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Composites Part B 191 (2020) 107977

Contents lists available at ScienceDirect

Composites Part B
journal homepage: www.elsevier.com/locate/compositesb

Accelerated testing methodology for durability of CFRP


Yasushi Miyano *, Masayuki Nakada
Materials System Research Laboratory, Kanazawa Institute of Technology, Hakusan, Japan

A R T I C L E I N F O A B S T R A C T

Keywords: An accelerated testing methodology (ATM) for measuring CFRP laminate durability developed by the authors
CFRP over many years is reviewed in this paper. First, the applicability of ATM to static, creep, and fatigue strengths of
Durability various load directions for CFRP laminates of various kinds is examined experimentally based on time­
Life prediction
–temperature superposition principles for matrix resin viscoelasticity. Second, the formulation for time-
Statistics
Viscoelasticity
dependent and temperature-dependent statistical static, creep, and fatigue strengths for CFRP laminates was
done based on the matrix resin viscoelasticity. Third, these strengths of unidirectional CFRP were predicted
statistically using the formulated equations. The predicted ones were compared with experimentally obtained
data measured from resin-impregnated CFRP strands as specimens of unidirectional CFRP. Finally, the statistical
long-term tensile static, creep, and fatigue strengths are discussed in terms of the role of the matrix resin
viscoelasticity.

1. Introduction 2018 by the authors [25].


The tensile strength along the longitudinal direction of unidirec­
Carbon fiber reinforced plastics (CFRP) have been used for primary tional CFRP constitutes important and basic data for the reliable design
structures of airplanes, ships, automobiles, and other vehicles, for which of CFRP structures. Phoenix et al. [26] presented a theoretical model and
high reliability must be maintained during long-term operation. experimental data for the strength and lifetime in creep-rupture of
Therefore, an accelerated testing methodology (ATM) is strongly unidirectional carbon fiber/epoxy matrix micro composites at ambient
anticipated for long-term life prediction of CFRP structures exposed to conditions. Otani et al. [27] discussed the lifetime statistics for unidi­
actual environmental temperatures, water, and other influences. ATM rectional carbon fiber/epoxy matrix micro composites in creep rupture.
for measuring CFRP laminate durability developed by the authors over Engelbrecht-Wiggans and Phoenix [28] shows a stochastic model based
many years is reviewed in this paper. on fiber breakage and matrix creep for the stress-rupture failure of
The mechanical behavior of CFRP matrix resin exhibits time unidirectional continuous composites. These researches were focused to
dependence and temperature dependence, so-called viscoelastic the micro and meso failure mechanisms and did not discuss the actual
behavior, not only above the glass transition temperature Tg, but also life time prediction. The authors developed a testing method for the
below Tg. Consequently, the mechanical behavior of CFRP presumably static, creep and fatigue strengths at elevated temperatures using
depends strongly on time and temperature [1–4]. Therefore, the dura­ resin-impregnated carbon fiber strands (CFRP strands). Their strengths
bility of CFRP is highly depended on the environmental effects of tem­ of CFRP strands were measured at various temperatures. Also, their
perature, water absorption and so on. There are many research papers strengths were inferred statistically using the formulated equations. The
on durability of CFRP under actual environmental conditions [5–9]. The predicted values were compared with experimentally obtained data
author’s earlier reports presented an accelerated testing methodology measured using CFRP strands as unidirectional CFRP specimens
for predicting the life of fiber-reinforced polymers (FRP) based on the [29–31]. Finally, in terms of the roles of matrix resin viscoelasticity, the
matrix resin viscoelasticity [10–20]. Statistical formulations for scat­ inferred long-term tensile static, creep, and fatigue strengths are dis­
tered time and temperature dependent static, creep, and fatigue cussed herein.
strengths of CFRP were done based on Christensen’s viscoelastic crack
kinetics [21–24]. The overall results have been published in the book
titled “Durability of Fiber-Reinforced Polymers” from WILEY-VCH in

* Corresponding author.
E-mail addresses: miyano@neptune.kanazawa-it.ac.jp (Y. Miyano), nakada@neptune.kanazawa-it.ac.jp (M. Nakada).

https://doi.org/10.1016/j.compositesb.2020.107977
Received 30 November 2019; Received in revised form 11 March 2020; Accepted 11 March 2020
Available online 16 March 2020
1359-8368/© 2020 Published by Elsevier Ltd.
Y. Miyano and M. Nakada Composites Part B 191 (2020) 107977

Fig. 1. Master curve of creep compliance and time–temperature shift factor [25].

