PSD-185 Treatment of Industrial Waste

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Treatment

of Industrial

CEU 185
Waste
Continuing Education from the
American Society of Plumbing Engineers

MARCH 2012

ASPE.ORG/ReadLearnEarn
READ, LEARN, EARN

Note: In determining your answers to the CE questions, use only the material presented in the corresponding continuing education
article. Using information from other materials may result in a wrong answer.

“Industrial wastewater” is a generic term used to describe Definitions


nonsanitary (plumbing) effluent, such as that typically found Hazardous substance Under Section 311 of the Clean
in chemical, pharmaceutical, and other manufacturing facili- Water Act, the EPA has compiled a list of hazardous sub-
ties. It also may be applied to wastewater from commercial stances (40 CFR 116). If a substance on this list is spilled or
facilities, such as self-service laundries or large restaurants. discharged, it must be reported to the EPA.
The definition also includes storm water runoff containing Priority pollutant The Natural Resources Defense
anything considered harmful by the U.S. Environmental Council and the EPA determine priority toxic pollutants.
Protection Agency (EPA) discharged from sites involving These pollutants have been incorporated into several regu-
any industrial activity or construction. latory programs, including NPDES permits, pretreatment
This chapter describes the regulatory framework gov- standards (40 CFR 403), hazardous wastes (40 CFR 261),
erning industrial wastewater, hazardous substances, and and CERCLA (42 USC 103).
hazardous wastes and the impact of these regulations on Hazardous wastes The EPA has adopted regulations to
industrial-process plumbing design. It also contains design control hazardous wastes under RCRA. These regulations (40
considerations, describes a few of the more common treat- CFR 261) list hazardous wastes, including specific chemicals
ment technologies, and provides resources from which more and mixtures defined by their characteristics. It should be
detailed information can be obtained. noted that controls under RCRA apply to waste only and not
Whether discharged to municipal sewers, surface waters, to hazardous substances that are being stored prior to use in
deep wells, or land, industrial wastewater and some storm product manufacturing or that are to be reclaimed, recycled,
water runoff are subject to government permitting require- or reused. RCRA regulates the generation, transportation,
ments. In most cases, these wastes must be treated before storage, treatment, and disposal of hazardous wastes.
discharge to abate pollution. Permits specify the maximum Hazardous materials This term means substances
allowable concentrations of pollutants in the discharge and or materials that have been determined by the secretary of
the frequency and type of monitoring required to show transportation, under 49 CFR 172, to be capable of posing
compliance. Pollution abatement by dilution is no longer al- an unreasonable risk to health, safety, and property when
lowed. The segregation of incidental water streams, such as transported in commerce. Chemicals included in this defini-
non-contact cooling water or storm water runoff, from pro- tion are hazardous substances, hazardous wastes, most of the
cess wastewater is almost universally required. Even clean, priority pollutants, and many other chemicals in commerce
incidental wastewater streams require a permit. that are too numerous to mention here. In this chapter, the
Most nonaqueous liquids (including solvents, oils, and term “hazardous materials” is used to describe all the previ-
sludge) and some solids and gases are regulated as hazardous ously defined materials and substances.
substances or hazardous wastes during their generation, use, For detailed listings of these and other regulated chemi-
collection, storage, transportation, treatment, and disposal. cals and wastes, refer to the regulations cited in the above
Some aqueous wastes that are not regulated under a waste- definitions.
water permit are regulated as either hazardous substances
or hazardous wastes. Regulatory Framework
As a result of these regulations, plumbing designers must The most important pieces of environmental legislation
either consult with an experienced environmental engineer affecting the design of plumbing systems for hazardous
or become familiar with the various environmental require- material and waste facilities serving industrial plants are
ments to ensure an acceptable installation. New facilities the Clean Water Act (CWA), Resource Conservation and
must meet both environmental and plumbing code require- Recovery Act (RCRA), and Comprehensive Environmental
ments. For novel manufacturing processes, the designer, Response, Compensation, and Liability Act (CERCLA), oth-
environmental engineer, and owner may be required to erwise known as Superfund. These regulations, promulgated
work with regulatory authorities during the design stage to by the EPA and enforced by either the EPA or counterpart
ensure compliance with the intent of the various codes and state agencies, provide a comprehensive framework of pollu-
regulations. The designer is responsible for producing an tion control. The National Pollutant Discharge Elimination
installation with a low probability of failure. For plumbing System (NPDES) permitting program has recently been
design, this means minimizing the possibility of leaks and revised to include the discharge of storm water from selected
providing a means to limit the impact of spills on the public’s industrial sites. Current EPA regulations can be found in
safety and the environment.

