G U Cea TOPE erry 4 )aifaise seercofier v softer (coftera, Ha Rtafee, site) gfMo KN edistty BTS FO ace She cotera aaa) BACH FTG CATT CREAT TOTS Rots AC ATOMS ECG freay rat | Carer RIwA carat Pathe TeNpETAT GONE AA OF OUMTTAT HF | FAT SOT APA ICR TNT writ ofa, att FAT ced. Pret weTyTT cena are RR OORT | WAR A A cea em 8s, Pee TENT T | @auisg wy srecofve > safer (aces, MR, FAS) sgh4) itt 5 3 »& CRAG “s" wfieg Fret aaa, OD “CS ots erie ye sa BEee, CURIE aA sIRiSe TET EE | aor yt aoe orpyt SEPA aT BF re RE, TH aver aE oven Fr-4 Solas ery yt Bren Le OPO TOA Saree nee pot rarer Boa cat CREAT eT BAAS PFE eration ST CRO wT ae eT RHA aT RIT GT are ace Sea “ROTC Te” cc SAE PT BT LT Ram orp Briere RET Veter Sera Sat AACE | aR ere aaiits snore FTAA Bite Te ATETTAT | AACE CPceR ac ST STOTT HT AEST AAT FAT aR viel Ror wor fafemeRecT fire we APEPTL Pde capt ay @ AME | aETEA CAT GST BU BTS ioe Fa oMpyt Am sem Borgo Sat ANH ARE ‘vret Fauferrerera wf srt MCQ 6 Written Sex eacrT eet OF IEF | CIE FATIT ATTR MCQ 6 Written enreO ervey | aren Ft Fora Bore coaang ATER COT ACITR T COTMTEN sr FEASTS HEN BCT | Sora ef creo RET Ie SAE EET wer GET COTTA TVET eee AHA FATS MT) CRE Reform wie saraTT BTCA GIT FA AAT AT STAT a eaoow acMCE snfoe map RC TTT aps ort wae MPa afer at COMICTT WIRET Bee MANNE CT | HTT TRAM ete COTTE See AT ze TS Carpet Bereta Drees Aa fred | ACCT MCQ 8 Written emafoa eterno rece wear wes et Frew ARP FACT | Cort OE eeferw Fai MrT AIC APTA AT STAT AP FEM | COPA FA GT CSET |° Mfedialty de CIPS = rtcrtt I “qatar 9a a teria Ge" CORE CHAT GAA TAT FATA ARNT GRY AAR Y 1G, Heater Sie Peg Rest ist 21-G, AST Cmts BSTEET Fels OTT | Aieo Fas e8 IA / v seercofiee y softer (cafbrcon, Haftafie, fe) sgaS EBM (ar MONG) o> x BTR-08 | OTS FAT rt 03-02 [= SOH-o0 : Gites Hinge of apres THT 99-6 [= x WO-08 + APTS aawT f bo-398 08 3 BOH-o¢ : SAT PT ye 39@-329 [ee AUB GBB- 0d Y dQR-92B [~ x WCwA CGB- 08 { d90-OR_ Le eaeorensaa Ret . iar Cierra] Patt as atte] [Sattar stat eo ee wise: (i casita (p) 1,673 10-7 | 1.61079 +H CECI, 1886 (i) RATA (e) 9aax10 | =1.6% 107°C =1 CRS. CHF, 1897 Gi) FREER (a) 1.675 x 10-7 oc 0 wiwERe, 1932 seit yr siien: (JnU17-18,RU’11-12) aor (fide (oh Feet. () SPCR Ec Orr © afer (@ anfeoa Femnfee SAA: (w EBLDA eA (D*/FH*) (BIEL wT ($He?*) [3U°16-17] are Ke ers often aa Bera, can © MBIA eT Ade + . ty Aor ara Tew: Aoyr/ serie cues 2 aye mre / ceria est] —> Z, > RRS RT teore eBre Ror, catde 6 FARE ret Reta ans: @ {He (P=2,e=2-2=0,n i) 10 e=8+2=10, (ill) {H* (p= 1e=1-1=0,n OT CBA Ht WANG SFP aT BA > REC ener age Teo.CO} Herc RERUN ART = 32 GAT C6 O Ae AATSET FATT STC CHAT RTA FLAT TATETH 6 6 81 ‘wade, COR a RAT eT = AA ROMA AAT + (3 x SARC ATRIA AON + 2 (HH MNS STA BT) =6+(3x8)+2=32 NH} wercea Sera ART = 10 | ARCH NG HA STARS ART SEAR TOA ROA ARAIT VATEAT 78 1 « aR NHS yale pan mail daaalalaliaal +@x1)-1=10 I Bi Te ox 9 OIC TE eH oe Bet ‘Cay or RRS = Ce cemgteta weTe ‘eo rae ee a AR C-12 0H INT we 2 HEM ATEA = 1.6605 % 10°27 hg CHARA am, , (tome mass unit) Wat Sr ATT A MTA = SAP TATA A X Lamu Example-O1, PHARE CA FAA OX ALOT FH? @) re (b) cai ora @ srt Ss (a); CHIOA Pa fee SAT Example-02. ARES SHANA FA RAN TALL? @19 31 ©2 @2 ‘SO; (d); NOx SAAR OUTTA | N- 2 RCRA ATT = 7 GA, SCTE 'O' 4 VOGT ANT = B + GIS OTR, (€7) = 7+ 3 x84+1=32 Example-03. CHM “ANA OF FO? @ 282 x 107g (b) 3.82 x 10-3 (©) 182% 107g (482 x 10-33 Sol?:(b); Na oa af eptatgs SA = (11 x 1.6 x 107) + (12 x 1.7 x 1074) g = 38 x 107g =3.8 x 10° Fewer pe: aT eH, AE maT Sa = ICE AAAI wx Lamu ‘a Naa oof raat wa = 23 x 1.66 x 10° g[ 1 amu = 1.66 x 107 g] = 38.18 x 107 g = 3.82 x10" Example-04. % SY NaAl(OH), TET PATA PERC AAT FO? [cu'18-19} [Na(Z = 11,4 = 2: )s ANZ = 13,A = 27);0(2=8,A= 16);H(Z = 1,A=1)] @34 (0) 36 (0) 62 @s8 Sol”: (4); Ny = 123 Nas = 14; No=8; Nu=0* Neotat =12414+ (8+0)x4=58 Example-05, arg ora AerraceT TTA? {Ans: d] (JnU°17-18, RU'11-12] (@) Ber, CIT (b) cara, FREES (© RRs, rR OF, [cu'22-23] [pur19-20] [3019-20]i) RT CoC AD eT BTR APB wT ew FTAA | aR STR aC ATS CPT AT AEH IT RH TET RTD saree era FABER STE HS TT | OLRPRTOA MATS ATS STIS OTe SIN AAS SA PAGE! Gi rae Frage ere FS Aemrern carer Teh es MTA He TET OTS ROE TE RPI sficafte sa a4 Gi) Terence =yCe Crafres yATATA StOTITR ACEI oT ReTAITOT aa ray AB GPMIOT vralhce rer eres ERAT REEIOM 6 Sore OMAAE BoE TT mie fis Copier TRS TS CoRTT er ee MTA Reena eRPTTN ae era TA Be ATS Aten eA owt eer fi areTacerToe a — (He?) Fivgae er TACRTCe erate NTETHTA AATATET: @ Giarerra sor aafirens HERE, was Ror ETR wage orgs aa ae fie Capfes TT SRT RS Sea 1 HATS STIR TS TH TA MMA HG HA SA ANON OT AT abe Gi) SRR STATA HVAT TEAS TH AT PA CHA FVM MCC GAT BT LEMOS Re APR ATS aR, wa eraeroare Fa Ses Face areca ER SCM SoTES UIATS Vere Tt AS ace VAI Rete fee za Care ra ACT: > Roralicrs fa were a feacaa Ta: IATL PAL AAA AAS ATS BIS 8 ST HAS OH HANGS; eC Ta PRE HSEMT eT a AVP re ea Sere FAME ~iften Fares PRRs ATES OIC TES RoR MERITS Brace SHAE HLH AOL HI RRC HS MT ATAARTTR H PAAAT CTCA BETA OH Ol RT STE HA FAS, BHR Gl HAT Ae Peat aT Cora aCe AT aR HHMCTTRS fils FHA (stationary orbits) Sr aa aT AE TT SA ACF n TAT APT FAT HI CHAN, n= 0,1,2,3, > Roralicra cits wacacrs a: fC FARE arpa aT teate ASAT Tora AR SHC ARE aa ot Faroe a Et TTT offer aq) afte, mr = QAR m = RRA GF, v = ROTA AHA SAM, r= PHT TG, h = PICA Re, n = BHO ALATA, 1, 2, 3, 4 SASS oY ALT! n es OTS NIC wo FRAS Bea Te eg, fad gis Fra Revie ai h = 6.626 x 107 J.s [S.1.];h = 6.626 x 10-?7erg.s [C.G.S] (+ 1] = 107 erg) E> WW ° aftatora cere FASE OTT.a > mia cree a faa oar ata ata: SR CHT RRR a pe TIA RTS TMA aT FHMC TTT OT, st A one at RATS a Fea wT ow eT mH DO OA om CHT RT, ‘Bes fra ace ra foram mec ey, oe mer one eB a te HCN ROMA AS Ey Fest wreetce Reval cra S E, H, Ws Affe Wa AE = E,— Es! wee 8 Ber TAT FE Cao Gee be eiebo RRR aE = By-Ey~ ho Be oT Lenton Fer BS RAE ET ‘Bae career MATL TET @ ret weirs BOT a =i Regs Gretta Patras Reorea Refs aca tose arpa oF FaRReac fa 6 PH ART w FC ‘tenet rat Pdf wa: AE = (E, - E,) = ho = *. i) > cas orang NCETeTa ATASTT: (@ Ga ate HOSAT Hora are ROAM STOTT (CT: Het, Li?) ara eT BAC TATE aati SOATARAB eo AAT TOT FACS MCAT (i) ae “tram Bw te Re RR ATTA