1

Sri Chaitanya AITS NEET Grand Test-05 (23-04-2024)

KEY AND SOLUTIONS

PHYSICS
(1) 3 (2) 4 (3) 2 (4) 2 (5) 4 (6) 2 (7) 4 (8) 3 (9) 2 (10) 2
(11) 3 (12) 1 (13) 4 (14) 4 (15) 3 (16) 1 (17) 4 (18) 1 (19) 3 (20) 3
(21) 1 (22) 2 (23) 4 (24) 3 (25) 4 (26) 2 (27) 3 (28) 4 (29) 1 (30) 2
(31) 3 (32) 1 (33) 1 (34) 3 (35) 3 (36) 1 (37) 3 (38) 3 (39) 2 (40) 4
(41) 3 (42) 3 (43) 2 (44) 4 (45) 3 (46) 4 (47) 3 (48) 2 (49) 4 (50) 2

BOTANY
(51) 3 (52) 3 (53) 3 (54) 1 (55) 2 (56) 3 (57) 1 (58) 3 (59) 3 (60) 3
(61) 3 (62) 2 (63) 4 (64) 1 (65) 3 (66) 3 (67) 2 (68) 3 (69) 3 (70) 2
(71) 3 (72) 2 (73) 4 (74) 3 (75) 1 (76) 2 (77) 3 (78) 3 (79) 1 (80) 2
(81) 1 (82) 2 (83) 1 (84) 2 (85) 3 (86) 3 (87) 3 (88) 4 (89) 2 (90) 2
(91) 2 (92) 3 (93) 4 (94) 3 (95) 2 (96) 3 (97) 1 (98) 2 (99) 3 (100) 3

ZOOLOGY
(101) 1 (102) 4 (103) 1 (104) 4 (105) 3 (106) 1 (107) 4 (108) 1 (109) 2 (110) 4
(111) 1 (112) 3 (113) 3 (114) 3 (115) 2 (116) 2 (117) 2 (118) 3 (119) 2 (120) 2
(121) 2 (122) 1 (123) 4 (124) 1 (125) 3 (126) 4 (127) 2 (128) 3 (129) 4 (130) 3
(131) 2 (132) 1 (133) 3 (134) 1 (135) 1 (136) 4 (137) 1 (138) 2 (139) 3 (140) 4
(141) 1 (142) 3 (143) 2 (144) 4 (145) 2 (146) 3 (147) 3 (148) 1 (149) 3 (150) 2

CHEMISTRY
(151) 2 (152) 3 (153) 1 (154) 1 (155) 1 (156) 3 (157) 4 (158) 4 (159) 1 (160) 3
(161) 1 (162) 2 (163) 2 (164) 1 (165) 4 (166) 3 (167) 2 (168) 1 (169) 4 (170) 1
(171) 3 (172) 1 (173) 4 (174) 3 (175) 2 (176) 4 (177) 4 (178) 2 (179) 1 (180) 4
(181) 2 (182) 2 (183) 1 (184) 1 (185) 3 (186) 2 (187) 1 (188) 2 (189) 1 (190) 2
(191) 4 (192) 1 (193) 4 (194) 3 (195) 4 (196) 1 (197) 3 (198) 1 (199) 1 (200) 2
 2 Sri Chaitanya AITS NEET Grand Test - 05 DATE: 23-04-2024

PHYSICS 16. Conceptual

1. Effective air distance becomes infinitive ∆d ∆M ∆r ∆L
so F =0 17. = +2 +
d M r L
A T .2  4 π ( 2r ) − 4 πr 2  18. Applying kirchoff ’s voltage law in given
2
2. Energy E = T ∆=
  loop −2i + 8 − 4 − i − 9i =0
KE particle V V=iR
3. =
KE photon 2C 19. w=
AB w=
CD 0
4. Conceptual W = WBC + WDA = 6R 1400 + 6R ( −600 )
5.
= 40kJ
Bird 20. V = nλ = n ( 4ab )
y
n=1
Path between b and a
s = x + ny
3λ 3π
Fish So ∆φ =
x 4 2
n
µ0 I
21. B = 8 2 r = 2l
4 πr
hC 7 E hC x1 t1 V
6. 4=
E−E & = −E 22. = &α=−
λ1 3 λ2 x2 t 2 t1
V 1 V
7. t= ⇒ t α ⇒ t αm β=−
a a t2
8. Application of Lenz’s law
Q Q Q Q
23. + + = 60 ⇒ = 30
dU 2C C 2C C
9. For stable equilibrium =0
dr 24. K eff = 4 K
ERMS
10. iRMS = 2 IA
1/ WC 25. Favg =
C
11. I 0 4 I 0 cos2 φ / 2
=
26. Conceptual
2π ∆x 27. Time of flight T= t1 + t2
=
φ ⇒ sin=
θ
3 d 28. Conceptual
12. Conceptual
= tan α
29. M
13. Conceptual
2K λ1
I IC + Mr 2
14. = 30. F = QE = λ 2l
R
15. B = ( NMn + ZM P − M 0 ) C 2 F K 2λ1λ 2
=
l R
DATE: 23-04-2024 Sri Chaitanya AITS NEET Grand Test - 05 3

