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Keywords: Cement production is a major consumer of energy and the largest source of industrial CO2 emissions. This study
Cement and clinker production aims to perform an environmental life cycle assessment of clinker and cement production in Ethiopia, using
Environmental concerns ReCiPe impact assessment method. Inventory data (material, energy, and transportation) is collected from seven
Life cycle assessment
major Ethiopian cement industries. The midpoint analysis identified nine hotspot environmental concerns: global
Cement industries
Ethiopia
warming, ozone formation (human health and terrestrial ecosystem), particulate matter formation, terrestrial
(acidification and ecotoxicity), freshwater eutrophication, human carcinogenic toxicity, and fossil resource
scarcity. Human health emerged as the most significantly affected endpoint damage category by the midpoint
impacts. Among the process stages included in clinker system boundary, clinker production phase (kiln emis
sions) is a significant contributor to the total score of the hotspot impacts, ranging from 60.7% to 91.8%. The
clinker system is responsible for over 81.03% of the overall environmental burden of cement. The sensitivity
analysis reveals that a 5% change in kiln energy consumption and transportation burden could lead to a
reduction in hotspot impacts ranging from 1.8% to 5%. To foster reliability of this study, uncertainty analysis is
also conducted. Overall, the findings indicate the need to enhance environmental sustainability in Ethiopian
cement production.
* Corresponding author.
E-mail addresses: mickfeke@gmail.com (M.G. Wolde), dilip.khatiwada@energy.kth.se, dilipk@kth.se, dilipkhatiwada@gmail.com (D. Khatiwada).
https://doi.org/10.1016/j.cesys.2024.100180
Received 31 January 2024; Received in revised form 14 March 2024; Accepted 18 March 2024
Available online 26 March 2024
2666-7894/© 2024 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
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M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
Table 1
Previous clinker and cement LCA studies.
LCA scope Functional Unit Impact assessment method Indicator type Paper
Cradle-to- 20 bags OPC (1 bag ~ 100 lb) Eco-Indicator 95 Midpoint Huntzinger and Eatmon
gate (2009)
1 tonne of cement (blended and OPC) IPCC climate change 100 years (2001), CExD, and Characterization Boesch and Hellweg (2010)
factors developed by the CML method
1 kg of clinker IPCC climate change 100 years (2001), CExD, and Characterization Valderrama et al. (2012)
factors developed by the CML method
1 tonne of clinker and cement International Reference Life Cycle Data System (ILCD) García-Gusano et al. (2015)
(blended cement and OPC)
1 kg of OPC ReCiPe Midpoint/ Olagunju (2021)
1 ton of OPC Impact 2002+ Endpoint Chen et al. (2015)
Global Warming and CExD Midpoint Makhlouf et al. (2023)
1 tonne of OPC Eco-Indicator 99 Mbohwa and Moyo (2008)
Characterization factors developed by the CML method Stafford et al. (2016a)
ReCiPe Midpoint/ (Thwe et al., 2021; Tun
Endpoint et al., 2020)
ReCiPe Midpoint Stafford et al. (2016b)
ReCiPe Ige et al. (2022)
1 tonne of blended cement ReCiPe Palermo et al. (2022)
1 Mg of clinker and cement (blended Characterization factors from EN 15804:2012+A1:2013/Eco-Indicator Moretti and Caro (2017)
cement and OPC) 99/CML
1 ton of clinker CML/Eco-Indicator 99 Georgiopoulou and
Lyberatos (2018)
1 ton of clinker and cement (blended IPCC climate change 100 years (2007), CExD Beressa and Vijaya Saradhi
cement and OPC) (2021)
Impact 2002+ Midpoint/ Çankaya and Pekey (2019)
Cradle-to- 1 ton of clinker and cement (blended ReCiPe Endpoint Petroche and Ramirez
grave and OPC) (2022)
1 m3 of ready-mixed concrete
OPC: Ordinary Portland Cement, CExD: Cumulative Energy Demand, CML: Centrum voor Milieuwetenschappen Leiden, IPCC: Intergovernmental Panel on Climate
Change.
fuels, particularly coal, has led to a substantial increase in carbon preserved, i.e., human health, ecosystem, and resources (Huijbregts
emissions, rising from 2.6 Mt in 2013 to 6.3 Mt in 2018 (Mossie et al., et al., 2016). To foster reliability of this study, sensitivity and uncer
2021). Ethiopia’s growth and transformation plan, which prioritize tainty analyses are included. Sensitivity analysis measures the magni
urban, industrial, and infrastructure development, positions the cement tude to which changes in main production system parameters influence
industry as vital sector (MPD, 2021). Currently, there are ongoing new environmental impacts. On the other hand, uncertainty analysis quan
construction projects for increasing domestic capacity (Global Cement, tifies the uncertainties associated within impact assessment results,
2021). With the anticipated expansion of domestic production in which arises from estimations of emission and inherent variations in the
Ethiopia, it is expected that the environmental burdens will intensify. A input or collected data. The scientific evidence gained from this study
comprehensive LCA study is imperative to identify the most critical can inform the revision of policies related to environmental impacts, as
environmental issues. well as energy efficiency. Additionally, the results of this study can also
The current research aims is to bridge the knowledge gap in the be used as input data in evaluating the environmental impact of a spe
Ethiopian cement sector regarding comprehensive environmental LCA cific construction project that utilize Ethiopian cement for concrete
assessment. The scope of this study is cradle-to-gate and covers seven production.
cement plants. To the best of our knowledge, there is a limited body of The remainder of this paper is organized as follows: Section 2; pre
research on clinker and cement LCA studies in the East African region sents the description of the materials and methods; Section 3 provides
(for detail further explore LCA studies in Table 1); hence, this study also the LCA results for clinker and cement production, including sensitivity
contributes to the environmental impact evaluation of clinker and and uncertainty analyses; Section 4 briefly discusses the findings of this
cement production in the region. The main objectives of this study are study in comparison with similar studies, as well as policy recommen
to. dation and future outlooks; Section 5 concludes the study.