VOM, AR AAT ROS TCS RAB ar AA HE LOTTA wea Bes STS CMTC TAT ATT AC HAT AT, HOHE caret BCHATD Ap eT Frew TSI CAT NTT PF FR AA Behe HIT TIT FACS ACA AT (Gi) cara wre we AR, FR eC ROTA AH EAM, L = rave = mF RA CA TAAL LH RTT FT HH Fa VA ivy re come CHITA BA AATCC CAT LH CHUTE FOE RM MGT aT FETA IETS (Zeeman effect) TA! aR CAG CRA Twa Sart WB; Acar “OE FTA (stark effect) WHI GE CYS CRN TAT TAT rT FAR marae FH PRETO (splitting) WBC CATA NCSL AAT CTA HCO a AA (v) Racers rR AE rTM PAM aH COAT AT HTN SAPS ROR SIAEPT © GACT AR aren Fifa aa aT AT Gui) cara mem ora Smear erate wet Aare AT ATT ALERT CC ATE RE FT “SATE TAT AT ANAT THT AT = 590.0 nm d= $89.60 Na-D mie Na-D ait meee or ra oe ower oot fom Na-rresiga af care ais Farr ere Naa? Aare ereTeH RAT ASOT...Example-06. He 43 34 6 2u “feared “fa o1de7 @o eV? [GST’22-23] (34 (b) 10.2 (©)408 918 Sol": (0); E = -13.6x Zev He ot CFG, E> — b= 136(% 2s) ) = -136(- 13.6 x (-3) = 408 Example-07. sarge CRIT Ro Pare ote Bw or IE. {Ans: a] (JU717-18) (orem AAS APT oT Gi) ETD oa eA (ii) EEA MRS GR oT Frcoa Gra aie? @i (b)i, ii ©ii, itt Example-08. SPT FA R- Ans: ¢}[JU'16-17] (@) He *maTy, (b) He* ory (©) He®* Sine (@ Dt ar Example-09, aTATACRIOSH era Hr FURR RT TAT ANTE A UTS RATE? {Ans:aj(CU"10-11] (o) Feta Ota (©) RRR (2) sss aot Example-10. (a) Ta AOS SPATE VR TTCTA TCTs Feat ara Bee fBrarA ATCT CHATS [DU"19-20 ) Cate OER Ta A ATARI OTR Sol": @ crfte “ff, AE =; -E, writ (e) pL fits mf, AE= 6,5, = OF s, oferte were SRA wee () () care ICE FRAT etera «OE sreTa AMAT FACS AAT Gi) RACER Cate THREAT oergerTA Aha TANT eS ACA ATH Bj Fae 6 war eat RT @ TR wat orem erara, waa OTTA Fata Frcoa IM TARA eA THT aA me, f= $5 [A CAMA, ¢ = SIT AT] (i) FRA CHENG GAT STS CST STA, SAA GAA aH cos I Tea Hea Say Ae a sag STAT, V @ Problems Example-L1. aetara GxAAG 700 nm By, a SAF AAT FO? [JU"18-19] (@) 132.44 x 10*m™! —(b) 114.95 x 10*m™"(c) 142.86 x 10*m™?(d) 122.39 x 10¢m™ Sol”: (c); QR, SAAT, A = 700 nm = 700 x 10? m = 7 x 10-7 m [1 nm = 10-? m] orsat a, CaN ART = B= 3 = = 5 x 107 = 0.14286 x 107 = 142.86 x 104m (Note: waifire ar fice acm, riRicen oreo ee aH we the ACS RH \ fede etre Prse “NT,Example-12, CHEAT RISE A mrace ewid era fe MeTIETH 6.3 x 10-17] AAR 12.926 x 1079) aft Be wifion ere Fig sfiewca RereA epTatte we, era AeA afte HAE 6 CHATS FS TA? [h = 6.626 x 10-™4Js @ayc = 3 x 10° ms~*] Sol eter, c= 3 x 108 ms™ ; Ey = 63 x 10 J ; Ey = 12.962 x 10"* | ;h = 6.626 x 10"%*Js AE = E, — Ey = 12.926 x 10" — 63 x 10" 3) x 107" = 6.626 x 10-7 J 0-19-(-30) = 10-2944 = 1085 orrat wns, PSA MIS, AE = hv sv =F = v= To wns, v= 1x 105s? want =f = AF = 3 x 1019) = 3 x 10-7 m, o> io Example-13. %&%-e Shere Besa SHCA SAALAG 6 x 107m AL 2 ALM OALAA FMT FS? Sol: AAT, BHAA, A= 6 x 10-7 m ; BHAT AA, C= 3.x 10° ms~* erway, f= S = PH 8 PE 3 agnor a 25 1087 = x 109 = 05 x 10 = 5 x 10st 2 2 i [Note: were ar Free wr, HAR A TOA HE ea WOH MEATA FAITE ATI a0 ~ 3x tes ard Uh eral ARE oA, mur = QR, m = CASA, v= nO PHA AAT AM, oe Rerathors can, wrrct TPG 6 a © GRR eI GTI Vy = eee Ms] = no PRCT TPG oo Example-14, GECgCo TANT 11x 107g] aeration af PHI TPG 8.5 x 107m Br Rees SATA 6 AT FO? (KU'18-19] . mh xerox 626 met 10-4 thoy = sth = saaaneusete TET ~ Tioenssa «OID 8328 gg -a4t08) Tinea, at, 33252 x 197 ms“ (Ans) aaioxasvoa * 1 7 4 wacast, my = 2 seactgas Kems“* [O1eter, n= 3.1416) [Note: Written s CFE, BE Caeula Boa fet ores IF ATE MOM ACI A. ase |SRR coco e SS a + SRRCTEETM: AAT RAT AT COUR ATT AAT RATA A: { SREB “or CS caida eT TATA \ () TH, 7H, 7H (%) 7350, 33U, 38 (st) 351, el 0, %70, *0 LL ‘Sito: FEBS eT TA SRAM + A" CS FRA ART TTA (7) 385i, HEP, 22S [DU"13-14) (@) "$0, 28Ne (1 #$0, *5N [CU"20-21] © 4c, 4 SRO: FA AT | SRO + IH = SH = Sa Fe TA CH) 188Ba, Fla, Bice) 73He 74D) $$cu, $$zn [RU'11-12, JU°09-10] SRCTATR: GER RIE RERRIOTE AAS TT @ GHETOTT TATA Fry GSTS Ow COBRH Mola we COMET FARR, CAAT MICAS ACATATA TH CA: NH,CNO, NH,CONIH; 92Br @ 82Br wR ReraaTe: [TOTS CaID Reeves Fee TAT]- 07", Fé, Ne, Nat, Mg?* (qUTE SCRTLAA RETAIN Ae 10) SR Sera ara Bers AT AT Cate ef fo contours, ergo | am | fem | fer ae FE | rat sateen | EGR, fom sromm | fx [fen [ome] te | fe fr Cu, 20 atern | fox | oan | fox fem fon fem Si, UP Example-15. CO, <4 WRUCTRDAAAAE OITA BAT- (DU"22-23) (@)No- (©) 05 (©clo- @N5 Sol": (4); CO, @ RETREA AH = 6 +2 x B= 22 ; NO- 4 eA ALOT +84+2=16 05 a Rema Fee= 3 x B+ 1 = 25 ; ClO @ RRA AT = 17 +B +1 = 26 Ngo Rene Ae = 3x 7 + 2 Example-16.45N @ "$0 fara {cu’20-21) (Sree () SRC © SReToR @ aR mi Sol: (6); 75N 4a FEI AM = 15 — 7 = 8; 160 wa FAVA ART = 16-8 =8 RRA ATTA, RST vos ARTECTE OTT FAG NOT...WIA DAT Example-17. 3H ¢ {He oR Larsebl ISHS 24 @ sere (stoners (store coyereencrt Example-18. Gem oman a STATA Reel @ RE COT TA? eee (@) 3Be (3 © @RNat ae Sol": (4); "$0? aa ery, n= 18-8 = 10;e=8+2=10 Example-19. CH BeaRS TAT CH MCATA NeeG CHAE ora SHRCATEOTA? (Ui 1S ITS. @cano —HsiaRys — QYPareiss —_—/78P awe *iHe Sol": (a); 4C 42x '$0 aa FERS Te A Example-20. ators Barer. oq (INR (Stan Sea © Sea BK Ree Sol": (A); ROTA Reet FEET AT AA FT| SEP aa PREGA Tee 31 — 15 = 16; 1§5 waa BDH aT 32 — 16 = 16 Example-21. fACba Species GTA TTA fit BIC? [Ans: e} [DU"11-12, 01-02] 20Ne, 9F-,24Mg?+ (@) Isotopes to each other (©) isomers of each other (©) Isoelectronic with each other (4) isotones to each other Example-22. $$Cu 4x $3Zn @t 1™"153- [RU'11-12, SU°09-10] @ stent @ Sere (eRe @erahaar Sol": (b); WBA SA ATS 64 1 SR a MT RAAT | SF CHTAPETA FRAT, Teer como Aer, | | ara OPES CHTAPETA ATT, for or ‘Pore corerorT AT, s |e CIE fara ata eT sre CAB: @ n>] nF] UE IG RAL (ii) m QA 1 RT AR 41 GAA MAAS AAT TS) (ii) s a +31 FRA af Berea CO 3 HE TS TAT RA, WLI TALRBI LTA FD (n, |, 5) STRATA AT a: 9 SaeedScihmchicesin + CaEroTH 9 Rory eT Ke aioe we: water rent Af n peewee, nF = 1? = 1 HPP, n? = 2? = 4 Swarr anes were tors Fite IN ant . ‘Sornfeaca cde Ror AMT | 2C21+1) | 8 2(2.04 1) =2 Rea s Brea om ea #2 (2.1+1) = 6 f Bera a p Bows Fo ea) 1 : 2st2ps 3 aae 0 35 0 1 3 on 3p + 3 ast3pegae 0.1.2 3d | -2,-1,0,41,42] 5 10 | 0 4s 0 1 2 ot 41 1,0, 4 3 6 a = ts 4st4ps O12 4d |-2-1.0,41,42] 5 10 | 4diogne =3,-2,-1,0, Te 01.2.3 af snes 7 | 7(+3-3)] 14 9% GTRPCT eT Coa