Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_Elite, Target & LIIT-BTs Paper -1(Adv-2023-P1-Model) Date: 14-04-2024
Time: 09.00Am to 12.00Pm GTA-24 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 B 2 BD 3 ACD 4 B 5 A 6 D

7 C 8 2 9 125 10 1348 11 840 12 0

13 1 14 C 15 A 16 B 17 C

PHYSICS
18 A 19 ABCD 20 AD 21 A 22 B 23 A

24 B 25 8 26 6 27 2 28 6 29 3

30 3 31 C 32 B 33 C 34 A

CHEMISTRY
35 ABCD 36 D 37 ABD 38 A 39 D 40 D

41 D 42 8 43 729 44 10 45 2 46 5

47 7 48 A 49 D 50 A 51 A
 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s

SOLUTIONS
MATHEMATICS
1. Key: B
Sol: Any point on the line through P  1,1 at a distance of r from P will be
 1  r cos ,1  r sin   , where tan  is slope of the line.
If this line meets xy  1 in A & B, then  1  r cos 1  r sin   1 will have PA & PB
as its roots.
r 2 sin  cos   r  cos  sin    2  0
Also, for the point R, x  1  PR cos  & y  1  PR sin  .
x 1 y 1
Hence cos   & sin  
PR PR
Now as PA, PR & PB are in A.P., hence PA+PB=2PR
y 1 x 1

sin   cos  PR PR  2 PR  2 xy  x  y
  2 PR 
sin  cos  x  1 y 1
.
PR PR
2. Key: ABD
Sol: P  A  B   P  A  P  B   P  A  B 
5 3 4 2 1
   P A  B  P A  B  
8 8 8 8 4

Now p  A  
c 
P Ac  B   P B  P A  B  1 2. 8  1
 B PB P B 8 4 2

 
2P  A c  

2P A  Bc   2  P  A  P  A  B    4  3  2   1   A is correct
 B  P Bc   1 P B

8

8 2

P A  B 1 2 1
P A / B   .   PB   B is correct
P B 4 1 2

Again P  A c  
c 
P Ac  B c   1  P  A  B   2 1  5   3
 B   
P Bc 1 PB



8 4

1 1

 B  P B  P A  B 2 4 1 8 2
P    . 
 Ac  5/8 5 4 5 5
8
 c   
Hence 8P  A c   15 P  B c    C  is not correct
 B   A 
  1   1
Again 2 P  A c   from (1)  P  A c   P  A  B 
 B  2  B  4
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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s
Hence (D) is correct.
3. Key:ACD
Sol: We have S   x, y  : x2  y2  2024; x, y  R
 2024, 2024  doesn’t satisfy the relation S
 S is not reflexive.
Let  x, y   S .  x 2  y 2  2024
 y 2  x 2  2024   y, x   R
 R is symmetric.
  
2021,1 , 1, 2022  S but  2021, 2022  S 
 R is not transitive.
4. Key: B
Sol:Multiply R2 by z and R3 by y and use R1  R1  R2  R3
5. Key:A
Sol:  x  235,  y  250,  x 2  6750,  y 2  6840
2 2
    xi2    i   .6750  
2 1  x  1  235 

10  10  10  10 
 675  552.25  122.75    11.08
Similarly, for y  250, n  10, y 2  6840
6. Key:D
  x, x  0
Sol: f  x   
 2 x, x  0
y
y  x2 y  4 x2

x
0
y  gof  x 
 x 2 , x  0
Now, gof  x   
 4 x 2 , x  0
y
y  x y  2 x2

x
0
y  fog  x 

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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s
 x, x  0
Similarly, fog  x    2 which is continuous at x  0 but not differentiable at
2 x , x  0
x0
7. Key: C
Sol: We know that in any triangle b  c  a  0, c  a  b  0 and a  b  c  0
Since, AM  GM , we get
 b  c  a    c  a  b    b  c  a c  a  b 1/ 2
2   
1/ 2
 c   b  c  a  c  a  b  
1/ 2 1/ 2
Similarly b   b  c  a  a  b  c  and a   c  a  b  a  b  c  
Multiplying the above equations, we get
abc   b  c  a  c  a  b  a  b  c 
 /2  /2
8. Sol: f n  
0 0 
cos n x cos nxdx   cos n x cos  n  1 x  x dx 
f  n  
0
/2
cos n 1 x cos  n  1 xdx  
/2
0  
cos n x sin x sin  n  1 xdx
 /2
 sin  n  1 x cos n 1 x   /2
f  n   f  n  1      cos n 1 x cos  n  1 xdx
n 1 0
 
