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INORGANIC CHEMISTRY_PRACTICE SHEET-1

GROUP-13
1. How many groups are present in p-block and why?

(1) 6 groups because maximum number of electrons that can be accommodated in a set of p orbital is
six.

(2) 3 groups because three orbitals are present in p-orbital set, i.e, px, py and pz

(3) 6 groups because its valence shell electronic configuration is ns2np1 – 6.

(4) 4 groups as there are four orbitals

2. The valence shell electronic configuration of p-block is ____

(1) ns2 (n – 1)p0 – 6 (2) ns2 np0 – 6

(3) ns2 np1 – 6 (4) ns2 (n – 1)p1 – 6

3. Oxidation state shown by members of Boron family is ____

(1) +3 and +1 (2) +1 and +2

(3) +5 and +3 (4) –3, and +3

4. Oxidation states shown by carbon family other than +4 is

(1) +1, –2 (2) +2, –2

(3) +2, –4 (4) –3, +4

5. The first elements of p-block differs from the remaining members of their corresponding group is due to
____

(1) Small size (2) Unavailability of d-orbitals

(3) They are Highly electropositive (4) Both (A) and (B)

6. Boron is a fairly rare element, mainly occurs as____

(1) Orthoboric acid (2) Borox

(3) Kernite (4) All of these

7. The two isotopes of Boron are ____

(1) 10B(19%) and 11B(81%) (2) 10B(81%) and 11B(19%)

(3) 9B(25%) and 11B(75%) (4) 9B(19%) and 11B(81%)

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Group-13 Practice Sheet-1

8. The important minerals of Aluminium. is/are

(1) Kernite, Bauxite, Cryolite (2) Bauxite and Cryolite

(3) Mica and Bauxite (4) Mica and Kernite

9. Why the discontinuity is observed in the Ionisation enthalpy values between Al and Ga and between In and
TI?

(1) Due to increase in size down the group.

(2) Due to presence of d and f orbitals and their inability to screen effectively.

(3) Increase in Nuclear charge down the group

(4) Decrease in nuclear charge down the group.

10. Which element have the highest boiling point in Group-13?

(1) Boron (2) Aluminium

(3) Thalium (4) Galium

11. The correct variation of tendency to behave as Lewis acid of Group-13 elements on moving down the group
is.

(1) BCl3 > AlCl3 > GaCl3 (2) BCl3 < AlCl3 < GaCl3

(3) BCl3 < GaCl3 < AlCl3 (4) BCl3 > GaCl3 > AlCl3

12. Consider the reaction give below:

BCl3 + NH3  X

What is the hybridisation of product X?

(1) sp2 (2) sp3

(3) dsp2 (4) sp3d

13. Why TI+ is more stable is solution than TI3+?

(1) Highly (negative) E° value

(2) Positive E° value of Tl3+/Tl

(3) More electropositivity

(4) Tl+ is powerful oxidizing agent

14. Which gas will liberate when aluminium dissolves in dilute HCl?

(1) H2 (2) Cl2

(3) O2 (4) N2

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Group-13 Practice Sheet-1

15. What will happen when borax is heated at high temperature.

(1) B2O3 is formed (2) H3BO3 is formed

(3) It decomposes. (4) It looses water molecules.

16. What will be the product formed when orthoboric acid is heated strongly?

(1) Metaboric acid (2) H2B4O7

(3) HBO2 (4) B2O3

17. What will happen when diborane is exposed to air?

(1) Oxidised to boron sesquioxide (2) Catches fire spontaneously

(3) Forms higher boranes (4) Both (A) and (B)

18. What will be the final product B formed when diborane is heated with ammonia as given below?

B2H6  NH3 
 A 
Heat
B

(1) BH3 monomer formed (2) No reaction

(3) Borazole is formed (4) B2H6.2NH3 is formed

19. What are the bond angle a and b values in B2H6?

(1) a = 120°, b = 97° (2) a = 97°, b = 120°

(3) a = b = 97° (4) a = b = 120°


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INORGANIC CHEMISTRY_PRACTICE SHEET-2

GROUP-14
1. Which element of group-14 is important component of ceramics, glass and cement?