wat: NaC11) aa aes 105 Reereliera oes Oral CoTaTBH RAI ATR CAAA aiNa 15?2s?2p63s1 10a ere APL! n=2,1=1m=+1@Rs=—3 Cr(24) Sa ACES 19 8 24 wm RATA Brae CHAE AT AA AR FH 2Cr 15725?2pS3s2ap6 451 3a5 ooh 2 be-3 19th Rorels (45!) = s=+i 24th Serra (3d*) = @ fat WpAR: Berra CMT eH CHAT MTR ATTA AE SS ALY AA THLALD ROHT MT 222, ‘wafer: co fica a Beer em eATA AAT ARTA (90-95%) RI TLE AAAI TAT (v2.21 waRtO 9 wai a5 GT: ORG eH a co te ca Beers OCT BAA AIC | 2 pata i Teh G) TERETE eH ROT Reba ea See ear aT | Gi) Vere MeCN creme ReewaT ea aT = (i) Sar ReRAPTe fia Bertie Gi) BARD Cor Roratiera fens fhe for aatire Fire Prot Gv) SARROCE N=1, 2, 3,4 OHM ANT WAT ATT AT RAL | (iv) SARUM 5, p, do FART AMT AT (0) RFS SHRED Reet is Fen Fem EH aT fy) eR Borat SARTO EAM ‘Fae saftorcera foarryE: ,-s omer Ff § exer Zz 6 aE fe gr poariorr s Safebre (org) (eer eet) fou: s Cafabrers TFTA @ TBS fia: p wahoo wre 6 Ugh j a j j " j Y i ; a oaftbrr (ore orca ore) ‘fom: 4 wrafabira rata 6 UTES [DU"20-21) water: © S Saar aa ato am fea AMRIT Ee) 9s aa Drcere BTS corn ITAA erste wo eer TT ARTE CHAT 9s ARABI TRH x SH y OS 2 TATA AASICS PAGS NC 2 S109 CRATOTA FRAN 'n! A TO IG WA, AVIA cHiTeTeiOS BS TEM s-oafeorT © TER META FOAAG IA p SAAD SICK; TAAL py, py © pz THROM TAT I + p SDP STS SeART GICAL (dumbel) =F pearanort 9 a TS ae FRET RH; FAT WENNER X,Y, ZC CAT Oo RET ICH 2p SaRRORRER s TafaSToA WEI MERIC Dec TRE REE ee AT dante vip eam finite Ror Het See oie ea deat Se a-srafer GOAT ay, yas ays Cy? yt TO 2 d-rafabicrra IGS bral CNAME wraM-IETA ATT! fate + Saf eTT SOLE ees RTA GAT FEA OTST Cea Ste AIC ips: Modem Inorganic Chemistry SAM- of p-WAROICAA EFT: P,(m = 0),Ry(m = +1),P,(m = —1). dA EPH: dyx(m = 0), dye(m = +1), dya(m = ~1),d,2_y2(m = +2),dyy(m = —2)] WISI BITTE 1p, 2d, 3f VHT x0 fiom ctor Paar oT.)WA DA | BAITT-02 GIST CT (n) s 0 P 1 d 2 F 3 = { Example-23. SEROIea SRR COM COMBI ARNT TCH ASO? [Ans: ¢] puns (@) 0% (b) eR Opn @ Pm Example-24. Ficoa rats ae? (a) “SaROrer ar SH MTOTE Ogicw Rereia Tecra TUTA MeC CATA (b) “SafRS” erat FRE EPUCTe Oefice Reefs ETA (X, Y 6 Zo) Roraha SIGs Tea FAT [Ans: dj [RU’22-23] (©) 78 BARRO SEAS ee ER (@) SFOS K, L, M,N, O aT PRS at Se Example-25. Gm See 3e97w? {DU"21-22}[CU"07-08} (@2d ©) 3p 4 @1s v5 Gea AS Sores FATT. 25, 2p Example-26, SCefSw SAH PATE AANA COTTA ALT n = 4,1 = 1 FAME ARTA fe? [DU"19-20} (a)s orbital (©) p orbital (dz orbital @ dye orbital Sol": (b); 1 = 1 = porbital Example-27. tea GR BARDS Tee AT? [RU’19-20] @)! 1=0 )n=3,1=0 ()n=3,1=1 @n=11=0 Sol: (c); | = 0 GH GT s TARA OA CHAT s BafD eg TABS comeTATA Example-28. FCI CHM ARTO CE RA aE RRA FU AET AN (JU? 16-17, DU'I2-13, 10-11, 02-03] (@n=2,1=1,m=0,s=+12 ())n=3,1=1, 12 (n= 1,1=0,m=0,s=-12 (@n=2,1=0,m Sol®: (b); m 44 AH OF +1 TARTS AMT Example-29. 628 Gem oer eee AA n = 4 a, COS Gea Caio SAAT FS? [RU'IS-16, ‘JnU’14-15) @rB ) 12 (© 16% Out Sol: (¢); ST TS WaT AM n VY, 2 mS wea IB AAO FeasT = 21 os 4 Bm, BARAT AAT = 4? = 16, Example-30. 2p Saf@O1R n, 1 38 m GH A TATA [Ans; b][DU'14-15, RU’ 11-12] @2,10 (©) 2,1 (-1.0,1) (©22,(-2,-10,12) @) 1,10 Example-31. 3d Borataa FOO Tew PA HATO AIT GIR? [Ans: ¢][JnU"10-11] (@3 ®7 (5 @> Example-32. 'f Saftore W4caid Fa RAN Ma BATS A? [Ans:d][DU709-10) @10 (b)8 (18 ou Example-33. Sabra $1? ofp d. afin AIH Firt wae ore fe-wfire fo TCA FAL (DU? 20-21) So: PRE Brastreet cx faa sac RAE NSA STAT 90 — 95% HR BTC wrARRDTET wT I AB A ARRBICTAATH: day, dyes dex, dya-y2, die Supe tae ne Kae Bil eS Ty een cere Fase rr..Sumner ore aT AI, RCSA AS we IB TATE AS | + store sehr ae: ee MART CHT AS Rem wT BAS CHTAT OTA ATA A HAAS HE WO CH ATI” A ETE AR A, oR oS aft BS Rema RA corarOrm wee ATA eR RA, WI TLE HATO ACTA AIA TTR FH wa CHR HAT ARTES AB Remralia HRC TR, AAS oa fee rece ROM ATP aR RS A, BEA OTE FR rama Fate AT ‘Bares: FRAT (Hee) ATS 2 1B Reeve TC 1 aS Rewranc 4 A oraT MTTA HeAT ae FEE ER RMT HEE CHAT HAT TS PH HATTA ARTA ATA FSH VA ACF | Ge SFT ROTA AT = 1, 1= 0,m = 0, s= +2 ROMO GATT = 1, 1= 0, sit=0,5= —H1 © me RRra rer Af exc paca cad Rorraey ras TH ff aT: 0 2s 2 a rr 2p 2 1 0 43 3x2=6 + i 2 £3 a +3 3d 3 2 0 43 5x2=10 (5 +1 # +2, 4h 3 aE 2 # a i ra 4 3 ° ah Tea=14B +1 #} 42 4} +3 #3 + Borate: ae seg CRROTeTOTAA Nera PITT RCSA I wat aie ae Eros Fale wT one RR erahQO Tem RATA SAAR ACI HC HA TAT AMAR MAT FACOG IAAT MTT ICH a AR FACETS georaliera Prt eeez eT aH” pare core Brace AG wea AE eR ROTATE AT aT 1S eS CTT ARATE RATA CASTRO TEM ACTA | MG, ON MAE weer MAS a HAART ca BTA | REA RARE Me SCA MATES ROTO METATH S wea FRAN OLR PICA eAcat STHmi Gar: ARETE TOT FOr, N(7) + 1s?2s?2p? = 1s? 25? 2p 2p} 2pt Is 25 2p ty a} LaLa aeRO, 0(8) > 1s?2s*2p* = 1s? 2s? 2p? 2p} 2p} ( Is 2s fH ) Ga ‘ \ Be cx Coat Ss! raf AD Cre CR RCTS Fa ATT AT eTdeTd AB: ‘STERAS (Aufbau) Geo Uris 4H, Wt TE Building up were Boras fics dt ak AfS erp, “orAMTETE eearars Reale teen FAO MTT ER MH a A MeTRC ee MMTN A T AT Pro fear fatter ar Case-1: Ol SARI (n+ 1) SH Gra Ae HH TS RA aE AAAI TCH AH FATS | TTA: 3d 4s n+l=342=5 ntl=4+0=4 48.63 n+ 1H TH AS FH OE 3d oF STC ROTA 45 CIT A Case-2: (n+ 1) FATA RA, CH SAAB n A ATA FH CIT em GI CTT FAA 3s n+1=3+0=3 n=3 ntl=2+ eg, BR e- TIO Zp CS AC ALA 1=0 [m1 1=2 1=3 4 fom: Fay ratsbien Sores yf ReuTa weT [Note: Rcereian wre CHER HACE MASUR CU CH AMA FATA! CANA: 2gFe%* -» 15? 2s? 2p6 35? ap 3d 45°, 29Cu* + 15? 2s? 2p® 3s? 3p° 3d? 45°, ,,AI** + 15? 25? 2p® 35° 3p") de. atascrm eteren Fase Tao.¢ SORE AS carrer cleoraR cafearM Beran Feu): Cr(24), Cu(29), Nb(41), Mo(42), Ru(44), Pd(46), Ag(47), La(S7), W(74), Au(79), Ac(89), Th(90) @ Cre2ay Gi) Cus) Gi) Nb (41) 2 2s? 2pS 3s? 3p 3d5 451 'S? 2s? 2p6 3s? 3p6 B40 4st 1s?2s?2p®3s?3p°3d!°4s?4p%4d*5s? (iv) Mo (42) = 1s72s*2p®3s?3p83d"°4s74p%4d55s" (v) Ru (44) = 1s?2s?2p®3s?3p%3d?°4s?4p%4d75s* (vi) Pd (46) = 1s? 2s? 2p6 392 3pé 3d" 4s? 4p 4410 Sse (vii) Ag (4 1s? 2s? 2pé 3s? 3p6 3d10 4s? 4p6 4410 Ss! (viii)La(S" 1s? 2s? 2pé 3s? 3p6 3d10 4s? 4pé 4410 4fe Ss? SpS Sd? 6s? (ix) W (74) = 1s?2s?2p*3s?3p*4s?3di4p®5s24d!SpSos?4f'45d* (x) Au (79) = 1s?2s2p63s?3p83di045?4p%4di04f45s?5p6Sd?6s" (xi) Ac (89) = 1s?2s?2p®3s?3p63di04s?4p4di04f145s25p 65d! £%6s76p%6d" 7s? (xii) Th (90) = 1s?2s?2p°3s?3p3d!4s?4p%4d°4f"*45s?5pSSd"°5£%6s?6p%6d*7s* ‘BCR, La (57) sR Ac (89) a FARRER eraTe ee MecHTOR NG coe THA ST RTA 6s SAARI 4 HERTS FH SAT Hef (La) GUAT SF (Ac) APA EH eet aT WA Sd (La) AT 6d (Ac) AMOI SCAT HAR Example-34. arate *céte “fare? (Ans: e] [JU"22-23] (@34 wad 5s @4s Example-35. Co G38 Co?