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Desalination 524 (2022) 115451

Contents lists available at ScienceDirect

Desalination
journal homepage: www.elsevier.com/locate/desal

Life-cycle environmental assessment of solar-driven Multi-Effect


Desalination (MED) plant
Mohamed Alhaj , Furqan Tahir , Sami G. Al-Ghamdi *
Division of Sustainable Development, College of Science and Engineering, Hamad Bin Khalifa University, Qatar Foundation, Doha, Qatar

H I G H L I G H T S

• A life-cycle assessment (LCA) study is conducted on an optimized solar-driven multi-effect desalination (MED) process.
• The LCA results revealed that most of the life-cycle impacts occurs during the operation phase based on electric pumping energy.
• The linear Fresnel collector has a better LCA rating than the parabolic trough collector.

A R T I C L E I N F O A B S T R A C T

Keywords: Seawater desalination supplies 97 million m3 of freshwater daily to more than 300 million people worldwide.
Life-cycle Assessment (LCA) The global desalination market is dominated by two technologies, thermal and membrane desalination. These
Solar Desalination processes have adverse impacts on the environment in the form of harmful emissions into the air and water and
Linear Fresnel Collector (LFC)
also on human health. Therefore, our main research questions are: to what extent can we minimize the life cycle
Parabolic Trough Collector (PTC)
Multi-Effect Desalination (MED)
environmental impact of conventional thermal desalination processes through the integration of concentered
solar power collectors, and how do various collectors compare in this regard? We answered these questions by
conducting a life-cycle assessment (LCA) study on an optimized solar-driven multi-effect desalination (MED)
process. The LCA results revealed that most of the life-cycle impact in the climate change, fossil depletion, and
water depletion categories occurs during the operation phase based on electric pumping energy. The solar-driven
process reduces climate change impact by 10 kg-CO2 eq., for every 1 m3 of freshwater as compared to the
conventional one. We also found that the linear Fresnel collector has a better LCA rating than the parabolic
trough collector. The broader implications of this work pertain to renewable energy and water resources poli­
cymaking and resource conservation.

1. Introduction namely: thermal desalination (multistage flash (MSF) and multi-effect


distillation (MED)) and membrane desalination (e.g., reverse osmosis
Providing safe potable water is the sixth sustainable development (RO)) [4,5]. These processes, although critical for remedying water
goal defined by the United Nations. Approximately two billion people poverty, have adverse impacts on the environment. Their impact is
live in regions with severe water shortages [1]. Two of the main reasons primarily based on energy consumption, which originates from burning
for these shortages are the uneven geographical distribution of renew­ fossil fuels, a significant factor for climate change. Desalination tech­
able water resources and escalating demand for freshwater, which puts nologies are a classic example of the interlink between energy, water,
more stress on limited water resources [2]. As a result, desalinating and the environment [6]. By integrating renewable energy with desa­
seawater has become essential to providing safe potable water for lination, it is possible to mitigate the environmental impacts of energy
municipal consumption. More than 300 million people receive around consumption. Given that the global production of renewable energy has
97 million m3 of water each day from seawater desalination [3]. This been increasing at a fast pace, we can conclude that renewable-energy-
process is an essential pillar of global water security. Two major desa­ driven desalination has the significant potential [7].
lination technologies dominate the global seawater desalination market,

* Corresponding author.
E-mail address: salghamdi@hbku.edu.qa (S.G. Al-Ghamdi).

https://doi.org/10.1016/j.desal.2021.115451
Received 28 August 2021; Received in revised form 10 November 2021; Accepted 14 November 2021
Available online 25 November 2021
0011-9164/© 2021 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
M. Alhaj et al. Desalination 524 (2022) 115451