(1) Silicon (2) Germanium

(3) Tin (4) Lead

2. Compare the electronegativity of Group 13 and Group-14 elements.

(1) EN of Group 13 > Group 14 (2) EN of Group 13 < Group 14

(3) EN of Group 13 = Group 14 (4) Cannot be compared.

3. Which elements has highest melting point among Group -14?

(1) C (2) Si

(3) Ge (4) Sn

4. Why tendency of show +2 oxidation state increase down the group?

(1) Electropositivity increases

(2) Ionisation enthalpy decreases

(3) Inability of ns2 electrons of valance shell to participate in bonding

(4) Covalency decreases

5. Why carbon tetrachloride cannot act as electron acceptor or electron donor?

(1) Octet of central atom is complete

(2) 4 chlorine atom make it electron deficient

(3) Carbon cannot exceed its covalence more than 4

(4) It has spherically symmetric structure

6. Among Dioxides of group-14 elements which elements show amphoteric character?

(1) SnO2 and GeO2 (2) SnO2 and PbO2

(3) CO2 and SiO2 (4) SiO2 and GeO2

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Group-14 Practice Sheet-2

7. Comparing the stability of GeX4 and GeX2, PbX4 and PbX2. Find the correct order.

(i) GeX4 > GeX2 (ii) GeX4 < GeX2

(iii) PbX4 > PbX2 (iv) PbX4 < PbX2

(1) (i) and (iii) (2) (ii) and (iii)

(3) (i) and (iv) (4) (ii) and (iv)

Why SiF6  exists but SiCl6  does not?

2 2
8.

(i) Interaction of Chloride ions and Si4+ ion is not very strong

(ii) Six large chloride ions cannot be accommodated around Si4+ due to limitation of its size

(iii) Si cannot expand its octet with Cl

(1) (i) and (ii) (2) (i), (ii) and (iii)

(3) (i) and (iii) (4) (ii) and (iii)

9. Carbon monoxide is used in the extraction of many metals from their oxides ores because

(1) Powerful oxidising agent (2) Powerful reducing agent

(3) Highly reactive (4) Forms coordination compounds with metals

10. By which among the following methods, carbon dioxide is produced in laboratory?

(1) Heating limestone

(2) CaCO3 + conc. HCl

(3) CaCO3 + dil. HCl

(4) Burning Hydrocarbons in presence of air

11. CO2 is used as fire – extinguisher because:-

(1) Lighter gas and supporter of combustion

(2) Heavier gas and supporter of combustion

(3) Heavier gas and non-supporter of combustion

(4) Lighter gas and non-supporter of combustion

12. Which of the following is not the resonating structure of CO2.

(1) (2)

(3) (4)

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Group-14 Practice Sheet-2

13. What is the repeating unit of organosilicon polymer?

(1) (2)

(3) (4)

14. What is the starting material used for the manufacturing of silicones?

(1) Aryl or alkyl substituted silicon chlorides

(2) Silicon chlorides

(3) Alkyl halides

(4) Silicon hydroxides

15. What is the basic structural unit of silicates?

(1) SiO34 (2) SiO34 

(3) SiO24 (4) SiO44 


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INORGANIC CHEMISTRY_PRACTICE SHEET-4

GROUP-17, 18
1. What is the order of melting point and Boiling point: of X2? (X = halogens)?