* G4 OU CHA GTTEI BEATA TG ASS? [RU'22-23] (a) 4475s? ae 447559 (b) 3424s" ae 40545? (©) 40735? ae 30735" (@) 3474s? ae 3d745° Sol”: (d); 27Co = [Ar]3d”4s?, ,,00** = [Ar]3d” Example-36. Co oR Co™ a8 SU FTE HA ETS STARA FTG HS? {Ans: dj [DU?17-18] (@) 4d7Ss?and 4d75s° (b) 3d4s'and 3443 (c) 3d73s?and 3d73s° (4) 3474sand 3d74s° Example-37. Food GAA RU anti Tea AS 6 Ew Aife Ad sea? [DU'17-18] @DDODODD HODOHODD OODDOODD wOOD DODO Sol?: (d); ATT abe Bow Fras aay aA Example-38, Cu ‘ang af Reva Fert cata? Ans: e]{ Jn°17-18, JU’ 14-15, RU°08-09) (@) [Kr}4s'3¢"° (b) [Kr]4s*30” (©) [Ar}4s'3'° (@) [Ar}4s*30? Example-39. ofS aaTEH ROTAIN OPT 152s2p°3s*ap? Wa, oA Ra [Ans: e][RU'14-15] @ a (b) Frere (© Rar, (@7nearer Example-40. FCO CHA SAAB RATT AC AT OA? [DU'13-14] @4t (b) 5d © 6p @7s Sol: (a); Reever “irae Sear (n+ 1) aT SFT aT RH ITS Veer AS He I SH SCH (m1) EAT HT ESA TA TATA ALOT FH TATA ROTA TCM SM CAT af RATA (4-4 3) = 7; Sd HERA (S + 2) = 7; 6p MAEM (6 + 1) = 7:75 “FEMA (7 +0) =7 HAO A OMT ROTA SICH AF (RE 4 A n AA ACEC AN) STH ICT ATT ‘Example-41. Cr(24) G8 3d SAAT ROAGA HLA FS? (cw123) @1 (2 5 @3 he Sol": (c); 15?2s*2p*3s?3p*[zd' s+SCRE Vv ‘SARA 95 $l : DRITT-02% GBas, Rent ater + feat aieat: (Du'21-22) done AIT Rear qe Sanh ww ster acs a, Bera aa eet @ WaT eR ele FATAL aces wiles Sepa, cabora “fe, E = he wort, ETO Ra Satie ateat oA, E = mc? SATE, m = RET SATE TOMAS BF, c= TEM CM EAT, mc? = hf = hf => me =* 5 Ceiba aT OAT SF = m, TM ELAM = ¢ = CRDCAA SAAN, me =P AS arta We, Fe DTA TET As oe HATE CAT BABS ecw DRT TEP SMA, p= mv A, my=* . A= =P [CU°07-08] ‘See ORT TPH BITE () = SERGI * hac Lodi, mM Hoc ARE E-aiia aAteat ae BS TTI, AAT SAA TACT ROMALTA ATOMS SALA CATA RACH | were — ori om istemr GRRE, foatbos yaa Serais 5B oe Car Hy Ae, ORY, aI S wT RN ¢ | Ronen aa oar acs arent: ‘Ae aitia wea ICH, ere wae CLP Ora TAT Mee BLT Ar TTA acm AAT Dateremre a) as ire (a) efter ae wa) S30 mvr = carat Rovers care ware at Ef ROTA CAO, BR eFONCS CAA TOTO AEN WG wes Roe BEE 15 Sua Bers, A= Dope creer Sree sara aide, ee, eM fe x = 0, SHUT aa CRM aie AE wp? = E— mc2, we, m, wea fi ea ¢ Renata roe AS: seer Borers Fie wae Bow of rere VTA snfeworce erat ACA a, aA COTA A SATAN frigate facta sar ea eH, was am aE ida BARRED er sifiewrere, ax x Ap > % (Constant) = dx x ap 24; (orate, k=] aibeast 2c Far ATA a, Ax ee Ap aIPEN MICA TEIGSHER Bi * Fito se ROT,| caifoercaa war a Aeat: cafeoncas car ates wen, SF 4 EF 4 SF EEE UY = 0 SRO GraTera wraree x FAAR Fire Tea core FAR men RMR STARTER ETT AM, TH 90- 959% a, ace FRAT Tas SaPaDTe TER SS CAA | SAE WF aa ACR TTS PAE x safsbrr rari Sea) w ar ores YF WR CAL RUN Re TTA STAT TAT AMY, CURT ROP OHA Fe aT er A RA, HAA SHH aT HHS a A I ACA AMAA EMTALA CAM ATYT FAT TA A A so Renata nm RTA 1 wa Me ATS eH, [dy = 11 CROAT A Et RR a we ee aT RATA HY BHO MA AH eH RAT IH BLMOTMICR SALRO T BH LEO HALO ATL ROTA FSH ra PA A wife: era er “a cece Real ra aN TH APH Tc MA FSM a ATR Cae onear art reat aa afierrt septic, 2 = Ru (S34) x? GIG, V= aS aes THRACE ATT = Aiea wa UG; Ry = RLRIC ATT wT HwaTT HAS, Ry = 109678cm™*, Z= Gora onaaTaee AT ny, = A Wa; ny = BH STA ftvert Feat oo fy cre im Paice BeeTN ATA | TET Series MAST my, AA AME | AOA RT a sted ‘Lymen Series 1 ferreft Set Balmer Series 2 EDTA Se Paschen Series 3 Ecoicckral ‘Brackett Series 4 SARS AT ‘Pfund Series s Ricca ‘Humphreys Series 6 = SACRE HET Bema, ny, aH ATA 6 BA, BOM er GaMRS ah a ers a1 aTafaer Pihcore SOEE | ees et FRAT A, SATET ODT PHRCORE my, AHI fixed FH ny FAP era TT PCR PAF HRT WHR AACA, OHH AAT © AF TATA ROM: Gs =9) 8 wim(ed) | He 8nf of, M Cte — L eat 2. (M2 = 4) > (ms = 2) p=Ryf--2]=2 ATS Ie a Nor Lott D=Rale-al=se 486.1. nm ‘Bluish green) Hp anf 3, iz = 5) > a = 2) 0, O CRT = L CTC 4, (iz = 6) > (ms = 2) or, POT LO > ah a TSA GAA AI CIA FACS LA, Dy > eg RS! API TRIAS SAMOA SAAC, Nyy = y+ > caret PAFRCERT n EH TEAR ED, mtn > aCe A en =Ri [2-2] 434..om | Atr(bluey Hy oH v=Ry[S-a]== 410.1nm | craft (violet) | Hs 84 =fFATWA OF AafeH era wipe Gea eters eat | PMT SICA eer af AeA BTCRTA CaNDTT PA RASMASS AAT : < 0.0005 A ef : 380 — 424nm ‘tat PH (y-ray) : < 0.005-1.5A ‘Sm: 424 = 450 nm 30 3A (X-ray): <0.1- 100A ‘SPraTA : 450 — 500 nm ‘afecaof af (UV): < 3800 A ‘ge : 500-575 nm TIM SIM (Visible): 3800 A- 7800 A WPT: S75 - 590 nm {RU'08-09,07-08), SBATARE (IR) > 7800 A FAT: 590 — 647 nm Gales @ OME waH OTT: > 22% 106A | A: 647 — 780 nm 2 cope fort: > oes Grete afta remrnTeT waar CekaeN: HUM TT GS PMA SIMIC AI AICS | ms at, ae we TERR wae aH BRS, ny GHA 6 BM, Beem aah SACS aPhna ao ere aT NRT PICEA OE erste aft fear a, ercoretr fice n, aa ATH FARE rg ny ae aT PRET Example-42. Com 35 ecu CH Mica ACEH RCATCENAATA CHAS 0, aa ATA MAT AIA? [Ans: al [JU19-20] (@NearIR (®) Middle-IR (Far IR (@MRI Example-43. A HY CRA SATA Gla FA OTA AS MPAA TA ALS ALAA AA? [Ans] [JU"19-20] (@) Near-IR (©) Middte-R Fark (@UV-ray Example-44, MRI WG ATICT AAAS aI Face car Ariba Shire zeae? [Ans: c] [DU"19-20] (a)Neon (b) Oxygen (©) Hydrogen (@ Silicon Example-45. 