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Salt Procedure
Salt Procedure
Salt Procedure
XI - Chemistry
General Procedure for the Systematic Analysis of a Simple Salt
I. Preliminary Tests
S.No Observation Inference
Experiment
Solubility: Soluble May be chloride, sulphate, Nitrate,
A small amount of salt is taken in Acetate or Ammonium chloride
a test tube and dissolved in water
1
Insoluble May be Carbonate or Sulphide
Action of heat: Colourless, pungent smelling gas giving Presence of Ammonium salt
A small amount of salt is taken in a dense white fumes with a glass rod
dry test tube and heated gently. dipped in Con. HCl and also turns red
litmus paper into blue is evolved.
Evolution of reddish brown gas Presence of Nitrate salt
with fishy odour.
Salt turns yellow when hot and white Presence of Zinc salt
when cold.
Characteristic vinegar like smell. Presence of acetate
The salt decripitates (gives crackling Presence of lead nitrate
sound) with evolution of reddish brown
2 gas
No characteristic change Absence of Ammonium, Nitrate,
acetate, lead nitrate and Zinc salts
3
II. Analysis of Acid Radicals
Action of Dil.HCl: Colourless, odourless gas with Presence of Carbonate (CO32- ) is
To a small amount of salt, 1ml of brisk effervescence, turning lime water confirmed
4 dil. HCl is added and heated milky is evolved.
gently. Reddish brown gas with fishy odour, Presence of Nitrate
turning moist ferrous sulphate paper
brown is evolved.
Colourless gas with smell of vinegar is Presence of Acetate
obtained.
No characteristic change Absence of Carbonate, Nitrate,
Acetate and Sulphide.
Action of Con H2SO4: Colourless gas giving dense white fumes Presence of Chloride
To a small amount of salt, 1ml of with a glass rod dipped in NH4OH is
5 Con. H2SO4 is added and heated evolved.
gently. Reddish brown gas turning acidified Presence of Nitrate
ferrous sulphate paper green is evolved.
Barium Chloride test White precipitate soluble in dil. HCl Presence of Carbonate (CO32- ) is
To a few drops of salt solution, dil. confirmed
HCl is added until the
HCl is added until the
effervescence ceases and then 1ml CO3 2- + BaCl2 → BaCO3 (white ppt)+ 2Cl-
of Barium Chloride solution is BaCO3 (white ppt) + 2HCl → BaCl2 + CO2↑ + H2O
added.
10
4Cl- + K2Cr2O7 + 6H2SO4→ 4HSO4- +2KHSO4 + 2CrO2Cl2↑
(orange brown gas chromyl chloride) + 3H2O
CrO2Cl2 + 4NaOH → Na2CrO4(yellow solution)+ 2H2O + 2NaCl
Na2CrO4 + (CH3COO)2Pb → PbCrO4(yellow ppt) + 2 CH3COONa
Silver Nitrate test: Curdy white precipitate soluble in excess Presence of Chloride
To a few drops of salt solution, dil. of NH4OH is obtained (Cl- ) is confirmed
HNO3 is added until the
effervescence ceases and then 1ml Cl- + AgNO3 → AgCl(white ppt) + NO3-
of Silver Nitrate solution is added. AgCl + 2NH4OH → [Ag(NH3)2]Cl(soluble complex
Brown Ring test: Brown ring is formed at the junction of Presence of Nitrate
To a few drops of salt solution, two layers (NO3- ) is confirmed
dil. H2SO4 is added until the
NO3- + H2SO4→ HSO4- + HNO3
effervescence ceases and then 1ml
of freshly prepared FeSO4 solution 6 FeSO4 + 3H2SO4 + 2HNO3→3Fe2(SO4)3 +4H2O +2NO
and Con. H2SO4 is added along the FeSO4 + NO + 5H2O →[Fe(NO)(H2O)5]SO4
sides of the test tube. brown ring
Oxalic acid test:- Smell of vinegar or acetic acid The presence of Acetate (CH3COO-
Take a small quantity of the salt ) is confirmed
on a watch glass and mix it with
solid oxalic acid and make a paste
with few drops of water. Rub the H2C2O4 (oxalic acid) + 2CH3COO-→ C2O4 2- + 2CH3COOH
paste and smell.