31. Centre of mass does not depend on

internal Forces 3a
=
32. From wheatstone bridge principle 2b2c
40. Conceptual
1 1 1 1 41. r1 < r2 ⇒ F1 > F2
= + +
Reff 4 R 2r 4 R
Fnet= F1 − F2
33.
Towards the wire
V/ 3 1 1 1 1
42. = + +
F f1 f 2 f 3

V u 43. T = mrw 2 about 0

v2 Kq K ( −q )
V 2=
+
3
(
42 sin2 θ + cos2 θ ) 44. =
V1
R
+
R2 + a2
2V Kq Kq
u= V2 =
− +
3 R R2 + a2
34. A= r1 + r2 V= V1 − V2

=
r1 r=
r2 0 45. n1 : n2 : n3 = 3 : 5 : 7
r=A 3
n3 = V
sin i i 2
=
µ =
sin r r =
46. L.C 1M .S.D − 1V .S.D
i =µr =µA 19
= 1M .S.D − M .S.D
35. Power = FnetV 20
47. N1 cos 60 = N 2 cos 30
= ( R + ma )V
VS V2
36. Conceptual 48. iz = is − iL = −
RS R2
37. Conceptual
P
49. Current in bulb =
i = 3A
1 2 V
38. mv= mc∆θ Current in resistance = 1.5A
2
E=V+ir
FL
39. ∆ =
AY 50. m1u1 = m2u2
∆ S FS LS AB YB 3 M 1 1
= × × × = ×a× 2 × Gm1m2 1 1
∆ B FB LB AS YS 2 M b c = m1u12 + m2u22
r 2 2
 4 Sri Chaitanya AITS NEET Grand Test - 05 DATE: 23-04-2024