0
f  n  1 1
f  n   2 f  n  1  
f n 2
9. Key: 125
Sol: Vertices of the tetrahedron are  6,6, 6  ,  6, 6,6 ,  6,6,6 &  0,0,0 
Two adjacent vectors representing the base are 12 j  12k &12i  12k .
iˆ ˆj kˆ
1
   
Area= 12 ˆj  12kˆ  12iˆ  12kˆ  72 0 1 1  72 3
2
1 0 1
10. Key: 1348
Sol: a  c  2b  3b  2025  b  675  a  c  1350
Number of positive integer solutions will be 1349 C1  1349 which includes 675,675 as
the solution but shouldn’t be included
11. Key: 840
 n 1
 x 1  
2
n 1 x 1  x 1 
Sol: E   x  2  1     ....    
 x  2  x  2   x  2  
  x 1 
n 
1       x  2 n   x  1 n 
E  x  2
n 1  x2    x  2 n     x  2  n   x  1 n
 x 1    x  2 n 
 1 x  2 
 

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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s

Now co-efficient of x r in  2  x   1  x    rnb  n Cr 2n  r n Cr  n Cr 2n  r  1


n n
  
Hence 10 10 3

7 b  C7 2  1  840 . 
12. Key: 0, Sol:  x  a  x  b  x  c  x  d   9   x  r 4
On comparing coefficient of x3 a  b  c  d  4r
13. Key: 1
Sol: Using G.M.  A.M. we get
1 2 2 2 1 1
 a b c 
a b c a b  c a  b  c

abc
, a b c   
b c a a  b  c ab  bc  ca
& a b c
abc
  
c a b a b  c ac  ba  cb
abc
2
Hence a abbcc  a b c  a b c  a 2  b 2  c  2ab  2bc  2ca   a  b  c   1
b c a c a b 2

14. Key: c
Sol: (P) 2sin x,sin 2 x & 2cos x are in A.P., hence sin 2 x  sin x  cos x
Now Let sin x  cos x  t , then sin 2 x  t 2  1 , then the above equation gives
1 5
t 2  t  1  0 or t  sin x  cos x 
2
  
(Q) Let  be the greatest angle, then angles will be  , ,  
3 3 3
1     
       Hence angles are , ,
3 3  6 6 3 2
a b c a b c
Now      .
   1 3 2
sin sin sin
6 3 2
(R) Let AB  a, BC  3a, CD  3a & AD  3 3a
a 2  27 a 2  BD 2 3a 2  9a 2  BD 2
Now cos A  cos C  0   0
2 2
3 3a 3 3a
BD
 BD 2  20a 2 2 5
or
AB
2 a 2c 2 2 8a 2 c 2
 S  a  c  2b & b  2 2   a  c   2 2
2
a c a c
4 2
  a  c   2ac  a  c   8a 2c 2  0 
 a  c 2  8
ac
a
But 4 gives a=c, hence by taking -2,  a 2  4ac  c 2  0   32
c
15. Key: a
Sol: (P) Equation of any curve through the points in which given lines meet coordinate
axes will be  a1x  y  b  a2 x  y  b   xy  0 . If these points are concyclic then
a1a2  1

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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s

