., Duan, P., Zhang, Y., & Li, J.
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