1.1. Global solar resources and solar desalination technologies MED, and RO. These three technologies account for 93% of global
desalination capacity [14]. In this paper, the focus is only on MED. MED
Among the various renewable energy sources available, solar power requires less pumping energy and a lower heating steam temperature
is the most suitable for desalination technologies. Solar energy can be than the MSF [15–17]. Furthermore, a literature review revealed sig­
easily converted into thermal or electrical energy, the two main energy nificant interest in coupling solar-thermal collectors with MED, as
types consumed in desalination plants. Furthermore, the geospatial indicated in [12,18–24]. These studies investigated MED coupled to
distribution of solar intensity is aligned mainly with regions facing some solar thermal collectors and provided technical results on system per­
form of water scarcity, as shown in Fig. 1. These regions include the formance from steady-state models, estimations for cost of produced
western coast of the United States, the Middle East, and North Africa freshwater, assessment of the storage systems integrated with solar-
regions and Australia. The World Resources Institute compiled a list of driven MED, experimental test results, and highlighted the main chal­
countries potentially facing water shortages by 2040 [8]. The lenges in solar-driven MED (and solar desalination in general) research.
geographical distribution of these water-stressed countries matches the
geographical distribution of insolation, as shown in Fig. 1.
1.2. Applications of life-cycle assessment in desalination
Solar collectors are devices that convert solar energy from one form
into another. There are two different types of solar collectors: solar
Life cycle assessment (LCA) is a systematic approach for evaluating
thermal and solar electric collectors. Solar-thermal collectors convert
the environmental implications of products and systems across several
incident solar radiation into heat. The most commercially mature and
impact categories [25]. The ISO 14040 standard defines the four major
reliable solar thermal collectors are the parabolic trough collector (PTC)
phases of any LCA: goal and scope definition, inventory analysis, impact
and the linear Fresnel collector (LFC). Solar electric collectors convert
assessment, and result interpretation. There is significant interest in LCA
incident solar energy into electricity. Photovoltaic (PV) panels are the
in the scientific community because it sheds light on the potential near-
best examples of solar electric collectors. The technical challenges and
term and long-term impacts. It provides a scientific basis for evaluating
opportunities for coupling solar collectors with desalination processes
several impacts and can assist in systems development and policy­
were discussed in depth in previous studies [10–12]. The concentration
making. Given the crucial role of desalination, the applications of LCA in
of solar collectors, such as PTCs and the LFCs, is expected to significantly
desalination are highly relevant.
diversify the global electricity supply [13].
One of the earliest LCA studies on desalination technologies powered
The most commercially mature desalination technologies are MSF,
by fossil fuels is [26], where MSF, MED, and RO were compared utilizing

Fig. 1. Global solar insolation alignment with water-scarce regions. a) Potentially water-scarce regions by 2040 (image is published under the creative commons
license) [8]. b) Global solar insolation/irradiance as the annual sum (image is published under the creative commons license) [9].

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M. Alhaj et al. Desalination 524 (2022) 115451

