Professional Documents
Culture Documents
PSD-185 Treatment of Industrial Waste
PSD-185 Treatment of Industrial Waste
of Industrial
CEU 185
Waste
Continuing Education from the
American Society of Plumbing Engineers
MARCH 2012
ASPE.ORG/ReadLearnEarn
READ, LEARN, EARN
Note: In determining your answers to the CE questions, use only the material presented in the corresponding continuing education
article. Using information from other materials may result in a wrong answer.
Reprinted from Chapter 3, ASPE Plumbing Engineering Design Handbook, Vol 3 (2011).
Table 3-2 General Properties of Materials Used for Storage Tanks and Piping
Containment Materials Advantages Disadvantages
Carbon steel Compatible with petroleum products Subject to attack by corrosive soils and
and dry organics and incompatible chemicals.
with many aqueous solutions.
Stainless steel Better corrosion resistance than Corroded by chloride and exposure to
carbon steel and higher structural reducing environments.
strength—There are more than 70
standard types of stainless steel and
many special alloys.
Fiberglass-reinforced Compatible with a wide range of Lacks the structural strength and impact
plastic (FRP) petroleum and chemical products, if resistance of steel tanks.
proper resin is selected.
Polyvinyl chloride Excellent chemical resistance to Lower structural strength than steels,
acids, alkalis, and gasoline. generally not suited for the storage or
handling of organic solvents such as
benzene, carbon tetrachloride, and acetone,
or use at temperatures above 140°F (60°C).
Concrete Generally good resistance to alkaline Subject to cracking and spalling with
chemicals, epoxy coatings often changes in temperature such as during
applied to concrete to increase freeze/thaw cycles, uncoated concrete
chemical resistance. absorbs solvents.
Polypropylene Resistance to all aqueous solutions Low structural strength, temperature limit of
except strong oxidizers. 248°F (120°C).
Lined steel Chemical resistance of plastic and Relatively high cost for material and
structural strength of steel. installation.
RCRA and CERCLA RCRA permits for a facility may take six months and may
These two laws, together with the federal and state regula- require public hearings and disclosure of detailed process
tions derived from them, have had a major impact on the and waste information, including chemical material safety
industrial management of hazardous substances and hazard- data sheets (MSDS).
ous wastes. Almost all nonaqueous liquids, many aqueous When evaluating waste streams to determine if they are
mixtures, and many solids and gases are regulated when regulated as hazardous wastes, it is important to check both
they become wastes or are spilled. federal and state regulations. This is because states are al-
The purpose of CERCLA is to limit the uncontrolled re- lowed to be more stringent than the EPA. States may define
lease or threat of release of hazardous substances into the certain wastes as hazardous when the EPA doesn’t consider
environment and to provide for a coordinated and effective them so. For example, waste oil is considered hazardous by
response to mitigate actual releases. CERCLA requires in- many states, but not by the EPA.
dustrial risk evaluations, in the form of contingency plans, The relationship between RCRA and CERCLA is shown
and establishes a mechanism for governmental response to by this example: A tank containing a hazardous substance
environmental and health hazards. CERCLA does not require begins to leak onto the ground. Under CERCLA, the owner
any permits and does not force changes in current hazard- must notify the EPA and the state, stop the leak, and clean
ous substance handling methods. Nevertheless, a great deal up the spilled material. If the owner fails to take action, the
of publicity can result when the mishandling of hazardous regulatory agency may act under CERCLA and then seek
substances leads to an environmental incident. There also reimbursement up to triple the cost of its expenses. Under
can be an enormous cost to dispose of the hazardous wastes RCRA, the spilled hazardous substance and any contami-
generated during a spill. These are strong inducements to nated soil become hazardous waste. The hazardous waste
chemical manufacturers and users to install process systems must be removed, stored, transported, and disposed of in
that minimize risk. accordance with RCRA requirements.
RCRA’s purpose is similar to CERCLA’s, except that
RCRA regulates hazardous wastes from ongoing manu- Design Considerations
facturing activities. The goals of RCRA are accomplished For plumbing designers, the challenge is to design systems
through strict licensing and operational standards for every that minimize the chance of leaks, contain any spills that
aspect of hazardous waste management. might occur, and segregate hazardous substances from both
RCRA requires identification numbers and/or permits nonhazardous process streams and incompatible hazardous
for every hazardous waste activity. The permit applica- process streams. The design of a system that anticipates the
tion requirements are lengthy and technical for some of potential for leaks and spills must include suitable materi-
the regulated activities. In some cases, the regulations als, reliable joining, good fabrication, and provision for the
give performance standards that the designer must meet secondary containment of liquids in areas and systems that
to obtain a permit for the facility. In other cases, the com- pose a high spill risk.
pliance method is almost completely specified. Obtaining
4 Read, Learn, Earn MARCH 2012
Figure 3 -1 Acid/Caustic Neutralization Diagram
Many leaks occur as a result of material incompatibility Minimal equipment and practices for preventing trans-
between the equipment and either the hazardous substances fer spills should include overfill prevention including level
handled or the atmosphere in which the equipment is uti- sensors, gauges and a high-level alarm, automatic valve and
lized. The incompatibility can be physical, such as polyvinyl pump shutdown, established transfer procedures including
chloride (PVC) pipes melting at high temperatures or plastic an operator on duty, proper curbing and containment, re-
pipes dissolving in solvents they were not designed to contain. dundant valves and controls, vapor recovery, alarms, regular
Table 3-2 lists the general properties of the most common inspections, and a maintenance program. The equipment
tank and pipe materials. Specific applications should be used in water treatment is operated to achieve the following:
checked with the appropriate chemical compatibility refer- mixing and flocculation, sedimentation, clarification, filter-
ences from the manufacturer. ing, turbidity removal, metals removal, and disinfection.
