MAP

MSD,S NO. l0ll02 ACCOr"LOC Nl00 1/4

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Flocculant
MAP
MSDS N0.: 101102
CAS NO.: 25A85421
Issued oIr Jan. 27,2004

1. CHEMICAL PRODUCT AI{D COMPANY IDENTIFICATION

PRODUCT GROUP NAME: ACCOFLOC N1OO

(ACCOFLOC N102, NL04 Applicable)

PRODUCT DESCRIPTION: Nonionic PolyacrYlarnide

COMPANY IDENTIFICATION: Mitsui Chemicals AquaPolymer, Inc'

Totan Bldg., 2nd Floor, 44-10
Nihonbashi-Muromachi, Chuo-ku, Tokyo, 1034022, JAPAN
EMERGENCY PHONE: TEL: ++81€12314062
FAX: ++81-3-3231-6080

t. coMposITIoNANFoRMATIoN oN INGREDTENTS

HAZARDOUS INGREDIENTS

No Hazardous Ingredients

3. HAZARDS IDENTIFICATION

HEALTII BFFECTS
INGESTION
Low toxicity product.
SKIN CONTACT
May cause slight irritation, especially with repeated or prolonged exposure.
BYE CONTACT
May cause some irritation.
INHALATION
May cause some irritation to the respilatory system if dust is inhaled.

PHYSICAL/CHEMICAL BFFECTS
. Not classified as hazardous by physicavchemical properties.
This type of product has a tendency to create dust if roughly handled. This product does
not burn readily, but as with many organic powders, flammable dust clouds may be formed
in air. Avoid creating dust and keep away from sources of ignition.
IMPORTANT! VERY SLIPPERY WHEN WET.

4, FIRST AID MEASURES

INGESTION
If swallowed, induce voniting immediately as dilected by nedical personnel.
SKIN CONTACT
Take off imrnediately all contaminated clothing.
1n:lediately wash the contaminated area thoroughly with plenty of water and soap.
Insufficient washing may cause skin irritation.
 MAP

l4,sD,t No. l0l l(Jz ACCO|"L]C Nl00 2/4

Obtain ntedical attention if necessary.

EYE CONTACT
L-r.igate imnediately with plenty of water for at least i5 minutes.
Insufficient washing may cause eye ilritation.
Obtain medical attention immediately.
INHALATION
Remove affected person to fresh air.
In case of vomit, keep respiratory tract clear.
If there is difficulty in bleathing, take measure of oxygen inhalation or artificial respiration.
Obtain rnedical attention immediately

5. FIRE FIGHTING MEASURES

EXTINGUSHING METHOD
Cut off the origin of the fire immediately, and extinguish the file with extinguishing media.
Amesting the spread of fire, keep surroundings cool by spraying with water.
Wear self<ontained breathing apparatus to avoid inhale of nitrogenous compounds,
carbon
nlonoxide and carbon dioxide liberated in a flre situation'

EXTINGUSHING MEDIA
Use water spray, foam, powder, carbon dioxide or dry chemical'

6. ACCIDENTAL RBLEASE MEASURES

PBRSONAL PRECAUTIONS
Avoid contact with skin and eYes'
Spills of this product are very slippery when wet'
Wear suitable protective clothing.
METIIODS FOR CLEANING UP
Wear impervious boots.
Spillecl material should be absorbed with inert material such as sawdust or sand, and scooped
up.
Sweep up into containers for disposal.
The area should be thoroughly flushed with water and scrubbed to remove residue.
If slipperiness remains apply more dry*weeping compound.
Prevent liquid entering sewers.

7, HANDLING AND STORAGE

HANDLING.
As with many organic powders flammable dust clouds may be formed. Avoid creating dust
and keep away from sources of ignition.
Do not breathe dust.
Wear protective glasses and gloves.
Do not eat, drink or smoke whilst handling the product'
Remove contaminated clothing immediately and launder before reuse.
Gargle, wash hands alld face thoroughly after handling.
Spills should be scooped up or wiped up irnmediately, and the spill area flushed with water.
STORAGB
To avoid product degradation and equipment corrosion, do not use ilon, copper or aluminum
containers or equipment.
Avoid wet, damp and humid conditions. Keep in a dry, cool place. Avoid extremes of
temperahrre.
 MtlP