• evaluate the cradle-to-gate environmental impacts of cement and 2. Material and methods
clinker production,
• determine hotspot environmental issues and their significant influ ISO 14040, the present standard for a LCA study, describes the
encing factors, principles and framework for LCA. These include goal and scope defi
• perform sensitivity and uncertainty analyses on the impact assess nitions, LCI, LCIA, and interpretation of the results of either LCI analysis
ment results. or LCIA (ISO, 2006). This study is accomplished following these four
core phases. In addition to the core phases, sensitivity analysis and un
This study considers the relevant process and energy-related emis certainty analysis are conducted. This section discusses the description
sions (including hazardous and heavy metal emissions) from raw ma of the four phases’.
terial extraction to clinker and cement manufacturing, as well as indirect
emissions from auxiliary activities such as transportation, electricity, 2.1. Goal and scope definition
and fossil fuel production. The study compares eighteen midpoint and
three endpoint impact results for the two most common cement types This LCA study assesses the environmental impact of clinker and
(PPC (blended) and OPC), thereby contributing to the advancement of cement production in Ethiopia. The scope is a cradle-to-gate system,
cement LCA studies. The inclusion of endpoint analysis allows better which means that it excludes the usage and disposal stages of cement.
understanding of the effect of midpoint impacts on areas that need to be The scope is constrained due to practical difficulties in obtaining
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M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
complete data for the use (concrete) and disposal phases of cement. Following these guidelines, the gathered data on the type and amount of
Fig. 1 depicts the system boundaries of this LCA study. Two systems are fuel, as well as cement production technologies, are utilized to estimate
analyzed: clinker and cement. The studied system covers 70% of the the atmospheric emissions. For the background systems, i.e., raw ma
Ethiopia’s cement production capacity. The system boundary for clinker terial extraction (limestone, clay, silica sand, etc.), electricity and fossil
includes five modules: raw material preparation (including extraction), fuel production, and transport, the most appropriate Ecoinvent LCI
transportation, fossil fuel production, electricity, and clinker production database (Version 3) is used in this study (see, Table S3).
phase (rotary kiln/VSK and clinker cooling). The system boundary for
cement includes four modules: clinker cradle-to-gate system, cement 2.2.1. Production scenarios and calculation of inventory flows
additives extraction, transportation, and electricity. In this study, In this study, the inventory values of the seven cement plants are
cement plant infrastructures and facilities are excluded since they have a aggregated under four production scenarios to simplify results presen
negligible environmental impact (Thwe et al., 2021). The two tation and interpretation. The scenarios are created based on technology
mass-based functional units are 1 t of clinker and 1 t of PPC or OPC and the capacity to produce clinker (see, Table 2). First, the seven plants’
(depending on the cement type produced). inventory flow is normalized to functional units in Microsoft Excel.
Second, the weighted average is calculated to construct the LCI of the
four production scenarios. The LCI results for each scenarios is sum
2.2. Life cycle inventory and data sources marized and presented in Table S4, supplementary material.
Table S2 shows a brief summary of the inventory data sources of this 2.2.2. Raw material and product flows
study. The relevant inventories are compiled from seven cement plant Limestone, clay, basalt, and silica sand are the primary raw materials
databases of the year 2020. These databases contains information on used in the production of Ethiopian clinker. PPC is produced in all
raw materials, energy types and amounts, and the material composition production scenarios, while OPC is produced only in the moderate and
of clinker and cement products. After a careful review of each plant large scenarios. PPC was the dominant product with an 80% production
database, an interview is conducted with key personnel of the com share in 2020. Portland Limestone Cement (PLC) is not considered in the
panies. The interviews further verified the accuracy and completeness of analysis due to its low production volume (0.9%). Table 3 shows a short
the inventory data used in this study. Additionally, fuel calorific values, summary of material and products used in the production scenarios.
fuel energy sources, and fuel and material transport data are gathered Water is another important resource in the production of clinker and
during the interview. However, atmospheric emission databases is not cement. Most of the cement plants pump up water from wells located at
available from the companies. their production site. Typically, the water is used for raw material
The cement companies in Ethiopia primarily utilize the real-time
emissions data from their continuous monitoring system for only
adjusting the kiln conditions. However, this data is not stored for long- Table 2
term purposes. Due to confidentiality issues, companies are unwilling to The four production scenarios.
permit access to record the real-time emission data from the control
Production Kiln Technology Daily clinker production capacity
board and measurement reports on heavy metal emissions of individual Scenario (in tonne)
clinker kilns. Furthermore, environmental auditing reports containing
Small Dry process rotary kiln 500–2000
real emissions data from the cement sector, compiled by relevant
Moderate (Qty. 6) 2000–4000
stakeholders, are also not available (Ministry of Environment and For Large >4000
est, 2015). Therefore, in this study, atmospheric emissions are estimated VSK Shaft kiln (Qty. 1) 1000
using emission factors provided by standard guidelines (IPCC, EME VSK: Vertical Shaft kiln.
P/EEA, and U.S. EPA) for cement manufacturing (see, section 2.2.4).
Fig. 1. Cradle-to-gate system boundary for the LCA of clinker and cement production in Ethiopia (author’s diagram).