the SimaPro tool and three life-cycle impact assessments (LCIA) that solar energy integration could reduce carbon emissions by 47%
methods: CML 2 baseline 2000, Eco-Points 97, and Eco-Indicator 99. The compared to conventional desalination plants. Recently, Lee and Jepson
results revealed that the highest environmental impact occurs during the [40] conducted a literature survey of LCA studies related to desalination
operational phase of a plant. RO plants had the smallest environmental technologies. They concluded that RO desalination has lower environ­
impact, followed by MED and MSF plants. They also investigated the mental impacts as compared to MED and MSF technologies. However,
renewable energy integration with desalination (for providing elec­ the integration of renewable energy resources may significantly reduce
tricity only) and found that the environmental load decreases when a the impacts of MSF and MED technologies compared to RO. Addition­
clean source provides electricity. This work was unique and valuable ally, technology improvements in desalination may further lower the
since it relied on commercial plant data for the life-cycle inventory and life-cycle impacts.
calculated the specific emissions of three major desalination technolo­
gies. However, its conclusions are region-specific because they relied on 1.3. Solar-driven MED: concept development
the European electricity and natural gas supply profile.
Further, the above study considered using renewable energy for In this study, we apply the concept of LCA to quantify the environ­
supplying electric energy only to the chosen thermal desalination mental impacts of solar-driven MED desalination that uses the low-
technologies (MSF and MED). This limits the conclusions that can be pressure MED process and is powered by a solar linear Fresnel collec­
drawn from this study. Many other relevant studies examined the tor. Fig. 2 presents a schematic and description of the investigated sys­
environmental impacts of desalination plants from a purely qualitative tem. Utilizing the Engineering Equation Solver (EES) tool, we
viewpoint, such as [27–29], which are insufficient for sound policy­ established and validated the mathematical model for the entire plant
making. In [30], the authors carried out an environmental impact and examined the plant’s performance under the climate conditions of
assessment of MSF and RO plants in Saudi Arabia utilizing an index (that Qatar (see Section 1 of supplementary information for modeling details)
evaluates the sustainability of desalination plants as a function of [41]. The plant comprises a low-pressure MED chamber and a solar
environmental footprint and net economic value) which they referred to linear Fresnel collector that supplies the saturated steam to the MED
as the “inclusive impact index light.” The results revealed that RO plants evaporators. The EES model includes monthly solar direct normal irra­
have a lower impact because of their lower electrical energy consump­ diance for Doha, Qatar; energy balance equations for the solar field,
tion. The authors also highlighted that if 40–50% of the power energy, and mass; salt balance equations for the MED section; and en­
consumed comes from renewable sources, then desalination plant sus­ ergy balance equations for the air-cooled condenser. The solar radiation
tainability can be realized. However, it didn’t consider a desalination data fed into the model is based on ground measurements taken in Doha,
system powered by renewable energy. In the study by [31], the authors Qatar. The seawater temperature and salinity data fed into the model are
conducted a LCA study on a hybrid renewable-energy-driven (wind and typical for seawater in the Arabian Gulf region (30 ◦ C and 48 g/kg,
solar PV) RO system with variable contribution levels of the solar PV respectively). The MED plant’s recovery ratio is 30%. The EES model we
resource. Surprisingly, it was reported that greenhouse gas (GHG) developed was validated through comparisons with data from com­
emissions from the plant depend primarily on the treatment chemicals mercial desalination plants (see Table S1 in supplementary information
used. This ran counter to most studies that indicated that the operation for details) [41]. The process is optimized with the number of effects,
phase of desalination plants creates the largest environmental impact (in cost, specific heat transfer area, cooling requirement, and gain output
categories affected mainly by GHG emissions, such as climate change), ratio. The results from our EES model simulation revealed that by uti­
such as [26,30,32]. In the previous study, the solar PV system had only lizing low-pressure steam and a relatively large number of evaporators
an 8% contribution to the energy requirements of the RO plant. Hence, (10 evaporators), it is possible to reduce mechanical energy consump­
the results of this study are not very representative of a solar-driven tion by 59% (compared to conventional high-pressure MED plants).
desalination system. Furthermore, the optimized process reduced the required solar field
Most LCA studies on desalination focus only on RO, while limited aperture area by 25%, representing significant savings in capital and
studies focus on thermal desalination processes [34–39]. Alhaj and Al- operating costs. The incorporation of an air-cooled condenser minimizes
Ghamdi [33] compared the global warming potential associated with the plant’s water consumption by 2 m3 for every 1 m3 of feed water. The
the solar-powered MED plant for various regions. Their results showed water storage concept results in low plant availability (approximately

Fig. 2. The proposed desalination plant integrated with solar field (reproduced with permission from the publisher) [41]. A solar LFC with pressurized water as a
heat transfer fluid provides thermal energy to the MED plant. The MED plant consists of cascaded falling film evaporators. Instead of employing a water-cooled
condenser in the MED unit, an air-cooled condenser is used. The water storage tank is used to store the excess water produced throughout the day. Because the
solar collector produces thermal energy and the electric pumping energy comes from the grid; therefore this is a hybrid arrangement. Hence, the proposed
configuration only operates through the daytime.

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M. Alhaj et al. Desalination 524 (2022) 115451