Reprinted from Chapter 3, ASPE Plumbing Engineering Design Handbook, Vol 3 (2011).

2 Read, Learn, Earn MARCH 2012


the Code of Federal Regulations (CFR), which is an annually Table 3-1 Industries Affected by the Effluent
updated compendium of all federal regulations. Any updates Guidelines Program Plan
or regulation changes after the last publication date of the Number Industry Category
CFR can be found in the Federal Register, a daily government 1 Aluminum Forming
newspaper in which all agencies and departments publish 2 Asbestos Manufacturing
their notices, proposals, and final regulations. Most states 3 Battery Manufacturing
with counterpart regulations have similar codifications and 4 Canned and Preserved Fruits and Vegetable
Processing
newspapers.
5 Canned and Preserved Seafood Processing
The great body of codes and regulations can easily be a
6 Carbon Black Manufacturing
labyrinth, even for those persons with a good understanding 7 Cement Manufacturing
of the overall outline and purpose of the statutes. Anyone 8 Centralized Waste Treatment
with questions should not hesitate to seek advice from 9 Coal Mining
trade groups, regulatory officials, environmental engineers, 10 Coil Coating
lawyers, and other specialists as needed. Numerous current 11 Concentrated Animal Feeding Operations
event reporting services digest federal and state regulatory 12 Concentrated Aquatic Animal Production
actions and publish readable evaluations as well as reprints 13 Copper Forming
of important regulations, policies, and case notes. 14 Dairy Products Processing
15 Electrical and Electronic Components
Clean Water Act 16 Electroplating
The CWA establishes a mechanism for setting uniform 17 Explosives Manufacturing
national standards for discharge to surface waters and sew- 18 Ferroalloy Manufacturing
ers. The EPA has established categorical effluent standards, 19 Fertilizer Manufacturing
usually prorated to production volume, for 56 industrial clas- 20 Glass Manufacturing
sifications under the Effluent Guidelines Program Plan. The 21 Grain Mills
affected industries are listed in Table 3-1. The EPA has also 22 Gum and Wood Chemicals
promulgated general standards for discharge to public sewer 23 Hospitals
systems. These standards restrict pollutants that interfere 24 Ink Formulating
with sewage treatment, pass through the system untreated, 25 Inorganic Chemicals
26 Iron and Steel Manufacturing
damage sewer lines or treatment facilities, or overload treat-
27 Landfills
ment processes.
28 Leather Tanning and Finishing
State laws and regulations follow the federal format, with 29 Meat and Poultry Products
a few important differences. All states are allowed to make 30 Metal Finishing
their regulations more stringent than the federal standards. 31 Metal Molding and Casting
Additionally, some states regulate discharges to the land (and 32 Metal Products and Machinery
hence to the groundwater). States also set goals for water 33 Mineral Mining and Processing
quality levels in streams, lakes, and coastal waters. They then 34 Nonferrous Metals Forming and Metal Powders
determine the allowable loading of each pollutant and allocate 35 Nonferrous Metals Manufacturing
portions of that loading based on low-flow conditions where 36 Oil and Gas Extraction
dilution is minimal. Water quality-based discharge permit 37 Ore Mining and Dressing
limits are almost always more stringent than industry-wide 38 Organic Chemicals, Plastics, and Synthetic Fibers
limits of the categorical effluent standards. 39 Paint Formulating
Two types of water discharge permits may require treat- 40 Paving and Roofing Materials (Tars and Asphalt)
41 Pesticide Chemicals
ment processes. Permits for a direct discharge into a surface
42 Petroleum Refining
water (stream, lake, ocean) are called National Pollutant
43 Pharmaceutical Manufacturing
Discharge Elimination System permits. These permits may 44 Phosphate Manufacturing
be issued by the EPA or a state or jointly, depending on the 45 Photographic
location. Application is required well in advance of initiating 46 Plastic Molding and Forming
a discharge. 47 Porcelain Enameling
The other type of industrial discharge permit is obtained 48 Pulp, Paper, and Paperboard
from a publicly owned treatment works (POTW). Industrial 49 Rubber Manufacturing
discharges to a POTW are called indirect discharges and are 50 Soaps and Detergents Manufacturing
regulated by pretreatment ordinances to ensure that the 51 Steam Electric Power Generating
POTW meets the conditions of its NPDES permit. The ordi- 52 Sugar Processing
nances are usually administered by the POTW, except when 53 Textile Mills
the industrial discharge is large, the POTW fails to meet its 54 Timber Products Processing
permit requirements, or the discharge is from an industry 55 Transportation Equipment Cleaning
56 Waste Combustors
regulated under the Effluent Guidelines Program Plan. Source: U.S. Environmental Protection Agency, 2008