2. Experimental studies of accelerated testing methodology � � �


1 � �� E ðt; TÞ
[25] logσs ¼ logσ 0 þ log ln 1 Pf þ nR log s (2)
α Er ðt0 ; T0 Þ
The most important condition for the accelerated testing methodol­ In the equation above, Pf signifies the failure probability, t denotes
ogy (ATM) is the time-temperature superposition principle (TTSP) for the failure time, t0 represents the reference time, T denotes the tem­
the nondestructive matrix resin deformation: that is, the viscoelasticity. perature, T0 stands for the reference temperature, and σ0 and αs
The master curve of the creep compliance Dc of matrix resin against the respectively denote the scale parameter and the shape parameter on the
reduced time t’ at a reference temperature T0 shown on the left side of Weibull distribution of static strength. In addition, nR is the viscoelastic
Fig. 1 can be constructed by horizontally shifting Dc measured at various parameter. Er and Es* respectively represent the relaxation and visco­
temperatures. The horizontal shift amount defined as the time- elastic moduli of matrix resin. The viscoelastic modulus Es* for the static
temperature shift factor aT0 shown on the right side of Fig. 1 is the ac­ load with a constant strain rate is presented as the following equation.
celeration rate.
Fig. 2 presents a generalization of time-temperature superposition Es� ðt; TÞ ¼ Er ðt = 2; TÞ (3)
principle (TTSP) for non-destructive matrix resin deformation to those Rosen’s model is well known as the failure model for the tensile static
for quasi-static, creep, and fatigue strengths of CFRP. The same TTSP for strength under the longitudinal direction of unidirectional fiber com­
the matrix resin deformation holds for the strengths of CFRP. The same posites [34]. Viscoelastic parameter nR in Equation (2) can be shown by
time-temperature shift factor (accelerating rate) for the matrix resin the following equation based on our earlier work [35], as shown below.
deformation holds for the strengths of CFRP, as shown by the following
equation. nR ¼ 1=2αc (4)

ti tsi tci tfi Therein, αc signifies the shape parameter of tensile strength of a
aT0 ðT i Þ ¼ ¼ ¼ ¼ ; i ¼ 1; 2; 3 (1) single carbon fiber.
t0 ts0 tc0 tf0
The statistical creep strength σc can be ascertained by shifting the
Time compression by elevating the temperature for the matrix resin master curve of static strength with log A based on Christensen’s theory
deformation is also realized for the CFRP strength. Therefore, the long- for viscoelastic crack kinetics [21]. Therefore, the master curve of creep
term strengths of CFRP can be predicted from the measured short-term strength can be represented by the following equation.
strengths of CFRP at elevated temperatures and the time-temperature � � �
shift factor aT0(T) for the matrix resin deformation. 1 �
logσc ¼ logσ 0 þ log
��
ln 1 Pf þ nR log c
E ðt; TÞ
(5)
Table 1 presents experimental verification of TTSP for various FRP α Er ðt0 ; T0 Þ
strengths. As shown in the table, the PAN-based CFRP strength conforms
In this equation, Ec* represents the viscoelastic modulus for a con­
to the time-temperature superposition principle (TTSP), irrespective the
stant stress load.
structural configuration and loading style. These facts were confirmed
by experimentation [10–20]. Ec� ðt; TÞ ¼ Es� ðAt; TÞ ¼ Er ðAt = 2; TÞ (6)

The shifting amount log A, as ascertained by the slope of the loga­


3. Formulations for statistical CFRP strengths [32,33]
rithmic static strength – logarithmic failure time curve is calculated
using the following equation.
The time-dependent and temperature-dependent static, creep, and
� �
fatigue strengths of CFRP are formulated based on the matrix resin 1
logA ¼ log 1 þ ; kR ¼ nR mR (7)
viscoelasticity by assuming that the CFRP deformation is perfectly kR
controlled by the high elasticity of carbon fibers.
Therein, mR represents the slope of logarithmic creep compliance of
First, the statistical time and temperature dependent static strength
matrix resin against logarithmic time.
of CFRP can be formulated using the following equation based on two
We proposed the formulation of statistical fatigue strength of CFRP σf
conditions: A and B.
with fatigue degradation parameter Ff based on the matrix resin visco­
Condition A: Failure probability is independent of the temperature
elasticity, as shown below [36].
and load histories.
� � �
Condition B: Time-dependent and temperature-dependent strength 1 � �� E ðt; TÞ � ��
logσf ¼ logσ0 þ log ln 1 Pf þ nR log f Ff log 2Nf
are controlled by the matrix resin viscoelasticity. α Er ðt0 ; T0 Þ
(8)