(Q) Any point on x 2  y 2  a12 will be  a1 cos , a1 sin  . The chord of contact of the
tangents drawn to x 2  y 2  4 from this point will be a1x cos   a1 y sin   4 .
If this touches the circle x 2  y 2  a22 , then a1a2  4 .
(R) If the two circles cut orthogonally, then 2  a1  a1  a2  a2    1  1
 a12  a22  1
(S) Centre of the given circle is  2, 3 & radius is 5. Now distance between  8,5 & the
centre is 10. Hence a1  5 & a2  15
16. Key: b
P A  C  PB  C   P A  B  C
Sol:(P) P  A | C   P  B | C   P   A  B  | C  
P C 
P  A  B   C 
  P A  B | C
P C 
P A  B  C   P A  B  C 
 
(Q) P  A  B  | C  P   A  B  | C  
P C 

P A  C
  P A| C
P C 

(R)
1  P  A  P  B  C   P  A   B  C  

1  P  A   B  C 


P A  B  C 
1 PB  C 1 PB  C 
P B C 

P A  B  C P

PB  C 
 A |  B  C 

(S) P  A  B   P  A  B   P A  B  P  A  B   1 
17. Key: c
Sol: We have AE  EP  AP  1  AP  PT  1
A
13
1 60 30 3
1 120
60 60 30 150
E X
1 P 1 2
 APT is isosceles
This makes AET a 30  60  90 triangle,
So AT  3x and ATX  150
Since TX=2  By applying Cosine rule in ATX , we get
 AX 2  3  4  4 3 cos150  7  6  13  AX  13
13  1  16 2 1
 cos XAE   
 
 2  13 1 2 13 13
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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s

PHYSICS
19.
20. Under normal conditions total energy, potential energy and kinetic energy in ground state
and first excited state are -13.6eV , -27.2eV , -13.6eV , -3.4eV , -6.8eV and 3.4eV
respectively. If potential energy in ground state is taken to be zero, then kinetic energy
will remain unchanged but potential and total energies are increased by 27.2 eV.
Therefore, the new values are 13.6 eV, 0, 13.6 eV, 23.8 eV, 20.4 eV and 3.4 eV
respectively.
21. Capacity with partially inserted slab (upto depth x)
x

d
V0
l

 b  l  x  K 0bx
=Capacity f air capacitor + Capacity of dielectric field capacitor = 0 
d d
 b 1
b=plate width  C  0 1  x  K  1   dU  V 2  dC 
d 2
 b  b
And  dC   0  K  1 dx  dU  0  K  1V 2dx
d 2d
 bV
Work done by force=Fdx, Increase in charge=dq  dq  Vdc  0  K  1 dx
d
This charge is transformed from negative terminal to the positive terminal inside battery.
0bV 2  K  1 dx
Hence, work done by battery, dW  dq.V 
d
0bV 2  K  1
As, dW  dU , Hence,  F 
2d
Clearly, force does not depend on x.
F 0bV  K  1
2
Also, acceleration of slab a   and acceleration is also independent of
m 2dm
dimension x.
 Time period of oscillation is also independent of x.
22. Let voltage phasors along be PA, AE be x, 2x
P Q

B
A

E F

1
And voltage phasors along QB, BF be y, y. (as R  ).
C
The phasors diagram representing them can be drawn as shown

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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s
B

y
y

45
P,Q E,F
x A
2x

So phasor length AB (i.e; reading of V2 ) is= x 2  y 2  2 xy cos 45 (using cosine rule in
PAB )
V 5
Also x  2 x  V and 2 y  V  Reading of V2 
3 2
23. Let assume the average value of steady state voltage across capacitor is V. Net charge
does not change over a cycle, so
i1t  i2t  0
 1  V  t   1  V  t  0
R1 R1
 R  R
V  1 2 2 1 Ce=CV
R1  R2
L
24. b  radius of spot b  a 
a
Geometrical spread+ spread due to diffraction
L 
ba 1 L0
a a2
 a 2  L  a  L
bmin  4 L
25. Induce e.m.f= Bv  0.125V
10  e 10  0.125V
Current I  
R 2
 0.5 T