Lead acetate test:- A white ppt is formed which is soluble Presence of Sulphate (SO42- ) is
To a little of the water extract in excess of hot ammonium acetate confirmed
1ml of lead acetate solution is solution.
added. SO42- + (CH3COO)2Pb → PbSO4 (white ppt) + 2CH3COO-
Lead (Group - I)
To a few drops of original Yellow precipitate is obtained Lead (Pb2+) is confirmed
1 solution, K2CrO4 solution is
added. K2CrO4 + Pb2+ → PbCrO4 (yellow ppt) + 2K+
To a few drops of original solution A yellow precipitate soluble in hot water Lead (Pb2+) is confirmed
KI is added. To the yellow and reappearing as “golden yellow
2 precipitate 1ml water is added, spangles” on cooling
boiled and cooled.
boiled and cooled. PbCl2 + 2KI → PbI2 (yellow precipitate) + 2Cl-
To another part of the blue White precipitate is formed in brown Copper (Cu2+) is confirmed
2 solution, add acetic acid and solution
potassium iodide solution. The white precipitate is Cu2I2 and the brown colouration is due to I2
1. Lead Nitrate
S. Experiment Observation Inference
Solubility: Soluble May be chloride, sulphate, Nitrate,
A small amount of salt is taken Acetate or Ammonium chloride
1 in a test tube and dissolved in
water
2 Action of heat: The salt decripitates (gives crackling Presence of lead nitrate
A small amount of salt is taken in sound) with evolution of reddish brown
a dry test tube and heated gently. gas
3
II. Analysis of Acid Radicals
Action of Dil.HCl: Reddish brown gas with fishy odour, Presence of Nitrate
To a small amount of salt, 1ml of turning moist ferrous sulphate paper
dil. HCl is added and heated brown is evolved.
4 gently.
Action of Con H2SO4: Reddish brown gas turning acidified Presence of Nitrate
To a small amount of salt, 1ml of ferrous sulphate paper green is evolved.
Con. H2SO4 is added and heated
gently.
5
MnO2 test: No characteristic change Absence of Chloride
To a small amount of salt, a pinch
of MnO2 and Con. H2SO4 are
added and heated gently.
6
Action of NaOH: No characteristic change Absence of Ammonium salt
To a small amount of salt, 1ml
ofNaOH is added and heated
gently.
7
Barium Chloride test No white precipitate Absence of Carbonate and Sulphate
To a few drops of salt solution,
dil. HCl is added until the
effervescence ceases and then 1ml
of Barium Chloride solution is
added.
8
Confirmatory test for Acid Radicals
Brown Ring test: Brown ring is formed at the junction of Presence of Nitrate
To a few drops of salt solution, two layers (NO3- ) is confirmed
dil. H2SO4 is added until the
effervescence ceases and then 1ml
effervescence ceases and then 1ml
NO3- + H2SO4→ HSO4- + HNO3
of freshly prepared FeSO4
6 FeSO4 + 3H2SO4 + 2HNO3→3Fe2(SO4)3 +4H2O +2NO
solution and Con. H2SO4 is added
FeSO4 + NO + 5H2O →[Fe(NO)(H2O)5]SO4
along the sides of the test tube.
brown ring
9
III. Analysis of Basic Radicals
Preparation of Original Solution
To 1g of salt, 3ml of water is added in a test tube and shaken well. The clear solution so obtained is called as
Original solution.
Group Identification
Zero Group: No reddish brown precipitate Absence of Ammonium salts
To a few drops of original
solution, 1ml of NaOH and
Nessler's Reagent are added.
1
Group - I No white precipitate Absence of Group - I (Lead)
To a few drops of original
solution, 2ml of dil.HCl is added.
2
Group - II No black precipitate Absence of Group - II
To the above Group - I solution,
H2S gas is passed.
3
Group - III Gelatinous white precipitate is Presence of Group-III
To a few drops of original obtained (Aluminium)
solution, 1ml of NH4Cl and 2ml
Al3++ 3NH4OH → Al(OH)3 (white gelatinous precipitate)+ 3NH4+
of NH4OH are added.
