International Journal of Hydrogen Energy 32 (2007) 4978 – 4987

www.elsevier.com/locate/ijhydene

Performance simulation of metal hydride hydrogen storage device

with embedded filters and heat exchanger tubes
G. Mohan, M. Prakash Maiya, S. Srinivasa Murthy ∗
Refrigeration and Air Conditioning Laboratory, Department of Mechanical Engineering, Indian Institute of Technology Madras, Chennai 600 036, India

Received 6 June 2007; received in revised form 7 August 2007; accepted 8 August 2007
Available online 29 September 2007

Abstract
A practical metal hydride based hydrogen storage device would consist of many filters to distribute hydrogen gas and heat exchanger tubes
to cool or heat the hydride bed depending on whether hydrogen is being absorbed or desorbed. This paper presents the simulation of such a
device with LaNi5 as the hydriding alloy. A study of the geometric and operating parameters has been carried out to identify their influence
in the hydriding performance of the storage device.
䉷 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

Keywords: LaNi5 ; Metal hydride; Heat and mass transfer; Simulation; Hydrogen storage

1. Introduction Majority of the work on theoretical issues of metal hydride

Metal hydrides as hydrogen storage media offer various ben-
eficial features such as high volumetric storage capacity, fast
reaction kinetics, large number of charge–discharge cycles and
safety. Metal hydrides are formed on exposure of certain met-
als or alloys to hydrogen at ordinary temperatures and pres-
sures. One of the major drawbacks inherent to metal hydride is
the poor heat and mass transfer characteristics, which call for
special attention in the design of the storage device.
Early heat and mass transfer studies on metal hydrides were
based on the mass and energy balance of hydride beds (Powers
and Cummings [1] and Yu et al. [2]). Corresponding research
activities on the kinetics of hydrogen sorption were carried out
towards the advancement of metal hydrides as storage media.
Goudy et al. [3] reported an experimental study on the reac-
tion kinetics of metal hydrides which ascertained the impor-
tance of heat transfer in controlling the hydrogen evolution.
Later on, Kawamura et al. [4] developed a lumped parame-
ter model for hydride beds. Since then, many models dealing
with the theoretical aspects of metal hydrides have appeared in
literature.
∗ Corresponding author. Fax: +91 44 2257 4652.
E-mail address: ssmurthy@iitm.ac.in (S. Srinivasa Murthy).
0360-3199/$ - see front matter 䉷 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
doi:10.1016/j.ijhydene.2007.08.007
in the recent past dealt with one dimensional treatment of metal
hydride beds. Ram Gopal and Srinivasa Murthy [5] developed a
one dimensional heat transfer model based on the experiments
carried out on a cylindrical metal hydride reactor filled with
MmNi4.5 Al0.5 . Their model and experiments confirmed the im-
portance of heat transfer as a rate controlling phenomena. Sev-
eral two dimensional models [6–11] treated the metal hydride
bed as an exothermic porous media. These studies showed that
the hydrogen absorption rate is high near the reactor walls and
established the importance of bed thickness as the major geo-
metric parameter that influences the hydriding process. How-
ever, the importance of physical configuration of the storage
device and the associated geometric parameters are not fully
represented in the studies reported so far. The region near the
walls where the temperatures are lower gets saturated with hy-
drogen earlier and forms a reaction front which propagates into
the inner hotter regions of the reactor. While the mechanism of
hydride formation is independent of the geometry of the reac-
tor, the shape of the reaction front and the speed of its move-
ment depend on the reactor configuration.
In general, configuration of metal hydride devices falls into
following categories:
(i) A cylindrical tube with axial filter and outer cooling jacket
filled with metal hydride in the annulus.
 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987
Nomenclature
b bed thickness, m
Cp specific heat, J kg−1 K −1
D diffusion coefficient, m2 s−1
d diameter, m
Ea activation energy, J mol−1
h heat transfer coefficient, W m−2 K −1
k thermal conductivity, W m−1 K −1
ṁ hydrogen mass absorbed, kg m−3 s−1
N number of cooling tubes
p pressure, Pa
r radial coordinate, m
R universal gas constant
(8.314 J mol−1 K −1 )