ZOOLOGY the larger proteins and most of the

formed elements in the blood vessels.
101. NCERT – XI Pg no – 51, 54, 58
An elaborate network of vessels called
Organisms Characteristics the lymphatic system collects this fluid
A. PlatyhelminthesIII. Bilateral and drains it back to the major veins.
symmetry with
incomplete diges- 107. NCERT Pg no – 297
tive system ADH can also affect the kidney function
by its constrictor effects on blood
B. Echinoderms IV. Radial symme- vessels.
try with indirect
development Va s o p r e s s i n i s r e l e a s e d f o r m
neurohypophysis
C. Hemichordates I. Cylindrical body
with no 108. NCERT XI Pg no – 307
segementation
Action potential spreads through the
D. Aves II. Warm blooded muscle and causes the release of calcium
animals with direct
development ions into the sarcoplasm. Increase
in Ca ++ level leads to the binding of
102. NCERT – XI Page no – 339
calcium with a subunit of troponin on
Trypsinogen not a hormone it is a actin filaments.
pancreatic enzyme
109. NCERT XI Page no – 312
103. NCERT – Page no – 101
Fibrous joints do not allow any
Simple squamous epithelium found in movement. Cartilaginous joints, allow
the walls of blood vessels and airsacs of limited movments.
lungs
Synovial joints allow considerable
104. NCERT – Page no – 113 movement.
Anterior aorta arises from 1st chamber 110. NCERT – XI Page no – 318
of heart
If sodium potassium pump stops
105. NCERT – XI Page no – 288 working
Cardiac arrest – heart stops beating ⇓ Na + out side the axon
Heart failure – heart not pumping blood
⇑ Na + Inside the axon
effectively
⇓ K + in side the axon
Heart attacke – Heart muscles are
suddenly damaged ⇑ K + out side the axon
Angina - Acute chest pain 111. NCERT – XII Page no – 37
106. NCERT – XI Pg no – 282 hCG, hPL , Relaxin produced in women
As the blood passes through the only during pregnancy
capillaries in tissues, some water 112. NCERT - XII Page no – 44
along with many small water soluble
IUDS increase phagocytosis of sperms
substances move out into the spaces
within the uterus and the Cu ions
between the cells of tissues leaving
released suppress sperm motility and
DATE: 23-04-2024
the fertilizing capacity of sperms. The 118. NCERT – XII Pg NO – 265
hormone releasing IUDs make the
uterus unsuitable for implantation and
the cervix hostile to the sperms.
113. NCERT – XII Page no – 44, 45
Method Mode of action
A. The pill (III) prevents
ovulation
B. condom (I) prevents sperms
reaching cervix
C. Vasectomy (IV) semen contains
no sperms
D. copper T (II) prevents
implantation
114. NCERT – XII Page no – 72
- sex unspecified
- male
- Parent with male child affected
with disease
115. NCERT – XII Page no – 105
DNA fingerprinting involves identifying
differences in some specific regions in
DNA sequence called as repetitive DNA.
116. NCERT – XII Page no – 121, 122, 123
Natural selection can lead to stabilisation
(in which more individuals acquire
mean character value)
117. NCERT – XII Pg No – 247
as only 10% energy is tranfered from
one trophic level to next trophic level,
energy decreases towards higher trophic
levels so number of trophic levels in a
food chain are limited
Sri Chaitanya AITS NEET Grand Test - 05 5
Bioprospecting - exploring molecular,
genetic and species level diversity for
products of economic importance
119. NCERT – XII Page no – 236, 237
120. NCERT – XII Pg No – 211 to 213
ABD statements are correct C –
Statement wrong - In mammals pro-
insulin contains all three A,B and C
peptides
E – statement wrong – Transgenic mice
were used to test safety of polio vaccine
to replace monkey’s 95% of all existing
transgenic animal are mice
121. NCERT-XII Pg no – 213
Rosie is a transgenic cow developed to
produce milk with α - lactalbumin –
human milk protein 2.4 grams per litre
122. Newly added syllabus to Human Health
and Disease by NTA
Dengue vaccine (Dengvaxia) is given
only to the children of 9-16 years age
who are already infected otherwise if
vaccine is given without prior infection
they develop severe disease symptoms
when they are infected with dengue
123. NCERT-XI Pg no – 57
All are cartilaginous fishes examples
with their zoological names and with
their common names
124. NCERT-XI Pg no – 116
Frogs are poikilotherms – cold blooded
animals, their body temperature varies
with surrounding temperature
So during summer and winter they
remain in burrows to avoid fluctuations
in body temperature
 6 Sri Chaitanya AITS NEET Grand Test - 05 DATE: 23-04-2024

125. NCERT-XI Pg no – 103 131. NCERT XII Pg no - 60

Tendon and ligments are dense regular
connective tissumes, the collegen fibres
ar present in row in parallel bundles
126. NCERT-XI Pg : 270
Relaxation of diaphragm and inter
costal muscles returns diaphragm to
their normal positions and reduce to
their normal positions and reduce
the thoracic volume there by lung 132. NCERT-XII Pg no – 119
volume this leads to an increase in
intra pulmonary pressure causing the
expulsion of air
127. NCERT-XI Pg no –
Protonephridia are exevetory structures
in flat worms rotifers some annelids and
cephalochordates
Diaphragms, cervical caps and vaults are
barriers made of rubber that are inserted
into female reproductive tract to cover
during coitus. They prevent conception
by blocking the entry of sperms through
the cervix they are reusable. Male and
female condoms are disposable, they
are not reusable
The sequence of chromosome 1 was
completed only in May 2006 – this was
the last of the 24 human chromosomes.
It is the largest chromosome with 2968
genes
133. NCERT XII Pg No – 90

Nephridia – Earthworms and other Haemophilia is X – linked recessive

annelids disease
Malpighian tubules – Insects The affected female for haemophilia
transmits the disease to all her sons.
Antennal glands or green glands –
As sons recessive X-chromosome only
Crustaceans
from mother.
128. NCERT XI Pg No – 312
X linked genes are hemizygous in male
Synovial joints are with fluid filled –
synovial cavity allows considerably 134. NCERT XII Pg no – 134
movement Nature selects for fitness, that so called
3 optionis incorrect joint between
rd fitness is based on characteristics
carpals is gliding joint which are inherited. Adaptive ability
129. NCERT XI Pg no – 316 is inherited.
The nerve fibres of peripheral nervous 135. NCERT XII Pg.no – 151
system are two types afferent fibres Acquired immune responses are two
transmit impulse from tissues / organs types
to CNS and efferent fibres transmit
1. Humoral immunity (HI) – anti body
regulator y impulse from CNS to
peripheral tissues / organs mediated
130. NCERT XI Bio Pg no – 333 2. Cell mediated immunity (CMI) – T
lymphocytes mediated
Excess secretion of growth hormone
in adults especially in middle age 136. NCERT Pg.no- 243 & 244
can results in severe disfigurement Previous NEET 2023 question
(especially of the face) called acromegaly,
Different processes that occur under
which leads to serious complications
and premature death if unchecked. decomposition are asked
DATE: 23-04-2024 Sri Chaitanya AITS NEET Grand Test - 05 7