4
IV. Confirmatory test for Basic Radicals
Aluminium (Group - III)
To a few drops of original A bright red lake is obtained Aluminium (Al3+) is confirmed
solution, NH4OH and Aluminon
Reagent solutions are added. Al(OH)3 (white gelatinous precipitate) + 3HCl → AlCl3 + 3H2O AlCl3 +
3NH4OH → Al(OH)3( blue colour adsorbs on this precipitate) + 3NH4Cl
1
Result:
The given Simple Salt contains
1. Acid Radical : Nitrate
2. Basic Radical : Aluminium
Therefore the given simple salt is Aluminium Nitrate.
3. Zinc Sulphate
S. Experiment Observation Inference
No
Solubility: Soluble May be chloride, sulphate, Nitrate,
A small amount of salt is taken Acetate or Ammonium chloride
in a test tube and dissolved in
1 water
Action of heat: Salt turns yellow when hot and white Presence of Zinc salt
A small amount of salt is taken in when cold.
2 a dry test tube and heated gently.
Flame test: No characteristic coloured flame Absence of Copper, Calcium,
To a small amount of salt taken Strontium and Barium salts
in a watch glass, 2 drops of Con.
HCl is added and made into a
paste. The paste is introduced into
the Non-luminous part of the
Bunsen flame.
3
II. Analysis of Acid Radicals
Action of Dil.HCl: No characteristic change Absence of Carbonate, Nitrate,
To a small amount of salt, 1ml of Acetate and Sulphide.
dil. HCl is added and heated
4 gently.
Action of Con H2SO4: No characteristic change Absence of Chloride and Nitrate
To a small amount of salt, 1ml of
Con. H2SO4 is added and heated
gently.
5
MnO2 test: No characteristic change Absence of Chloride
To a small amount of salt, a pinch
of MnO2 and Con. H2SO4 are
added and heated gently.
6
Action of NaOH: No characteristic change Absence of Ammonium salt
To a small amount of salt, 1ml
ofNaOH is added and heated
gently.
7
Barium Chloride test White precipitate insoluble in Con. HCl Presence of Sulphate (SO42- )
To a few drops of salt solution, is obtained
dil. HCl is added until the
effervescence ceases and then 1ml
of Barium Chloride solution is
8 added.
Confirmatory test for Acid Radicals
Test for Sulphate
Barium Chloride test White precipitate insoluble in Con. HCl Presence of Sulphate (SO42- ) is
To a few drops of salt solution, is obtained confirmed
dil. HCl is added until the
effervescence ceases and then 1ml SO4 2- + BaCl2 → BaSO4 (white ppt) + 2Cl-
of Barium Chloride solution is BaSO4 (white ppt) + conc. HCl→no reaction
added.
Lead acetate test:- A white ppt is formed which is soluble Presence of Sulphate (SO42- ) is
To a little of the water extract in excess of hot ammonium acetate confirmed
1ml of lead acetate solution is solution.
added. SO42- + (CH3COO)2Pb → PbSO4 (white ppt) + 2CH3COO-
9
III. Analysis of Basic Radicals
Preparation of Original Solution
To 1g of salt, 3ml of water is added in a test tube and shaken well. The clear solution so obtained is called as
Original solution.
Group Identification
Zero Group: No reddish brown precipitate Absence of Ammonium salts
To a few drops of original
solution, 1ml of NaOH and
1 Nessler's Reagent are added.
Group - I No white precipitate Absence of Group - I (Lead)
To a few drops of original
solution, 2ml of dil.HCl is added.
2
Group - II No black precipitate Absence of Group - II
To the above Group - I solution,
H2S gas is passed.
3
Group - III No Gelatinous white precipitate Absence of Group - III
To a few drops of original
solution, 1ml of NH4Cl and 2ml
4 of NH4OH are added.