MARCH 2012   Read, Learn, Earn 3


READ, LEARN, EARN: Treatment of Industrial Waste

Table 3-2 General Properties of Materials Used for Storage Tanks and Piping
Containment Materials Advantages Disadvantages
Carbon steel Compatible with petroleum products Subject to attack by corrosive soils and
and dry organics and incompatible chemicals.
with many aqueous solutions.
Stainless steel Better corrosion resistance than Corroded by chloride and exposure to
carbon steel and higher structural reducing environments.
strength—There are more than 70
standard types of stainless steel and
many special alloys.
Fiberglass-reinforced Compatible with a wide range of Lacks the structural strength and impact
plastic (FRP) petroleum and chemical products, if resistance of steel tanks.
proper resin is selected.
Polyvinyl chloride Excellent chemical resistance to Lower structural strength than steels,
acids, alkalis, and gasoline. generally not suited for the storage or
handling of organic solvents such as
benzene, carbon tetrachloride, and acetone,
or use at temperatures above 140°F (60°C).
Concrete Generally good resistance to alkaline Subject to cracking and spalling with
chemicals, epoxy coatings often changes in temperature such as during
applied to concrete to increase freeze/thaw cycles, uncoated concrete
chemical resistance. absorbs solvents.
Polypropylene Resistance to all aqueous solutions Low structural strength, temperature limit of
except strong oxidizers. 248°F (120°C).
Lined steel Chemical resistance of plastic and Relatively high cost for material and
structural strength of steel. installation.

RCRA and CERCLA RCRA permits for a facility may take six months and may
These two laws, together with the federal and state regula- require public hearings and disclosure of detailed process
tions derived from them, have had a major impact on the and waste information, including chemical material safety
industrial management of hazardous substances and hazard- data sheets (MSDS).
ous wastes. Almost all nonaqueous liquids, many aqueous When evaluating waste streams to determine if they are
mixtures, and many solids and gases are regulated when regulated as hazardous wastes, it is important to check both
they become wastes or are spilled. federal and state regulations. This is because states are al-
The purpose of CERCLA is to limit the uncontrolled re- lowed to be more stringent than the EPA. States may define
lease or threat of release of hazardous substances into the certain wastes as hazardous when the EPA doesn’t consider
environment and to provide for a coordinated and effective them so. For example, waste oil is considered hazardous by
response to mitigate actual releases. CERCLA requires in- many states, but not by the EPA.
dustrial risk evaluations, in the form of contingency plans, The relationship between RCRA and CERCLA is shown
and establishes a mechanism for governmental response to by this example: A tank containing a hazardous substance
environmental and health hazards. CERCLA does not require begins to leak onto the ground. Under CERCLA, the owner
any permits and does not force changes in current hazard- must notify the EPA and the state, stop the leak, and clean
ous substance handling methods. Nevertheless, a great deal up the spilled material. If the owner fails to take action, the
of publicity can result when the mishandling of hazardous regulatory agency may act under CERCLA and then seek
substances leads to an environmental incident. There also reimbursement up to triple the cost of its expenses. Under
can be an enormous cost to dispose of the hazardous wastes RCRA, the spilled hazardous substance and any contami-
generated during a spill. These are strong inducements to nated soil become hazardous waste. The hazardous waste
chemical manufacturers and users to install process systems must be removed, stored, transported, and disposed of in
that minimize risk. accordance with RCRA requirements.
RCRA’s purpose is similar to CERCLA’s, except that
RCRA regulates hazardous wastes from ongoing manu- Design Considerations
facturing activities. The goals of RCRA are accomplished For plumbing designers, the challenge is to design systems
through strict licensing and operational standards for every that minimize the chance of leaks, contain any spills that
aspect of hazardous waste management. might occur, and segregate hazardous substances from both
RCRA requires identification numbers and/or permits nonhazardous process streams and incompatible hazardous
for every hazardous waste activity. The permit applica- process streams. The design of a system that anticipates the
tion requirements are lengthy and technical for some of potential for leaks and spills must include suitable materi-
the regulated activities. In some cases, the regulations als, reliable joining, good fabrication, and provision for the
give performance standards that the designer must meet secondary containment of liquids in areas and systems that
to obtain a permit for the facility. In other cases, the com- pose a high spill risk.
pliance method is almost completely specified. Obtaining
4 Read, Learn, Earn MARCH 2012
Figure 3 -1 Acid/Caustic Neutralization Diagram