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M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
For LCA clinker, the EC ranges between 76.91 and 96.4 kWh/t of
The midpoint results (characterization and normalization) and
clinker. On average, 50.9 kWh of electricity is consumed per tonne of
endpoint results (weighting) are carefully scrutinized and interpreted
PPC/OPC in the LCA of cement.
for all production scenarios. In addition to that, contribution analysis,
The thermal energy consumption (TEC) for the LCA of clinker is
comparison analysis, and sensitivity and uncertainty analyses results are
calculated using Eq. (3). TEC for the LCA of cement is not calculated
interpreted. Sensitivity and uncertainty analyses are performed to
since the clinker system is an input for the LCA of cement, according to
adequately support the conclusions drawn from the LCA study. In this
this study system boundary.
study, the collected data lacks uncertainty ranges, such as standard
∑K
FEj deviations. Hence, the uncertainty ranges for the inventory data are
TECclinker = (3) defined based on secondary sources (i.e. from published database, such
CLP
as (Kellenberger et al. (2007)). Then, a Monte Carlo simulation, built in
j=1
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M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
sensitivity and uncertainty analyses are performed only for LCA of is manly attributed to the large use of petroleum coke compared to coal
clinker; this is due to the fact that clinker system is the most energy- and in VSK scenario. Petroche and Ramirez (2022) and Stafford et al.
emission-intensive process. (2016b, 2016a) considered fuel production stage in their analysis and
reported similar findings.
3. Results and analysis In all production scenarios, raw material preparation (which in
cludes raw material extraction) dominantly contributes to the mineral
This section presents the analysis of the LCIA results for clinker resource scarcity and slightly to other impact categories. In this study,
(section 3.1) and cement (section 3.2) production. Environmental im electricity has a negligible effect across all impact categories due to
pacts resulting from Ethiopia’s clinker and cement production have Ethiopia’s electricity mix, which is primarily composed of hydropower
regional, local, or global effects. GW and ozone depletion have impli sources (98%) (ITA, 2022). Regarding electricity, similar findings were
cations on the global climate; mineral and fuel resource scarcity can reported by Stafford et al. (2016b), Tun et al. (2020), and Petroche and
have both global and regional scale environmental effects; eutrophica Ramirez (2022), where hydropower dominates the electricity mix. Other
tion, acidification, particulates matter formation, ecotoxicity, and land processes, which in this study represent the acquisition of miscellaneous
use can have regional and local scale environmental effects. input materials (refractories and lubricating oil), also have a minor in
In the supplemental material, additional results are provided in the fluence on most impact categories.
form of tables and graphs. This results include process stages contribu The VSK production scenario has the highest contribution to the total
tion, normalization, and uncertainty. score across all impact categories except marine eutrophication (ME),
ranging from 27% to 60% (see Table 4). This is because the VSK scenario
3.1. LCA results of clinker production uses less coal compared to other scenarios (see Table S4), resulting in a
lower contribution to the total score of ME (21%). The VSK scenario
3.1.1. Midpoint results analysis for clinker exhibits higher environmental burden due to several contributing fac
Table 4 presents the midpoint characterization results (impact tors. Firstly, its high thermal intensity (5.75 GJ/t of clinker) leads to
scores) per tonne of clinker for each production scenario. Fig. 2 presents elevated kiln emissions. Secondly, the high consumption of raw material
the contribution of process stages (modules) to impact categories in each (limestone, clay, and basalt, 1.68 t) per a tonne of clinker and the use of
scenarios. For all scenarios, the clinker production stage contributes outdated kiln technology (vertical shaft kiln) further contribute to its
significantly to various environmental impacts, including global high environmental burden.
warming, ozone depletion, ozone formation (human health and terres The small production scenario has the second-highest contribution to
trial ecosystem), and fine particulate matter formation, terrestrial the total score across most impact categories, mainly, due to its rela
acidification, and human non-carcinogenic toxicity. These findings are tively higher coal consumption compared to moderate and large sce
consistent with previous studies (Moretti and Caro, 2017; Petroche and narios (see Table S4). Large and moderate scenarios contribute
Ramirez, 2022). Transportation contribution is observed in most of the comparably to the total score in most impact categories. These scenarios
impact categories, with its contribution being dominant in ecotoxicity exhibit the lowest environmental burden due to their advanced kiln
impacts across all production scenarios. Additionally, in technology, i.e., rotary kilns equipped with 5–6 stage pre-heaters and in-
small-to-moderate scenarios, its highest contribution is observed in line pre-calciner vessels. These technological stacks have improved
ionization radiation and human carcinogenic toxicity. This is due to the thermal energy efficiency, which in turn reduces environmental impact.
fact that the transport distance to source fossil fuels (road and sea) and Normalization is carried out with the aim of identifying the hotspot/
raw materials (road) varies from 1.5 to more than 900 km in Ethiopia’s dominant midpoint impacts, (see Fig. S3 in supplementary material).
clinker production. Similar findings are reported by Chen et al. (2015) Furthermore, Table S7 presents the process stage that significantly
and Stafford et al. (2016b). The contribution of fossil fuel production is contribute to the hotspot impacts across all production scenarios. In all
observed in most of the impact categories. In Small-and large production production scenarios, global warming, ozone formation (human health
scenarios, its highest contribution is observed in fossil fuel scarcity, and terrestrial ecosystem), fine particulate matter formation, freshwater
eutrophication, land use, and water consumption. In the VSK scenario, eutrophication, terrestrial ecotoxicity, human carcinogenic toxicity, and
in addition to those impact categories, ozone depletion and ionization fossil resource scarcity impact categories emerge as dominant. The
radiation are also significantly influenced by fossil fuel production. This prevalence of the GW impact category is primarily attributed to the
Table 4
Midpoint impact scores per tonne of clinker for each production scenario (Small, Moderate, Large, and VSK-Vertical Shaft Kiln). For each impact category, the total
score represents the sum of the impact scores from all production scenarios. The percentage in parenthesis indicates the contribution of each production scenario to the
total score.