Group - IV Dirty White precipitate is obtained Presence of Group - IV (Zinc)
To the above Group-III
solution, H2S gas is passed. Zn(OH)2 + H2S → ZnS (dirty white precipitate) + 2H2O
5
IV. Confirmatory test for Basic Radicals
Zinc (Group - IV)
To a few drops of original Bluish white precipitate soluble in Zinc (Zn2+) is confirmed
solution, potassium ferrocyanide NaOH and insoluble in dil. Acid is
solution is added. obtained
2 Zn2+ + K4[Fe(CN)6] → Zn2[Fe(CN)6] (white or bluish white precipitate) +
4K+
1
To a few drops of original White precipitate soluble in excess of Zinc (Zn2+) is confirmed
solution, NaOH is added. NaOH is obtained
Zn2+ + 2NaOH → Zn(OH)2 ↓(dirty white precipitate) + Na+ Zn(OH)2 ↓(dirty
white precipitate) + 2NaOH → Na2ZnO2(soluble) + 2H2O
2
Result:
The given Simple Salt contains
1. Acid Radical : Sulphate
2. Basic Radical :Zinc
Therefore the given simple salt is Zinc Sulphate
4. Calcium Acetate
S. Experiment Observation Inference
No
Solubility: Soluble May be chloride, sulphate, Nitrate,
A small amount of salt is taken Acetate or Ammonium chloride
in a test tube and dissolved in
1
water
Action of heat: No characteristic change Absence of Ammonium, Nitrate,
A small amount of salt is taken in acetate, lead nitrate and Zinc salts
a dry test tube and heated gently.
2
Flame test: Brick red flame Presence of Calcium salt
To a small amount of salt taken
in a watch glass, 2 drops of Con.
HCl is added and made into a
paste. The paste is introduced into
the Non-luminous part of the
Bunsen flame.
3
II. Analysis of Acid Radicals
Action of Dil.HCl: Colourless gas with smell of vinegar is Presence of Acetate
To a small amount of salt, 1ml of obtained.
dil. HCl is added and heated
4 gently.
Action of Con H2SO4: No characteristic change Absence of Chloride and Nitrate
To a small amount of salt, 1ml of
Con. H2SO4 is added and heated
5 gently.
MnO2 test: No characteristic change Absence of Chloride
To a small amount of salt, a pinch
of MnO2 and Con. H2SO4 are
6 added and heated gently.
Action of NaOH: No characteristic change Absence of Ammonium salt
To a small amount of salt, 1ml
ofNaOH is added and heated
7 gently.
Barium Chloride test No white precipitate Absence of Carbonate and Sulphate
To a few drops of salt solution,
dil. HCl is added until the
effervescence ceases and then 1ml
of Barium Chloride solution is
added.
8
Test for Acetate
Ethyl Acetate Test: A pleasant fruity odour is obtained. The presence of Acetate (CH3COO
-
5. Barium Chloride
S. Experiment Observation Inference
No
Solubility: Soluble May be chloride, sulphate, Nitrate,
A small amount of salt is taken Acetate or Ammonium chloride
in a test tube and dissolved in
water
1
Action of heat: No characteristic change Absence of Ammonium, Nitrate,
A small amount of salt is taken in acetate, lead nitrate and Zinc salts
2 a dry test tube and heated gently.
Flame test: Apple green flame Presence of Barium salt
To a small amount of salt taken
in a watch glass, 2 drops of Con.
HCl is added and made into a
paste. The paste is introduced into
the Non-luminous part of the
Bunsen flame.
3
II. Analysis of Acid Radicals
Action of Dil.HCl: No characteristic change Absence of Carbonate, Nitrate,
To a small amount of salt, 1ml of Acetate and Sulphide.
dil. HCl is added and heated
4 gently.
Action of Con H2SO4: Colourless gas giving dense white Presence of Chloride
To a small amount of salt, 1ml of fumes with a glass rod dipped in
Con. H2SO4 is added and heated NH4OH is evolved.
gently.
5
MnO2 test: Greenish yellow gas turning starch Presence of Chloride
To a small amount of salt, a pinch iodide paper blue is evolved.
of MnO2 and Con. H2SO4 are
added and heated gently.
6
Action of NaOH: No characteristic change Absence of Ammonium salt
To a small amount of salt, 1ml of
NaOH is added and heated
gently.
7
Barium Chloride test No white precipitate Absence of Carbonate and Sulphate
To a few drops of salt solution,
dil. HCl is added until the
effervescence ceases and then 1ml
of Barium Chloride solution is
8 added.