3063 CS S41 Ge @ cat effecares 1S Gare WITS Bea — [Ans: c] [JU*19-20} (@near IR (©) middle IR (© fark (@uv Example-46. G2GaTO ATG BORA, *f UAACA air em aA Fra BIC era wifes aeTETATICS aed Fifer ox wea feta SG FS TH Example-47. COR IH CARAS CaO? (Ans: ¢][RU"10-11] @ siete (b) PTT SCAT (© sT @ a Example-48, SfSrae CrATART ICAI BAT LA AKA [Ans: a][RU°08-09] (@) <4000A 6 >7000A (6) 2.2x106A (¢) 500A ¢ 650A (@) None Example-49. [VAR SIFTS CAAA AH FS? [Ans: c][RU"08-09,RU"07-08] (@) 100-300 mm (b) 300-360 mm (©) 380-780 mm (@) 700-100 mm 8 oftaCem rere PagT Teo,‘AR DF | TETI-02 aa ATR [Ans: ¢][CU"07-08} Omnia — @eaitater aero Example-51. Weird (as ergo By? fE-anfha afew ore [DU'21-22) Solr: CUCRTEAT CoTETBTA FICO Sate wa Boca eof ede Bea AT ae AHA TAHA TSTEAN CAPABT | Rev 3s corte Pree wor Be acta are Ra eT PI | A= 2 (rN A= Reina CMT, p = Rea SHAT] Example-S2. SHa2AG5 (wave length) Ee AT wipe AA AA (electromagnetic spectrum) st FAFEH STA | bball al [JnU"18-19} | Sore: CaMTE: a AGS ER TEATT He etm wat a Aha aA A CHET OAR OT yah 5x 10-*— 15x 10"! nm Xa 1x 10-@nm = 10 nm Uv ah 10nm — 380 nm SP Se 380-780 nm IR 3 780 — 2% 10%nm ‘aiRoRTSTTS 100 um —1cm Ghee etre 100 m= 5m Example-53: IR (Infra-Red) @ FaCMFes TH TITS H Fa? fH eemT cre IR aA TAA BEN FA! [InU"18-19] Sol": 780 nm CRC 2 x 10° nm Bacar aR ere RS aA fofeencren Te: + Near-IR 3%: ©) sfocera ee RecaTeMacA contre freer ERE watce eI eaterra aT wPCeA cae FFA (i) DOT (diffuse optical tomography) ef ee wea ATA YH (Cortex) wrArratS MAN Gil) 7HNEAIS Pres werent ¥S FFA CT Scanning FcR! © Middle-IR #1: “Midale-IR 51 1c Pm CAA IR-RICAA MHTR FAAS Cat FF © Far-IR 3A: () aca ceatet © cart effec of BETS (a) De AAT BoM AG OH ASP ATCT FLA (Gi) Wega META +e EAT A Frozen Shoulder 44 FFA! PONG, c= UA AN, A = CAMA]; Cae ART T Example-54. 440 cafe acme 0a GAMA 0.1 kim | oH ME AS Hz? [KU'19-20) (@)3 x 10% (b) 3 x 108 ©) 3x 10% (@3x 10% Sola); A917, A= 0.1 km = 0.1 x 1000 m = 100 m [1 km= 1000 m] ; C= 3 x 108 mst spore, f= f= Bat = 3 106 te Example-55. Fito HAND TCA HART? {Ans: e] [CU'16-17] @a=2 (DE=me @E=hf @x=crt 5 ” mae Cs a feo ererea Fraga em...Example-$6. a TCTs aPAIR GAMA 1000 nm Re a SIH ALI FB? (TATA MS = 3.0 x 10%ms~1) x10m-! —_ (b) 3333.33m"! (©) 10%m=t (@ 10m" IRU'IS-16] Sol" :(c); A819, SARA A = 1000 nm = 1000 x 10-° m = 1x 10° m [1 nm = 10-* m] 2 ower, G2 P= hs = 1x 108m Example-S7. SOTA CHATS OR SAE Ans: b][RU"07-08] (@) HARTA (b) saree (eo STHT @ SPR Example-S8. FRAT Mg cece Fivfe err aifera WAIT 662,6nm 1 ceriba aera ie Fda [h = 6.26 x 10-4Js} \ 81, A = 662.6 nm 9.626 X 10-7 m [1 nm = 10-® m];C = 3 x 10° ms“? | 10 2 1 x 1074 x 3 x 108 x 107 662.6 x 10-? m =3 x 10-487 = 3x 10-19) Ru (G+ gz) #9, Ry = 1.09678 x 107 mot Problems Example-S9. Ryy REM ee Rey, GROTTO Ah ara Pier aw MCA war BS UA? (DU"2-23] os Oram om Osim Sol: (b); AUTH PRAT BUA HT, ny =n, +2 =24+2=4 [aeer,n, = 2] 3 aa 16 dery(S-3) erage .09678 x 105 cm=* x e 3 Example-60. feat FFF Ry Wal Hert Fal Ver, VRE eas Ace aM Phices wT aT se CAT Reo ahr Rfehre ex? (DU"20-21) @ Rn @ERu (© $Ru Sov 55 = Ru (Ge— ps mL = 25 AAR OMT COTA OT My = 5 Example-61. @RCaTCRR raga WR (Hydrogen atom spectrum) CHa AAT PHA (Balmer series) afta Fret rae whe Oa oe Soo (JnU"19-20) Sol?: wars Piftcera 1S: TS H, SY Se H ATTICS Fw 1 Ga Ha ORR ORTEGA Rome fear care a BAP we fen Barrwea Wer aT ime ea Bem aan Hm aT Fafen Oe “feara ao “fea feat eben Faea Meer ACH BIC! auics Bawa ites Ke BETA TA SAT TCT TCA A PASAT Sem OH RTT ITH GIST, OIA ae aera Pifrers arate Fifer aT PS: AATF, ny = 2 [aaa Paste] ; 2 = 1 [Haag] ‘arma ara, Emax > Amin > Ba =©Example-62. (©) BRR erat sew ror 8 eR cas TATRA RCM AA ATCA PH RCTH BES NH IE Ae wantin RATA Gi) BR TRTCEs Fafa aifhre oI aie mfeA aT Crs Sol": Areal HFS, Ry = 109678.cm™*, z= 1 $69 apihan ges Ru Xap 2x = Ra Tg BRT Or aa HreTOH rey a Fe AO Bae wer aye eet Te HALE | SC: ATT HAM ASA TT SATE RTS ITS OTH HLTA WSS FACT FACT Fe MST MAT) aT COR ATIC + om BR aT erence ee x arr ae eee Bonar AT ett wa EAT AA, tee APE A TT HG eft aT ATT SSAA HTH (TPT) 10-7 AA CHCA CRIS ACF BI AA oe ET: ‘BARE ror 9 Breet HTT PHAR cara AE ALA OR HA HANGS MATE ATA ae AH AT IC EAT Pe UCRE HI STSS CI, Bea A BAT YS HAT oP ae: ARB Horatio CHICA FAB TTC BAA ACA WORE UA BRET MATS ee, AA Cie CeCe TT ET BAGS ACF, Wes A BACT SIMS BATT + Siew aa SAAT INA, CHAT TAH ACHAT BA BAGS FAA HT OS HHL Ol CHA 1A IGA Stor A HR STAAL G& det Bact ATMTAS TORS BA MTP Sel CALS APM HA ACH aR ETT oR TH BATT OST (supersaturated) B44 70H aR OBE Hae UA A cHMITHIAT (seed crystal) CUM A WGI SPVIATTETA OBC AS APOC TAs TO OF FAI arvet: eS ACT AA MTT A HIATT WOT SEAT, oie FARE CHerTOTE ALAS AG sit BA 100g BACH Bigw AHS THT Be HEH SH ceHTT HUNT OTHMAN Y MAT 2 MCA ATCT TH aE wat STR HHS ROS MT TATE ST TTR MAES FEMETCA MTA BA ( g/100g > GaIAa: a TaFETS aS 100gm BRC# BAGS HA ACT CH (g) CF BTS ATT @ ae: Aateeg TR Toop Fog 6 Example: 100g *IFce *C41 36 g NaCl BASS AS Aiea, WALA NaCl aH HIATT 36, @g/L > (Ga): AR erator af 11 Bat BATS eae ACA SH (g) CH BTC TM eS: ght Example: 1L St 541 AB "a4 50g BES Be MAC, AB ATA ETT SOg/L. (i) mol/L > (He: aE RASCH 1L BACT BAYS AAA A A ARATC BITO AA AA: moll“? TM. arene Frew: HRA aes | + oak ace aay eras FoR fon FO BCA BITS fen FEN comer agts © COTS RTS (SHPTE TAH @ WATT BATS) CS STA CAI HAS BT 2 SUSIE CMH SHICRTRCA ST LMT BAC HAA AT TAT RNS AA APH AT © Cea iar ena Se FAC Sree a aa maT RTS NaNO3,KNOs, KCI, KI, AgNO3,Pb(NO3)2, NH,Cl, NaCl Semthi1 feSirs: 32.4°C watery Ferfte zy, wee: wera t -BtaTet 1 © 25°C WInatay NaCl 4 BTS 4.558 ‘mol/L. i? © Sreoneennt Fafaea werent gh Sa Brae Hera Braet ates her ls (orn G44 CAM WA Li,S0,, NazSO,, Ca(NO,)2, Ca(OH), NaOH Zentrs * Uo FA (NazS0,.10H20) a CHEM SreTS: wremTat t= Bret T, s+ © Diet gfe SALT ST Head BTST MITOTA CATS AT © Biba 9 ware CREM DIC eTETE EI © ceaftar pa: fs ornare FRB OTTER CO wae ATed CHTCAT SOIT BTATOT aa Bora om SEA AUTEN *Sa GFF : g/100g H20/atm 4 gL-tatm— at molL“tatm-* ‘ibm Alera BITSY SETTTT: He ATETER LisPO4 Nap HSb05, ‘sremtara (WHY) BEN KaNa [Co(NO;)el.Ks[Co(NO2)e] RRGED (NOS: ete es ern reece Bi(NOs)3,CH3COOAg GRRE (CI-) GaraeH (Br-) fire TSR Pb?*, Hg?*,Agt, Cut wat aifde cer SICATSTEEA (1) 7 Pb, Hg’, Ba*, Ag Sr? Wal ae oe a G@hPRR, caso, ofS aT we ‘BCI (COP) LizCO3, LisPO, 2101 71 es (rot) =r eT ATEN Ee 90 Cranyt SH MT Te) RETHRET e eraree |e AEST NH; Ba’ [(OH7),0?-] Sr?*, Ti+ Tt Seyey ‘aIPRaET (S?-) NHG, 1A aa 1A aPTR aie Tec TERRE (S03) SFt1A 6 NH Gt ‘aif ere Si a! - “Biden acre ar wo.. + . ‘yentiin engn ears Rea BTC we: Be(OH )2 < Ba(OH) ee ees SAN 5 0 pas Da exer ann ane fb fatto Woat frre eT Werte age weed we aes BIOTA wT: BeSO, > MgSO, > CaSO, > SrSO, > BaSO, BeCO; > MgCO3 > CaCOs > SrCOs > BaCOs BTS OFA (Kp) RB rer we AA MAC HME AT ME TS OS STA MAT AT, TCA TS PTAA TOT SAAT TER HAT LETH 1 ETH LATA PATA MITE OT TT! ATS OTE OPT AS HAT ST MATCH | GIR aA BACT CT eg TCT OT FCA BTS @ BTS ote: (@) BRT + BrTET oe: MNy FRU CEU FPS HT, SATA TAM, [M* Jone = XS oa oa SOAP SAY, [N*Jeate = yS Kp = (xS)*. YS)” @ [Ksp = x*-y’. (S)**7] Gi) FIAT TST TAS BTS, BAT ote Se AMT (ii) Ae HA IAA HA ARCS AA FHT ASAT FR (ii) ALM DAIS CHA 'S* FS HA CHTAR mol L-t | (Ra: SEHR SB eraIcs ak DPcea AAT SPA ASTI SCE] (esr eters: ACR (ii) AE FL AN TR (i) FE LH ANG FA ATS ANI FPS BCT SPRINT FRC ‘common Ion C# FACaPATH AMOS REA | CO: @ 0.1M PbSO, Batt Pbl, a Brave Ffcae Crem, [Pb?