Many leaks occur as a result of material incompatibility Minimal equipment and practices for preventing trans-
between the equipment and either the hazardous substances fer spills should include overfill prevention including level
handled or the atmosphere in which the equipment is uti- sensors, gauges and a high-level alarm, automatic valve and
lized. The incompatibility can be physical, such as polyvinyl pump shutdown, established transfer procedures including
chloride (PVC) pipes melting at high temperatures or plastic an operator on duty, proper curbing and containment, re-
pipes dissolving in solvents they were not designed to contain. dundant valves and controls, vapor recovery, alarms, regular
Table 3-2 lists the general properties of the most common inspections, and a maintenance program. The equipment
tank and pipe materials. Specific applications should be used in water treatment is operated to achieve the following:
checked with the appropriate chemical compatibility refer- mixing and flocculation, sedimentation, clarification, filter-
ences from the manufacturer. ing, turbidity removal, metals removal, and disinfection.
Even the best designed liquid-handling systems are sub- Historically, underground tanks up to 10,000 gallons
ject to occasional failure, particularly during liquid transfer (37,854 L) in capacity and occasionally larger have been
operations. Secondary containment is an important aspect of preferred for hazardous materials, primarily to minimize
any hazardous material system design to protect employees fire risks. Unfortunately, many of these tanks were kept in
and the environment. Secondary containment may include service too long and, because of corrosion, have leaked and
a dike around a tank or tank farm or pipes within pipes for contaminated drinking water supplies. As a result, designers
systems handling extremely hazardous liquids. Common now must compare the environmental and fire risks of the
secondary containment systems typically have the following aboveground tank. In either case, more attention must be
features: given in the design to ensure that an installation is resistant
• Containment floors, pads, ponds, and dikes constructed to leaks and capable of containing spills. Soil conditions and
of materials impervious to the substance stored groundwater levels, which affect the design, must be evalu-
• Perimeter diking and storage reservoirs sized to contain ated for each installation. Secondary containment of these
110 percent of the largest tank plus the maximum rain- tanks is the primary method of ensuring against leakage.
fall predicted to occur over 24 hours once in 10 years in
exterior areas (or 20 minutes of sprinkler water flow for Elements of an Industrial
interior areas) Wastewater Handling System
• Pumps, drain valves, or siphons to empty the secondary pH Control
containment area to either a storage tank or a treatment
Neutralization for pH control involves the chemical reaction
facility
of an acid with an alkaline substance (a base), resulting in the
• Controls and procedures to prevent the accidental release
formation of a salt and water. In an aqueous solution, the acid
of contained spills and an alarm system to notify opera-
or base molecules dissociate and form ions. Sulfuric acid is
tions personnel if a spill occurs
presented in the solution as H+ (hydrogen) and SO4 (sulfate)
ions and caustic soda as Na+ (sodium) and OH– (hydroxide)
MARCH 2012   Read, Learn, Earn 5
READ, LEARN, EARN: Treatment of Industrial Waste

Figure 3-2 Conventional Electroplating Industry Wastewater Treatment


Note: Not to scale.