20% as the solar irradiance is not constant and available throughout the Table 2
day/year [33,41,42]), but it was found that this results in lower plant LCA design parameters.
capital costs when compared to utilizing a sensible or latent heat storage Parameter Description
system. The concept development and validation in this study are
Functional unit 1 m3 of fresh water at the plant
extremely important because the inputs for the LCA study are based on Thermal energy consumption 76 kWh/m3
the EES model developed. Electric energy consumption 4.2 kWh/m3
System lifetime 30 years [45]
Region Doha, Qatar
1.4. Purpose of this work
Construction material inventory for Commercial plant data provided by [43]
the solar field
Based on the literature review, it can be deduced that little attention Treatment chemical dosage Usual operating quantities for plants in the
was given to evaluating the environmental impacts of thermal desali­ Arabian Gulf region [46]
nation in a systematic way (conventional or powered by solar power).
This work focuses on quantifying the environmental impacts of an
plant in Spain) [43]. This plant is the largest of its kind globally and one
energy-efficient solar-powered MED plant equipped with an air-cooled
of only a few that utilize an air-cooled condenser, meaning it is very
condenser. Furthermore, a comparison between solar-driven thermal
similar to our proposed design. In Table 2, the functional unit is 1 m3 of
desalination and conventional desalination was also conducted. This
freshwater at the plant (which is the unit used in all LCA studies on
comparison helps quantify the environmental benefits of solar desali­
desalination), the thermal energy consumption was calculated from the
nation and can be used for benchmarking various solar-driven desali­
EES model we developed (this value is actually very typical for low-
nation technologies. Additionally, the effect of selecting a different solar
pressure MED), and the electrical energy consumption (which was
collector was also studied. The LFC was compared with the PTC (which
also calculated from the EES model) is effectively the pumping energy
has higher optical efficiency and requires less aperture area). Ultimately,
for both the solar field block (the heat transfer fluid (HTF) pumps) and
we quantified the environmental benefits of this technology as a means
the desalination plant (the brine recirculation pumps). The seawater
of supporting environmental and energy policymaking.
pretreatment chemicals utilized are hydrochloric acid (30% blended),
anti-foaming agents, sodium hypochlorite, sodium bi-sulfite, and an
2. Methodology
anti-scaling agent (sulfuric acid). The final distillate is also treated uti­
lizing calcium hydroxide (for remineralization) and sodium hypochlo­
In this study, we conducted an LCA study on the optimized solar-
rite (for disinfection). The bill of materials for desalination system
driven MED plant shown in Fig. 2. The results of the LCA were
construction consists of the materials for the evaporator walls, tube
expressed as a contribution analysis that allows us to understand the
plates, and tubes. It was assumed that the construction materials were
relative impact of each phase in the plant’s life cycle. The data required
processed in the EU. The environmental impacts of brine discharge are
to conduct the LCA is:
not considered in this work as limited studies focus on the aquatic eco-
toxic potential (ETP) [42].
• Bill of materials for the solar and the desalination units
The LCA was conducted utilizing the Gabi software (by Thinkstep).
• Thermal and electrical energy consumption of the entire plant
The plant data in Table 1 and Table 2 was input in GaBi by locating the
• Chemical dosages for the feedwater pre and post-treatment processes
appropriate reference flow names from GaBi’s local databases (including
• Plant capacity (or freshwater productivity) and lifetime (in years)
the life-cycle inventories for the materials construction and energy
processes). The ReCiPe 2016 impact assessment method in GaBi was
Table 1 and Table 2 provide the data used to conduct the LCA. The
used to calculate the impact scores for five mid-point impact categories;
bill of materials for the solar field was based on commercial data for LFC
climate change, ozone depletion, fossil depletion, water depletion, and
and PTC power plants supplied by manufacturers. This data was scaled
human toxicity. The end-of-life phase for the MED plant and the LFC
down by assuming a linear relation between materials mass and aper­
solar field was neglected because it has a minimal contribution, as found
ture area. The construction bill of materials for the solar fields comprises
in previous LCA studies [26,44]. The system boundaries are illustrated
steel, aluminum, glass mirrors, insulation, and concrete foundations. We
in Fig. 3. The electric pumping energy is taken from Qatar’s grid mix
utilized commercial plant data for construction material inventory for
(100% natural gas) provided in GaBi’s local database.
the LFC solar field (based on the 30 MW Puerto Errado 2 (PE2) power
3. Results and discussion
Table 1
Bill of materials for the LFC and PTC solar fields (scaled down from the values Fig. 4 presents a contribution analysis of the proposed solar-driven
given in [43]).
desalination plant. This result is representative of the construction and
Component LFC solar field (Aperture PTC solar field (Aperture Units operation phases. One can observe from this figure that most of the
area of 221 m2) area of 192 m2)
impact arises from the operation phase (solar field operation and MED
MED plant 1 1 m3/ operation) in all categories, with the exception of ozone depletion and
productivity h human toxicity. The operation phase is strongly affected by natural gas
Optical efficiency 66 76 %
usage, which is the only source of electricity in Qatar, while the use of
Float Glass 1617.06 1848.12 kg
Mirrors pretreatment chemicals primarily causes ozone depletion. In fact, 84%
Steel (support 4758.57 5025.86 kg of ozone depletion is caused by the anti-foaming agents utilized to
structures) pretreat the feed water. Unfortunately, because these agents include a
Steel (receiver 4.26 121.19 kg
large number of ozone-depleting chemicals, this is an “unavoidable” side
tube)
Steel (cold and hot 159.42 172.72 kg effect of their use. Seawater foaming is a common phenomenon due to
pipes) its contaminants and impurities. The anti-foaming agents are required to
Borosilicate Glass 131.07 96.70 kg maintain the optimum performance of evaporators in all thermal desa­
Fiber Glass Wool 22.66 10.12 kg lination plants. The construction phase of the solar field influences
Concrete 234.70 1284.53 kg
human toxicity because of the large quantity of steel required, with solar
Aluminum Pipes 12.90 18.35 kg
Condenser 34.20 15.27 kg field construction accounting for 84% of human toxicity impact (stain­
HTF (Water) 339.79 151.73 kg less steel constitutes 70% of the total mass required for solar field). This