s pitch distance, m
t time, s
T temperature, K
u velocity, m s−1
(ii) Multiple heat transfer tubes and filters embedded in the
metal hydride bed in a cylindrical container.
The single tube design has been widely studied in literature
referred above, mainly to understand the heat and mass transfer
mechanisms. Even though this can yield good heat and mass
transfer performance, it is poor from the overall system weight
point of view. For mobile applications requiring large hydro-
gen storage quantities, low overall system weight is an essential
requirement. A well designed multiple tubes and filters config-
uration provides the possibility to optimize the system weight
for given specifications. In the light of the above, a parametric
study of a hydrogen storage device with embedded filters and
heat exchanger tubes highlighting the influence of important
geometric and operational parameters on the hydriding perfor-
mance of the device is presented in this paper.
2. The physical model
The metal hydride storage device considered in the present
study is shown in Fig. 1. The device contains several tubes and
filters spaced uniformly inside a cylindrical shell. Hydrogen
storage material evenly packed within the cylindrical storage
vessel forms the reaction bed in which the cooling tubes and
filters are located. Heat transfer fluid is circulated through the
cooling tubes to carry away the reaction heat generated in the
sorption process. The filters serve the purpose of distributing
hydrogen evenly within the bed. Reiterating the fact that ab-
sorption process will be faster in the close vicinity of cooling
tubes and it will be saturated earlier than the rest, we can vi-
sualize a smooth interface, known as a reaction front which
demarcates the fully hydrided portion from the rest of the un-
saturated regions. As time proceeds, these reaction fronts move
outwards from the periphery of cooling tubes to the unsaturated
4979
Greek letters
H 0 heat of formation, J kg−1
 porosity
 permeability, m2
 dynamic viscosity, kg m−1 s−1
 polar coordinate, radian
 density, kg m−3
Subscripts
amb ambient
e effective
eq equilibrium
f cooling fluid
g gas
in inlet
o initial
s solid
sat saturated
areas of the alloy. Each tube could be identified as a nucleus
for the reaction fronts to propagate into the unsaturated region.
When all reaction fronts meet one another at the same instant,
the bed is left with the least amount of unsaturated alloy. Such a
configuration could be considered as the most efficient in terms
of hydriding performance.
The reactor considered in the present study has an outer
container of radius ‘r1 ’, in which cooling tubes of radius ‘r2 ’
are arranged in a triangular configuration. Filters of radius ‘r3 ’
are placed at the centre of each triangular arrangement. The
centre to centre distance between the cooling tubes is termed
as the pitch distance ‘s’.
Various assumptions made for the simplified treatment of the
problem are given below.
(i) Hydrogen is assumed as an ideal gas as the pressure within
the bed is moderate.
(ii) Effect of hysteresis and plateau slope is neglected in sim-
ulation as their corresponding values for LaNi5 is very
small [12].
(iii) Natural convection and radiation effects within the bed
are neglected.
(iv) The hydride bed is assumed to have uniform porosity and
is isotropic. Brittle metal hydride materials upon cyclic
hydrogenation asymptotically reach a minimal particle
size [13]. Therefore, effect of powdering and variation in
porosity is more pronounced in the early stages of absorp-
tion. After a certain number of charge–discharge cycles
the variation in porosity with time is insignificantly small.
(v) Pressure drop within the bed is negligible.
(vi) Local thermal equilibrium is assumed between the gas
and solid within the bed. Non-local thermal equilibrium
effects are confined to cooling tube wall and hydrogen
filters. However, its overall effect on the performance of
4980 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987

Fig. 1. Schematic diagram of cylindrical metal hydride reactor.

Table 1
Thermo-physical properties of LaNi5 and hydrogen [8,10,16]

Parameter LaNi5 Hydrogen

Density, kg m−3 8200 0.0838 at NTP

Specific heat, J kg−1 K −1 419 14,890
Effective thermal 1.2 0.12
conductivity,
W m−1 K −1
Diffusivity, m2 s−1 – 4.6 × 10−12
Permeability, m2 10−8 –
Activation energy, J mol−1 21179.6 –
Constants in Eqs. (2), (3): Ca 59.187 –
A 12.99 –
B 3704.59 –

