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Lec 01 Introduction
Lec 01 Introduction
INTRODUCTION
M L Palash
PhD. & M. Eng. (KU, Japan), M. Sc. (DU, Bangladesh)
University of Dhaka 2
Research fields and interests
environmental issues
Hot
water
Adsorption
Desorption
Electrical
energy
Expansion
Valve Mechanical
Compressor
Thermal
Evaporator Compressor
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Research Collaboration
SAHA
Advanced materials Laboratory Components, system & simulation
Algal Nutrients
Superfood
CO2
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Current student activities on research
(0.3 L)
Uptake [g/g]
(Silica gel)
High uptake (0.6 L)
capacity (PIZOF-2)
Adsorbent
(2.0 L)
Solar heat is collected Cr-soc-MOF-1
and transferred to
Heat exchanger to Silica
desorb vapor High cycle stability
Zeolite
Condensation occur in
relatively cold plates MOF
Harvested water is stored
in a water reservoir 300
MOF
temperature 100
Zeolite
Silica
801
841
0
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Recent publications
Impact factor: 17.881 Impact factor: 13.273 Impact factor: 7.147 Impact factor: 7.053
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My profile
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Our Syllabus
Future courses
• EEE-3205 Material Science
• EEE-4233 Nanoelectronics
• EEE-4253 Power Plant
Engineering
• EEE-4271 Renewable
Energy Technology
Research
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Expected knowledge
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Concepts of Thermodynamics
➢ The most important concept in thermodynamics is “Temperature”.
➢ Temperature distinguishes thermodynamics from other
macroscopic branches of science such as geometrical optics,
mechanics, electricity and magnetism.
➢ Thermodynamics has a bearing on most branches of physics,
including elasticity, hydrodynamics, electrostatics and
electrodynamics.
➢ Temperature is important in all fields of natural science including
physics, geology, chemistry, atmospheric sciences, medicine and
biology as well as most aspects of daily life. (Source: Wikipedia)
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First Law of Thermodynamics: Numerical Examples
Ex: 2.11 (Cengel): A fan that consumes 20 W of electric power when operating is claimed to
discharge air from a ventilated room at a rate of 0.25 kg/s at a discharge velocity of 8 m/s (Fig.
2–48). Determine if this claim is reasonable.
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Language of Thermodynamics: System, Boundary &
Surroundings
➢ The study of any special branch of natural
science starts with a separation of a
restricted region of space of a finite
portion of matter from its surroundings
by means of a closed surface called the
“Boundary”.
➢ The region of interest within the
“Boundary” is called the “System”.
➢ Anything outside the “System” that has a
direct bearing on the system is called the
“Surroundings”.
➢ Surrounding can be another system
➢ The boundary can be either “Physical” or
“Imaginary”.
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An example of Thermodynamic System
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An example of Thermodynamic System
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An example of Thermodynamic System
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Description of Systems
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Macroscopic Point of view
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Microscopic Point of view
❑ From the perspective of the microscopic, a system is considered to
consist of an enormous number of particles
❑ Each particle in the system is capable of existing in a set of states
with energies ε1, ε2, ....
❑ The interaction among particles involves collisions of forces
caused by fields
❑ The system of particles are considered to be embedded in a set of
similar systems or ensemble systems
❑ Statistical mechanics is applied to find the number of particles in
microscopic energy state
Properties of the microscopic coordinates are:
➢ Assumptions on the structure of matter, fields or are made
➢ Cannot be suggested by our sensory perception, needs mathematical models
➢ They cannot be directly measured, but calculated
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Scope of Classical Thermodynamics
❑ In thermodynamics, the interior of the system is always the
interest.
❑ A macroscopic view is adopted emphasizing on the macroscopic
quantities affecting the internal state of the system.
❑ Such macroscopic quantities are called thermodynamic
coordinates.
❑ Thermodynamic coordinates are employed to determine the
internal energy of a system.
❑ Thus, the purpose of thermodynamics is to evaluate
thermodynamic coordinates and their relations consistent with
the fundamental laws.