Fragmentation – Earthworms break 143. NCERT – XII Page no - 143

down detritus into smaller particles, so Coca alkaloid or cocaine is obtained
statement E is wrong from coca plant Erythroxylum coca,
The detritus food cahin begins with native to south America. It interferes
dead organic matter, so statement D is with the transport of the neuro –
wrong transmitter dopamine.
137. NCERT XII Pg No – 227 144. NCERT – XII Page no - 181
Population ecology is important because If the gene isolate from marrow cells
it links both genetics and evolution. producing ADA is introduced into cells
Evolutionary changes that occur are at early embryonic stages, it could be
observed only at population level permanent cure.
138. NEET XII – Pg no – 131 145. NCERT – XII Page no – 199
Analogous structures are a result of If two species compete for the same
convergent evolution. Similar habitat resource, they could avoid competition
that has resulted in selection of similar by choosing, for instance, different
adaptive features in different groups times for feeding or different foraging
of organisms but towards the same patterns.
function 146. NCERT – XI Page no – 191
139. NCERT XII Pg no – 53 Birth rate = number of births / initial
140. NCERT XI Pg no 334 total
Vasopressin acts mainly at the kidney 16/40 = 0.4 of spring per lotus per year
and stimulates resorption of water 147. NCERT – XII Page no – 217
and electrolytes by the DCT and Rauwolfia vomitoria growing in
thereby reduces ass of water through himalayan ranges has variation in
urine (diuresis) hence it is called ADH the potency & concentration active
antidiuretic hormone chemical Reserpine is an Example for
Hyposecretion of this hormone results Genetic diversity
in a diminished ability of kidney to 148. NCERT – XII Page no – 210
conserve water this condition is known
In an aquatic ecosystem, GFC is the
as diabetes insipidus
major conduit for energy flow. As
141. NCERT XI Pg no. 287 against this, in a terrestrial ecosystem
Normal activities of the heart are a much larger fraction of energy flows
regulated intrinsically i.e auto regulated through the detritus food chain
by specialized muscles hence heart is 149. NCERT – XII Page no – 33
called myogenic.
During oogenesis, a glycoprotein
Neural system regulate heart activity layer called zona pellucid is formed by
through ANS. Secondary oocyte
142. NCERT – XI Page no – 55 150. NCERT – XI Page no – 271,272
Branchisotoma is an example of RV, FRC, TLC can not be measure by
cephalochordata using spirometer.
 8 Sri Chaitanya AITS NEET Grand Test - 05 DATE: 23-04-2024

CHEMISTRY
156. Unlike NH 3 , PH 3 molecules are not
associated through hydrogen bonding
1
151. SO2 ( g ) + O2 ( g )  SO3 ( g ) in liquid state. That is why the boiling
2
of PH 3 is lower than NH 3
K p = K c ( RT )
x

157. Chlorine has more negative electron

Where x = ∆ng = number of gaseous gain enthalpy than fluorine due to
moles in product – number of gas- bigger size and lesser electronic re-
eous moles in reactants pulsion
158. Total number of nodes (angular +
 1 3 1
=1 −  1 +  =1 − =− radial)
 2 2 2
=n–1
152. IUPAC name of *
159. N 2 : σ ( 2s )2 σ ( 2s )2 π ( 2 px )2 π ( 2 p y ) σ ( 2 pz )2
2

 Pt ( NH 3 )2 Cl ( NO2 )  is diammi-
1
nechloridonitrito – N – platinum (II) Bond order = ( 8 − 2 )= 3
2
2
* 
( ) (π 2p )
2
O2 : ( σ2s )  σ 2s  ( σ2 pz ) π y 2 p y
2 2 2
z x
 