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M. Alhaj et al. Desalination 524 (2022) 115451

Fig. 3. LCA system boundary for a solar integrated desalination plant. The proportionate mass contribution of each material to the total bill of materials is shown in
the solar field and MED plant construction phases.

Fig. 4. The percentage contribution of the construction/operation stages for the solar-driven desalination plant.

is due to the presence of heavy metals such as chromium in stainless very little fossil fuel usage within the system’s life cycle boundary (the
steel, as well as the welding process used in stainless steel production, only consumption of fossil fuel occurred during the construction of the
which releases chromium into the environment [47]. By comparing the wind turbines). Similarly, if we were to change our plant’s configuration
results in Fig. 4 with a similar LCA study on a RO plant powered by wind to have 100% solar energy dependence (for thermal and electric energy
and solar power [31], we can conclude that the relative contribution of requirements), the results would be very different.
each subsystem in a renewable-energy driven desalination system is The LCA results of this system were compared to those of a con­
highly dependent on the plant configuration. The LCA study by Shahabi ventional MED plant operating on natural gas. Such plants are cogene­
et al. [31], which investigated a RO plant powered entirely by wind ration plants that produce both desalinated water and electricity based
power, revealed that 60% of the impact in the category of greenhouse on a combined power cycle (natural gas combined cycle (NGCC)). NGCC
gas emissions was a result of chemical usage. This was because there was desalination will be referred to as conventional MED. The power plant’s

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M. Alhaj et al. Desalination 524 (2022) 115451