Table 2
Parameter values used in the present simulation study

Parameter Range of values

Initial temperature of 293 (constant)

hydride bed, T0 (K)
Inlet pressure of hydrogen, pin (bar) 8.0–15.0
Cooling media temperature, Tf (K) 293–323
Fig. 2. Spatial variation of pressure and velocity of hydrogen within the metal
Porosity 0.5 (constant)
hydride bed after 3600 s absorption (b = 15 mm, r1 /s = 4 corresponding to
Overall heat transfer 500–1500
N = 55, d2 = 20 mm, Tf = 300 K, h = 500 W m−2 K−1 and p = 15 bar).
coefficient, h
(W m−2 K −1 )
Bed thickness, b (mm) 10–27.5
Cooling tube diameter, d2 (mm) 5–20 considered independent of bed temperature, pressure and
Ratio of container 3–7 (corresponding to N = 31.163) concentration.
radius to pitch (r1 /s) (viii) Isothermal condition is assumed at the cooling tube walls.

the device is minimal [14]. In most bulk portions of the
bed, local thermal equilibrium is still valid. So it may be
justified in simulation.
(vii) Thermo-physical properties such as thermal conductiv-
ity, dynamic viscosity and permeability of the bed are
3. Problem formulation
3.1. Mass balance of metal
Hydrogen entering the alloy bed through filters gets absorbed
and converted into metal hydride with associated changes in
 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987 4981

mol/m3

X 104

1.920

1.915

1.910

1.905

1.900

Fig. 3. Formation of hydride around cooling tubes during absorption at different time intervals (Tf = 300 K, p = 15 bar, h = 500 W m−2 K−1 , r1 /s = 4
corresponding to N = 55, b = 15 mm, d2 = 20 mm). (a) 600 s; (b) 1200 s; (c) 1800 s; (d) 2400 s; (e) 3000 s; (f) 3600 s.

density. Transient changes in hydride density are attributed to 3.2. Reaction kinetics
both absorption reaction and diffusive transport due to spatial
variation in concentration. As listed under assumptions, con- The amount of hydrogen absorbed is directly related with
stant values of porosity and diffusion coefficient are taken for the reaction rate, and could be given as follows [7]:
simulation. Thereby conservation of mass for the solid phase    
Ea P
of the reactor in polar coordinates is expressed in the following ṁ = −Ca exp − ln (sat − s ), (2)
form: RT Peq
where Ca is a material dependent constant, Ea is the activation
 
js 1 j js energy of the material, sat is the density of hydride at satura-
(1 − ) = ṁ + (1 − )D r tion. The change in volume if any, due to hydrogen absorption
jt r jr jr
  is not considered in the computation of density of the bed. The
1 j js
+ (1 − )D 2 , (1) equilibrium pressure is determined by the van’t Hoff relation-
r j j
ship as given below
B
where s denotes the density of the hydride, D denotes the dif- ln Peq = A − , (3)
fusion coefficient and ṁ represents the reaction term. Transient T
variation in density on the left-hand side is expressed as a sum where A and B are van’t Hoff constants.
of three terms on the right-hand side. The first term represents
the mass of hydrogen absorbed due to reaction. The second and 3.3. Darcy law
third terms of the equation signify the effect of diffusive trans-
port due to the concentration gradients existing within the bed. The following relation represents the flow of hydrogen in
Convection term is neglected in Eq. (1). porous bed. It combines the Darcy law and mass conservation
4982 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987

K
360

350

340

330

320

310

300

Fig. 4. Evolution of temperature in metal hydride bed at different time intervals (Tf = 300 K, p = 15 bar, h = 500 W m−2 K−1 , r1 /s = 4 corresponding to
N = 55, b = 15 mm and d2 = 20 mm). (a) 600 s; (b) 1200 s; (c) 1800 s; (d) 2400 s; (e) 3000 s; (f) 3600 s.

equation for hydrogen. Eq. (5) assumes the existence of local thermal equilibrium be-
   tween the solid and gas within the bed. Hence the heat trans-
jg − 1 j jp fer between the two phases is omitted. Radiation heat transfer
 + rg
jt  r jr jr to the ambient is also neglected. Heat of formation of hydride
   