*],ae = 1S + 0.1 x1 (PSO, HAT zs) ees AMX GLE AATTATAT EAT) [aie = 25 5 + Kap = AS + 0.1)! x (25)? OL HITED VILA HA FMI FATS A (i) 0.1M Mgl; Batt Poly aa wrTer Fc CEM, [Pb?*Jeae = 1S [I Jeate = 2S +01 x2. [Mglz 441 TS] 2 Kgp = (1S)(25 + 0.1 x 2)? SB SHTTHON TIAA HA TA FACS [ox ree GAR oeStrnra sererqeriba Fars oH aT SAS oat a MCA ete PTA ASAT HR] > HATTA SPST A CHM HA PATI BITS, MATS BTC CocH Ha BT ‘ara eee (Kip): rather ester Bee Braver ectwCeTA ACER, Oo MT RHE AT OT HPS SAEPTE CHAT SATE wT FAL FAUT GA Ky ATAPI BE K,, MAACO ANAM, Koy, Kip a ee Ce TT gen BAA Aad PI, A ET- Kgp = (Pb**Joane» OI Teare Kp = [Pb] (FE [Pb?* ga = AS SARIN PL? et WT Sempee R [- TATT CSE CAC Pb? aT TATRCE Eg 6 Bremer A: carat wiper meta weet ahh ‘FARA OF 1a : TRIT-O}R Kip > Kop | Wa9 ctw oa Westie Sar PH ETAT OTR (Kn) cM een oN eeEReG ear Kip a Ae Coral de? {30"22-23] @i ii (©) iit @i,ii SolP: (©); PoCl, SIRF creat Git Fhe eiFice Anta iba MA > eR mA we PoCl, Aher afFCw ‘senet fg sa ace outa Ber a a aber oT woe, Va > MMB es Re Rico Example-64. otfCe UTAH Re TAA BTET Faw eH CUT? [Ans: ¢] [JU"22-23] @ Brie bt a (0) SPreneta my Fa I © rrr @ ates Example-65. FR rsa 750 mL IS BAT 200 g NaCl BAGS CHER NaCl MAAATET gl! a Fe? (@) 166.67 (&) 366.67 (©) 66.67 (@ 266.67 [Ans: d] [RU’22-23] Example-66. Mg(OH)2 “1 BITS G4 2.0 x 10-22 (BAC pH 10 BT IS Mg?* at WRKAT FS mol /L2[GST? 20-21] (@)2.0x 10 (©) 2.0 x 10-9 (©) 20x 10-2 (@) 2.0 x 10-7 Sol":(a); Mg?* aa STATA = x ‘SINaT GI, pH + pOH = 14 = pOH = 14-10 > pOH = 4 > —log(OH-] = 4 > log(OH-] = —4 > [OH-] = 10-*M. Mg(OH)2 + Mg?* + 20H- + Kp = [Mg?*] x [OH~}? => 2 x 1071" = x x (10-4)? > xx 10-8 = 2x 10-11 xa 2 = 2 x 10-1) = 2x 108 Fr ‘Example-67. M2X, @4C*4 BIST 1.1 x 10-?moll=* WA Ky, FE A? ‘[KU"19-20] (a)1x 10-1? (b) 1.74x 10-® (©) 2.1 x 106 @6x107 Sol”: (b); MpXq 4 BIAVET S RM Kgy = (25)? x (35)? = 108s #10855 = 108 x (1.1) x 10-1 = (1.1)5 x 1.08 x 1078 [AT option (b) aia HacbcH Mere Example-68. 20°C CITA 6 0.98 atm BIA O, CAT STATS FS? [20% IAAT O, TIO CAAT TE 1.38 x 10°°M/atm] IkU'19-20) (a) 1.3524 10-M (0) 2.3524 10-°M_—_(¢) 1.5524x10-7M (A) 2.4524 x 10-2M Sol®: (a); SPAT BIA, HAI, S = Ky x P = 1.38 x 10-3 x 0.98 = 138 x 0.98 x 1079 [0.98 Heep 1 LS cad IR Baa 1.38 cacw cio] = 13524 x 10° M (Notes wee mesa ect Te MAR AI FATAL ANITA WT A OTR MAE TATA CHEM WAT 8 OCT weiicea ora cnt 4B wee wie estecH wire aerCE WAS AE 4 Ta TT] Example-69. 50 mL 7°YS BAt4 Sg CaCl, Wie POT af CaCl, MA BATT FS? {JU"18-19] @) 10 gu (b) 100 gi-* (©) 101 gL? @ 1011 gt Sol": (b); 3 x 1000 = 100 EA | atiremnwn |PATA D7 : BRNTT-03 Example-70, CaF, 8 HVE 2.0 x 10-* MIM fs Kyp FO? (RU'18-19) (a) 1.6 x 10-14 (b) 3.2 x 1072? (32x10 @ crear Sol": (€)5 ICH, BATH, s = 2 10-4 M ; CaF, = (Ca"*) + 3F- ksp(CaF,) = [Ca2*] x (F-]? = S x (25)? = 48% = 4(2 x 1074)? = 4x 2? x LO4)? = 4B x 10 = 32x10 = 32x 10-8 | Example-71. oo eta Berne Boat BA CAA Cag(PO4)2 | ATE OTA FS? (Ans: e] [KU"18-19) | (@ 278° (b) 1048° (©) 108s° @ 20185 i | Example-72. 3% PTA 75g SAA NaCl aa aS OE A (saturated solution) 20g NaCl BAS wees SIRT NaCl St STATET (solubility) FE? GauHs-19 (@) 4033 (b) 39.22 (c) 36.36 (@ 26.26 Sol": (¢); HIVE = Wt — #4 = (75 - 20)g = 55g 55g BACHE Bea 20g Ig Sace aeyw wea 22 100g Brace Wye wa 2 x 100 = 2 x20 = 42 = 36.36 g/1008 i i irene sme ove crt epee xt di? 1 FGA BITS Gee TI SE? (x? @ae (@) 2x? Ans: ¢] [RU*07-08] SoP: (0); PbCl: «. = 4x3 (Ans) ‘Example-74, 30°C STATA CHAT AACA BATS 901 SIMIAN 170g BACH ACK 70gm Hat BASS FIT SIRI FTE BAAS YS PALS Hoa MAT ATATOTA RA? Sol”: BATS 90 A, HA = 90 g [Seal MEE OMA MATH 8/100 MF ALATA FACS RA], ITF = 100g 190g SF, 1905 ATC TAS EG 3 1g REINS TA A 2 170g Meet Wy eA x 170 g = 32x 170 = 2x 170 offic rac “fiat = (80.53 - 70) g = 1053 g Example-75. 100°C Sr*ATH0 700 gm KNOg at 1S HTT 20°C wloratana Ste ea RCH A ova mat HTT “Ra? [KNO, 7 BITS 20°C @ 100°C wr BeTaPCH 20 eae 250] Sol": KNO3 1, 20°C CMTE BTA, Szorc = 20,34 = 20g, BA = 100g BRA = (100 +20) = 120g 100°C CITA BITS, Syoore = 250, HF 250g, BAF = 100g = (100 +250) = 350g BAT 100°C + 20°C AR, CPMMPTE FAT 4350 g PACA BA Cac ComIPTE AAI 230 g a Lg mace He caer comthre mast 22 8053 g 250 - 20) = 230g X 700 = 460g 350 2.700 g Bete Ret cae Com wae 222 18.2831 Shorteut: CP*MPAS 74 MT BT CUM = areca manag * OM STS BRC 230 = (250-20) Bo 2 coir erat = 25224 x 700 = BP x 700 = 460gRRR ‘WANA OF 1a : TAGTT-0% lereg raft we Roe TATE, CHES ot OT a MBE AT] Fara ate rer nth eT SAE FRE rac Hor STTOCeT aT PT sear a MCE sf ren eae. eet ee (eg, Cu2*) 6 ET TH (eg. SOF) | ‘ra eet FRCHFET (Qualitative analysis) Rn MCA TA (OTE Ab) @ wt re hey yee ATES 6 SPA CTIA Meer Tay af Li Cee ay, fiers Teer at Na eet aT eT SPA K aeti Rb Are rere cs _ ater Ca Roa TTA a4 (RTM) SA ‘Sr eget am, fT Ba SST YL BACH ICA KzHzSbz0, | sare CAT Be @ Mg Fiera corer af 8 aca at erat Tara CR, wratent “Re cat wR Awa (Ea?) [cv'20-21) oe (orbit NagH Sb, 0, a FIAT ata erases Bee fe HR) GIT FNS Wl ae | Na*(aq) + KH,Sb,0, + : | oer ‘ions wat Beef | NazHSb20, + 2K*(aq) Sree Fat a TS a UST BOM ST aS Serre ee Tar ones Fe(OH)a(s) + NHi (aq) (corre) Rt oe ‘eral Fat aoa Gat Beery eT Kq[Fe(CN)6] Beet cart wate | Fe?* (aq) + Ky [Fe(CN)e] > KaFe[Fe(CN)<] + K*(aq) ATTCS TATa aoa wre. coRM BEM A ESET OE EST Ye NT Gal ENCORE 3 FotGe e NHg(@q) Fei+ Tae eH ifs ong Ate aca Bat Bein eA (cafe ore) | Ky LFe(CN)¢] Bart cat wat | Fe>* (aq) + KalFe(CN)g) > KFe[Fe(CN),] + 3K*(aq) re Sores Fe Wha Eat Bey aT STCUTATRTEAD BAA CM at BA | Fe?*(aq) + NH,SCN ~> [Fe(CNS)_]**(aq) + NH (aq) I ashe ae AREER eTOTER PAGE TOM...BET ERCT Aca ICA NHOH GU | ong er ace HAT BAH A WaT Wi HGF NH,OH CATCH | CuSO, (aq) + NH,OH(aq) ~ CuSOs. CUCOH)2(s) + Cur+ BRR BASS AT WH © | (NH,)2S0,CuSO,.CuCOH)2 + (NH4)2S0, Cras) | ofa gaat Beem eA 4+NH,OH(aq) ~ [Cu(NH3)4]S04 + H20 Ea Se aT TRA | reco TATA wef rae Beet CRCAPATRTATR Ca we ATA__| Cu(NOs)2 + KalFe(CN)e] ~ CuslFe(CNe] + KNO, a ART eT eae THATS NaOH Bat cant ea AT NHy Sagas err Rare writ cle ee comenfaary: Fara GPT i: WHYS | NH,Cl-+ NaOH - NaCl + H,0 + NHs ao (| NaOH/KOH +) = *1Rrarr Nig + KzHel, — NH;[Hg2l5] + NH4l CONSTR SETAE (KeHgly) Gore feere wi + MRC one Faceted araae sre fear 1 | Pb AYHCI PDCl2 CATA) PbS, CuS, BizS, Hes CTEM Sn?