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Practice Sheet-26
for CLASS : XII
Academic Session : 2020-21 JEE (MAIN+ADVANCED) 2021

CHEMISTRY
Time : 1 Hr

TOPIC: CHEMICAL BONDING

1. Choose the incorrect statement:
(A) All S – F bond lengths are identical in SF4 (B) All Cl – F bond length are identical in ClF3
(C) All ÐFClF angles are identical in ClF3 (D) All possible angle in BF2 Cl are 120°
2. Select the correct statement (s) :
(A) When d x 2 - y2 or d xy orbitals combine in parallel planes, then d or d * molecular orbitals are formed.

(B) When d x 2 - y2 or d xy orbitals combine in parallel planes, then N.B.M.O, are formed

(C) When d yz and d xz orbitals combine in along the y-axis, then N.B.M.O. orbitals are formed
(D) No interaction is possible when p z and d xz orbitals overlap with collinear z-axis.

3. The dipole moment of AX3 ,BX 3 , and CY3 are 4.97 ´10-30 ,0.60 ´10-30 , and 0.00 C.M .repectivelpy, then
the shape of molecules may be :
(A) Pyramidal,T-shape,trigonal planar (B) Pyramidal,trigonal planar, T-shape
(C) T-shape, pyramidal, trigonal planar (D) Pyramidal,T-shape, linear
4. Select the correct statement (s) following molecules :
(I) PF2 ( CH 3 )3 (II) PF2 ( CF3 )3
(A) Both have trigonal bipyramidal structure
(B) Both have the dipole moment
(C) P–F bond length is longer in PF2 ( CH 3 )3 than in PF2 ( CF3 )3

(D) P – F bond length is longer in PF2 ( CF3 )3 than in PF2 ( CH 3 )3

5. Select the incorrect statement for adjacent bond angle
(A) In CF2 and OF2 ,OF2 has higher bond angle (B) In PF4+ and PF4- , PF4- has higher bond angle

(C) In CIF3 and BF3 has lower bond angle (D) Both NH 3 and PH3 have the same bond angle
6. Which of the following relationship is correct for the following figure :

CHEMISTY 1
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PRACTICE SHEET-26
(A) x = y = z (B) x =y > z
(C) x > 120° (D) z < 120°
7. Select the correct statement for non-bonding and anti-bonding orbitals :
(A) Non bonding orbitals have same energy than the atomic orbitals from which they are formed
(B) Anti-bonding orbitals have higher energy than the atomic orbitals from which they are formed
(C) Non-bonding orbital have higher energy than the atomic orbitals from which they are formed
(D) Anti-bonding orbital have lower energy than the atomic orbitals from which they are formed
8. Select the correct statements :
(A) The combination of s-orbital and p-orbital, with the increase of p-character, the bond angle decreaes

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(B) H - C - H bond angle > H - C- F bond angle in CH 3 F molecule
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(C) F - C - F bond angle > H - C- F bond angle in CH 3 F molecule

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(D) H - C - H bond angle =H - C- F bond angle in CH 3 F molecule
9. Select the incorrect statements :

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(A) Peroxide ion has longer bond length than O 2
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(B) Superoxide ion has longer bond length than peroxide ion.

(C)
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Dioxygenyl ion ( O2 ) has longer bond length than O2

Dioxygenyl ion ( O2 ) has smaller bond length than O2

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(D)
10. Select the correct order :
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(A) Bond strength : NO - < NO < NO +

(B) N – O bond angle NO+2 < NO 2- < NO3-

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(C) Thermal stability : LiF > NaF > KF > RbF > CsF

(D) Size : Be 2+ ( aq ) < Mg 2+ ( aq ) < Ca 2 + ( aq ) < Sr 2+ ( aq ) < Ba 2 + ( aq )

11. If x is internuclear axis which type of overlapping is/are responsible for the formation of N.B.M.O ?
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(A) d xy + p x (B) d xy + s
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(C) s + p y (D) s + p z
12. Select the correct statement(s)
(A) CH 3 NCS is angular while SiH 3 NCS is linear