Midpoint Impact Category (Unit) Small Moderate Large VSK Total Score
Global Warming (kg CO2-eq) 978 (24%) 928 (23%) 915 (22.6%) 1224 (30.3%) 4045
Stratospheric Ozone Depletion (kg CFC11-eq) 1.08E-04 (20%) 1.23E-04 (23%) 1.38E-04 (26%) 1.66E-04 (31%) 5.34E-04
Ionizing Radiation (kBq Co-60-eq) 3.19E-01 (9%) 2.38E-01 (7%) 8.69E-01 (24%) 2.13E+00 (60%) 3.55E+00
Ozone Formation, Human Health (kg NOx-eq) 1.25E+00 (20%) 1.1E+00 (18%) 1.1E+00 (18%) 2.79E+00 (45%) 6.25E+00
Fine Particulate Matter Formation (kg PM2.5-eq) 8.54E-01 (26%) 7.62E-01 (23%) 7.13E-01 (21%) 9.94E-01 (30%) 3.32E+00
Ozone Formation, Terrestrial Ecosystem (kg NOx-eq) 1.26E+00 (26%) 1.1E+00 (18%) 1.12E+00 (18%) 2.81E+00 (45%) 6.30E+00
Terrestrial Acidification (kg SO2-eq) 1.35E+00 (23%) 1.2E+00 (21%) 1.2E+00 (21%) 2.02E+00 (35%) 5.76E+00
Freshwater Eutrophication (kg P-eq) 3.85E-02 (23%) 3.73E-02 (23%) 4.03E-02 (24%) 4.93E-02 (30%) 1.65E-01
Marine Eutrophication (kg N-eq) 4.63E-04 (28%) 4.2E-04 (25%) 4.3E-04 (26%) 3.48E-04 (21%) 1.66E-03
Terrestrial ecotoxicity (kg 1,4-DCB) 7.97E+02 (28%) 5.95E+02 (21%) 6.54E+02 (23%) 8.44E+02 (29%) 2.89E+03
Freshwater ecotoxicity (kg 1,4-DCB) 1.29E-01 (23%) 1E-01 (18%) 1.39E-01 (25%) 1.98E-01 (35%) 5.67E-01
Marine ecotoxicity (kg 1,4-DCB) 6E-01 (25%) 4.54E-01 (19%) 5.73E-01 (23%) 8.2E-01 (34%) 2.45E+00
Human Carcinogenic toxicity (kg 1,4-DCB) 8.63E-01 (25%) 7.78E-01 (22%) 8.19E-01 (23%) 1.04E+00 (30%) 3.50E+00
Human Non-Carcinogenic toxicity (kg 1,4-DCB) 3.4E+01 (27%) 2.88E+01 (23%) 2.86E+01 (23%) 3.33E+01 (27%) 1.25E+02
Land Use (m2a crop-eq) 4.41E+00 (23%) 3.89E+00 (20%) 4.97E+00 (26%) 5.72E+00 (30%) 1.90E+01
Mineral Resource Scarcity (kg Cu-eq) 2.67E+01 (22%) 2.85E+01 (24%) 3.00E+01 (25%) 3.35E+01 (28%) 1.19E+02
Fossil Resource Scarcity (kg oil-eq) 1.19E+02 (23%) 1.03E+02 (20%) 1.3E+02 (25%) 1.77E+02 (33%) 5.29E+02
Water Consumption (m3) 2.18E-01 (22%) 1.88E-01 (19%) 2.11E-01 (22%) 3.63E-01 (37%) 9.81E-01
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M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
Fig. 2. Contribution of process stages (in %) to midpoint impacts in each production scenarios (small (a), moderate (b), large (c), and VSK-Vertical Shaft Kiln (d)) for
clinker LCA.
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M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
decomposition of limestone (CaCO3) and burning of fossil fuels in kiln. category. The electricity consumed does not make a significant contri
This processes result in significant GHG emissions. In all production bution to any of the damage categories.
scenarios, CO2 emissions contribution to GW ranges from 95% to 98%,
methane (CH4) contributes 1.6% to 4%, followed by nitrous oxide (N2O) 3.1.3. Sensitivity analysis for hotspot clinker midpoint impacts
at 0.2% to 0.3%. Ozone formation (human health and terrestrial In this study, kiln thermal energy consumption (or heat demand in
ecosystem) becomes a relevant impact category due to the releases of clinker production) and transportation burden, and electricity are
NOx and NMVOCs from the combustion fossil fuels and transportation. identified as main parameters for the sensitivity analysis. These pa
NOx emissions highly contribute (97.6–98.8%) to ozone formation rameters are selected due to their importance in the clinker system. As
throughout the production scenarios. discussed earlier, the amount of thermal energy consumption (TEC)
Freshwater eutrophication occurs due to accumulation of phos directly influences the atmospheric emission levels of the kilns. More
phorus or nitrogen compounds and oxygen depletion condition in the over, a change in TEC indirectly influences the fuel transportation
aquatic ecosystem. The depletion is measured as biological oxygen de burden in this study. To conduct the sensitivity analysis, a 5% decrease is
mand (BOD) and chemical oxygen demand (COD)). Fossil fuel produc modeled in TEC and fuel transportation (FT). The result indicates a
tion, particularly coal-washing and petroleum refinery operation, decrease of 2%–5% in the hotspot midpoint impacts (see, Table 6). In
substantially contributes to these emissions and conditions. Phosphate contrast, if the electrical input is switched from the Ethiopian grid,
contributes 83–90% in small-to-large production scenarios and only where 98% of the electricity is produced using renewable energy sour
28.6% in VSK scenario. In the VSK scenario, petroleum coke production ces, to the Kenya grid, where 80% of the electricity is produced using
at the supply contributes 35.8% and 35.5% to COD and BOD conditions, renewable energy, the hotspot midpoint impacts increases by 1.4%–
respectively. Fine particulate matter formation is influenced by primary 15.3% (ITA, 2022a, 2022b).