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Language of Thermodynamics: Phase diagram
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Thermodynamics Contacts
❑ Direct bearings (interaction) on the
system or between the systems are
achieved via thermodynamic
contacts.
Types of interactions
➢ Mechanical interaction:
▪ Interaction by mechanical or
electromagnetic forces results in work
done.
➢ Thermal interaction:
▪ Interaction that results in the exchange of
energy in the form of heat transfer.
➢ Mass interaction:
▪ Interaction that involves the exchange of
matter across the boundary.
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Types of Thermodynamics Systems
❑ Based on the types and nature of the
interaction, thermodynamic systems
can be classified as:
➢ Isolated system
➢ Closed system
➢ Open system
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Types of Thermodynamics Systems
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Example of closed systems
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A Special Case of Open System:
Adiabatic System
Adiabatic O X O
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Language of Thermodynamics: Property
Any characteristic of a system is called a property. Every system has
certain characteristics by which its physical condition may be
described.
Example: volume, pressure, temperature, velocity, viscosity, thermal
conductivity, modulus of elasticity, coefficient of thermal expansion,
resistivity, elevation, etc.
The salient features of a thermodynamic property are the following:
(a) A property is a measurable characteristic, describing the state of a system.
(b) It has a definite value when the system is in a particular state.
(c) It also helps to distinguish one system from another.
(d) The magnitude of a property depends on the state of the system, and it is
independent of the path or route followed by a system during a process.
(e) A property is an exact differential.
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Language of Thermodynamics: Property
The differential quantity of a property P is designated as dP, and its
integral between states 1 and 2 of the system is:
2 xydx + ( x + 3 y )dy = 0
2 2
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Language of Thermodynamics: Property
Solution:
Try to do it: Find out the following quantity is a thermodynamic property or not:
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Language of Thermodynamics: Property
Types of properties:
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Language of Thermodynamics: Property
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Language of Thermodynamics: State
The thermodynamic state is the condition of the system as
characterized by certain thermodynamic properties like pressure,
temperature, specific volume, etc.
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Language of Thermodynamics: Path
When a gas expands in the cylinder, the piston moves outward, the
properties of a system change and the system reaches to the new
state 2. It is called a change of state.
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Language of Thermodynamics: Process
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Language of Thermodynamics: Process
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Language of Thermodynamics: Process
Process Constant
Isothermal Temperature
Isobaric Pressure
Isochoric Volume
Isentropic Entropy
Isenthalpic Enthalpy
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Language of Thermodynamics: Process
work = force displacement w = f .ds
Similarly in Thermodynamics energy/work can be expressed by the
multiplication of two thermodynamic properties.
Thermodynamic energy = intensive property x d (extensive property)
These pairs are known as conjugate pairs/variables
❑ Process in conjugate pairs (The product of two quantities that are
conjugate has units of energy or sometimes power.)
➢ p‒v(Isobaric process, isochoric process)-Mechanical parameters
➢ T‒s(Isothermal, isentropic)-Thermal parameters
➢ μ-N(chemical potential, Particle Number)-Material parameters
Internal Energy:
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Language of Thermodynamics: Process
(conjugate pairs)
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Language of Thermodynamics: Cycle
➢ A cycle is a process where the initial and final states of the system
are identical.
➢ A series of two or more thermodynamic processes that bring the
system back to the initial state is called a cycle.
➢ At least two processes are required to get a thermodynamic cycle.
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Language of Thermodynamics: Equilibrium
A system is said to be in equilibrium state when there is no unbalance
potential (driving force) within the system. It means that the intensive
properties are same throughout the entire system and there is no
tendency for a change of state.
Types of equilibrium:
Thermal equilibrium: No temperature difference.
Mechanical equilibrium: No pressure difference.
Phase equilibrium: No phase change.
Chemical equilibrium: No Chemical reaction.
An isolated system has no interaction with its surroundings and is
always in internal equilibrium. When any one of the above conditions
of equilibrium are not satisfied, the system is not considered to be in
thermodynamic equilibrium.
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