(B) Both CH 3 NCS and SiH 3 NCS are linear

(C) CH 3 NCS is linear while SiH 3 NCS is bent
(D) The Lewis acid strength of boron halides runs as BF3 < BCl3 < BBr3 < BI3

CHEMISTRY 2
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PRACTICE SHEET-26
13. Select the incorrect order for the given properties :
(A) Li + ( aq ) > Na + ( aq ) > K + ( aq ) > Rb + ( aq ) > Cs + ( aq ) : Ionic mobility

(B) Li + ( aq ) > Na + ( aq ) > K + ( aq ) > Rb + ( aq ) > Cs + ( aq ) : Hydrated size of ion

(C) F- ( aq ) > Cl- ( aq ) > Br - ( aq ) > I - ( aq ) : Hydrated size of ion

(D) F- ( aq ) < Cl- ( aq ) < Br - ( aq ) < I - ( aq ) : Ionic mobility

14. Select the correct statements :
(A) For a given cation, covalent character increases with increase in the size of the anion

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(B) For a given anion, covalent character increases with decrease in the size of the cation
(C) Covalent character increases with increasing charge on either ion
(D) Covalent character is greater for cations with pseudo-inert gas configuration than the noble gas

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configureation.
15. Select the correct order of lattice energy
(A) TiC > ScN > MgO > NaF (B) BeO > MgO > SrO > BaO

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(C) NaF > MgF2 > AlF3 (D) CdI 2 > CaF2 > LiCl > KCl
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16. What is the correct order of solubility of following ionic compounds in water.
(A) BeSO 4 > MgSO 4 > CaSO 4 > BaSO 4

(C) CS HCO3 > RbHCO 3 > KHCO 3 > NaHCO 3 ss (B) CaS2 O3 > SrS2 O3 > BaS2 O 3

(D) LiCl > CsCl > RbCl > NaCl

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17. Which is/are not correct for B2 H 6 structure ?
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(A) It has 4B–H terminal bonds and two 3C–2e bonds
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(B) It has six B-H terminal bonds and one 3C–2e bonds
(C) It has four B–H terminal bonds two 3C–2e bonds and one B–B bond
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(D) It has ionic interaction between [ BH 2 ] and [ BH 4 ]

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18. Select the correct statements :

(A) More electronegative atom prefers the hybrid orbital of the central atom in which the s-character is
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less
(B) More electronegative atom prefers the hybrid orbital of the central atom in which the s-character is
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more.
(C) Lone pair prefers to stay with that hybrid orbital which has less s-character
(D) Lone pair prefers to stay with that hybrid orbital which has more s-character.
19. Select the correct statement(s)
(A) Compared to Me3 N, ( SiH 3 )3 N has got almost no basicity

(B) BiH3 > SbH3 > NH 3 > AsH 3 > PH 3 : Boiling point

(C) The dipole moment of R 3 NO is much greater compared to that of R 3 PO

(D) All the B – O bond lengths are not identical in polyborates.

CHEMISTRY 3
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PRACTICE SHEET-26
20. select the correct order for the given properties:
(A) NaF > KF > LiF > RbF > CsF : Melting point order
(B) CuCl>NaCl : Covelent character
(C) BeSo4 < CaSO 4 < SrSO 4 < BaSO 4 : Thermal stability order
(D) Lil> Nal>Kl>Rbl>Csl : Solubility order

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D

CHEMISTRY 4
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PRACTICE SHEET-26

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Practice Sheet-26
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for CLASS : XII

Academic Session : 2020-21 JEE (MAIN+ADVANCED) 2021

CHEMISTRY
Time : 1 Hr

ANSWER KEY

Q.No 1 2 3 4 5 6 7 8 9 10
Ans. A,B,C,D A,B,C,D A,C A,B,C A,B,D C,D A,B A,B B,C A,C
Q.No 11 12 13 14 15 16 17 18 19 20
Ans. A,B,C,D A,D A,B A,B,C,D A,B A,B,C,D B,C A,D A,B,C,D A,B,C
CHEMISTRY 5