aerosols with diameters of 2.5 μm and above and secondary aerosols
(SO2 and NOx) released during clinker production. In all production 3.1.4. Uncertainty analysis of clinker midpoint impact results
scenarios, PM2.5 contributes 20–54.7%, SO2 contributes 28.5–50%, and The uncertainty analysis provides insights into how the in
NOx contributes 16.8–30.6% to fine PM formation. consistencies within the LCI database can affect the final impact
Terrestrial acidification occurs due to emissions (SO2 and NOx) from assessment results. Table S9 in the supplementary material briefly
clinker production and transportation, as well as NH3 emissions gener summarizes the results after Monte Carlo iterations for each production
ated from blasting processes during fossil fuel production (i.e., coal scenario. Based on the CV values, fine PM formation, water consump
mining operation) and raw material extraction. Terrestrial ecotoxicity is tion, and mineral resource depletion impacts exhibit a higher degree of
primarily caused by heavy metal emissions (Cu, Sb, Zn, Hg, and Pb) from uncertainty across all production scenarios. This suggests that the results
transportation and somehow clinker production phase. Copper (Cu) obtained from these impacts may not be adequate to inform policy de
emissions from all production scenarios are the major contributor cisions regarding environmental regulations. On the other hand, global
(52–56%) to terrestrial ecotoxicity, followed by Antimony (Sb: warming, stratospheric ozone depletion, ionizing radiation, terrestrial
12.5–15.3%) and Zinc (Zn: 12.6–18.6%). Human carcinogenic toxicity ecotoxicity, and land use impacts show a lower degree of uncertainty.
(HT) is mainly attributed to the chromium VI burden generated from The remaining impact categories exhibit a moderate degree of
transportation, petroleum refinery operation, and coal washing. Other uncertainty.
substances such as Ni, As, Benzo(a) pyrene, and formaldehyde (emitted
from clinker production and other stages) contribute to HT to a lesser 3.2. LCA results of cement production
extent. In this study, the predominant use of coal in clinker production is
the main contributor to fossil resource scarcity. 3.2.1. Midpoint results analysis for cement
Table S8 in the supplementary material presents the midpoint
3.1.2. Endpoint results analysis for clinker characterization results (impact scores) per tonne of cement (OPC and
The endpoint results (weighting scores) for clinker LCA are shown in PPC) for each production scenario. It also includes the total score per
Table 5. Compared to other production scenarios, the VSK scenario impact category (i.e., the sum of impact scores from all production
presents the highest score in all damage categories due to its high scenarios). Fig. 3 shows the percentage contribution of each production
thermal energy intensity and associated emissions and material resource scenarios to the total score. Since clinker is a core input in the produc
consumption. The small production scenario ranks second in terms of tion of cement, the hotspot midpoint impacts identified during the
contributing to the damage categories, followed by moderate and large clinker LCA are also evident in the cement LCA (Fig. S4). Among the four
scenarios. The moderate scenario shows the lowest score in the resource modules considered in cement LCA, the clinker cradle-to-gate system,
category, which can be attributed to its relatively lower consumption encompassing five modules (see Section 2.1), significantly contribute to
fossil fuels and material resources (see Table S4). In terms of process the overall environmental burden of cement production (see, Table 7).
contribution, clinker production is prevalent in the human and The remaining modules (i.e., cement additives extraction, trans
ecosystem damage categories. The raw material extraction and fossil portation, and electricity) have a minimal contribution. This finding
fuel production steps mainly contribute to the resource damage accords with previous studies (Moretti and Caro, 2017; Petroche and
Ramirez, 2022).
In PPC production, the VSK production scenario present the highest
Table 5 environmental burden across most impact categories due to its high
Endpoint results (weighting scores) in all production scenarios (Small, Moder energy consumption and clinker content (see Table S8). The small pro
ate, Large, and VSK-Vertical Shaft Kiln) for clinker LCA. The result shows the duction scenario has a relatively high environmental burden, followed
impact of each production scenario to damage category (endpoint), expressed in by the large scenario. The moderate scenario has the lowest environ
Points (Pt). mental burden for PPC production. In OPC production, the large and
Damage category Unit Small Moderate Large VSK Total Score moderate scenarios have a similar environmental burden almost in all
Human Health Pt 24.3 22.5 21.8 29.6 98.2 impact categories. When comparing PPC and OPC in large and moderate
Ecossytem 0.882 0.828 0.822 1.17 3.702 scenarios, PPC generates a lower environmental burden (see Fig. S2).
Resource 0.148 0.133 0.228 0.413 0.922 This is mainly due to the use of clinker substitutes (Pumice and Rhyolite)
Total 25.3 23.5 22.9 31.2 102.9 in PPC production (see Table 3). However, it is important to mention
Note: Pt (Point) is a dimensionless unit of measurement used in SimaPro to that extraction of these substitute materials impose environmental im
express environmental damage (Sustainability, 2023). pacts related to land and water use. Overall, the clinker content remains
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M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
Table 6
Sensitivity analysis of identified parameters in all production scenarios (Small, Moderate, Large, and VSK-Vertical Shaft Kiln) for clinker LCA.
Hotspot Midpoint Impacts Changes (% change from baseline values, see Table 4)
Reduction of TEC & Grid Reduction of TEC & Grid Reduction of TEC & Grid Reduction of TEC & Grid
FT by 5% change FT by 5% change FT by 5% change FT by 5% change
Fig. 3. Contribution of the four production scenarios (Small, Moderate, Large, and VSK-Vertical Shaft Kiln) to the total score per impact category (in %). See Table S8
for details on the total score (represents sum of impact scores from all scenarios, expressed per tonne of cement (OPC-Ordinary Portland Cement and PPC-Portland
Pozzolana Cement)).