*/Sn** As? ca? MHC aa Befeferw HS | Cds,As,Ss,SnS; I), Susie Sn carat, SbaSs CFM) Fe(OH) (TARE ATM), Al(OH); a_| $u2*,Pb?*, Bie*, Hg’, sb, aL 7 7 NA | Fe**, AP NH, Cla Sof@fece NH,OH (cath sr17) = 2 NH,Cl¢ NH,OH ZnS CA), NiS CICA, CoS IIB | Co**,Zn?*,Ni?*,Nb ie if asf Iv | Ca?*, Bat BE ieee Caco; BaCco. a, Bal Betexs (NH,),C0, a CATT), BACs CHAT) V_ | Nat, K*,Mg**,NHZ AT Pn Faas AS ‘Nat, K*, Mg**, NH aa Ct Example-76, NH SHRCAa Cafes ftca TaaS ee wn [pU'22-23) iaOH (b) Kg[Fe(CN).] (c) NaOH, Kz Hel, @) (NH4)26204 (o); NH STA GPT ART (Ka Hel, aA Has) ate ea ce OTM AIRPORT CCE ATER “arene Tra TR PB AA Example-77. ort fears B17 [Ans: e] [CU'22-23] (@) Heale (b) KzHgl,, (©) K,Hgl, + KOH (@ KHGgl, + NaOH Example-78, CHAT 1G PAT HAC BaCly BIT CUM HCH AAT AACR AGT AT HCI(ag.) od BBS VTA AAAS ‘Fipgy PSP CATA Rape AF ones SH SET AAAS SP IGST ee 20-21] (a) CuSO, (@)NazS0, (© NaNo, (@ Cuno), Sol: (b); Par sFaPeT OMT Ze ae > Nat BaCly CATO AIT SUT @ HCI a SHAE + SOF « CAH NazSO, Example-79. Frees Gert. Pan ater a4 TT AT? [Ans: e] [CU'20-21] (@Na Ba (Mg (ca as sraac v ‘FARA OF oy : BeNTY- Example-80. Fa COR sta ara hire aie 6 aR aficeH xT Ge FACS TRA FAT AA [DU'19-20] (ay arent Fore ica re (b) Creme BCA eB CATE (eo) arrears Fer caret (A) cafrars ARGS Bae care Sol": Ds HaSOs + BaNOs ~ BaSO, | 4 HNOs + BaNO3 ~ No reaction (white bp Example-81. C1 B44 Gat CHM SOIR “ATS war UT? [Ans: b] [JU"19-20) (@ar* () NEE (©) Cart (d) 2n?* Example-82. Ba(NO,), B84 Oa GHA COATT MA aT ATA? Ans: ¢] (JU'19-20] (a) S0;?,cl- (b) CO5?, NOs? (c) CO;?, $07? (a) NO52,c1 it Example 83. toa Gem ORR fa WAN Bat aA? [DU'16-17] (a) Ni* (b) Fe®* (©) cu (@ zm Sol": (@); Zn 3 COPRR WHR Bet VeRCH ATA @ 34H) Example-84. 234 Cu?* GI Ha ET erate (Ans: a] [CU'1S-16) () NH,OH BR (b) AgNO, Hat (©) BaCl, Fat @ orn zat Example-85. FSI 808TH CR Tet GTA ze Firat eos aa? {Ans: ¢] [DU’15-16] (2) Copper (&) Chromium (© Sodium @ Calcium Example-86. 216 OME AAC WF HS0, 4 BSC FATA ehh catara Beatie cara oraAa Bane Peter? @r Br ar (@F- Ans: a} (DU"13-14) Example-87, PTS UMTRCET SUL ATC NH, OH TMT Bae HERE At Fantge a, secretes (@) AgF (b) AgBr ©Agi (@) AgCl__ [Ans:b] [RU'13-14] Example-88. oe 3439 SAH BAe GH HAI CA AVA HAAG ATT aay ae TA AAR ARNO; BATU aT a aa THA OTT AT HATA a AA acAICE- (Ans: dj [DU’09-10) (@) Nac (b) NaNo, (©) Nays (@NaBr @ Rereera AS SAAT mur = 2 (n Gi) feito “fe, AE iy cobra fe, E = nt = (iy) SRB Re wate ahaa, E = me? (0) e-antta oar ater, 2 = 2 =" Ip = my = aefiee eacer] (caren Stang] ae mur = = JTF If (h = IRCA a = 6.626x10-2"J5] hi (2 = cramer sea, 2 = CARA, Ru = fwarf eres = 109678cm-1] (i 34 cra et = a= NDina=mt) (vill) Cra FoKce Bera ri, v, = VE = et VisomiFe — 2nney (Gx) cra wrereer TPM, ry = EES = 0.53 A xc eae cata wR CaS“, SEBS = -136ev x5 Hi) \ 8 asa ROTH PGE TAO...EE (er ey (3) SAR were, Q = [ORCA ace BINA [CARAT BAA ATT BRTC oH, Kop = PA aCe BTOTERIMON NN x HR ATA STATA I Perit @ STATA TATA HOTS HOOT HTC A FACE A] A: MpAg ACA CORR, AM CA MAC TATA ST ALN ATTA ITT S mo /L AAR CH CHP TT ‘FRAC VAATAT S, mol/L RA Mpg = pM + AP ps aS CRTS RTT CR) St PS QS, (A CHT BAC CTR) = (Si)? x (GS1)% = Q=pPx atx sir] t [imc cs ayaeracarr) Kp = OSX] fk Kye phx ate a 01. Rea St @55x 103g () 10.7 x 10-”g (©) 9.1 x 1077%g (&) 9.1 x 107g, 0, rma ae Bearer we Frew Brae cara TN Mee CIM AS TALI TTAT? (@®n=1,1=1,m=0, and s=+3 (b)n=3,1= 1,m=-2, and s=—} ©n =1,m=0, and s=43 (@n=2,1=0,m=1, and s=+2 03. Pee Pifacer 4 mrcre fB eH? (b)n=Ston=2 (@n=4ton=0 04, OTR CABIB a RRITTR RRC? (@ Mg?*,Ca®*,Sr2* (b) F,CI", Bro (©0*F> @ Ale*, Fe**, Cr+ 05, CER CaTAAER cent HT SHR (c) FAR CHB ACSIA FTA? @H Ht He @Hy 06, BC PReTcbIe FEA ART Fe? @6 13 7 OGRBRAT 07 ee aa PGE ee TAT Fy terme ee Fen eT ACE BY ae? (@ Sree SRT Osa @ area 08, MC ae aes a (0) expert mars HH Fata (b) fata sar Frat (© ra foFeoTT @ Weare afer cat FoF 09, SUTRA 2p cre 3s FHT IATA LAT CATE AP PRATER (o) Raho“ (0) core at SARS AT (0) AR A HT AT cikes2. 2, 25, Bi oS ‘SATA DA AT : TRAT-O2 25°C IATA BaSO, 1 HPS HAM Ba* ea WATT 4.0 x 10-5) AR AAT BaSO, ia WATE OTM Kyy AR moPL? eer (a) 4.0 x 10-5 (b) 4.0 x 10-6 (©) 16x10" (16x 107 =. OR SATA PS TS (11) GAAS BATA WANT x mol mS | area BAS eR A @x (b) 2x3 (4x8 @ 208 am Cerio ay Fora? (@o @s ©P @) He . Mgo ra orate Bas eo @ aa () a ©@er @ teat HP See eat Ca arr af rN? @ oa ©) Cra Cac @Ore GR Te gO Atha eae ea CHICA AF HAE BCH A? (Na Ca cs @ Mg NH, STC HCL are erat Fre aed store Hace @) Fr cote HB (b) arr cata APE eT (©) Fre cata RB @ @rbe ar Na,SO,. 10H,0 9% BITE 19°C ace 40°C aa AT @ ears ag OTe ay (©) SRA ATG, HAA FH @ are aT Rca Fafeatecena wear corfta sft Hacoee caf? (@) infrared (©) visible (©) ultraviolet @ microwave . Dial GE Gca Fos Draw acta SARA HAT STAT SIMATENA GAH SETS BCT eat aca OTA oe PR sree ora Baa Atereca? (@ Nacl (©) AgNO, (© Cd(Nos), (@ ZnS0, . lamu=? (a) 1.056 x 10-**gm (b) 1.66056 x 10-**gm. (©) 1.656 x 10-2°gm_ (d) 2.66 x 10-7°gm |. Rew carat 1R aia Tae AH? @at Beet (0) Be AS caTpr aATTATA BAT em (© sre Ree (© TERMS Ae DADA TERE Crea BPR Ae ANC CATA Cea BTS BG? (@) NaSO, (b) NaOH @xI @) Caso, ATR ACSA CTA DE Mears Rear Ae SATA FS? oz oz ot oF eh her stonbrrnce wn fem ace (@) sr eT (b) RAMA RAT (© canta Feet © Retr ret ale FMT EH FEE AP (@) cea Cara wy (0) Brora ses wy (© SraceraIcrs wise aE wy (@) “era ae BS ARTE ereyeH PAGE OT...SE re oer 26, FoR core raf ROTC Neer EH Ace CH? ed (b) 5a © 6 @7s 27, PRTC tang Rema, Me aR A ee we Frc TT we MAH CANTON - (@ are ater () ers ehh (© ama aie (@ sores ae 28, “are ones aR ae Hf Rem TT Ta a ETA AAT PO FARTOAA RA aS A ow () rt (©) SPOR @ a 29, Cora amt erat ere? @ RoR (b) a8 Or (@ rete 30. 