Confirmatory test for Acid Radicals
Test for Chloride
Chromyl Chloride test: Red orange vapours evolved are passed Presence of Chloride (Cl-) is
To a small amount of salt, pinch into another test tube containing NaOH. confirmed
of K2Cr2O7 and 3 drops of Con. Yellow solution obtained is added with
H2SO4 are added and heated dil. Acetic acid and Lead acetate
gently. solution. Yellow precipitate is obtained
Group Identification
Zero Group: No reddish brown precipitate Absence of Ammonium salts
To a few drops of original
solution, 1ml of NaOH and
1 Nessler's Reagent are added.
Group - I No white precipitate Absence of Group - I
To a few drops of original
solution, 2ml of dil.HCl is added.
2
Group - II No black precipitate Absence of Group - II
To the above Group - I solution,
H2S gas is passed.
3
Group - III No Gelatinous white precipitate Absence of Group - III
To a few drops of original
solution, 1ml of NH4Cl and 2ml
4 of NH4OH are added.
Group - IV No dirty white precipitate Absence of Group - IV
To the above Group-III
solution, H2S gas is passed.
5
Group - V White precipitate is obtained Presence of Group - V (Barium or
To a few drops of original Calcium)
solution, 1ml of NH4Cl, 2ml of
NH4OH and 2ml of (NH4)2CO3 Ba2+ + (NH4)2CO3 → BaCO3(white barium carbonate) + 2NH4 +
solutions are added. Ca2+ + (NH4)2CO3 → CaCO3(white calcium carbonate) + 2NH4+
6
IV. Confirmatory test for Basic Radicals
Barium (Group - V)
To a few drops of original Yellow precipitate is obtained Barium (Ba2+) is confirmed
solution, K2CrO4 solution is
(CH3COO)2Ba + K2CrO4 → BaCrO4(yellow ppt) + 2CH3COOK
1 added.
Result:
The given Simple Salt contains
1. Acid Radical : Chloride
2. Basic Radical : Barium
Therefore the given simple salt is Barium Chloride
6. Magnesium Sulphate
S. Experiment Observation Inference
No
Solubility: Soluble May be chloride, sulphate, Nitrate,
A small amount of salt is taken Acetate or Ammonium chloride
in a test tube and dissolved in
1 water
2 Action of heat: No characteristic change Absence of Ammonium, Nitrate,
A small amount of salt is taken in acetate, lead nitrate and Zinc salts
a dry test tube and heated gently.
Flame test: No characteristic coloured flame Absence of Copper, Calcium,
To a small amount of salt taken Strontium and Barium salts
in a watch glass, 2 drops of Con.
HCl is added and made into a
paste. The paste is introduced into
the Non-luminous part of the
Bunsen flame.
3
II. Analysis of Acid Radicals
Action of Dil.HCl: No characteristic change Absence of Carbonate, Nitrate,
To a small amount of salt, 1ml of Acetate and Sulphide.
dil. HCl is added and heated
4 gently.
5 Action of Con H2SO4: No characteristic change Absence of Chloride and Nitrate
To a small amount of salt, 1ml of
Con. H2SO4 is added and heated
gently.
MnO2 test: No characteristic change Absence of Chloride
To a small amount of salt, a pinch
of MnO2 and Con. H2SO4 are
added and heated gently.
6
Action of NaOH: No characteristic change Absence of Ammonium salt
To a small amount of salt, 1ml of
NaOH is added and heated
gently.
7
Barium Chloride test White precipitate insoluble in Con. HCl Presence of Sulphate (SO42- )
To a few drops of salt solution, is obtained
dil. HCl is added until the
effervescence ceases and then 1ml
of Barium Chloride solution is
added.
8
Confirmatory test for Acid Radicals
Test for Sulphate
Barium Chloride test White precipitate insoluble in Con. HCl Presence of Sulphate (SO42- ) is
To a few drops of salt solution, is obtained confirmed
dil. HCl is added until the 2- -
effervescence ceases and then 1ml SO4 + BaCl2 → BaSO4 (white ppt) + 2Cl
of Barium Chloride solution is BaSO4 (white ppt) + conc. HCl→no reaction
added.