1 1
 *   * 
 π y 2 py   π z 2 px 
153. , sp3d 2 , no. of lone pair    
=1 1
Bond order = (8 − 4 ) =
2
2
0
154. E Mn2+
/ MnO −
= −1.51V 2
2 
*
( ) (π 2p )
2
F2 : ( σ2s )  σ 2s  ( σ2 pz ) π y 2 p y
4 2 2
z x
 
ECl0 − /Cl = 0
−1.36V ; ECr 3+
/C O 2 −
=
−1.33V  *
2
  * 
2

 π y 2 p y   π z 2 px 
2 2 7

   
0
ECr = +0.74V
/Cr 3+ 1
Since Cr is having highest oxidation
Bond order = (8 − 6) =
1
2
potential, Cr is the best reducing 2
* 
( )
2
O : ( σ2s )  σ 2s  ( σ2 pz ) π y 2 p y
+ 2 2
agent. 2
 
1
155. Boiling an egg causes denaturation ( π z 2 px )
2  * 
 π y 2 py 
of its protein resulting in loss of its  

quarternary, tertiary and secondary 1

Bond order = ( 8 − 3) =
2.5
structures. 2
160. Salts of strong acid and strong base do
not undergo hydrolysis
DATE: 23-04-2024 Sri Chaitanya AITS NEET Grand Test - 05 9

161. Phosphodiester linkage 165. Pyridine , Pyrrole , Naphthalene are

cyclic, planar, conjugated, follows

( 4n + 2 ) πe − rule
166. Xe is oxidized from +4(in XeF4 ) to

+6(in XeF6 )

Oxygen is reduced from +1(in O2 F2 )

to zero (in O2 )
−
−2F ( 0.34 ) ...... ( i )
162. Cu + 2e → Cu, ∆G =
2+ 0
1
167. H3PO3 .....+3
+ −
−F ( 0.522 ) ...... ( ii )
Cu + e → Cu, ∆G = 0
2
168. According to IUPAC rules
Subtract (ii) from (i)
169.  Ni ( CO )4  → diamagnetic, sp3
2+ −
Cu + e → Cu , ∆G =
−F E + 0
3 ( )
0
hybridization, number of unpaired
electrons = 0
∴∆G10 − ∆G20 = ∆G30
2− 3
⇒ − FE 0 = −2F ( 0.34 ) + F ( 0.522 ) NiCl4  , → paramagnetic, sp
hybridization, number of unpaired
⇒ E 0 = 0.68 − 0.522 = 0.158V electrons = 2

163. 4 s 
=
→n =
4, l 0 170. CuSO4 .5H 2O
Angular momentum =
Cu2+ : 3d 9 4 s 0
h h 2h Unpaired electron present so it show
n =4× =
2ð 2ð ð colour due to d – d transition
As l =0, then Orbital angular momen-
4 3 2 1
h
tum = l ( l + 1) =
0 C H3 − C H − C H2 − C N
2ð |
171.
NH 2
164. (2) PbSO4 is formed
2 – Chloro – 1 – methyl – 4 - nitro-
(3) Specific gravity of H2SO4 de- benzene
creases 172. (1) positional isomers , (2) and (3) are
(4) Pb oxidizes to PbSO4 at anode chain isomers (4) functional group
isomers
 10 Sri Chaitanya AITS NEET Grand Test - 05 DATE: 23-04-2024

173. The order of substitution in different

177. CH 3OH + C6 H 5 MgBr → CH 3OMgBr + C6 H 6
alkanes is :
178. Phthalimide (I) on treatment with
0 0 0
3 > 2 >1 ethanolic potassium hydroxide (II)
Thus, the bromination of 2 – methyl- forms potassium salt of phthalimide
butane mainly gives 2 – bromo – 2 – which on heating with alkyl halide
methylbutane. followed by alkaline hydrolysis pro-
duces the corresponding primary
CH 3
| amines.
Br2
CH 3 − CH 2 − CH − CH 3  →
2 − Methylbu tan e

CH 3 CH 3
| |
CH 3 − CH 2 − CH − CH 2 Br + CH 3 − CH 2 − C − CH 3
|
Br
1 − Bromo − 2methylbu tan e 2 − Bromo − 2 − methylbu tan e
(min or ) (major )
179.
174. -
OH
(CH 3 ) 2C = O + H 2CH -COCH3 
Δ
→ (CH3 ) 2C=CH-CO-CH3
Methyl oxide

180. Phenolpthalein is most suitable in-

dicator for weak acid vs strong base
titrations

175. 181. Ethanol has higher boiling point than

propane due to intermolecular hydro-
gen bonding
182. Due to attainment of stable configu-
ration after losing 3 electrons, there is
sudden increase in I4 from I3, hence it
has 3 electrons in the valence shell.
H