− 1 j jp represents the source term in the equation.
+  = −ṁ. (4) Effective volumetric heat capacity is expressed as follows:
 r 2 j g j
(Cp )e = (g Cpg + (1 − )s Cps ). (6)
Darcy law considers the porous bed and the fluid as a single
homogenized media. The velocity vector is determined by the Effective thermal conductivity is expressed as given below
pressure gradient, the fluid viscosity and the structure of the
porous bed. ke = kg + (1 − )ks . (7)

3.4. Energy balance 3.5. Initial and boundary conditions

Heat generated due to exothermic reaction causes associated Initially the pressure and temperature of reactor bed are as-
spatial temperature imbalances within the bed. Energy conser- sumed to be uniform. Therefore,
vation equation of the bed could be expressed as given below
p = p0 ; T = T0 ;  = 0 at t = 0. (8)
   
jT 1 j jT 1 j jT
(Cp )e = ke r + ke 2 − ṁH 0 . (5) The boundary walls of the reactor are assumed to be imper-
jt r jr jr r j j meable and adiabatic. The reaction heat is removed from the
 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987 4983

mol/m3

X 104

1.920

1.915

1.910

1.905

1.900

Fig. 5. Formation of hydride around cooling tubes at 1800 s absorption for different bed thickness values (Tf = 300 K, p = 15 bar, h = 500 W m−2 K−1 ,
r1 /s = 4 corresponding to N = 55, d2 = 20 mm). (a) 5 mm; (b) 10 mm; (c) 12.5 mm; (d) 15 mm; (e) 20 mm; (f) 27.5 mm.

adiabatic. Based on these, the following boundary conditions

are written:
Reactor wall at r = r1 :
jp jT
= 0; =0 at t > 0. (9)
jr jr
Cooling tube wall at r = r2 :
jp jT
= 0; −k = hf (Tf − T ) at t > 0. (10)
jr jr
Filter wall at r = r3 :
jT
p = pin ; =0 at t > 0. (11)
jr
Fig. 6. Influence of bed thickness and elapsed time on absorption of hydrogen.
4. Simulation methodology