Lead acetate test:- A white ppt is formed which is soluble Presence of Sulphate (SO42- ) is
To a little of the water extract in excess of hot ammonium acetate confirmed
1ml of lead acetate solution is solution.
added.
SO42- + (CH3COO)2Pb → PbSO4 (white ppt) + 2CH3COO-
9
III. Analysis of Basic Radicals
Preparation of Original Solution
To 1g of salt, 3ml of water is added in a test tube and shaken well. The clear solution so obtained is called as
Original solution.
Group Identification
Zero Group: No reddish brown precipitate Absence of Ammonium salts
To a few drops of original
solution, 1ml of NaOH and
1 Nessler's Reagent are added.
Group - I No white precipitate Absence of Group - I (Lead)
To a few drops of original
solution, 2ml of dil.HCl is added.
2
Group - II No black precipitate Absence of Group - II
To the above Group - I solution,
3 H 2S gas is passed.
7. Ammonium Chloride
S. Observation Inference
No
Experiment
2
Flame test: No characteristic coloured flame Absence of Copper, Calcium,
To a small amount of salt taken Strontium and Barium salts
in a watch glass, 2 drops of Con.
HCl is added and made into a
paste. The paste is introduced into
the Non-luminous part of the
Bunsen flame.
3
II. Analysis of Acid Radicals
Action of Dil.HCl: No characteristic change Absence of Carbonate, Nitrate,
To a small amount of salt, 1ml of Acetate and Sulphide.
dil. HCl is added and heated
4 gently.
Action of Con H2SO4: Colourless gas giving dense white Presence of Chloride
To a small amount of salt, 1ml of fumes with a glass rod dipped in
Con. H2SO4 is added and heated NH4OH is evolved.
gently.
5
MnO2 test: Greenish yellow gas turning starch Presence of Chloride
To a small amount of salt, a pinch iodide paper blue is evolved.
of MnO2 and Con. H2SO4 are
added and heated gently.
6
Action of NaOH: Colourless, pungent smelling gas giving Presence of Ammonium salt
To a small amount of salt, 1ml of dense white fumes with a glass rod
NaOH is added and heated dipped in Con. HCl is evoloved.
gently.
7
Barium Chloride test No white precipitate Absence of Carbonate and Sulphate
To a few drops of salt solution,
dil. HCl is added until the
effervescence ceases and then 1ml
of Barium Chloride solution is
8 added.
Confirmatory test for Acid Radicals
Test for Chloride
Chromyl Chloride test: Red orange vapours evolved are passed Presence of Chloride (Cl-) is
To a small amount of salt, pinch into another test tube containing NaOH. confirmed
of K2Cr2O7 and 3 drops of Con. Yellow solution obtained is added with
H2SO4 are added and heated dil. Acetic acid and Lead acetate
gently. solution. Yellow precipitate is obtained
8. Ammonium Carbonate
S. Experiment Observation Inference
No
Solubility: Soluble May be chloride, sulphate, Nitrate,
A small amount of salt is taken Acetate or Ammonium chloride
in a test tube and dissolved in
1 water
Action of heat: Colourless, pungent smelling gas Presence of Ammonium salt
A small amount of salt is taken in giving dense white fumes with a glass
a dry test tube and heated gently. rod dipped in Con. HCl and also turns
red litmus paper into blue is evolved.
2
Flame test: No characteristic coloured flame Absence of Copper, Calcium,
To a small amount of salt taken Strontium and Barium salts
in a watch glass, 2 drops of Con.
HCl is added and made into a
paste. The paste is introduced into
the Non-luminous part of the
Bunsen flame.
3
II. Analysis of Acid Radicals
Action of Dil.HCl: Colourless, odourless gas with Presence of Carbonate (CO32- ) is
To a small amount of salt, 1ml of brisk effervescence, turning lime water confirmed
dil. HCl is added and heated milky is evolved.
4 gently.
Action of Con H2SO4: No characteristic change Absence of Chloride and Nitrate
To a small amount of salt, 1ml of
Con. H2SO4 is added and heated
gently.
5
MnO2 test: No characteristic change Absence of Chloride
To a small amount of salt, a pinch
of MnO2 and Con. H2SO4 are
added and heated gently.