overall efficiency is 48% [46]. This assumption aids us in the allocation efficiency, meaning they can operate with a smaller aperture area.
procedure for impacts resulting from the MED processes powered from a However, they have higher space requirements [49]. When comparing
natural gas cogeneration plant. In other words, we assumed that the the PTC to the LFC, we chose to add another impact category called
impact due to thermal energy from low-pressure exhaust steam (which metal depletion. This category was added because the construction
enters the MED plant) produced due to natural gas combustion is only phase is the distinctive phase when comparing these collectors.
52% of the total thermal energy entering the natural gas turbine (the The distinguishing feature in this analysis was the materials re­
remaining 48% will constitute impact that represents the power gener­ quirements to construct two solar fields, where each solar field was
ation phase which, in our case, is outside the system boundary). Due to required to power the same MED plant. The solar fields have different
the lack of comparable data for the construction phase of both systems, aperture areas because of the difference in optical efficiency between the
only the operation phase was selected for this comparative study. In the collectors. We assumed that the optical efficiency of the PTC is 76%
plant operation phase, a comparison between the solar-driven MED and [50]. We utilized commercial plant data from [43] to develop the bill of
conventional MED is presented in Fig. 5. It was observed that the solar- materials for each solar collector after scaling it to match our system size
driven MED plant decreases the climate change impact by 10 kg of CO2 (capacity of 1 m3/h). Table 1 shows the bill of materials for two solar
eq., for every 1 m3 of freshwater (i.e., 78% reduction). There is a fields: utilizing an LFC and using a PTC. Both collectors were assumed to
negligible difference between the systems in the ozone depletion cate­ have the same lifetime (30 years), and both are operating under the
gory because the systems have the same consumption rate of pre and same solar radiation profile. The desalination plant’s productivity is the
post-treatment chemicals. The solar system has a slightly lower ozone same in both cases. Since we are mainly interested in materials con­
depletion potential due to thermal energy utilization from a clean sumption and land use for this comparison, we plotted the normalized
source. Additionally, the human toxicity impact for the conventional impact for both collectors for the following impact categories: climate
MED plant is three times more than the solar MED plant due to the change, fossil depletion, metal depletion, and land area. The metal
extraction and processing of natural gas that supplies thermal energy to depletion and land area categories provide a good assessment of both
the plant. The water depletion impact is slightly higher for the solar MED collectors’ construction-related impacts. Climate change and fossil
system due to the more electric energy consumption (for recirculation of depletion were added as a validation step since we expect them not to
the HTF in the solar field). change significantly.
The effects of selecting a different solar collector for our plant, Fig. 5 also presents the results for this comparison. This figure rep­
namely the PTC, were investigated. PTCs are more commercially mature resents the life cycle impacts during the construction and operation
than LFCs and have been used extensively in large-scale solar thermal phases. One can observe that the LFC has a better LCA rating in all three
power plants. Currently, PTC solar power plants’ total power generation categories. It was found that the LFC solar field’s metal depletion impact
capacity in the US exceeds 1.6 GW [48]. PTCs also have higher optical is 24% less than the PTC solar field. This can be attributed to the

Fig. 5. Normalized impacts. Panel (a)


shows the normalized impacts of solar-
driven MED and conventional MED in
the plant operation phase only. The
impacts in each category were normal­
ized with respect to the conventional
MED plant results. Panel (b) shows the
LCA rating for two solar collectors in­
tegrated with MED. The results are
normalized with respect to the LFC.
Land area was calculated based on
reference values from commercial
plants. The results demonstrate the
normalized impacts of construction and
operation phases.

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M. Alhaj et al. Desalination 524 (2022) 115451

simplicity of the LFC in terms of structure (flat mirrors) and lower space impacts when choosing between various solar desalination technologies,
requirements. PTC solar fields are composed of curved mirrors, meaning rather than looking only at specific energy consumption, common in
they require more materials for a given aperture area. Additionally, desalination studies. In addition, it is vital to study the life-cycle impact
commercial PTC plants require high-pressure joints, which add to the of solar-driven desalination systems when operated in cogeneration
bill of materials. Land utilization is also a drawback of PTCs. In fact, by mode. Such systems can tap into a larger pool of users in remote coastal
calculating the ratio of land area to aperture area for two commercial areas who require power and clean water. The findings of this study can
concentrating solar power plants (Andasol PTC plant and PE2 LFC plant also be used as a benchmark when comparing different desalination
in Spain), it was observed that the required land area per aperture for the systems. Additionally, it is crucial to explore how expanding LCA system
LFC is 24% lower than that for the PTC. This translates into a significant boundaries can help us understand the optimal conditions for sustain­
reduction in land use impact for the LFC. able desalination processes.
Lastly, environmental scientists need to address the methodological
3.1. Results uncertainty challenges in conducting LCA studies for desalination technologies in
more depth. Among these issues is the definition of the functional unit
Our results’ primary source of uncertainty is estimating plant oper­ and its relative value. As an example from this paper, desalination sys­
ational energy usage (effectively the electric energy consumption), tems produce freshwater with variable values in different parts of the
directly affecting the solar field operation and MED operation phases. world (i.e., 1 m3 of fresh water in a water-stressed country like Qatar has
Our assumptions for the corresponding reference flows here, although more value than 1 m3 in another country with multiple water supply
based on the validated EES model; yet these values are not 100% alternatives). This issue emphasizes the need to weigh and rank the LCA
representative of real-life operation. Our EES model is a steady-state impact scores accordingly when comparing various scenarios. Further­
model, whereas desalination systems are very dynamic systems. The more, a quantitative uncertainty analysis must always be included to
above uncertainty will affect the impact categories of climate change, provide policy-makers with a sense of confidence about the outcomes of
water depletion, and fossil depletion, which are all highly dependent on the LCA study.
the operation phase, as shown in Fig. 4. Further, although taken from
real plants, the bill of materials for constructing the LFC and PTC sys­ CRediT authorship contribution statement
tems may not resemble a small plant-like ours, especially considering
that we assumed a linear relation between materials mass and solar field Mohamed Alhaj: Conceptualization, Data curation, Formal analysis,
aperture area when scaling down the values. This is not necessarily true. Investigation, Methodology, Software, Validation, Visualization,
The uncertainty in materials consumption affects human toxicity and Writing – original draft. Furqan Tahir: Investigation, Formal analysis,
land use impact. However, the general trend in the results is expected to Visualization, Writing – review & editing. Sami G. Al-Ghamdi:
be the same (i.e., the LFC system has a lower environmental footprint). Conceptualization, Funding acquisition, Project administration, Re­
The results for ozone depletion are highly dependent on the dosages for sources, Software, Supervision, Writing – review & editing.
the pre and post-treatment chemicals, which in our analysis, were
representative of thermal desalination plants in the Arabian Gulf. The
chemical usage for desalination plants can vary significantly as water Declaration of competing interest
quality changes, and hence we must evaluate the ozone depletion impact
as being very region-specific. The authors declare that they have no known competing financial
interests or personal relationships that could have appeared to influence
4. Conclusions the work reported in this paper.

