=> Addition compound (' nO OO Ks0, + Al, (S04); Stable stable salt | salt K,S0, -Al,CS0), 24140 i | ‘Potash Alun Kit/s0y /av? Double salt! Tons in aoldition compounds clowt lose thelr identity, m aq-sol Ex" camaltte Kel mgch 6H,O Mohx’s satt FeSO, (Hy SO, 6H2O FED -oRDINAMON COMPOUNDS the combination of 4wo (@) more Stable sorapouncls) TeCed,tuket Ry Ea lol J stale Sat ee Ky LrecerDe_] ay 120 co-ordination covalent bond Kt + [Fecen) cea] “complex jon complex sait'-some forms in a eos compounds lose thety identity i aq, sol” a co-ordination ent = teed @) co-ordination sphere, count ov) complex ental ton Whetal tigansl Pim ion# Devticity (Belated 49 ligand) *¥ alumber of co-ordinate bonols that a iqanol can form with metal. * Ofonodentate- jai [Helast 2p? fv) GhE HAO O,:- [Hel 25° 2p" “HeO: 9M Mm BoE Exr HA — Ha” CHyotrazene) ¥ Bidentate- en —> ethylene diamine ene oy ethane 1,2 oiamine CHy AH \ ay | i F cH, — Ate#& chelation :- chelates are generally morestable than non-chelate complexes H# polyclentate O>s EQTAS- ethylene diamine tetra acetate So eg c00 eee cscO0e | cu Bem etnco® tHexa olentate cco? > classityy the lqande* 7 ey. @) J Fw CORES. a o es e Woe (40,7 @# (ox) Ri ) Catty-eth— 2 - ) 0 So oxalate ue Gilycmate \ it Gidosymmett cal le ie i“ iy unsymmehiialHac a) “Ve \ wo re BB Sod dimethyl gly oximate Colma" GY) Har —ctha= ety — ch eth, — CHa A eth CHa He H H Trethylene tetra amine (tren) a tetracentate 4 (VD Hy cH CHa > CHa CH= NH Aiethylene -mamine Chien) Trdentate cco? M@) fel Ethylene otamine Cth cco? = Pentadentate | Clty —N—4 ~~ cty000 tiacetate4 Flexiclentate: 4 Polydentate ligamat with different dentiu'ty in different co-ordination compounds Ex: @) so? (--4) B) cay Guy EOTA™ (8-4) 4 [eocos 604] [coer W950 7 ambidentate ligand Ligands that have more ee one kind of donor sites of a 1B fen: a go | ; 0 ~ cyomice nitrito He [ito [ite ide | ido [ 982 > hyobroxiclo ate | ato hydtroaide Shhyclroxe CO," —> carboonato } carbonate The — amidd cH,Co0® __> acetato OP ——+ hyctroricle/myctro xo W© ——> fryoindlo/ hyotro cn®°——> eyomido/ cyano 0 ——> oxidlo/oxoo ——— ferwxio/Pewn xo O ——.s super oxide /supex ae F° ———-+4luondo/ fluor a? + nittndlo N35 ——= azdo G0," —— dxalato S0;* > sulphato $.03°——> thiosutphato SO;* ——+ sulphito Ss? —— sulphiolo=> Neutral and +ve lgands:- nee are™ ww yw H,0 ——7 aqua co ——> caroonyl NO ——> nitrosyl QH3——> ammine oe Hs —> pyridine CH3-OHs — methyl amine Hart —chy—CHa-NHa— thay lene oliamine @) ethane-1,2-dtamine (en) PPh3 ——> tripheny| phos phine AO* —— mitrvsonium aatis ——> hydlrazontum @) + AAy- rHAE UPAC I~ ane Ky Tre cern), | v 4,“ lg nd Counter ion ¢ 12a) common gth ‘ . qm name — oma Contdoantion) -zoman EL! GO) [niccoyy fe neutral complex @ kylFeCem ge kt (Fecer)¢]* Anionic Compt ex GE [eocrttade] clap Looe] + set” catronrc Complexcewtral L oe cr Sn » Neutral @) ave complex chromium bon lead silver gol tm —ve compte x chromate -ferrate plumbate argqentate aurate stannate2H Praetie Gl Kg [Fe cere] 2" AYEO),] Qs! [aqcanadttagcen? Qu Erich (PPh) ] @.5) [er (rita), (i203) cls Qc: [pt crits), UB G.4- Corby), Ln Ca.0,),CH20,)] G8: [PECHIN CH Cy rvb)e lal ch 8. [recco), | QO" Hg Ty] Giese ent)HF Wemer's thenry- we ARE (A) Coclg. 6H3 (B) cocly. SAMS ‘water Joa Soluble Splable Excess Excess Agno; Agno, 3 moles of a | Leona] 3ct” prt 113 electrolyte Loci soc" ions = 4 tie electrolyte ions=3, aloof fons ® conductivity T CO) cocls. UAH oe Soluble conductivity: ATB>C Excess Aqn0s L-mole of Agel white ppt [eo And cll” he electrolyte tom =2= Valence of metal:- www Aa i valence :- Prmary valence 7 Tonisable valency + Non-dtrectionat 7 J Equal to oxrdation state of metal. > Representation:-(y 1) Tonic interaction ep eee 7 Aon -ionisable + Dywechonal > Equal tv co-ordination number of metal atom > Representation = (m—t) Als ct val WN 2.00 <—r\Ha A . Nis AWS cyFormula as CP) Pde 4NHs, Crdcritts.]ce A OW) Ach. 640 [nico] ch cGy piety QHel Hol Pt cle] 8 (i) Coc UN [cotta ctalct OW) Pech: arity CPt GAH, cle] Ao-of Aq ppt 0Q oe Con = nos aa Ngan onde xCentiity) 4“Valence Sond then vO) Qordination ist hubrci sation vnurtler hybeichisotm shops 4 sp* rretrahedral ASP Cctyaag) square planar 6 ; Spot" Cola/ de. Pp) octahedral - dsp? Cole obeys) octahedral ) L ; . D spa 2d cD: outer orbital Th Ly | Otahectrat (ap \ dt sp ; (anver orertal) PERL * octahedrat wmetad |= cn=6 Coctahedial) Ce EO de bine Chyonalisatod: gad ¢ eo de ot of ot ol eee csp Tap pe Spat always) CveTran0 Cawwoays) Geen all clear AY A5/ol§ —+ Hybriolisation ee onl, E No:of unpaired ens mognetc moments Csp/dsp) magnetic mature @) TecCueodgl” ; scl: ac”: asp? probiem:— Gi) LanCy,0XJ > a8: act?) spid* [FeCorJ” g @) PRCHOgPT ) Ti? acl! 1 oltsp? Fe) sac Oe Me § @ [vereod.J® + vi3 sad: al?sp? J vA crTi crt): # crystal field theory Cort i Etectrpstatic mpodel : volnich consider the metal- ligand bond to be aontc Cm®.- ID): > Ligands * Point charges im © case — of anions. Cex: cl?) (mt... ot) *¥ Aipoles im cases of neutral molecules CH). ” bi! He a -orbitats:- 4 zc: oe Zz a cheap L 4 — fey a) 34ECET im cn=é¢ (octahedral): oa Pos ow igands Nea kiganals approaching, 7 ¥ i iz : along %y Frans eee Jase CFSE: 1 tig l-O- 4s) + NEq C+0.640) Toe, ~ [AR C20), ee it: 3d* Dy 3) Ex [WOO]; es 3 (HPD fal 2 > & cir tg <4 CFSE = -0:@4e novof unpaired 2°" =s;para AL. 8Y exe [veo] pv" > 3d? Coltsp*) Octahedial capital a soias aad ty ca CFSE:> -1-240 N0-of unpaired eS © 3: para = 3.89* dt(sF bY) —-% A241 —€..W. aka 4 by A, »>® painng