6
Action of NaOH: Colourless, pungent smelling gas giving Presence of Ammonium salt
To a small amount of salt, 1ml of dense white fumes with a glass rod
NaOH is added and heated dipped in Con. HCl is evoloved.
gently. On heating with NaOH ammonia gas is evolved
NH4+ + NaOH → Na+ + H2O + NH3(g)↑
HCl + NH3(g) → NH4Cl (white fumes) + H2O
7
Barium Chloride test White precipitate soluble in dil. HCl Presence of Carbonate (CO32- )
To a few drops of salt solution,
dil. HCl is added until the
effervescence ceases and then 1ml
of Barium Chloride solution is
added.
8
Confirmatory test for Acid Radicals
Test for Carbonate
Action of Dil.HCl: Colourless, odourless gas with Presence of Carbonate (CO32- ) is
To a small amount of salt, 1ml of brisk effervescence, turning lime water confirmed
dil. HCl is added and heated milky is evolved.
gently.
CO32- + 2HCl → 2Cl- + CO2↑ + H2O
Ca(OH)2 + CO2→ CaCO3 (white or milkiness)
Barium Chloride test White precipitate soluble in dil. HCl Presence of Carbonate (CO32- ) is
To a few drops of salt solution, confirmed
dil. HCl is added until the
effervescence ceases and then 1ml CO3 2- + BaCl2 → BaCO3 (white ppt)+ 2Cl-
of Barium Chloride solution is BaCO3 (white ppt) + 2HCl → BaCl2 + CO2↑ + H2O
added.
9
III. Analysis of Basic Radicals
Preparation of Original Solution
To 1g of salt, 3ml of water is added in a test tube and shaken well. The clear solution so obtained is called as
Original solution.
Group Identification
Zero Group: Reddish brown precipitate is Presence of Ammonium (NH4+) salt
To a few drops of original obtained
solution, 1ml of NaOH and
Nessler's Reagent are added.
1
Group - I No white precipitate Absence of Group - I (Lead)
To a few drops of original
solution, 2ml of dil.HCl is added.
2
Group - II No black precipitate Absence of Group - II
To the above Group - I solution,
3 H2S gas is passed.
Group - III No Gelatinous white precipitate Absence of Group - III
To a few drops of original
solution, 1ml of NH4Cl and 2ml
of NH4OH are added.
4
Group - IV No dirty white precipitate Absence of Group - IV
To the above Group-III
solution, H2S gas is passed.
5
Group - V No white precipitate Absence of Group - V
To a few drops of original
solution, 1ml of NH4Cl, 2ml of
NH4OH and 2ml of (NH4)2CO3
solutions are added.
6
Group - VI No white precipitate Absence of Group - VI (Magnesium)
To a few drops of original
solution, 1ml of NH4Cl, 2ml of
NH4OH and 2ml of Ammonium
hydrogen phosphate solutions
7 are added.
IV. Confirmatory test for Basic Radicals
Ammonium (Zero Group)
Ammonium (Zero Group) Reddish brown precipitate is obtained Ammonium (NH4+) is confirmed
To a few drops of original
solution, 1ml of NaOH and
Nessler's Reagent 2[K2HgI4] + NH3(g)↑+ 3KOH → NH2.HgO.HgI↓(brown ppt) +7KI + 2H2O
are added.
1
Result:
The given Simple Salt contains
1. Acid Radical : Carbonate
2. Basic Radical : Ammonium
Therefore the given simple salt is Ammonium Carbonate
Group
List of Salts Cations Symbol Anions Symbol
No
Lead nitrate Lead -
1 Pb2+ I Nitrate NO3
Aluminium nitrate Aluminium -
2 Al3+ III Nitrate NO3
Zinc Sulphate Zinc 2-
3 Zn2+ IV Sulphate SO4
4 Barium chloride Barium Ba2+ V Chloride Cl -
Magnesium sulphate Magnesium 2-
5 Mg2+ VI Sulphate SO4
6 Ammonium chloride Ammonium NH4+ Zero Chloride Cl -
+
7 Ammonium carbonate Ammonium NH4 Zero Carbonate CO32-