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M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
Table 7
Contribution of process stages/production subsystem to the overall environmental burden of cement in each production scenario at midpoint analysis.
Cement Production Clinker cradle-to-gate system Cement Additives extraction Transportation of cement additives Electricity for grinding and
type Scenario (%) (%) (%) packaging (%)
Table 8
Endpoint results (weighting scores) in all production scenarios (Small, Moderate, Large, and VSK-Vertical Shaft Kiln) for cement LCA. The result shows the impact of
each production scenario to damage category (endpoint), expressed in Points (Pt).
Damage category Unit PPC OPC
Small Moderate Large VSK Total Score Moderate Large Total Score
the key factor influencing the environmental impact of cement pro clinker and thermal energy consumption. In case of OPC production,
duction, followed by fuel energy consumption. both large and moderate scenarios presents a comparable effect on
damage categories, with the exception of resource category. The large
3.2.2. Endpoint results analysis for cement scenario contributes significantly to the resource category due to slightly
The endpoint results for cement LCA are shown in Table 8. The higher clinker use in OPC production. When comparing OPC and PPC in
cement endpoint results mirrors the pattern observed for clinker (see the larger and moderate scenarios, OPC production results in higher
Section 3.1.2). In case of PPC production, VSK production scenario environmental damage. Overall, cement production presents significant
shows the highest contribution to damage categories due to higher environmental impact on human health, followed by ecosystem quality
Table 9
Results comparison between this study and similar studies for cement LCA. All values are expressed per functional unit (1 tonne of cement). The range values under
the” current study” column are results from the studied production scenarios (Small, Moderate, Large, and VSK-Vertical Shaft Kiln).
Midpoint Impact Category (Unit) Current Study Literature reviewed
10
M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
deterioration and resource depletion. This finding is compatible with the acidification (TA) values obtained in this study are lower compared to
findings of Chen et al. (2015) and (Tun et al. (2020). the literature values. The lower TA value is attributed to the dominance
of hydropower in Ethiopia’s electricity mix, which avoids atmospheric
4. Discussion depositions that would otherwise occur with coal-fired power plant (Ige
et al., 2022).
4.1. Comparison of LCA results of cement with similar studies The values for freshwater eutrophication (FE) obtained in this study
fall within the range reported in the literature. The Marine eutrophica
Comparisons of LCA results of cement is also needed to enhance the tion (ME) values for both PPC and OPC in this study are significantly
credibility of this study. In this section, the study solely discusses the lower than those reported in the literature (see Table 9). FE and ME
possible reasons for similarities or variations between this study and values are influenced by fuel types (i.e., there production) and trans
others study’s findings. A summary of LCA result comparison is provided portation burden. In Ethiopia, coal is the predominant fuel used in
in Table 9. For the blended cement products (which includes PPC), the clinker production (except VSK production scenario), and its production
results from similar studies are compiled without accounting for the at supply contributes both to FE and ME values in this study. Petroche
specific percentage of the clinker substitute materials. This is because of and Ramirez (2022) observed high FE potential and minimal ME po
the variation in the types and proportions of clinker substitutes (such as tential due to using petroleum coke as the main fuel for clinker pro
natural pozzolana, blast furnace slag, and fly ash) within the cement LCA duction, this is also evident in this study for VSK scenario. Conversely,
studies (Rhaouti et al., 2023). Stafford et al. (2016b) reported a significant influence of transportation
In this study, the GW potential for PPC ranges from 614 to 974 kg on both FE and ME, while fuel production contribution was relatively
CO2-eq/t, while for OPC it ranges from 853 to 864 kg CO2-eq/t. Ac low in their study.
cording to literature, the GW potential for blended cement fluctuate Significant differences in ecotoxicity impact scores are observed
from 452 to 850 kg CO2-eq/t, and for OPC, from 850 to 1440 kg CO2-eq/ between this study and those reviewed in the literature (see Table 9).
t. Some studies reported an extreme value of GW potential. For instance, These impacts are primarily influenced by heavy metal emissions from
Stafford et al. (2016b) obtained a value of 2160 kg CO2-eq/t of OPC, background systems (transportation and fuel production) and, to a lesser
which is significantly higher due to the extensive use of road transport in extent, by clinker production in this study. As in this study, most of the
the production system. GW potential is also influenced by factors such as reviewed studies (see Table 9) sourced heavy metal concentrations data
fuel types, materials (limestone/clinker) consumed, and electricity mix for background systems directly from the LCI databases (e.g., Ecoin
(coal, hydropower, etc.) (Petroche and Ramirez, 2022; Stafford et al., vent). Thus, several explanations can be assumed for the significant
2016a). In this study, the VSK production scenario is responsible for the variations observed in ecotoxicity impact results. Firstly, there may be
higher upper bound value of cement GW potential. This can be attrib inconsistent heavy metal emissions data within the LCI databases for
uted to its higher clinker and energy consumption during cement background systems. Secondly, there is variation in terms of impact
production. labeling substances within the impact assessment methods, and inherent
The stratospheric ozone depletion (SD) values for PPC are higher uncertainties exist within the impact methods. Finally, the studies might
than reported in the literature, while for OPC the values fall within the have either neglected heavy metal emissions from clinker production
reported literature range (see Table 9). The VSK production scenarios stage (kiln system) entirely or considered only a limited items of them.
significantly contributes to the elevated SD value in PPC. Previous Similarly, there is a noticeable level of result uncertainty in human
studies on LCA of OPC (e.g., Ige et al. (2022)) identified electricity carcinogenic/non-carcinogenic toxicity impact scores.