Figure 3-3 Treatment System with Wastewater Stream Segregation


Note: Not to scale.

6 Read, Learn, Earn MARCH 2012


Figure 3-4 Typical Continuous Treatment of Wastewater and Solids-handling System for Heavy Metals
Note: Not to scale.

ions. The H+ ions of the sulfuric acid and the OH– ions of the subsequent repetitive chemical additions. Overfeeding is
caustic soda have a strong attraction to each other and combine most probable in wastewater with no buffering capacity near
to form H2O (water). For example, in the neutralization reac- the pH setpoint (e.g., deionized and soft water). Controllers
tion of H2SO4 (sulfuric acid) and NaOH (sodium hydroxide), with multi-rate response adjustment should be specified for
the following process occurs: each application.
H+2SO4 + 2Na+OH– Sulfuric acid is the most costly method for pH adjustment
Na+2SO4 + 2H2O purposes, although in some cases the commercial 93 percent
If excess hydrogen ions remain, the liquid will be acidic, acid must be diluted prior to use. The manufacturer’s rec-
and with a surplus of hydroxide ions, the liquid will be al- ommendations for materials of construction, control of the
kaline. heat of dilution, and safety precautions should be carefully
The acidity or alkalinity of a solution is expressed on the followed. Carbon steel pipe and tanks are commonly used
pH scale, with neutral water at a pH of 7, in the middle of for 93 percent sulfuric acid, with stainless alloy 20 (a high
the range between extremely acid (pH = 0) and extremely nickel alloy) valves, as well as PVC and chlorinated polyvinyl
alkaline (pH = 14). The scale is logarithmic, so a pH of 3 is 10 chloride (CPVC) plastics. For sulfuric acid at concentrations
times more acidic than a pH of 4. Buffers, such as bicarbon- below 93 percent, polypropylene (PP), fiberglass-reinforced
ate/carbonate, undergo a chemical change when strong acids plastic (FRP), PVC, CPVC, and lined steel are preferred.
or bases are added to a solution and thereby act as capacitors Sodium hydroxide (caustic or caustic soda) in 50 percent
that must be filled before the pH will change. solution is the most convenient commercial alkaline material
A typical two-stage, continuous-flow pH neutralization for pH adjustment. Unfortunately, 50 percent caustic freezes
process is shown in Figure 3-1. For flows less than 10 gallons at 54°F (12.2°C), so indoor storage or heated tanks are neces-
per minute (gpm) (37.85 L/min), neutralizing in a batch basis, sary. (Note that 20 percent caustic freezes at -18°F [-27.7°C].)
with two tanks alternating between collection and treatment, Caustic solutions may be handled in carbon steel, stainless
is sometimes preferred. steel, and PVC tanks and pipe. Lime and hydrated lime are
The most critical feature of the pH adjustment system is considerably less expensive than caustic but must be fed with
the controller that activates the chemical feed pumps. The dry feeders and/or slurry tanks, which require considerable
controller must have the ability to prevent overfeeding of maintenance. Consequently, lime is favored in applications
either acid or base, which would cause wide pH swings and where the cost outweighs the convenience of caustic.

MARCH 2012   Read, Learn, Earn 7


READ, LEARN, EARN: Treatment of Industrial Waste

Figure 3-5 Emulsified Oil Removal Flow Sheet


Note: Not to scale.