energy Splitting, gap # ot OOF) 4-4 od eel ee a <= Pains = ont gyty mts to solve ueshon:- Most imp pyints fo gowe any aucston GI spedtrochemtcal senes:-Cstrength of tgandls): oon nit gen leo Halogen atoms & eae ri < paw Zz bom eB e Sco cc ester OH 24072 HO Ncs"é ENTA~* ZNHy < EN cn 200 Y® 3d, Yl Sd elements § electronic confiquratim Ga) = I" ty en(weFt) Wit Metatcty): Atl Iwgamols ore SFL @); 3d-senes:- Met 2 30- Sons Coste G@v)r Metal(+3): © #2 HOCwWeFL) GEG? CH0/ 07/ OW'/ 0x) Metals) | Wgandls Gy 4d/sd Semes: metatcrr) 7 alt 0 | | Yea] domar’ srt metal(+4) ~ Are sFL= Do Ceptiting gap) (oD CFSE depends on charge T > AT sewes: adeydesd Ligand : SFL: Ae tT WL; ab # Practice: & ‘Croce J” g. a: Lolansy]” @. frecHs02]** [coca] B. CRhtat]” En Sort Sort © Ear Candy” 36+ WEL ctg)} tian Nae ere CESE: ~O-4do No.of Unpaired €MS=4 Cparay magnetic moment = 4.90 yb": spectQ. [ree J” a-[oncende]” Fe? SFL ECs 49 CFSE +- -2-4A0 wed es ‘I umpaired e"=0 Cora) @. Fe cen MM=0 G. Crm cu” Q. [eoCaoy al 9. Creel @. [oreAE Tetrahedral ond Square planar wee v cn = 4 (sp3/d.sp*) d-(me for hyowdrsa tion: dada? J aft ft Re eee sp sp> CPT tetrahedral tetrahedval Mex: [zndq] ono, 2n* 2 3d => ops diamagnetic Om 305 4st PLnico 4] Pat: 3aqe, 3g mn*# = 301° sp diaa7" we ert= 4 C5p3 /olsp) = OD ate ese oe csp) set Cos p") Ek Env cond)” aut = 3d? 4sFe dsp; square planar a 2 Ex Cre cly) Ai* ~ 3d6+0FL trahedral a Shel Ex. Coated tadgl” cum 2 ad sre ids Most important:- 7 ad-seses: (+3, +4) cat dd/ set: (42,43 +4) J spe: ee al [pct], [Potcend]? zoey- at a * Evel? savy 3dl + WEL * [eucetttyJ™ > cult 3 acl" us wiafafaya) oO — Sp3 para ag”LenclyT* + Sp? , Tetrahedrat ; oliamaqnetic [ou CoHDI cusp, ro [ns cen: olsp*: square planar ; diamagnetic ence > Sp: tetrahedral + paramagnetic t [evrccory] = spe: tetrahedral > olvamaqnetic (prctyJ™ * dsp: square planoy [Pot cen) ope & olsp? : Square planarCece eee — Reason fer colourt~ Gy d-d tansition @) charge bansfer @ (wgand “metal (&) metatmetat Cri Cty1"* — 4 > H2O "elo colour Wgand Cvtolet) Reasons= al'Cd-d transition ¥ GusOy~—> NO colour 7 Puloy, shone + Gr S04. SH20 —> Blue Al.O3 +Or¥8 Cah) Reason :- Ligand C0) d-d transitimwavelength of (exs) > @-erdination compound light observed Cooet Crt) ** [eo Cotteds Cool” a [oC ts) 1" a Loocende}> ae Cia H201 7 St ch tr 7 > charge transfer Reason! Ligamd-metal Charge transfer toy : mn MaxtrO4 Yeltove ~O- 3ol? ~ purple al= Beer ang complex: (tagand~ metal charge transfer) [re ctia 010] $0 pee +S CO)+CI+CA =O metal ligand mee tH ret ge , a ie) Pentaaquanttosonium tn) sul phate tal ©) metat te Fa? Lpcerd, a ©* transfer Prussian Blue.stably of Omiplezsse > EAN: aoof ens present ™ + 9 /nooF Es metal ton in Co-ordination CSenas X olenticity) Compound ©) To tnts ] cls EG 244 2Cexi) = 36 (stable). G@) [Fe cen)” Ea: 24+ 2Cexi) = 36 Cstable) Git) Eran coor.) Ean: 25+ 2Gxi) = 3 ber GY) [mnccod.] RAIN! 244 206x1) = 36 *# MnCeo), = Feducing agent’ CV) Leo Cen] = 36 Cstatcte) tchelating ligand Gomplexes are mor stable oH Low spin = spin paired complex Csre) # High spin unpaired e* complex Cor)* Orgamo Metaiite compounds:~ “metal-caroon bond exi-G@Mn-c @)@-¢ Organo metallic compound y fe f &A Both © god W-bonded “GMM, Corr metal ligand po © eo OL Berne 4 | /| of & of & metal ~metal m™n- On Coon) = metal - carbonyl” Mee) © Re Aue to synerg bond Metal —carbpn,- B.0 T conboon-orygen'” 8:0 in Feccods ? ‘© Mrceo Go, Code og (De oc VAN x 7 ~/ N synergic bon BST. BLy Bsy BLT Cswghthy) #DE cw bond length is Li2gaz then what is the Yalue of © bond length (@) wisvar @B) trea’ cep THAT i nea=F some important points ' t chlorophyll complex +~ ma 2 Haemoglobin complex t= Fe 3. wtamin B, *& 4. Eptcattsjecl] + Antycancer crs platin 5. EOTA 2 Treatment of lead’ poisoning 6- Cen Cpph ct] +> wetkinson catalyst > do Csplitting gap) Sizey At stability chelating > non -chelating, charge * 4» t Stooviv'ty e& Ont Of ConA SpkLt At 3deydesdst rsomensm Ft rae a. guctural isoMensm:~ Qn 1. co-ordination Ispmens™ 2. Kydrate/solvate Case(f)t- [CNEY tetrahedral complexes . doesn't exhibrt aa Ext- Eriecly? incom Lanctyt*case) square planar complex (éxhibtt Gt) ase, quare p \p Tv conti), Cec ely ]* [™ ay] Im @6] | doemt exhibit a I M-metal ©.® monodentate Coren ligand (aa) — symmetrical bidentate Es) unsymmetrical biolentate [may] O [mas8] ° [mar BI 2 [may Be] o [mae <4) 3 [mM@®,] RQcaseliti) » octahedral amptex. (mae 1, [m(aars], [Mas B] doesn't exhvort Ga x complex nga ae (mayBs] -----°> [mayBc] ------ 2 [mas®] ------ 2 (facial ¢ mendonal ) as 90" Trans \g0" [masec]--- ~~ 3 (mMasBeo] ------ 4 Ima, Ba] s [Mar Bc0E) fesitct| [mascoer] > - > -Is [mas @cO] ------ 6 [m cad), 2] -- ~~ [Imcaa),6¢] - ~~~ — 2 Emaey] - -----> 2# optical isomen smi- AA caseG>: [CA] etrahedrat (Ovesn't exhibit ) optical fsomersm square planar Cooesnit exhibit ) ophical isomeviom case Wii): Jen octahedral Mag. MAsB, MANE, | P Aoesntt exhilert MayBo As, and ™A3B: optical ssomensmcomplex Ao.of Gt enantipmenc glo of bagatuneshs arr stereo & ey (otiatn) FS nese [may8s] A . 2 TmayB] 2 0 2 [masb3] ---. 2 ° = Cma,ec] - 3 - 0 3 [mae] ----4 0 - ~~ a 5 [ma BGal---- 5 a ¢ [mee Bic]: - --6 af --- +2 & [Cmargche]---4 | - “6 's [masceieF].-- is. -- - Is ----°30 [mcaa), 83] -- - 2 4 3 Cmcnayag-- 2. a Imcaey] ----- 2 2* AOTE: only cis form of [m(aa). 8] exhibrt optical isomerism. Coprraatty active). 7 roms form of [mcaa>6s] doesn’t exhtlort optical isomensm Coptically inactive). iF [mcaan] oe exhibit Ga SS shibit of,