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Y. Miyano and M. Nakada Composites Part B 191 (2020) 107977

Fig. 2. Generalization of TTSP for matrix resin deformation to those for quasi-static, creep and fatigue strengths of CFRP [25].

The viscoelastic modulus Ef* is calculated using the following � �� � ��3 � ��2 � ��
equation for the cyclic load for the case in which the stress ratio of the Ff log 2Nf ¼ a log 2Nf þ b log 2Nf þ c log 2Nf (10)
minimum stress/the maximum stress is zero, assuming that the matrix The fatigue strength at Nf ¼ 1=2 is equal to the static strength when
resin deformation in CFRP during cyclic loading is perfectly constrained failure time t is equal to 1/2f.
by the carbon fiber rigidity.
� � � � ��
1 1 Nf 1 4. CFRP strand molding and testing [25]
Ef� ðt; TÞ ¼ Er ; T þ Er ; T ; Nf ¼ ft (9)
2 4f f 4f
The carbon fiber used for this study is high-strength PAN-based
Fatigue degradation parameter Ff , as a function of the number of carbon fiber (T300-3000; Toray Industries Inc.). Its mechanical prop­
cycles to failure Nf , is obtainable by the following polynomial function erties, as referred from catalog descriptions, are in Table 2.
of logð2Nf Þ, which is determined based on experimentation. Fig. 3 shows that the CFRP strands, combined with the carbon fiber

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Y. Miyano and M. Nakada Composites Part B 191 (2020) 107977

Table 1
Experiment-based verification of TTSP for various FRP strengths [25].
Fiber Matrix Deformation Type Fiber/Matrix Loading direction TTSP

Dc E0
Static Creep Fatigue

Carbon PAN Epoxy – ○ UDΔ T400/828 LT ○ ○ ○

HR40/828 ○ – –
T300/828 ○ ○ –
LC ○ ○ –

– ○ UD Ο
T400/828 LT ○ ○ ○

○ – UD Fortafil510/Cape2002 LB ○ – ○

– ○ SW T400/3601 LB ○ ○ ○

○ – PW T300/828 LB ○ – ○

– ○ QIL T800S/3900-2B LB ○ ○ ○

UT500/#135 ○ ○ ○

T800 S/TR-A33 ○ ○ –

PI – ○ QIL IM600/PIXA-M LB ○ – –
– ○ MR50K/PETI-5 ○ – –

BMI – ○ QIL G40-800/5260 LB ○ – –

Vinylester ○ ○ PW T300/VE LB ○ ○ ○

○ – T700/VE ○ – ○

NCF ○ – ○

PEEK – ○ UD T300/PEEK LB � � �
TB � � �

Pitch Epoxy – ○ UDΔ XN05/828 LT ○ – –


XN50/828 ○ – –
○ – UD XN40/25C LB � � �
XN70/25C � – �
YS15/25P ○ – ○

XN05/25P ○ – ○

Glass Vinylester – ○ PW E-glass/VE LB ○ ○ ○

– ○ WE18W/VE ○ – –

Notice

Dc: Creep UD: Unidirectional UDΔ: Strand UDΟ: Ring SW: Satin Woven PW: Plain LT: Longitudinal Tension LB: Longitudinal Bending LC: ○: Applicable
compliance Woven QIL: Quasi-Isotropic Laminates NCF: Non Crimp Fabric Longitudinal Compression TB: Transverse Bending � : Not
E’: Storage Applicable
modulus : No test

and a general purpose epoxy resin (jER828; Mitsubishi Chemical Corp.),


Table 2 were molded using a filament winding system developed by the authors
Carbon fiber and the mechanical properties. [13,14]. Actually, 200 CFRP strand specimens were molded at one time
Carbon Density Tex [g/ Elastic modulus Tensile Strength using this winding frame. The epoxy resin composition and the CFRP
fiber [g/cm3] km] [GPa] [MPa] strand curing conditions are presented in Table 3. Fig. 4 shows that the
T300-3000 1.76 198 230 3530 gage lengths of CFRP strands are approximately 200 mm. The grip
mechanisms to the CFRP strands were developed for static, creep, and
fatigue tests conducted at various temperatures.
The glass transition temperature Tg ¼ 160 � C of the epoxy resin was
ascertained from the peak of the loss tangent against temperature at 1 Hz
using a Dynamic Mechanical Analysis (DMA) testing machine. The CFRP