Even the best designed liquid-handling systems are sub- Historically, underground tanks up to 10,000 gallons
ject to occasional failure, particularly during liquid transfer (37,854 L) in capacity and occasionally larger have been
operations. Secondary containment is an important aspect of preferred for hazardous materials, primarily to minimize
any hazardous material system design to protect employees fire risks. Unfortunately, many of these tanks were kept in
and the environment. Secondary containment may include service too long and, because of corrosion, have leaked and
a dike around a tank or tank farm or pipes within pipes for contaminated drinking water supplies. As a result, designers
systems handling extremely hazardous liquids. Common now must compare the environmental and fire risks of the
secondary containment systems typically have the following aboveground tank. In either case, more attention must be
features: given in the design to ensure that an installation is resistant
• Containment floors, pads, ponds, and dikes constructed to leaks and capable of containing spills. Soil conditions and
of materials impervious to the substance stored groundwater levels, which affect the design, must be evalu-
• Perimeter diking and storage reservoirs sized to contain ated for each installation. Secondary containment of these
110 percent of the largest tank plus the maximum rain- tanks is the primary method of ensuring against leakage.
fall predicted to occur over 24 hours once in 10 years in
exterior areas (or 20 minutes of sprinkler water flow for Elements of an Industrial
interior areas) Wastewater Handling System
• Pumps, drain valves, or siphons to empty the secondary pH Control
containment area to either a storage tank or a treatment
Neutralization for pH control involves the chemical reaction
facility
of an acid with an alkaline substance (a base), resulting in the
• Controls and procedures to prevent the accidental release
formation of a salt and water. In an aqueous solution, the acid
of contained spills and an alarm system to notify opera-
or base molecules dissociate and form ions. Sulfuric acid is
tions personnel if a spill occurs
presented in the solution as H+ (hydrogen) and SO4 (sulfate)
ions and caustic soda as Na+ (sodium) and OH– (hydroxide)
MARCH 2012 Read, Learn, Earn 5
READ, LEARN, EARN: Treatment of Industrial Waste
ions. The H+ ions of the sulfuric acid and the OH– ions of the subsequent repetitive chemical additions. Overfeeding is
caustic soda have a strong attraction to each other and combine most probable in wastewater with no buffering capacity near
to form H2O (water). For example, in the neutralization reac- the pH setpoint (e.g., deionized and soft water). Controllers
tion of H2SO4 (sulfuric acid) and NaOH (sodium hydroxide), with multi-rate response adjustment should be specified for
the following process occurs: each application.
H+2SO4 + 2Na+OH– Sulfuric acid is the most costly method for pH adjustment
Na+2SO4 + 2H2O purposes, although in some cases the commercial 93 percent
If excess hydrogen ions remain, the liquid will be acidic, acid must be diluted prior to use. The manufacturer’s rec-
and with a surplus of hydroxide ions, the liquid will be al- ommendations for materials of construction, control of the
kaline. heat of dilution, and safety precautions should be carefully
The acidity or alkalinity of a solution is expressed on the followed. Carbon steel pipe and tanks are commonly used
pH scale, with neutral water at a pH of 7, in the middle of for 93 percent sulfuric acid, with stainless alloy 20 (a high
the range between extremely acid (pH = 0) and extremely nickel alloy) valves, as well as PVC and chlorinated polyvinyl
alkaline (pH = 14). The scale is logarithmic, so a pH of 3 is 10 chloride (CPVC) plastics. For sulfuric acid at concentrations
times more acidic than a pH of 4. Buffers, such as bicarbon- below 93 percent, polypropylene (PP), fiberglass-reinforced
ate/carbonate, undergo a chemical change when strong acids plastic (FRP), PVC, CPVC, and lined steel are preferred.
or bases are added to a solution and thereby act as capacitors Sodium hydroxide (caustic or caustic soda) in 50 percent
that must be filled before the pH will change. solution is the most convenient commercial alkaline material
A typical two-stage, continuous-flow pH neutralization for pH adjustment. Unfortunately, 50 percent caustic freezes
process is shown in Figure 3-1. For flows less than 10 gallons at 54°F (12.2°C), so indoor storage or heated tanks are neces-
per minute (gpm) (37.85 L/min), neutralizing in a batch basis, sary. (Note that 20 percent caustic freezes at -18°F [-27.7°C].)
with two tanks alternating between collection and treatment, Caustic solutions may be handled in carbon steel, stainless
is sometimes preferred. steel, and PVC tanks and pipe. Lime and hydrated lime are
The most critical feature of the pH adjustment system is considerably less expensive than caustic but must be fed with
the controller that activates the chemical feed pumps. The dry feeders and/or slurry tanks, which require considerable
controller must have the ability to prevent overfeeding of maintenance. Consequently, lime is favored in applications
either acid or base, which would cause wide pH swings and where the cost outweighs the convenience of caustic.
Please print or type; this information will be used to process your credits.
Name_______________________________________________________________________ ASPE Membership No._ ______________
Organization____________________________________________________ Daytime telephone______________________________
Billing Address_ ________________________________________________________________________________________________
City_ _________________________________________ State/Province_________________________ Zip_______________________
E-mail ________________________________________________________________________ Fax_ ____________________________
PE State _ _____________________________________________ PE No._ _________________________________________________
Notice for North Carolina Professional Engineers: State regulations for registered PEs in North Carolina now require you to complete ASPE’s online CEU validation form
to be eligible for continuing education credits. After successfully completing this quiz, just visit ASPE’s CEU Validation Center at aspe.org/CEUValidationCenter.