(generation dominated by coal) as major contributor to SD impact. For land use (LU) impact category, the results for PPC in this study
However, in this study, clinker production (i.e., fossil fuel burning) stage closely align with the values obtained by Palermo et al. (2022), where
significantly contribute to the SD impact of cement production, followed the same version of the ReCiPe method was used in their study. How
by fossil fuel production and raw material preparation (diesel fuel ever, direct comparison of LU impact scores between this study and
burning) stages. Therefore, emissions during fuel burning and extraction those reported by Thwe et al. (2021) for OPC is difficult due to difference
process are the main parameters for SD impact in various studies. in impact measurement metric.
The ionizing radiation (IR) values for PPC are close to those reported The water consumption (WC) impact scores obtained in this study
in the literature. However, for OPC, it is difficult to directly compare the are lower compared to those found in the literatures (see Table 9). In this
IR values due to differences in the measurement metric (or labeling study, the primary contributors to WC impact are fossil fuel production
substance) used between the reviewed literatures and this study. In case and raw material extraction. On other hand, in the reviewed studies, WC
of PPC, the upper bound values (2.25/2.27 kg NOx-eq/t of cement) for impact is primarily influenced by wet-process clinker production tech
ozone formation (human health and terrestrial ecosystem) considerably nology and electricity consumption. The differences in process stage
exceed literature values (1.48 kg NOx-eq/t of cement). This is mainly contribution, along with the uncertainties in WC data of this study (see
due to the impact of VSK production scenario. For OPC, the values in this Section 3.1.4) might contribute to the observed variation in results. The
study are lower than those found in the literature. Ozone formation (OF) mineral resource scarcity (MS) values for OPC are consistent with the
is also heavily influenced by the fuel types used in clinker production literature reported (Thwe et al., 2021; Tun et al., 2020). However, for
and electricity mix. For instance, in the reviewed studies (e.g., Petroche PPC, the MS values significantly deviate from the literature reported
and Ramirez (2022)), the coal-fired power plant further amplified the (Stafford et al., 2016b). This variation could be attributed to the dif
OF values due to additional NOx emissions. On the other hand, Stafford ference in the type and proportion of clinker substitute materials be
et al. (2016b) reported extremely high OF values due to road transport tween this study and reviewed studies. The fossil resource scarcity (FS)
emissions. scores in this study for PPC range from 71 to 142 kg oil-eq/t, and for OPC
The fine PM formation values obtained in this study for PPC are in it ranges from 96.5 to 122.5 kg oil-eq/t. However, Stafford et al. (2016b)
line with those reported in the reviewed literature. While, the PM for reported significantly higher value (736 kg oil-eq/t) for OPC due to the
mation results for OPC in this study exhibits a wider variability extensive use of fossil fuel in transportation (road). If FS value for VSK
compared to literature reviewed (see Table 9). This observation col production scenario is excluded from the comparison, the FS values of
laborates with this study’s finding on the uncertainties of PM emissions this study fall within the range found in literature (see Table S8,
(see Section 3.1.4). However, the result variation may not exclusively Table 9).
originate from PM emissions inconsistencies; they could also derived In summary, the variations in results observed between this study
from difference in pollution mitigation technologies employed by and reviewed studies stems from inconsistence of inventory data, ma
cement industries, as highlighted by Hong and Li (2011). The terrestrial terial composition, impact assessment methods (and labeling
11
M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
substances), and differences in production technology and fuel types warming. PM2.5 emissions contribute between 20% and 54.7% to fine
used in cement industries. PM formation, and NOx emissions contribute between 97.6% and 98.5%
to ozone formation (human and terrestrial ecosystem).
4.2. Policy recommendation and future outlook Across all production scenarios, the raw material preparation stage is
responsible for 99% of mineral resource scarcity in clinker LCA. The
This study identifies the hotspot environmental concerns, including fossil fuel production stage effect is observed on fossil fuel scarcity,
midpoint and endpoint impacts, arising from the production of clinker eutrophication, and water consumption impact categories. Trans
and cement in Ethiopia. These findings establish foundation for portation is a major contributor to ecotoxicity (43.2–63.3%) and human
anchoring sustainability in cement sector and guiding future decision- carcinogenic toxicity (33–39%) impacts. The contribution of electricity
making towards a more environmentally responsible industry. For to all impact categories is negligible. This study midpoint analysis
instance, this study reveals that energy (fossil fuel) related emissions identifies nine hotspot environmental concerns out of eighteen impact
during clinker production significantly contribute to atmospheric categories, including, global warming, ozone formation (human health
emission-related midpoint impacts. Additionally, fossil fuel production and terrestrial ecosystem), fine particulate matter formation, freshwater
at supply significantly contributes to aquatic system eutrophication and eutrophication, terrestrial (ecotoxicity and acidification), human carci
fossil fuel depletion. nogenic toxicity, and fossil fuel scarcity. Endpoint analysis further re
Ethiopia’s climate resilient green economy (CRGE) strategy projects veals that the most critical aspects is the damage on human health.
a significant increase in cement production, reaching 65 Mt by 2030. Mitigation measures primarily should focus on these hotspot midpoint
This strategy also aims to limit the nation’s GHG emissions at 150 Mt impacts. This ultimately limit Ethiopian clinker and cement production
CO2-eq by 2030 (FDRE, 2015, 2011). Extrapolating the current result damage on human health.