Fig. 3. Molding system for CFRP strands as specimens [25].

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Y. Miyano and M. Nakada Composites Part B 191 (2020) 107977

Table 3 strands’ fiber volume fraction Vf ¼ 55% is inferred from the CFRP strand
Composition and cure schedule of CFRP strand. weight.
CFRP strand Carbon fiber Composition of resin Cure schedule The original static testing machine with the temperature chamber
(weight ratio) shown in Fig. 5 can achieve a constant elongation rate over a wide range
T300/EP T300-3000 Epoxy: jER828 (100) 70 � C � 12 h and constant temperatures of 25–170 � C. Twenty sets of the original
Hardener: MHAC-P (103.6) þ150 � C � 4 h creep testing machines and five sets of the original fatigue testing ma­
Cure accelerator: 2E4MZ (1) þ190 � C � 2 h chines with temperature chambers shown in this figure can respectively
realize a constant load and a constant cyclic load in the maximum load 1
kN and constant temperatures of 25–150 � C.

Fig. 4. Configuration of CFRP strand specimens [25].

Fig. 5. Static, creep, and fatigue tests for CFRP strands [32,33].

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Y. Miyano and M. Nakada Composites Part B 191 (2020) 107977

Fig. 8. Weibull distributions of static strength of CFRP strands at various


temperatures [36].

Fig. 6. Dimensionless creep compliance and time–temperature shift factor of


matrix resin [29].

Fig. 9. Static strength of CFRP strands against the viscoelastic modulus of


matrix resin [36].

5.1. Static strength of CFRP strands at various temperatures

Static tension tests for CFRP strand were conducted at five temper­
ature of 25 � C, 120 � C, 135 � C, 150 � C, and 170 � C with cross-head speed
of 2 mm/min. The CFRP strand tensile strength σs is obtained using the
following equation.
Wmax
σs ¼ ρ (11)
Fig. 7. Static strengths of CFRP strands against temperature. te
In this equation, Wmax represents the maximum load [N]. Addition­
5. Statistically inferred CFRP strand static strength ally, ρ and te respectively denote the density of the carbon fiber [kg/m3]
and the tex of the carbon fiber strands [g/1000 m]. Fig. 7 presents the
The creep compliance Dc is measured at time t and temperature T and static strength versus temperature for the CFRP strands. Static strengths
the creep compliance at an arbitrary reference time t0 and temperature for CFRP strands decrease markedly with increasing temperature.
T0 is defined as the reference creep compliance Dc0. The dimensionless The Weibull distributions for static strength at various temperatures
creep compliance Dc/Dc0 at various temperatures is shown in the left are depicted in Fig. 8 for the CFRP strand. In this figure, αs is the CFRP
panel of Fig. 6. Long-term Dc/Dc0 at T ¼ 120 � C is obtained by hori­ strand shape parameter; βs is the scale parameter. Although the scale
zontally shifting those at various temperatures, as shown in the right parameter decreases according to the temperature rise, the shape
panel of this figure [29]. The reference time and temperature are parameter maintains an almost constant value for the CFRP strand to the
selected for this study as t0 ¼ 1 min and T0 ¼ 25 � C. Creep compliance temperature rise. Shape parameter αs and scale parameter βs at T ¼ 25 � C
Dc0 at the reference temperature and reference time is 0.33 GPa 1. The in this figure can be inferred as shape parameter α, scale parameter σ 0 of
relaxation modulus Er ðt; TÞ is determined simultaneously as the inverse static strength at the reference temperature T0 ¼ 25 � C, and the refer­
of creep compliance. The temperature condition and Er ðt0 ; T0 Þ at t0 ¼ 1 ence failure time t0 ¼ 1 min used in Equation (2).
min and T0 ¼ 25 � C is 3.0 GPa. The determined relaxation modulus and
time-temperature shift factor for matrix resin are used as the viscoelastic
5.2. Static strength of CFRP strand against viscoelastic modulus of the
moduli in Equations (2), (5) and (8).
matrix resin