 10 V 0.25 m
0.5 N
2
V
Q
 10  0.125 
Force BI   0.5   0.25  0.5 N  given 
 2 
Solving v  16 m / s.
hc hc 1 1 
26. According to conservation of energy   RchZ 2    n  6.03 quantum
2
1  2 l n2 
number=6
27. Let each plate moves a distance ‘x’ from its initial position
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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s
Let q charge flows in the loop. Using KVL
Q  Q 
  q d  x   q d  x
2  
2  0
0 A 0 A
Qx dq Q  dx  Qv0
q  ;I     I
2d0 dt 2d0  dt  2d 0
28. Refer theory
k  2Q  k  Q  7 kQ
29. Ei   
 2 R   4 R  16 R 2
2 2

30. Let K1 & K 2 and P1 & P2 are the K. E and momentum of the  - particle and remaining
nucleus, then K1  K 2  5.5MeV      i 
From conservation of linear momentum P1  P2
 2 K1  4m  2 K 2  216m  K1  54 K 2      ii 
From (i) and (ii)
5.5  54
K1   5.4 MeV
55
31.
32.
33.
dy1 dy2
34. A) x  
D1 D2
dy
B) x  1
D1
dy dy
C) x  1  2     1 t
D1 D2
dy
D) x  1     1 t
D1

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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s

CHEMISTRY
35. In the oxidation of oxalic acid by KMnO4 , the Mn2 ions formed act as catalyst.
dilute HNO
36. Glu cos e 
3  glucharic acid

2 2
37.  Ni  NH3 6   3en   Ni  en 3   6NH3  S  0 
 H  G 
38. S   
 T 
  E  
 H   nF  E  T    and G   nFE
  T P 
 E   0.0006 
S  nF    3  69500   
 T  P  10 
 17.37 J / k
39. Tb  80.26, Tb  0.16
0.26 / M
0.16  2.53   1000; M  367
11.20
That is almost molar mass of C20 H16 Fe2 .
40. P  CH 2  CH  CH 2 MgCl
Q  CH 2  CH  CH 2  CH 2  CH 2  OH
HgOAc
R=

S=

O
41. The reduction of a metal oxide easier if the metal formed is in liquid state at the
temperature of reduction. The entropy is higher if the metal is in liquid state than when
it is in solid state. The value of entropy change  S  of the reduction process is more on
+Ve side when the metal formed is in liquid state and the metal oxide being reduced is
in solid state. Thus the value of  r G  becomes more on negative side and the reduction
becomes easier.
42. cell  Ag / Ag  / / AgI / AgI / Ag
Left : Ag  Ag   e ; E   0.799V
Right : AgI  e   Ag   I  ; E   0.151V
AgI  Ag   I  ; E   0.95V
0.0591
E  E log Q
n

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 Sri Chaitanya IIT Academy 14-04-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P1)_GTA-24_Key& Sol’s
0.0591
0  0.9501  log Ksp
1
log Ksp  16.1
Ksp  8  1017

43. M AgX 
40
  N A  a3 6.022

 6.022  10 23
 6  10 8 3
 
4 4
 216 g / mole
 M X  216  108  108 g / mole
If all atoms along one body diagonal have been removed, the formula of unit cell
 Ag 41 X 1  Ag3 X 15
4
4 4
15
 Mass of 1 mole of these unit cell  108  3  108   729.00
4
44. 1 mole of acetone reduction to isopropanol requires 0.25 moles of LiAlH 4
45. (I, IV, V, X)

46. Co 2 : d 7 : Sq planar complex. d 2yz  d zx
2

 d 22  d1xy  d 2 2 (splitting of d –
z x y
orbitals )
47.

x   Fe3  OH 2  CH 3COO 6 

y   Fe  OH 2  CH 3COO  
48. For reaction A  product
Using the given formula we can solve all the options
 A0   At
For zero order reaction t 
k
1  A0
For first order reaction t  n
k  At

1 1 1 
For second order reaction t    
k   At  A0 
49. Conceptual
50.
51.
O O S O O O O

HO S O S OH HO S OH HO S S OH HO S S OH

O O O O O O

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