(1) Cl2  F2  Br2  I2 (2) F2  Cl2  Br2  I2

(3) Br2  Cl2  I2  F2 (4) Br2  F2  CI2  I2

2. Match the Column-I with Column-II

Column-I Column-II

Minerals Formula

(a) Carnalite (i) Ca3(PO4)2.CaF2

(b) Fluorspar (ii) Na3AlF6

(c) Cryolite (iii) CaF2

(d) Fluoroapatite (iv) KCl.MgCl2.6H2O

(1) (a)  (iv); (b)  (iii); (c)  (ii); (d)  (i) (2) (a)  (i); (b)  (iii); (c)  (ii); (d)  (i)

(3) (a)  (iii); (b)  (ii); (c)  (i); (d)  (iv) (4) (a)  (ii); (b)  (iv); (c)  (iii); (d)  (i)

3. All halogen are coloured due to

(1) Due to small size

(2) Highly electronegative

(3) Absorption of radiation in visible region and excitation of outer e– to higher energy level

(4) Strong inter electronic repulsions

4. The correct decreasing order of stability of Hydrogen halides is ___

(1) H — F  H — Cl  H — Br  HI (2) H — I  H — Br  H — Cl  H — F

(3) H — F  H — I  H — Cl  H — Br (4) H — F  H — I  H — Br  H — Cl

5. Which oxide of Fluorine is thermally stable at 298 K?

(1) O2F2 (2) OF2

(3) FO2 (4) O3F2

6. In the given reactions X and Y respectively are:-

NaOH  Cl2  NaCl  X  H2 O

 Cold and dilute 

NaOH  3Cl2  NaCl  Y  H2O

Hot and conc 

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Group-17, 18 Practice Sheet-4

(1) NaOCl and NaOCl3 (2) NaOCl3 and NaOCl

(3) NaOCl and NaClO3 (4) NaClO3 and NaOCl

7. Consider the reaction

NaCl  H2SO4 

420 K
NaHSO4  X

X  NH3 
 Whitefumes

Identify X.

(1) Cl2 (2) HOCl

(3) HCl (4) HClO3

8. The IF7 is exists as colourless gas, the shape of molecule is ____

(1) Pentagonal bipyramidal (2) Distorted octahedral

(3) Icosahedral (4) Heptagonal planar

9. Neil Bartlett observed that first ionization enthalpy of molecular oxygen was atoms identical with ____

(1) Radon (2) Xenon

(3) Krypton (4) Argon

10. The products formed when XeF2 is hydrolysed are ____

(1) XeO3, XeOF4 and O2 (2) Xe, HF and O2

(3) XeO2F2, HF and O2 (4) Xe, HF and H2O

11. The cationic and anionic species formed on reaction of XeF2 with PF5 are ____

 XeF3  and PF4   XeF and PF6 

   
(1) (2)

PF6  and  XeF   XeF3  and PF4 

   
(3) (4)

12. The shape of XeO3 and XeOF4 molecules are ____ and ____ respectively

(1) Square pyramidal and trigonal pyramidal

(2) Trigonal pyramidal and square pyramidal

(3) Square planar and trigonal planar

(4) Trigonal planar and square planar

13. Which noble gas is used in discharge tubes and florescent bulbs?

(1) He (2) Ne

(3) Ar (4) Kr

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INORGANIC CHEMISTRY_PRACTICE SHEET-5

d & f Block Co-ordination compounds
1. What is the shell number of outermost shell of elements of 3d series of transition metals
(1) 3 (2) 4
(3) 5 (4) 6
2. Which d block element has electronic configuration 4d105s°?
(1) Pt (2) Pd
(3) Cd (4) Rh
3. The Lattice structure of Cu, Ag and Au is____
(1) CCP (2) HCP
(3) FCC (4) SC
4. Which of the metal of 3d series has melting point greater than Zn and Cu but lesser than rest of the metals
of 3d series?
(1) Ni (2) Co
(3) Ti (4) Mn
5. The loss of exchange energy ........ the stability of electronic configuration.