Thermal desalination technologies can help reduce freshwater scar­ Acknowledgements


city, which affects two billion people globally. In many countries in the
Middle East region, such technologies are the only source of potable This research was supported by a scholarship from Hamad Bin
water. Integrating solar power with desalination plants can potentially Khalifa University (HBKU), a member of Qatar Foundation (QF). Any
reduce their energy-associated impacts. This study examined the envi­ opinions, findings, and conclusions or recommendations expressed in
ronmental impacts of MED desalination plants powered by concentrated this material are those of the author(s) and do not necessarily reflect the
solar power collectors (LFC and PTC). We conducted an LCA on an views of the HBKU or QF. Open Access funding provided by the Qatar
optimized plant that utilizes a low-pressure, multi-effect distillation National Library.
process and solar heat from an LFC. Our results revealed that the plant
construction phase would have a negligible impact in all categories Appendix A. Supplementary data
other than human toxicity (due to the presence of heavy metals, such as
chromium in stainless steel and the welding process). The MED plant’s Supplementary data to this article can be found online at https://doi.
operation phase is affected by electricity produced from natural gas org/10.1016/j.desal.2021.115451.
power plants. The operation phase accounts for approximately 80% of
the climate change impact. Our integrated solar desalination plant can References
potentially lessen the climate change impact by 10 kg of CO2 eq., for
every 1 m3 of freshwater produced and decrease the human toxicity [1] United Nations Economic and Social Council, Progress towards the Sustainable
impacts by three times as compared to the conventional MED. Based on Development Goals: Report of the Secretary-General, 2017.
[2] J.W. Owens, Water resources in life-cycle impact assessment: considerations in
anti-foaming agents, chemical use in the desalination process has a choosing category indicators, J. Ind. Ecol. 5 (2001) 37–54, https://doi.org/
substantial effect on ozone depletion. This may give thermal desalina­ 10.1162/10881980152830123.
tion technologies an advantage over RO systems because of the minimal [3] International Desalination Association (IDA), Desalination by the Numbers, 2019.
[4] F. Tahir, A. Mabrouk, S.G. Al-Ghamdi, I. Krupa, T. Sedlacek, A. Abdala, M. Koc,
pretreatment requirements for thermal technologies. Given our bound­
Sustainability assessment and techno-economic analysis of thermally enhanced
ary conditions and assumptions, we found that the LFC has a smaller polymer tube for multi-effect distillation (MED) technology, Polymers (Basel) 13
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