The simulation of the metal hydride bed employing the above

porous bed using heat transfer media circulated through the mentioned partial differential equations were carried out using
cooling tubes. “No slip condition” is valid at the reactor walls. COMSOL MULTIPHYSICS commercial code [15]. The model
Hydrogen is supplied using porous filter tubes. Convective flux is drawn using AUTOCAD software package and exported to
conditions prevail at the filter walls which are assumed to be COMSOL MULTIPHYSICS. An unstructured mesh of element
4984 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987
Fig. 7. Schematic of different reactor configurations used in simulation with
different number of cooling tubes at constant bed thickness.
size 0.001 m and finer is generated by defining suitable mesh
parameters. Most of the cases involve degrees of freedom in the
range 50 000–100 000. The software package solves the mass
(convection–diffusion), momentum (Darcy’s law) and energy
equations (transient conduction) in differential form with spec-
ified initial and boundary conditions. Suitable solver settings
ensure fast convergence of the problem. Grid independence
study is carried out to arrest the variations in results.
5. Results and discussion
Results are obtained for LaNi5 as the hydriding material. Fast
reaction kinetics, low temperature hydriding and its wide appli-
cability in storage applications makes it a material of choice in
the present study. Reaction kinetics and thermo-physical prop-
erty data for LaNi5 are readily available in literature and are
given in Table 1. The simulation is carried out for various op-
erating parameters, the ranges of which are given in Table 2.
Performance of metal hydride device with embedded filters and
heat exchanger tubes demands the definition of two major geo-
metric parameters namely, bed thickness, b and the ratio of the
radius of the container to pitch (r1 /s). Once the bed thickness
is fixed to a constant value, r1 /s decides the number of cool-
ing tubes, N within the bed for a specified system capacity and
configuration.
Distribution of pressure and flow within the bed is repre-
sented in Fig. 2 for a typical case. Similar trend was seen over
the complete range of parameters. The spatial variation in pres-
sure is negligible due to which the convection effects are of
less significance. Diffusion plays dominant role in controlling
the mass transfer in the bed. The main parameters which rule
the mass transfer process in the hydride bed include the hydro-
gen gas pressure, hydrogen equilibrium pressure, hydride bed
temperature and the hydrogen concentration in the hydride. A
large amount of heat is generated due to the exothermic hydride
forming reaction. The reaction within the bed is proportional to
the pressure gradient between the gas supply pressure and equi-
librium pressure corresponding to the bed temperature. While
the supply pressure remains constant, the reaction is vigorous
when the bed temperature and the corresponding equilibrium
pressure are lower. The bed temperature increases rapidly dur-
ing the initial phase of the reaction. Heat transfer from the bed
to the cooling media dissipates the heat generated from the
process. Since the thermal diffusion process is comparatively
slower than the chemical reaction, the hydriding rate drops as
the time progresses.
Figs. 3 and 4 show the variation of concentration and temper-
ature with time for a typical case. Reaction rate is faster in the
vicinity of the heat exchanger tubes. Away from the tube wall,
the bed temperature rises rapidly to a peak value and decreases
slowly. Hydriding alloy requires large temperature gradients to
conduct the heat of reaction to the heat exchanger tubes due
to its low thermal conductivity. The high temperatures prevail-
ing farther from the cooling tubes increase the corresponding
equilibrium pressure, thereby reducing the reaction rate. Hence,
faster reaction rates in the vicinity of the tube lead to higher
saturation levels near the tube. As the reaction proceeds, the
reaction front progresses from the heat exchanger tube walls to
the unsaturated areas within the bed.
5.1. Effects of system configuration
Bed thickness is an important geometric parameter that in-
fluences the performance of any hydrogen storage device. For
thinner beds, the conduction path is relatively short. If the thick-
ness exceeds an optimum value, the gain due to higher quantity
of hydride is negated by the increased resistance to heat and
mass transfer. Hence it results in a higher charging duration for
the entire bed to get saturated. The above trend is illustrated
in Fig. 5, which shows the formation of hydride around cool-
ing tubes for different bed thicknesses. At specified conditions
of cooling media temperature, charging pressure and number
of cooling tubes, rate of absorption depends on bed thickness.
Fig. 6 shows the influence of bed thickness on absorption of
hydrogen. In all cases, the same saturated state of about 1.2 w%
H2 is achieved after different time intervals. It is obvious that,
at lower bed thicknesses the hydride bed reaches saturation ear-
lier. Higher bed thicknesses follow a flatter profile and reach
the saturation state much later. Higher bed temperature, lower
reaction rate, larger conduction path length and low thermal
conductivity of the material collectively contribute to the above
behaviour. For a given bed thickness, both heat transfer and
reaction kinetics are important in determining the absorption
time. As reaction kinetics is more material dependent, for a
specified effective thermal conductivity value, there exists an
optimum bed thickness satisfying the performance and system
weight.
 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987 4985

mol/m3

X 104

1.920

1.915

1.910

1.905

1.900

Fig. 8. Formation of hydride around cooling tubes at 1800 s absorption for different values of r1 /s and corresponding numbers of cooling tubes (Tf = 300 K,
p = 15 bar, h = 500 W m−2 K−1 , b = 15 mm, d2 = 20 mm). (a) r1 /s = 3, N = 31; (b) r1 /s = 4, N = 55; (c) r1 /s = 5, N = 85; (d) r1 /s = 6, N = 121;
(e) r1 /s = 7, N = 163.

Fig. 9. Influence of number of cooling tubes and elapsed time on absorption

of hydrogen. Fig. 10. Effect of cooling tube diameters and elapsed time on hydride
formation.

Sizing of high capacity storage devices demand a judicious

selection of its diameter and length strictly based on various with less number of cooling tubes, or the one with more number
limiting considerations. For a prescribed storage capacity at of cooling tubes and shorter length. Temperature of the coolant
constant bed thickness, they either require a long storage bed increases as it flows through the bed dissipating the heat of
4986 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987