Fig. 9 presents the dimensionless static strength σs/σ0 of a CFRP

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Y. Miyano and M. Nakada Composites Part B 191 (2020) 107977

Table 4
Parameters of statistically determined static, creep, and fatigue strengths for
CFRP strands.
4 4 4
σ0 [MPa] α nR mR αf a [10 ] b [10 ] c [10 ]

3721 27 0.0601 0.28 45 2.28 8.38 1.00

Fig. 12. Fatigue strengths of CFRP strand and the number of cycles to fail­
ure [36].

5.3. Master curve of static strength for CFRP strand

All parameters in Equation (2) for the master curve of static strength
are found for the CFRP strand, as shown in Table 4: shape parameter α
and scale parameter σ 0 of static strength at the reference temperature of
Fig. 10. Master curve of static strength of CFRP strand at T ¼ 120 � C [36].
T0 ¼ 25 � C; the reference failure time t0 ¼ 1 min; the viscoelastic
parameter nR; and the dimensionless viscoelastic modulus of matrix
resin Es*/Er0 found from the creep compliance of matrix resin shown in
Fig. 6. Master curves of statistical static strengths for CFRP strands are
portrayed in Fig. 10 with experimentally obtained data measured at
various temperatures. The master curve shows a smooth decreasing
single curve with increasing failure time.

6. Statistically inferred creep strengths of CFRP strands

Creep failure tests of CFRP strands were conducted at three constant


stress levels and one constant temperature T ¼ 120 � C. Results of the
creep failure tests are presented in Fig. 11. Tensile creep strength σc of
CFRP strands were obtained using Equation (11). The predicted creep
failure probability against the failure time calculated by substituting the
parameters on Table 4 in Equation (5) is also shown in Fig. 11. The
predicted statistical creep failure time agrees well with the experimen­
tally obtained data. Therefore, results clarified that the statistical creep
failure time can be predicted from the master curve of creep compliance
of matrix resin shown in Fig. 6 and the parameters for statistical static
strength of CFRP strands shown in Table 4.

Fig. 11. Creep strength and failure probability against failure time at T ¼
120 � C.

strand against the dimensionless viscoelastic modulus of matrix resin


Es*/Er0 for the same conditions of time and temperature. The relation of
σ s/σ0 against Es*/Er0 can be represented as one solid straight line with
slope of nR, which is the viscoelastic parameter in Equation (2), as ob­
tained from Christensen’s model of viscoelastic crack kinetics. The
dotted line in this figure is a straight line with the slope of viscoelastic
parameters nR obtained by substituting shape parameter αc of single
carbon fiber strength to the equation (nR ¼ 1/2αc) based on Rosen’s
model [34]. Both straight lines mutually agree well.
Fig. 13. S–N master curve of CFRP strands [36].

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Y. Miyano and M. Nakada Composites Part B 191 (2020) 107977

Fig. 14. Weibull distributions of dimensionless static, creep, and fatigue strengths of CFRP strands.

7. Statistically inferred fatigue strengths of CFRP strands 8. Weibull distributions of static, creep, and fatigue strengths