Removal of Dissolved and Suspended Metals Oil/Water Separation


Another common industrial wastewater treatment require- Oil/water separation may involve free-floating oils, mechani-
ment is the removal of dissolved and suspended metals. The cal emulsions or diversions, and chemical emulsions. The size
most popular method is to separate cyanide and chromium of the oil droplets in emulsions may range from less than 20
VI wastewater sources from each other and all other metal- microns (µ) to more than 150 µ. In selecting the separation
bearing wastewaters. The cyanide is destroyed by oxidation equipment, the designer must consider the oil quantities,
with chlorine (or a sodium hypochlorite solution) at a pH of droplet size, presence of emulsifiers, temperature of the water
9 to 11, and the chromium VI is reduced to chromium III and oil, difference in the specific gravity of the fluids, fluid
with sulfur dioxide or sodium bisulfate at a pH of 2. Various viscosity, pH, and other wastewater constituents.
treatment methods are shown in Figures 3-2, 3-3, and 3-4. Separators are on the market to suit every situation,
For trace metals up to 1,000 parts per million (ppm), the including simple settling tanks (e.g., American Petroleum
use of ion-exchange vessels containing resin beads tailored to Institute separators), tanks with coalescing media to promote
the application may be considered. Ion exchange is a revers- the agglomeration of dispersed oils, and tanks with chemi-
ible chemical reaction wherein an ion (an atom or molecule cal pretreatment to promote the separation of chemically
that has lost or gained an electron and thus acquired an emulsified oils. Equipment options include sludge removal
electrical charge) from a wastewater solution is exchanged and automatic oil skimming. In special conditions, such as
for a similarly charged ion attached to an immobile solid where oil is mixed with and adheres to suspended solids,
particle. These solid ion particles are either naturally oc- dissolved-air flotation separators may be necessary. Figure
curring inorganic zeolites or synthetically produced organic 3-5 shows a unit designed to remove free and mechanically
resins, which are the predominant type used today because emulsified oil.
their characteristics can be tailored to specific applications. Biological Treatment
This process is similar to the process for purifying water for
Wastewater discharging directly to surface or groundwater
laboratory or process applications. The exact ion combina-
must be treated to remove organic compounds, which would
tions are based on the metals to be removed. The exchange
deplete the dissolved oxygen in the receiving water. Typi-
vessels can be sized for the wastewater flow, or multiple ves-
cally, permits allow an average of 30 milligrams per liter of
sels can be manifolded together to handle higher wastewater
five-day biological oxygen demand (BOD5). Treatment is
flows or to allow standby capacity. Automated controls and
accomplished by processes that convert soluble organic
accessories can be furnished to back-flush or regenerate the
compounds to biological cell mass, which can be separated
vessels. The removed metals can then be reclaimed or safely
from the effluent by gravity in a clarifier. Colloidal material
disposed. This technology should be evaluated against other
and some nondegradable compounds are normally absorbed
technologies for overall operating cost based on size and the
in the settled solids.
type of application.

8 Read, Learn, Earn MARCH 2012


Biological wastewater treatment plants are expensive to • Treatment of Organic Chemical Manufacturing Wastewa-
build and operate, and specialized experience is necessary to ter for Reuse, U.S. Environmental Protection Agency
produce a successful design. Consequently, a company faced • Technology for the Storage of Hazardous Liquids: A
with biological treatment requirements should first compare State-of-the-Art Review, New York State Department of
the feasibility and economics of discharging to a municipal Environmental Conservation
treatment system to building its own facility. If the build • CFR 40: Protection of Environment, U.S. Environmental
alternative is indicated, a choice must be made among the Protection Agency
available application methods, including activated sludge, Technology and Industry Handbooks
aerated lagoons, trickling filters and rotating filters, and the
• DeRenzo, D.J., Corrosion Resistant Materials Handbook,
anaerobic process. Expert advice is warranted.
4th edition, William Andrew Publishing/Noyes, 1985.
References • Kirk-Othmer Encyclopedia of Chemical Technology, John
Wiley and Sons Inc., 2004.
Codes and Standards • Perry’s Chemical Engineers’ Handbook, 8th edition,
• ANSI/ASME B31.3: Process Piping McGraw-Hill, 2008.
• API Spec 12D: Specification for Field Welded Tanks for • Schweitzer, Philip A., Handbook of Corrosion Resistant
Storage of Production Liquids Piping, 2nd edition, Krieger Publishing, 1985.
• API Spec 12F: Specification for Shop Welded Tanks for • Ion Exchange for Heavy Metal Removal, Wastech Con-
Storage of Production Liquids trols and Engineering.
• API Std 650: Welded Tanks for Oil Storage
• International Boiler and Pressure Vessel Code Resources
• FM Global Data Sheet 7-83: Drainage Systems for Flam- • American National Standards Institute: ansi.org
mable Liquids • American Petroleum Institute: api.org
• NFPA 30: Flammable and Combustible Liquids Code • American Society of Mechanical Engineers: asme.org
• UL 142: Steel Aboveground Tanks for Flammable and • National Fire Protection Association: nfpa.org
Combustible Liquids. • National Technical Information Service: ntis.gov
Government Publications • New York State Department of Environmental Conserva-
tion: www.dec.ny.gov
• Activated Carbon Process for the Treatment of Wastewater
• U.S. Government Printing Office: gpoaccess.gov
Containing Hexavalent Chromium, U.S. Environmental
• Underwriters Laboratories: ul.com
Protection Agency
• Effluent Limitation Guidelines, U.S. Environmental
Protection Agency