reaction. Long storage beds lead to lower performance levels

owing to higher temperature rise of the coolant. The above
effect is compounded by the axial pressure variation within the
bed. Devices with large diameters but shorter lengths overcome
the above drawbacks and also ensure an even distribution of
hydrogen within the bed. However, they could turn out to be
bulky.
Fig. 7 depicts arrangements of different number of cooling
tubes in the storage bed. The configuration follows the scheme
described earlier in the physical model. The ratio, ‘r1 /s’ as-
sumes different values ranging from 3 to 7. Pitch retains a con-
stant value as the bed thickness and cooling tube radii are con-
stant. Keeping r1 /s = 3, 4, 5, 6 and 7 correspondingly require
31, 55, 85, 121 and 163 tubes to be arranged in the specified
manner. Fig. 11. Effect of supply pressure on hydride formation.
As depicted in Fig. 4, hotspots are observed in the periph-
eral regions of the bed, which get saturated much later than the
rest of the device. The extents of such regions are analogically
similar to the void spaces of a cylindrical shell stacked with in-
dividual cylinders of identical diameters. Bed thickness and the
ratio of container radius to pitch (r1 /s) collectively determine
the existence of such unsaturated regions, which are quantita-
tively much smaller compared with the rest of the device. For-
mation of hydride at different values of ‘r1 /s’ after 1800 s is
illustrated in Fig. 8. Disparity among different cases is evident
only in the peripheral regions and the inner regions develop a
uniform growth of saturated fronts. Based on the above fact,
it may be inferred that, bed thickness is rate controlling at all
spatial locations within the bed and throughout the hydriding
process. Effect of ‘r1 /s’ is limited to the peripheral regions and
towards the closing stages of reaction. However, there exists Fig. 12. Effect of cooling media temperature on hydride formation.
an optimum ratio corresponding to a fixed number of cooling
tubes which dissipates heat better than the rest at all different
locations within the bed and thereby minimizes the unsaturated
space. The above statement explains the apparent gain at N =85
(r1 /s = 5) over other cases, towards the final stages of reaction
(t > 3000 s) as seen in Fig. 9.
Fig. 10 shows the influence of tube size on hydriding time.
The analysis assumes isothermal conditions and constant heat
transfer coefficient at the walls. Bed thickness is also kept
constant. Increasing the heat exchanger tube diameter leads to
higher heat transfer surface area per unit available volume of the
container, which causes higher heat transfer rates and thereby
better hydriding performance. However, increasing the heat ex-
changer tube diameter correspondingly increases the size of the
container as well as the percentage of unsaturated area within
the whole available area of the bed, which acts as a negat- Fig. 13. Influence of tube side heat transfer coefficient on hydride formation.
ing factor. So the gain in hydriding performance progressively
comes down as we increase the cooling tube diameter. Selection operational parameters which influence the performance of the
of tube diameter should also be determined by the hydraulic hydride bed.
losses within the flow passage. Supply pressure is an important operating parameter con-
trolling the hydriding rates because the differential between
equilibrium pressure and imposed pressure within the reactor
5.2. Effects of operating conditions controls the absorption process. A higher pressure differential
reduces the elapsed time for hydriding as seen in Fig. 11. Two
Hydrogen supply pressure, cooling media temperature and other parameters namely, cooling media temperature and cool-
cooling tube side heat transfer coefficient are independent ing tube side heat transfer coefficient control the transport of
 G. Mohan et al. / International Journal of Hydrogen Energy 32 (2007) 4978 – 4987
exothermic heat generated within the bed. Effect of cooling me-
dia temperature on hydriding is shown in Fig. 12. At any given
supply pressure, lower coolant temperature causes a lower bed
temperature and thereby lower equilibrium pressure. It conse-
quently increases the driving potential for mass transfer, re-
sulting in a higher rate of reaction. Impact of tube side heat
transfer coefficient on hydrogen absorption is small as observed
in Fig. 13.
6. Conclusion
Simulation of a metal hydride hydrogen storage device with
embedded filters and cooling tubes is carried out with LaNi5
as the alloy material for various parametric values. Results of
the simulation reiterate the importance of bed thickness as a
major parameter controlling the rate of hydrogen absorption at
all locations within the bed. Effect of the ratio of container ra-
dius to pitch (r1 /s) on hydrogen sorption cannot be ignored.
Heat exchanger tube diameters are observed to have marginal
influence on hydriding time at higher values. Design of hy-
drogen storage device with embedded filters and cooling tubes
demands a suitable method for the calculation of above geo-
metric parameters satisfying the prescribed performance and
system weight. Studies of parameters which include hydrogen
supply pressure, coolant temperature and tube side heat trans-
fer coefficient highlight their influence at different operating
conditions.
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