(1) Increases (2) Decrease

(3) Does not change (4) Is not related to
6. How many different oxidation states of zinc is possible in their compounds
(1) 1 (2) 2
(3) 3 (4) 4

7. The shape of oxoanions MnO34 , MnO24 and MnO4 is…..

(1) All are tetrahedral except MnO34 (2) All are tetrahedral except MnO24

(3) All are tetrahedral except MnO4 (4) All are tetrahedral

8. The reaction 2I–  S2O82–  I2  2SO4– – is catalysed by

(1) Fe3+ (2) Fe2+

(3) Cu2+ (4) Pb2+

9. On reaction with alkalies V2O5 give VOn3 salts, the shape of VO3n  is ___.

(1) Triangular planar (2) Tetrahedral

(3) Octahedral (4) V shaped

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Group-d & F Practice Sheet-5

10. How many different Cr – O bond lengths are present in Cr2O72 ?

(1) Four (2) Three

(3) Two (4) All Cr – O bond length are equal

11. Which compound of manganese is prepared by fusion of MnO2 with an alkali and an oxidizing agent like
KNO3 or O2/air?

(1) KMnO4 (2) K2MnO4

(3) Mn2O7 (4) Mn2O5

12. Acidified KMnO4 solution reacts with C2O24 to produce

(1) CO2 and C3O2 (2) CO and CO32–

(3) CO and CO2 (4) CO2

13. Which of the Ln(IV) is used as analytic reagent?

(1) Eu4+ (2) Pr4+

(3) Ce4+ (4) Er4+

14. Find the number of moles of AgCl precipitated per mole of PtCl2.2NH3 (secondary valence is 4) with excess
AgNO3.

(1) 1 (2) 2

(3) 0 (4) 4

15. What is the denticity of Ethylenediaminetetraacetate ion.

(1) 2 (2) 4

(3) 6 (4) 8

16. What is the name of [NiCl2(PPh3)2]?

(1) Dichloridobis(triphenylphosphine)nickel (II)

(2) Dichlorodi(trisphenylphosphine)nickel (II)

(3) Dichloridotriphenylphosphine nickel (II)

(4) Bis(triphenylphosphine)dichloridonickel (II)

17. The number of geometrical isomers shown by [Co(NH3)3(NO2)3]

(1) 1 (2) 2

(3) 3 (4) 4

18. The red form and yellow form of [Co(NH3)5(NO2)]Cl2 belong to which type of isomerism?

(1) Solvate (2) Ionisation

(3) Linkage (4) Coordination

19. The correct hybridization of [Ni(CN)4]2– is

(1) sp3 (2) sp3d2

(3) d2sp3 (4) dsp2

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Group-d & F Practice Sheet-5

20. The number of unpaired elections present in [MnCl6]3– is:

(1) 0 and diamagnetic (2) 4 and paramagnetic

(3) 2 and paramagnetic (4) 5 and paramagnetic

21. Identify which of the following two complexes is red while other is yellow orange in colour [Co(NH3)5H2O]3+
[Co(NH3)6]3+
3
Co NH3 5 H2O  A

3
Co NH3 6   B

(1) A is yellow orange and b is red (2) A and B both are yellow orange

(3) A and B both are Red (4) A is red and B is yellow orange

22. The colour of [Ni(en)3]2+ and [Ni(H2O)4(en)]2+ respectively are:-

(1) Violet and Red (2) Violet and Pale Blue

(3) Red and Violet (4) Pale Blue and Violet

23. How many bridging CO groups are present in bridged Octacarbonyldicobalt (0)?

(1) 2 (2) 3

(3) 4 (4) 5

24. What is the molecular formula of Wilkinson's catalyst of rhodium complex?

(1) Rh3PPh3Cl (2) Rh3 PPh3 3 Cl3 

(3) Rh PPh3 3 Cl (4) Rh PPh3 3 Cl Cl2


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INORGANIC CHEMISTRY_PRACTICE SHEET-2

GROUP-14
1. Which element of group-14 is important component of ceramics, glass and cement?

(1) Silicon (2) Germanium

(3) Tin (4) Lead

2. Compare the electronegativity of Group 13 and Group-14 elements.

(1) EN of Group 13 > Group 14 (2) EN of Group 13 < Group 14

(3) EN of Group 13 = Group 14 (4) Cannot be compared.