I4SD,S NO. l0ll02 ACCO|"LOC Nt00 J/1

A PXPOSURE CONTROLS/PERSONAL PROTECTION

CONTROL PARAMETERS - Geruratt or US limits

No value have been

established

BNGINEERING MEASURES
Engineering controls are not usually necessary if good hygiene practices ale followed.
RBSPIRATORY PROTBCTION
Wear dustproof mask.
Use with adequate ventilation.
EYB PROTECTION
Wear eyelface Protection.
SI{IN PROTECTION
Wear impermeable gioves.
ADDITIONAL
with soap and water'
Before eating, drinking, or smoking, wash face and hands thoroughly

q. PTITSTCAL AND CHEMICAL PROPERTIES

APPEARANCE: Off white granular solid

ODOR: Odorless
SPECIFIC GRAVITY: 0.6 - 0.8
MELTING POINT: Decomposition at 2200C
SOLUBILITY IN WATER: Soluble
FLASH POINT: Not applicable
IGNITION POINT: Not available
EXPLOSION LIMIT: Not available

1.0. STABILITY AND REACTIVITY

STABILITY Stable under normal handling conditions

RBACTIVITY Stable under normal handline conditions

11. TOXICOLOGICAL INFORMATION

BEC SUBSTANCE/"REPARATION TOXICITY CLASSIFICATION

ACUTE TOXICiTY: OraI LD50 (rat): > 1000 mglkg (estimated)
Inhalation LC50: No data
MUTAGENICITY: No data
Direct contact with this material can cause skin and
IRRITATION:
eye i:'ritation.

12. BCOLOGICAL INFORMATION

MOBILITY: No data
RESIDUAL TENDENCY/BIODEGRADATION : 7 9%l28days (BOD) (estimated)
BIOACCUMULATION: No data
ECOLOGICAL TOXICITY:
LC50 (Killifish): > 1000 rng/L(Tlm)/48lirs (estimated)
LC50 (Killifish (fresh water)): 140 ppm(Tlni)/48hrs (estirnated)
LC50 Killifish (seawater adapted)): 2500 ppm(Tl-m)/48hrs (estimated)
LC50 (Rainbow ttout): No data
 A4AP

IfSD:j N0. 101 102 ACCOI'L)C N]00 4/,1

13. DISPOSAL CONSIDBRATIONS

MAP encourages the recycle, recovery ancl reuse of materials, where permitted.
If disposal is necessary,
MAP recommends that organic materials, especially when classified as hazardous
waste, be disposed of
by thermal treatment or incineration at approved facilities. In such case, the waste should
be disposed at
temperature higher than 800C.
All local and national regulations should be followed.

14. TRANSPORTAION INFORMATION

ADR/I{ID Not applicabte

INTBRNATIONAL SHIPPING INFORMATION

IMO
SHIPPING NAME: Not applicable / Not regulatecl
HAZARD CLASS: Not applicable
SUBSIDIARY CLASS: Not applicable
UN NUMBER: Not applicable
PACKING GROUP: Not applicable
. TRANPORT LABEL REQUIRED: None required

ICAO/IATA
SHIPPING NAME: Not applicable / Not regulated
HAZARD CLASS: Not applicable
SUBSIDIARY CLASS: Not applicable
UN NUMBER: Not applicable
PACKING GROUP: Not applicable
TRANPORT LABEL REQUIRED: None required

ADDITIONAL TRANSPORTATION INFORMATION

TECHNICAL NAME (N.O.S.): Not applicable
15. RBGULATORY INFORMATION

EEC MARKING AND LABELING

SYMBOL: None requiled
RISK PHRASES: None
SAFETY PHRASES: 524/25 Avoid contact with skin and eyes.
S82 Spills are very slippery when wet.

INVENTORY INFORMATION
EEC EINECS: All components of this product are included in European Inventory of
Existing chemicals Subsrance (EINEcs) in compliance with council
Directive 67/548/EEC and its amendments.

US TSCA: This product is manufactured in compliance with all provisions of the

Toxic Substances Control Act.15 u.s.c.2601 et. seq.

CANADA: Components of this product have been reported to Environment

Canada
in accordance with subsection 25 of the Canadian Environmental
Protection Act and are included on the Domestic Substances List.

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