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Arjuna JEE AIR (2024)

Redox Reaction DPP-02

SINGLE CORRECT QUESTIONS 6. In an iodometric estimation, the following reactions

1. What volume of O2(g) measured at 1 atm and occur
273 K will be formed by action of 100 mL of 2Cu2+ + 4I− → Cu2I2 + I2;
0.5 N KMnO4 on hydrogen peroxide in a acid
I2 + 2Na 2S2O3 → 2NaI + Na 2S4O6
solution? The skeleton equation for the reaction is:
KMnO4 + H2SO4 + H2O2 → K2SO4 + MnSO4 + O2 + H2O 0.12 mole of CuSO4 was added to excess of KI
(1) 0.12 litre (2) 0.028 litre solution and the liberated iodine required 120 mL
(3) 0.56 litre (4) 1.12 litre of hypo solution. The molarity of hypo solution
was:
2. KMnO4 reacts with oxalic acid according to the (1) 2 (2) 0.20
equation (3) 0.1 (4) 1.0
2MnO4– + 5C2O42– + 16H+ → 2Mn2+ + 10CO2 + 8H2O
Here, 20 mL of 0.1 M KMnO4 is equivalent to: 7. 32 g of a sample of FeSO4·7H2O were dissolved in
(1) 120 mL of 0.25 M H2C2O4 dilute sulphuric acid and water and its volume was
(2) 150 mL of 0.10 M H2C2O4 made up to 1 litre. 25 mL of this solution required
(3) 25 mL of 0.20 M H2C2O4 20 mL of 0.02 M KMnO4 solution for complete
(4) 50 mL of 0.20 M H2C2O4 oxidation. Calculate the mass % of FeSO4·7H2O in
the sample.
3. When 2.5 g of a sample of Mohr’s salt reacts (1) 34.75 (2) 69.5
N (3) 89.5 (4) None of these
completely with 50 mL of KMnO4 solution.
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The % purity of the sample of Mohr’s salt is : 8. A sample containing HAsO2 (mol. mass = 108) and
(1) 78.4 (2) 70 weighing 3.78 g is dissolved and diluted to 250 mL
(3) 37 (4) 40 in a volumetric flask. A 50 mL sample (aliquot) is
withdrawn with a pipet and titrated with 35 mL of
4. 4 mole of a mixture of Mohr’s salt and Fe2(SO4)3
0.05 M solution of I2. Calculate the percentage
requires 500 mL of 1 M K2Cr2O7 complete
HAsO2 in the sample:
oxidation in acidic medium. The mole % of the
(1) 25% (2) 20%
Mohr’s salt in the mixture is:
(3) 10% (4) none of these
(1) 25 (2) 50
(3) 60 (4) 75
9. A mixture of FeO and Fe2O3 is completely reacted
with 100 mL of 0.25 M acidified KMnO4 solution.
5. A mixture containing 0.05 mole of K2Cr2O7 and
0.02 mole of KMnO4 was treated with excess of KI The resultant solution was then treated with Zn dust
in acidic medium. The liberated iodine required which converted Fe3+ of the solution to Fe2+. The
1.0 L of Na2S2O3 solution for titration. Fe2+ required 1000 mL of 0.10 M K2Cr2O7 solution.
Concentration of Na2S2O3 solution was: Find out the weight % Fe2O3 in the mixture.
(1) 0.40 mol L–1 (2) 0.20 mol L–1 (1) 80.85 (2) 19.15
(3) 0.25 mol L–1 (4) 0.30 mol L–1 (3) 50 (4) 89.41
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10. 1 mole of equimolar mixture of ferric oxalate and 13. A 150 mL of solution of I2 is divided into two
ferrous oxalate requires x mole of KMnO4 in acidic unequal parts. I part reacts with hypo solution in
medium for complete oxidation, x is: acidic medium. 15 mL of 0.4 M hypo solution was
(1) 0.5 mole consumed. II part was added with 100 mL of 0.3 M
(2) 0.9 mole NaOH solution. Residual base required 10 mL of
0.3 M H2SO4 solution for complete neutralization.
(3) 1.2 mole
What was the initial concentration of I2?
(4) 4.5 mole
(1) 0.08 M (2) 0.1 M
(3) 0.2 M (4) None of these
11. An impure sample of sodium oxalate (Na2C2O4)
weighing 0.20 g is dissolved in aqueous solution of 14. A mixture of H2SO4 and H2C2O4 (oxalic acid) and
H2SO4 and solution is titrated at 70°C, requiring 45 some inert impurity weighing 3.185 g was
mL of 0.02 M KMnO4 solution. dissolved in water and the solution made up to 1
The end point is over run, and back titration in litre. 10 mL of this solution required 3 mL of 0.1 N
carried out with 10 mL of 0.1 M oxalic acid NaOH for complete neutralization. In another
solution. Find the % purity of Na2C2O4 in sample: experiment 100 mL of the same solution in hot
(1) 75 condition required 4 mL of 0.02 M KMnO4 solution
(2) 83.75 for complete reaction. The mass % of H2SO4 in the
mixture was:
(3) 90.25
(1) 40 (2) 50
(4) None of these
(3) 60 (4) 80

12. 0.5 g mixture of K2Cr2O7 and KMnO4 was treated 15. The concentration of an oxalic acid solution is ‘x’
with excess of KI in acidic medium. Iodine mol litre–1. 40 mL of this solution reacts with 16 mL
liberated required 150 cm3 of 0.10 N solution of of 0.05 M acidified KMnO4. Whatis the pH of
thiosulphate solution for titration. ‘x’M oxalic acid solution? (Assume that oxalic
Find the percentage of K2Cr2O7 in the mixture: acid dissociates completely.)
(1) 14.64 (2) 34.2 (1) 1.3 (2) 1.699
(3) 65.69 (4) 50 (3) 1 (4) 2
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Answer Key
1. (3) 9. (1)
2. (3) 10. (2)
3. (1) 11. (2)
4. (4) 12. (1)
5. (1) 13. (2)
6. (4) 14. (1)
7. (2) 15. (3)
8. (1)

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