3. Which elements has highest melting point among Group -14?

(1) C (2) Si

(3) Ge (4) Sn

4. Why tendency of show +2 oxidation state increase down the group?

(1) Electropositivity increases

(2) Ionisation enthalpy decreases

(3) Inability of ns2 electrons of valance shell to participate in bonding

(4) Covalency decreases

5. Why carbon tetrachloride cannot act as electron acceptor or electron donor?

(1) Octet of central atom is complete

(2) 4 chlorine atom make it electron deficient

(3) Carbon cannot exceed its covalence more than 4

(4) It has spherically symmetric structure

6. Among Dioxides of group-14 elements which elements show amphoteric character?

(1) SnO2 and GeO2 (2) SnO2 and PbO2

(3) CO2 and SiO2 (4) SiO2 and GeO2

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Group-14 Practice Sheet-2

7. Comparing the stability of GeX4 and GeX2, PbX4 and PbX2. Find the correct order.

(i) GeX4 > GeX2 (ii) GeX4 < GeX2

(iii) PbX4 > PbX2 (iv) PbX4 < PbX2

(1) (i) and (iii) (2) (ii) and (iii)

(3) (i) and (iv) (4) (ii) and (iv)

Why SiF6  exists but SiCl6  does not?

2 2
8.

(i) Interaction of Chloride ions and Si4+ ion is not very strong

(ii) Six large chloride ions cannot be accommodated around Si4+ due to limitation of its size

(iii) Si cannot expand its octet with Cl

(1) (i) and (ii) (2) (i), (ii) and (iii)

(3) (i) and (iii) (4) (ii) and (iii)

9. Carbon monoxide is used in the extraction of many metals from their oxides ores because

(1) Powerful oxidising agent (2) Powerful reducing agent

(3) Highly reactive (4) Forms coordination compounds with metals

10. By which among the following methods, carbon dioxide is produced in laboratory?

(1) Heating limestone

(2) CaCO3 + conc. HCl

(3) CaCO3 + dil. HCl

(4) Burning Hydrocarbons in presence of air

11. CO2 is used as fire – extinguisher because:-

(1) Lighter gas and supporter of combustion

(2) Heavier gas and supporter of combustion

(3) Heavier gas and non-supporter of combustion

(4) Lighter gas and non-supporter of combustion

12. Which of the following is not the resonating structure of CO2.

(1) (2)

(3) (4)

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Group-14 Practice Sheet-2

13. What is the repeating unit of organosilicon polymer?

(1) (2)

(3) (4)

14. What is the starting material used for the manufacturing of silicones?

(1) Aryl or alkyl substituted silicon chlorides

(2) Silicon chlorides

(3) Alkyl halides

(4) Silicon hydroxides

15. What is the basic structural unit of silicates?

(1) SiO34 (2) SiO34 

(3) SiO24 (4) SiO44 


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INORGANIC CHEMISTRY_PRACTICE SHEET-3

GROUP-15, 16
1. The formula of Chile saltpeter is ___

(1) NaNO3 (2) KNO3

(3) CaCO3 (4) LiNO3

2. Which of the following group-15 element will not show allotropy?

(1) N (2) P

(3) Sb (4) Bi

3. Why N – N single bond is weaker than single P – P bond?

(1) High electronic repulsions due to small bond length

(2) p – p bond formation tendency

(3) More bond length of N – N make it weaker

(4) Non availability of d-orbitals

4. What is the order of melting point of hydrides of group-15 elements?

(1) SbH3 > PH3 > AsH3 > NH3 (2) NH3 > SbH3 > AsH3 > PH3

(3) SbH3 > AsH3 > PH3 > NH3 (4) NH3 > PH3 > SbH3 > AsH3

5. The stable halide of nitrogen is

(1) NCl3 (2) NBr3

(3) NF3 (4) NI3

6. Which oxide of nitrogen contains two nitrogen atoms but does not contains N – N bond.

(1) Dinitrogen tetraoxide (2) Dinitrogen oxide

(3) Dinitrogen pentaoxide (4) Dinitrogen trioxide

7. Which reaction is not involved in the Ostwald's process of preparation of nitric acid?

(1) NH3  O2 

Pt / Rh
500K, 9 bar
 NO  H2O (2) NH3  O 2 
Pt / Rh
500K, 9 bar
 NO2  H2O

(3) NO  O2 
 NO2 (4) NO2  H2O 
 HNO3

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Group-15, 16 Practice Sheet-3