suggests that without mitigation measures, the GW potential of cement To further increase the reliability of this study, sensitivity and un
production could reach 42 Mt of CO2-eq by 2030. This translates to a certainty analyses are conducted. The sensitivity analysis shows that a
concerning issue where cement production contributes to nearly 28% of slight 5% decrease in kiln fuel energy consumption and transportation
the country’s GHG emissions in 2030. To reduce GHG emissions from burden reduces the environmental load of the identified hotspot im
the cement sector, the CRGE strategy has prioritized two measures: pacts. This findings suggests that substituting fossil fuels with locally
alternative fuels (AF) and energy efficiency measures. Implementing sourced, low carbon-index AFs could be an effective strategy for
these measures is estimated to have a mitigation potential of approxi lowering the environmental burden of Ethiopian clinker and cement
mately 9.2 Mt CO2-eq by 2030 (FDRE, 2015). This implies a significant production. Conversely, a hypothetical scenario where Ethiopian elec
reduction of 22% in the extrapolated GHG emissions. Previous studies, tricity (98% renewable) is substituted with Kenyan electricity (80%
such as the one by the World Bank (2017), have identified potential renewable) would increase the environmental load from hotspot im
low-carbon AF sources (biomass, RDF, and used tires) for the Ethiopian pacts. This highlights the significant role of Ethiopian electricity grid in
cement industry. However, despite this promising potential, mitigating environmental burdens. In addition to fossil fuel substitution,
co-processing of AFs in Ethiopian cement kilns is not currently recog this study also suggests that implementation of energy-efficient tech
nized. Furthermore, the Ethiopian cement industry average thermal nologies (e.g., switching VSK to multistage preheater and pre-calciner
(4.13 GJ/t of clinker) and electrical energy (129 kWh/t of cement) is equipped rotary kiln) and lowering clinker content in cement can lead
higher than the energy use targets set in cement sustainable initiative for to a more sustainable cement production.
2030 (IEA, 2018). This initiative suggests a target of 3.3 GJ/t of clinker The uncertainty analysis on impact assessment results reveals low (e.
and 87 kWh/t of cement. g., global warming (3.59–5.64%), terrestrial ecotoxicity (3.49–6.18%))
Development of a supportive and coordinated environmental and and moderate (e.g., human carcinogenic toxicity (6.2–7.74%)) degree of
energy policy framework, as well as enforcement of existing policies, is uncertainties for most clinker midpoint impacts. However, fine PM
crucial for enabling the implementations of abatement measures rec formation (22.07–33.43%), water consumption (26.48–54.06%), and
ommended in CRGE strategy and also in cement sustainability initiative mineral resource scarcity (16.06–17.96%) impacts exhibit higher degree
(e.g., clinker substitution, on-site heat recovery for power generation). of uncertainty. This reduces the pertinence of the final impact assess
In the meantime, a quick interventions and policy actions are currently ment result. Most of the cement midpoint impact assessment results are
needed: to phase out outdated kiln technologies (VSK production sce comparable with the results of similar studies, with the exception of
nario), enforce energy audits, and promote the upgrade of small pro ecotoxicity and human toxicity impact categories (see Table 9). Incon
duction scenario to moderate and large scale operations. To effectively sistent inventories of heavy metals and impact labeling substances could
support Ethiopia’s transition to sustainable clinker and cement pro explain the large variations observed in ecotoxicity and human toxicity
duction, assessing the environmental performance of a wider range of impact assessment results across studies.
cement-specific abatement measures and identifying factors that hinder To mitigate the hotspot environmental impacts, a coordinated policy
or promote implementation of these measures are also mandatory. framewrok that integrates both environment and energy aspects is
needed. In the future work, this study will continue to assess the po
5. Conclusion tential for environmental improvements through alternative production
measures and identify the barrier and driver factors that affect envi
The present study carries out a cradle-to-gate LCA for clinker and ronmental and energy efficiency improvement measures in Ethiopian
cement production in Ethiopia, to provide a comprehensive environ context. The latter is important for critical informing policy reforms.
mental profile. Four production scenarios are studied, categorized based
on kiln technology and production size (clinker). The VSK scenario ex Funding
hibits the highest environmental burden (27–60%) compared to the
others due to its reliance on older technology, which leads to increased The work was supported by SIDA- Ethiopian Bilateral programme
energy consumption and higher emissions. Emissions from the clinker (contribution No: AAU 51080124).
production phase, particularly the kiln system, substantially contribute
to most of the atmospheric emission-dependent midpoint impacts CRediT authorship contribution statement
throughout the production scenarios. Emissions from other process
stages (raw material preparation, fossil fuel production, and trans Micheal G. Wolde: Conceptualization, Methodology, Investigation,
portation) also contribute slightly to these impacts. In clinker LCA, CO2 Formal Analysis, Software, Validation, Data Curation, Writing – original
emissions from all process stage contribute 95%–98% to global draft, Writing – review & editing, Visualization. Dilip Khatiwada:
12
M.G. Wolde et al. Cleaner Environmental Systems 13 (2024) 100180
Conceptualization, Methodology, Investigation, Resources, Writing – Çankaya, S., Pekey, B., 2019. A comparative life cycle assessment for sustainable cement
production in Turkey. J. Environ. Manag. 249, 109362 https://doi.org/10.1016/j.
review & editing, Visualization, Supervision. Getachew Bekele:
jenvman.2019.109362.
Conceptualization, Resources, Writing – review & editing, Supervision, Chen, C., Habert, G., Bouzidi, Y., Jullien, A., 2010. Environmental impact of cement
Project administration, Funding acquisition. Björn Palm: Conceptuali production: detail of the different processes and cement plant variability evaluation.
zation, Resources, Writing – review & editing, Supervision, Project J. Clean. Prod. 18, 478–485. https://doi.org/10.1016/j.jclepro.2009.12.014.
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The authors declare that they have no known competing financial Federal Democratic Republic of Ethiopia. Ministry of Water and Energy, Addis
interests or personal relationships that could have appeared to influence Ababa, Ethiopia.
FDRE, 2011. Ethiopia’s Climate-Resilient-Green Economy: Green Economy Strategy.
the work reported in this paper.
Federal Democratic Republic of Ethiopia, Addis Ababa, Ethiopia.
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