MARCH 2012   Read, Learn, Earn 9


CONTINUING EDUCATION:
READ, EARN,
Treatment
LEARN:ofLaboratory
Industrial Waste
Gases

ASPE Continuing Education Application Form


This form is valid up to one year from date of publication. Expiration date: Continuing education credit will be given for this examination
through March 31, 2013. Applications received after that date will not be processed.
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Reading the article and completing the form will


CE Questions —
allow you to apply to ASPE for CEU credit. If you “Treatment of Industrial Waste” (CEU 185)
earn a grade of 90 percent or higher on the test,
Circle the correct answers below.
you will be notified that you have logged 0.1
CEU, which can be applied toward CPD renewal 1. Which of the following regulates the 7. Which of the following has excellent
or numerous regulatory-agency CE programs. generation, storage, treatment, and chemical resistance to acids, alkalis, and
disposal of hazardous wastes? gasoline?
(Please note that it is your responsibility to deter-
a. Clean Water Act a. stainless steel
mine the acceptance policy of a particular agency.) b. Resource Conservation and Recovery b. polyethylene
CEU information will be kept on file at the ASPE Act c. polyvinyl chloride
office for three years. c. Superfund d. polypropylene
d. CERCLA 8. Which of the following can be used to
2. Which of the following is considered a prevent transfer spills?
I certify that I have read the article indicated hazardous material? a. proper curbing and containment
above. a. hazardous substances b. overfill prevention
b. substances that are capable of posing c. redundant valves and controls
an unreasonable risk to health when d. all of the above
Signature transported in commerce 9. The ________ is the most critical feature of
c. hazardous wastes a pH adjustment system.
d. all of the above a. chemical feed pump
Payment: 3. ________ is also known as Superfund. b. controller
❏ Member: Free a. EPA c. pH probe
❏ Nonmember: Each examination: $35 b. RCRA d. agitator
c. CERCLA 10. What is the most convenient commercial
❏ Personal Check (payable to ASPE) d. NPDES alkaline material for pH adjustment?
❏ Business or government check 4. Industrial discharges to a publicly owned a. lime
❏ DiscoverCard ❏ VISA ❏ MasterCard ❏ AMEX treatment works are called what? b. 50 percent caustic
a. untreated sewage c. sulfuric acid
b. direct discharges d. bicarbonate
If rebilling of a credit card charge is necessary, a $25
c. indirect discharges 11. ________ may be considered to remove
processing fee will be charged. d. foreign substance trace metals up to 1,000 ppm from
ASPE is hereby authorized to charge my CE 5. ________ is designed to limit the wastewater.
examination fee to my credit card uncontrolled release or threat of release a. ion exchange
of hazardous substances into the b. pH adjustment
environment. c. neutralization
Account Number a. CERCLA d. biological treatment
b. RCRA 12. You must consider ________ when
c. Effluent Guidelines Program Plan selecting oil/water separation equipment.
Expiration date d. Clean Water Act a. temperature of the oil and water
6. Plumbing designers must design systems b. oil droplet size
that ________. c. fluid viscosity
Signature
a. contain spills d. all of the above
b. minimize leaks
c. segregate hazardous substances
Cardholder’s name (Please print)
d. all of the above

10 Read, Learn, Earn MARCH 2012

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