8. Which of the following is the complex formed in brown ring test?

2 2
(1) Fe H2 O 6  (2) Fe H2 O 5 NO 

 
(3) Fe H2 O 5 NO  (4) Fe H2 O 6 

9. Which is not true about the preparation method and properties of -black phosphorous?

(1) Obtained when Red P heated in a sealed tube at 803 K.

(2) Sublimed in air and has opaque/monoclinic crystals.

(3) It does not oxidises in air

(4) Prepared by heating white P at 473 K.

10. Which oxoacid of phosphorous is prepared by action of alkali on white P.

(1) Hypophosphorous acid (2) Hypophosphoric acid

(3) Orthophosphoric acid (4) Metaphosphoric acid

11. How many P — O – P bonds present in cyclotrimetaphosphoric acid.

(1) 1 (2) 2

(3) 3 (4) 4

12. Which element has least negative electron gain enthalpy value in 16th group?

(1) O (2) S

(3) Se (4) Te

13. The compound of oxygen, in which oxygen has +2 oxidation state?

(1) H2O (2) Cl2O

(3) OF2 (4) H2O2

14. The Anomalous behaviour of oxygen from other of it's family members is due to

(i) Small size (ii) High electronegativity

(iii) Absence of d-orbital (iv) Most negative electron gain enthalpy

(1) (i) (ii) and (iii) (2) (i), (ii) and (iv)

(3) (i) and (iii) (4) (i), (ii), (iii) and (iv)

15. The correct order of melting point of hydrides of oxygen family is

(1) H2 O  H2 S  H2 Se  H2 Te

(2) H2 O  H2 Te  H2 Se  H2S

(3) H2 Te  H2 Se  H2S  H2 O

(4) H2 O  H2 S  H2 Te  H2 Se

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Group-15, 16 Practice Sheet-3

16. Which of the following monohalides is unstable?

(1) S2Cl2 and S2Br2 (2) Se2Cl2 and Se2Br2

(3) S2F2 and S2Cl2 (4) S2I2 only

17. How many of the following oxides can produce O2 gas on thermal decomposition?

Ag2O, HgO, Pb3O4, PbO2

(1) 1 (2) 2

(3) 3 (4) 4

18. Which of the following correctly represents mixed oxides?

(1) MgO and Al2O3 (2) Al2O3 and Fe2O3

(3) Fe2O3 and Fe3O4 (4) Fe3O4 and Pb3O4

19. What are the products formed in the reactions in which Al2O3 shows behaviour of acid and base
respectivley?

 3 3 3
(1)  Al  OH 4  and  Al H2 O 6  (2)  Al  H2 O 6  and  Al  OH 6 

3 3 3 3
(3)  Al  OH 6  and  Al H2 O 6  (4)  Al  H2 O 6  and  Al  OH 6 

20. The colour of Rhombic sulphur is ___.

(1) Yellow (2) Red

(3) Blue (4) White

21. How many Sulphur atoms does the chair form of Sulphur has.

(1) 4 (2) 6

(3) 8 (4) 20

22. Sum of S = O, S — O — O — S, S — O — S, S — OH bond in H 2S2O8

(1) 5 (2) 6

(3) 7 (4) 8

23. What is the oxidation state of Sulphur in gaseous product when Cu react with conc. H 2SO4?

(1) +4 (2) +6

(3) +2 (4) +5

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