H# chemical Bonding > Hygndisabim:- cheder- valence eof central atom, surrounding atoms bona, hyb” calculaton, tone pairs and shape > eS 4 E (Lia, Ky Rb. Cs) pe ve SAP, As, So, BID Vv enNS 9+ (Be, Mq, Ca, Sr, Ba) we Vie™ Cr Co, S, Se, Te, Po) we vie 32-(6, AL Go tn, TH) a vers ai-(F ch By T, 44) w= vee" 4. Co, st, Ge, Sn, Pb) > vie BI Cre, Ar, Ky Xe, Bn) ® Except oxygen (o=0) and nitrogen (ren) remaining, surrounding, atoms forms (@ bonds). * Lomuta of hybridisation [roo not © bonds + Lone pars] +4 1-bonds are not considered @-sp + O-sp = @-sp? > ©spd © spt ® spe?SP ~----70> O-+--- Hnear sp. ------0 -Prigonal planar SPL. eH Ae eee sy! en Bent OD angular SP 0. - —--Tetrahedral spot --- + Pyvamialat Se 2-. ----*V' @D Bent ©» angular See neon “Trgpnal bipyramidal -see- SAW -'T- shape Linear —-octahedal Square pyramidal Square planar ~ pentagonal bipyramidal +--+ Qistorted octahectralFE M.0.T:- Total Electrons +, smg bonding es anol anti-bonding ens we Question form: (How many i write electrnic corfiquraton * wis Hy BS Ss Tapa TR, Sp ep, = Trop, imter change . i Above 14 es electronic confiquration As (aed 1) 1B ES are ie Ge Bet Teage= apy Gp! Bonding electrons = 4: antibonding electrons = 4 ae > o (e+e 49) 18 e™ GT TS Tp Taps a wape Hops =H apy Bonding electrons =!0 1 antibonding clectrons = g ~8 Bo er *ap, & - anti 7 J “Gonding Bo= I -a5Total a 3 a pgcof unpaved ens om uancor-fms “po 4, Bond order =o (molecule oloes not exrst) 2. Bond order T statility Tes, pond T Bond strength —_lissociat'sn nord energy 4 3. Number of unpaired electrons <7 14 2 =7 paramagnetic nature 4. No.of unpaired elechons Tes, poramagnenc nature Tes 5. Ao-of unpaired electons=0 Coiamagnetic mature) Stn case of same bond order, wv check antibonding elechons =. antibonding electron T stability d# Fajan's tule! Ccpvalent character of ionic compounct) character Cove) ¥ power of anioni- size of anion T polarisabilr| ® cwvarent ower of anton ° mt caret Se > Power of Cation- size of cation | ae covalent 9 a Best tick @) check charge é- charge fes , covatent chavacter (i) Tn case of same anions:- size of cation # covatent character T Git) TA cose of same cations: size of anton P covalent character# Dipole moment (w= | avery short short cnotesi- oot age, of elechoa'” te 6x10"N"C wm ae yg x 10ers Ho 4 (non-polar) En eA ALO 2 al covatent bon ie 4 cin ( i fy en en polar ot 30 MO units Debye = 10% esu-om 1Q =3-33 X 1030 anQuestim flame Polar @ clon ~polar 2 0 cite S| ° - 4 ° Ss oO a 6 ° ia 4 ° oy 2 3 ne 4 4 - 5S 2 —# some important cxamptes:- Mans > Ming > Meech Becl,, AHs, NB on Lar aN : “Fei Teo Seo soit u7 A J SF a F 40 am 2. Mag ct > Meuse 7 Mayor? Mens 3 CHg —cl ct cl: > cul; > ccly B. P= ch cl Eee 4 4 Lt af TS i 71 " 7 \ " f\y. a et io pen “ty ch ql 7 = oH Soil 2 Med = as-|, 2-dichlomethane > Troms -1, 2- dichtorvethane aA H ee eo i af Set (periment UAoeserved wal a) ——_ given ia prov X 100 y% of tonic = characte’ egiauated > Se@vatent bo- monee character character-# Bone parameters > Bond gngle i rick o1' check fefsisation inoestion olifferent ee bond angles Tack 92> check hyordisaoy hybrcsotion same kone pairs Calosen) v same bond angle Caan Tick 03: check hybrictisation ruylnicssotion (same) mn b cpresend) Lp Cobfferert) Le ter, BA vesqTritk QU: check hybrichis ation wy hyordisatin Csame) v Lp Cpresent) . iy same central atom (same) w check surrouncling atom B.A size 0 sumounding atom! Trice oS: check hyn cisation car wv hyondrsathon Csame) ¥ Lone pairs Csame) w sunounding, atoms (same) wv check central atom 1 BA *~ Saeof eA