M+3 (SO4)-2  M 2 ( SO4 )3

176. We have been given a bulky base,
hence elimination will take place & 183. 16g CH 4 contains 12g of carbon
not substitution.
12
100g CH 4 contains = × 100 =75%
16
DATE: 23-04-2024 Sri Chaitanya AITS NEET Grand Test - 05 11

184. In group 13 elements, stability of 3 mol

= = 2.79m
+3 oxidation state decreases down 1.0745kg
the group while that of +1 oxida-
OR
tion state increases due to inert pair
M × 1000
effect. Hence, stability of +1 oxida- m=
tion state increases in the sequence:
( dsolution × 1000 ) − M × GMM of solute
Al < Ga < In < Tl
185. Fehling’s reagent can oxidize 188. Water in excess does not influence

CH3CHO but not C 6 H5CHO rate. Therefore rate = K canesugar 

189.
186. Ba ( NO3 )2  Ba 2+ + 2NO3−
CH 3COONa + CH 3COOH , CH 3COOH ( pK a ) =
4.57
Initial 1mol 0 0
0.1 M 0.01M
After
50 mL 50 mL
Dissociation 1 − α α 2α
It is a mixture of weak acid and salt of
Total number of moles =
1 − α + α + 2α = 1 + 2α its conjugate base. Hence it is acidic
buffer.
Then, van’t Hoff factor, I = 1+2 α
Salt 
i −1 = pK a + log 
pH
or α = Acid 
2
2.74 − 1
or α
= = 0.87  0.1 
2 = 4.57 + log  
Degree of dissociation = 87%  0.01 
M = 3mol L−1 = 4.57 + 1 = 5.57
187.
Mass of NaCl =
190. Given, =
T1 300 K , T2 400K
In 1 L solution = 3 x 58.5 = 175.5 g
R = 8.314 J mol −1K −1
Mass of
k2 2 k Ea 1 1
1L solution = 1000 x 1.25 =1250 g ⇒ = ⇒ log 2 =  − 
k1 1 k1 2.303 × R  T1 T2 
(since density = 1.25 g mL-1)
Mass of water in solution = 1250 – Thus,
75.5 2 Ea  1 1 
= log −
= 1074.5g
1 2.303 × 8.314  300 400 


No. of moles of solute =

Ea 0.3010 × 2.303 × 8.314 × 3 × 400
Molality =
Mass of solvent in kg Ea = 6.91kJ mol −1
 12 Sri Chaitanya AITS NEET Grand Test - 05 DATE: 23-04-2024

191. Cr2O7−2 + 3SO3−2 + 8H + → 2Cr +3

+3SO4−2 + 4 H 2O
195.
192. (1) After freezing, the molecules at-
tain an ordered state and therefore,
entropy decreases.
196. Enthalpy of atomization of CH 4 ( g )
(2) At 0 K, the constituent particles involve breaking of four covalent
are static and entropy is minimum. If
bonds, when compared to others.
temperature is raised to 115K. these
begin to move and oscillate about 197. Due to poor shielding by 5f – elec-
their equilibrium positions in the lat- trons in actinoids compared to poor
tice and system becomes more disor- shielding by 4f electrons in lantha-
dered. Therefore entropy increases noids
(3) Reactant. NaHCO3 is a solid and
198. Fe3+ -3d 5
it has low entropy. Among products
there are one solid and two gases. Äo <P
Therefore, the products represent a
condition of higher entropy ∴Fe3+ -t 32g e2g
(4) Here one molecule gives two at-
oms i.e.. number of particles increase CFSE= 3(-0.4 ∆ o ) + 2(+0.6∆= o ) zero

leading to more disordered state. Two 199. Retardation factor =

moles of H atoms have higher entropy Distance travelled by sample/organic compound
than one mole of dihydrogen mole- Distance travelled by solvent

cule.
193. Di methyl glyoxime is the reagent 4.2
= = 0.6
which gives brilliant red precipi- 7
tate with Nickel ions in basic medi- 200. In (b) and (c)
um C-O bond cleavage of R-COOH taken
194. The alkyl iodide produced depends place
on the nature of the alkyl groups. If
one group is Me and the other a pri-
mary or secondary alkyl group, it is
methyl iodide which is produced. This
can be explained on the assumption
that the mechanism is SN2, and be-
cause of the steric effect of the larger
group, I- attacks the smaller methyl
group