Fatigue tension tests for CFRP strands were conducted at five tem­ The measured static strength σs ðiÞ for n specimens at an arbitrary
peratures of 25 � C, 120 � C, 135 � C, and 150 � C with frequency f ¼ 2 Hz failure time t and temperature T can be converted to the dimensionless
and the stress ratio of minimum stress/maximum stress R ¼ 0.1. Tensile static strength Ss0 ðiÞ, as in the following equation.
fatigue strength σ f of CFRP strands is obtained using Equation (11). The � � �
σs ðiÞ E ðt; TÞ
number of cycles to failure Nf was measured through testing. Fig. 12 log Ss0 ðiÞ ¼ log nR log s ;i ¼ 1 � n (13)
σ0 Er ðt0 ; T0 Þ
shows the fatigue strength versus the number of cycles to failure for the
CFRP strands at various maximum loads and temperatures. The fatigue The measured creep failure time tðiÞ for n specimens at an arbitrary
strengths of CFRP strands decrease markedly with the increased number creep stress σ c and temperature T can also be converted to dimensionless
of cycles to failure and temperature. creep strength Sc0 ðiÞ, as shown below.
The dimensionless fatigue strength of CFRP strand is defined as � � �
shown by the following equation.
σc E ðtðiÞ; T Þ
log Sc0 ðiÞ ¼ log nR log c ;i ¼ 1 � n (14)
� � � σ0 Er ðt0 ; T0 Þ
σf E ðt; TÞ
log Sf ¼ log nR log f (12) The number of cycles to failure Nf ðiÞ and failure time tðiÞ measured
σ0 Er ðt0 ; T0 Þ
for each test condition for fatigue strength σf , frequency f and temper­
Fig. 13 shows the relation between the dimensionless fatigue ature T can be converted to the dimensionless fatigue strength Sf0 ðiÞ at
strength Sf and the number of cycles to failure Nf . This relation clarifies Nf ¼ 1/2, as shown by the following equation.
only one curve that is independent of temperature. It is definable that � � �
σf E ðtðiÞ; T Þ � ��
this curve is the S–N master curve for CFRP strand. This curve is shown log Sf0 ðiÞ ¼ log nR log f þ Ff log 2Nf ðiÞ ; tðiÞ
by the polynomial function of Equation (9). These parameters a, b, and c σ0 Er ðt0 ; T0 Þ

are shown in Table 4. Therefore, the statistical fatigue strength at an
¼ Nf ðiÞ f ; i ¼ 1 � n (15)
arbitrary time, temperature, and frequency under pulsating load can be
predicted clearly from the master curve of creep compliance of matrix
The Weibull distributions of the dimensionless static, creep, and fa­
resin shown in Fig. 6 and the parameters for statistical static and fatigue
tigue strengths Ss0 ; Sc0 and Sf0 for each test condition are shown in
strengths of CFRP strands shown in Table 4.
Fig. 14. This figure shows that the shape parameters for static and creep
loads maintain an almost constant value for various test conditions.
However, parameter αf for fatigue strength is slightly larger than those
for static and creep strengths. Also, parameter αf is equal to 45, as shown

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Y. Miyano and M. Nakada Composites Part B 191 (2020) 107977

10. Conclusion

This paper presented a review of an accelerated testing methodology


(ATM), developed by the authors over many years, for measuring CFRP
laminate durability. First, the strength of PAN-based CFRP laminates
conforms to the time–temperature superposition principle (TTSP) for
matrix resin viscoelasticity irrespective of the structural configuration
and loading style. These facts were confirmed from experimentation.
Therefore, the applicability of ATM to the static, creep and fatigue
strengths of PAN-based CFRP laminates are verified based on experi­
mentation. Second, the formulation for statistical determination of time-
dependent and temperature-dependent static, creep, and fatigue
strengths for CFRP laminates was proposed based on the matrix resin
viscoelasticity. Third, the validity of that formulation was clarified from
experimentation to assess tension loading along the longitudinal direc­
tion of unidirectional CFRP using our developed CFRP strand system.
Results clarified that the long-term creep and fatigue failure time of
unidirectional CFRP under tension loading can be readily inferred, sta­
tistically, based on results of static tests conducted at various tempera­
tures and fatigue tests conducted at a reference temperature.

Declaration of competing interest

The authors declare that they have no known competing financial


interests or personal relationships that could have appeared to influence
the work reported in this paper.

Acknowledgments

The authors thank the Office of Naval Research for supporting this
project through an ONR award with Dr. Yapa Rajapakse as the ONR
Fig. 15. Comparison of creep and fatigue strengths for CFRP strands at high Program Officer starting from 2001, and Professor Richard Christensen
temperatures. of Stanford University as a project consultant. The authors thank Pro­
fessor Stephen Tsai of Stanford University, who organized the 1st
on Table 3. Additionally, as this figure shows, the static and fatigue through 20th Composites Durability Workshop from 1998 with the au­
strengths at high temperature in the vicinity of glass transition tem­ thors. The authors also thank the supplier of carbon fibers, Toray In­
perature do not fit to the formulation curves because the measured data dustries., and thank the many students of Kanazawa Institute of
do not make a straight line of Weibull distribution or the straight line of Technology as cooperative researchers of this project.
Weibull distributions is separated by great distance from the cross
points. References

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