3d WaRGTera Cran EHR COTE OTH AeeIT | Mia ATT FO? @2 @)3 @1 @o 31, SOCSPOTET ART N FACS Fa (@) 6.02110 (©) 6023x102 (© 6022x10 (6) 6.02210 32, gait Reread of ee ery? (@—Lsxt0-* (b) 1.6«10-° (©) 10x10" (@ 1.0x10-° DTI: Ts CoRR TTeTCRB a aTRT AT AT oTceT Fen areca ATT A aOR AFA BRIA BEA TM AAT BTS Sa SHR REE TR AR AE FHT AT RMT BT AE HTC HE AT PT HE FG TAT HES, CT areata aR eee oD ade sat h ae FARR ETE wT ES ARS ew ote Fey AIA aI Cat FrohT OH RIT h FIT AAHCR AR, TT AP re: MEET 4] 33. GRTCAT OCHA FATE 6 x 10'S? HY, CAT ATH FS? 34, GEV AGTH SACHA HHT S x 10%s~? RT aT TH a AS FS EA? 35, cern For A: (i) Cr (ii) La 36. Cam cele orefacs fafer reece saat 4C = 8%; °C = 7%; 7C = 85%; CNG TANTS CAFS? 37. Be eae Mg frat Rare Corea a4 CARLA CPA? 38, RCRTCORA RAISES SOA GE CO HF CCH OH CAT BOM ATH HOHE AM IMT NSH AST A? 39. Na2SO,. 10H,0 «8 aravers orafoa RCsat FH 40, 30°C 6 55°C TATA COTA eeeAE CAR ATTOT AACA 50 901 30%C STATA 50 g HAMEE 55°C CIARA Ble Sar VT a TT BAA AHS ALS A PS A OPO HTS A ATHTETA BLA? O1. Ans: (€); 9.1 x 107g 02. 03. 04. 05. 06. 07. m=0,t1=0,41,-1) s=+3,-5 = 2am aa BE mR n, = 2+4=6.n=2ton=6 Sol: (¢)s O7- A Ne et ReeTaRA RUPT; Fo A Ne sia ROA FETT 5 0 FI Cab 2 Bi He « Cano 2 1 : (es RAT SH, SATA — CHA AAT = MBIA ALT "2C a wT 13-6 = 7 Sol": (c)s HRCA = cea Mee AAT! STRATA = RED MeO TAY RETA = SA ANITA SERIA ATT TT EEA = renter)08. 10, Sot; (a); FYE EAT LAH TAAL HA TTT ATR, Ba ora WAKA 4 x 10S CETTE s = 4 x 10°F molL-* BaSO, = By’ + S03 Ksp (BaSO,) = [Ba**] x [S037] = Sx S = S? = (4 x 10-5)? = 4? x (10°5)? = 16 x 10-19 = 1.6 x 10-? mol’? 5 YS HAA BCAA VAS Sia HIATT | + PbCl, 44 HIS = x moldm=? [1L = 1dm*] PbClz $ Pk? + 2CI-* Ksp(PbCla) = [Pb**] x [CI-}? = x x (2x)? = 4x? RePrery Boa WS AT = Ca, CATA RH = Na, eh = K 17. Sol: (©); NagSO,.10H,0 4 fGe IAAT 32.4°C FSA, 19°C WS 32.4°C FS SrrraTal PACS a BAT IPTA aR 324°C Kw 40°C Fw WHrTATT yPlaTw aH BTATOT A Area lraviotet AENOs + Cu» Cu(NO,)s + 2Ag 20. Ans: (b); 1.66056 x 10-**gm ‘SIROTA same,tope — Ceid> Isotope > Proton same; Isotone ~> neutron same; Isobar -> mass (5% same) 25, Ans: (a); 20Cea oro ST 26. Sol": (a); Rrerelicrra ~iferecara ~Reatat (n+ 1) STA SFR Sa A AS AAA A SHC OT He ATT (+1) AH AT ATA SCA ATA nT ATH A TRA @ ICM TA HCA 4faReaR (4 + 3) = 7; Sd fUTA (5 + 2) = 7; 6p “AGATA (6 + 1) = 7; 75 “RATA (7 + 0) = 7 FAST AF ROM € SICA AF (HRY 4 A n GAA ARCH FH) SHC ATM PALA % 27. Sol*: (b); BRACE ANS VTRTA AS TCT > sauce fora epics areata Pater > ou aca feta wet — aaa Fis > on ara firca cre — orcs Paftet > ad aca firca oree — areas Pare > C8 6a feta SPT > AT 28. Sol*: (a); fra sein foe cera wae Veerey ATR | ear care orm Ta FT ewe ora | FReaIAT ew ATCT ere orca frre aif eet Fe 29, Ans: (a); ere 30. ‘or a, s=0,p=1, d= 2, f=3 WR 3dcwl=2 31. Ans: (d); 6.022102? ey mol~? Ans: (a); —1.6x10-9 32. B fi ° oe crore PAGE TO...34, 37. 39. 33, I, NS, f= 1 x 104 s-* ; h = 6,626 x 10-4}.5 = hf = 6.626 x 107% x 1 x 10* = 6626 x 10-7} i) Cr(24) > 15?2s?2p%3s2pé3ds4st Gil) La (57) + 15?2s?2p63s?3p%3d094s2 4p%4d?°415s?5p5d6s? Solv: Ca aes orrarga s1g a = SSAA 47.23 a mun Ca NG TAT SA 12.23 amu Solr: Bee Mg aa rar ore ea ATCO Roa VET BRITS ACH Be Mg ae acme eras Bows “foraca eter Saw cw oT AR eacHTETA RH, SIT SMTTAR TTT OF ART AAS eR aT ‘AT SIS gat Fret ofits a4 one at Sol*:n, = 24% n = 6 ‘STRAT eR, wi cree me = HEADED — ENED - 19 Sore fon arc araereferecawraa fa m CAT CR 32°C IMA BPTI FRCHTH SRS BA Ae 32.4°C wrvatais Gore CHT Braver Rea Ate RPT CS ACH | TAT 4 WHAT NazSO,, 10H 0 Be Coa PT ES RCH A ae HAT NazSO, 4 “aS AAA Ma BATS APA US AIC Sol": 30°C WIHT BITC, Ssore = 50, BA = 50 g, BTR = 100g = HA = 100 + 50 = 150g 55°C CAA BIST, Ssarc = 90, 4 = 90 g, BE = 100g FAT = 100 + 90 = 190g SPAT 30°C CALF 50°C 8 TAT RIM, 150 g Baa wT Bfwite we acHIER (90 — 50) = 40g 1g FAG orn af hire as erate AS 2.50 g 150 g Baca OU Ufo we eae Sx 50 = 2 = 13.33g Shorteut: FR aI = eS eg MM ATS RTT ON = 121 x 50 = 2 x 50 = 13.338 750 150 sé ap BY TATE HEY RATT AL TENS APO FT ARAAE ATES O00 "A ACOTAETE en erate, ore UBT TOT ent ReracT Rec cea ae See ner ona eaer aeeara Rear xe ARTEL A EAA TAS AT A We? ‘Michael Jordan e3,WHA 3A : TA-09 Periodic Table of the Elements ce ‘3i ‘a ‘aah ‘th i ‘ah Ell ali GU aii aH St * LU 2 gh oli, 2h “te ‘sh, eh eh att ‘ ol gh 3h, sh ome >it 2 elt ak AUST HAT ATE, AIC OTA MHIP SA TS OF Tera RATS Sea ACSA HATA AT STR Fag ace aca pT aa A RA aca Far ot 9 fea chee erensfae Scad wR ait 2188 FS at coir erat) Conaattara (BTA) dere dey mii deseMRCS TCH MATTE SHA TM TAC ANTE sees wr Reors (Ree) ew HA AA, CH TAT TT CR OE HT HET tH Ss o arraa oa PAYS WH fafa crcretne Cat) cha Bora ere ATT dew fie rata ene) | TORO Tere aTAAE yO, Grier rece oer | CATT eR af PAT RATT + MARTA: aa ARR Cer awe ARCS CaCe I HAG ATH BHT BM FAC CH TAA COR RAR Ss TARA aT (BG oraer ara cates + em aTARCE AACE (i) ATCA ordre iy STOICA Ft fRure15) + ere IaRCS are Fre core CMC STEHT (aufbau) FHS SEPIA [(n+ 1) FRAT ATCT TATE afar RTs etc FT RT: 1s 25> 2p > 3s > 3p + 45 + 3d + 4p > Ss > 4d > Sp + 65 + 4+ Sd + 6p 4 754 Sf 6d > 7p 0 Bers ort sepia Aterrycen bral ace Ort sat ee aeae ea oat frema: @ saa: HR CHA ARR TCA S! TAT s? ROG FATT IC aR ACT SCHR s AAAOTCT AT PTT ATT SP 1 6 26H NPR AR He 4 AFA ILS | SACHA Aa AAT EMM 14 $B [JU19-20) SOFA MATE TRA FRMTPH CHAAR ELA CHEM): ns | ARI n= 1, 2,3 Ror RA te STA ‘Fropre att (i) pat aia: 74 Tre MHATCS AOA STRAT p SARA AM TAT AAA SFH- 13, 14, 15, 16, 17 @ 18.SFCT He pOhe GMP 4 ARH HOLE | 4 IGT ARN SMPTE Nh (113), FIL14), Me (115) 6 Lv(116), Ts (117), Og (118) 4R AOA p-AS cara EAT 36 11 eer rea Reeras Fear OTah-g “fewcAT CRM: ns?np"61 QT n = 2,3,4,5 ee REM ster aE ME ATT (iii) dF GH: dre rat SPAS CH SF -12 EG CTD 10 1B akc dae eT aR eeTe CRcera Bera PTT TACT * gare d ARTIC Steet Fa MNTATS AF TPT SARTRE TAT {5U"19-20) dB Gera FAT CHAT (goTh) 6 CHTTAAP TTT (,12Cn) FE AIS 44 11 are SreMTeoS FARR efrerca carers ~Rraca dt ace d?° RETR MICE COTA: ‘Sc(21)= 1s? 2s? 2p® 3s? 3p® 3d! 4s? Fe(26)= 1s? 2s? 2p* 3s? 3p® 3d° 4s? co sa Rea POT OTR SU 8 eH ER MRT RTM: (4 — 1)g-10 yg? 4 aaa n = 4,5,6,7 FASerene cere div) fa Gite: sre ara oP 3 a raf a a em ReereA FROTOT acre Rema FeO ec aa Tt Sra PG oe POTIAT La(S7) cece MTT OPTI Lu(71) 1 TAG Ce emTeTATRS FE aT ‘fast 3ST Ct (rare earth elements) FT Bi UTTeBRATT Ac(89) cues east ereaRFATT Lr(103) “1S era es STTRE Pte Ae Ei CAT 30 B he a HS PACER TIES! (GUA: Ce(SB) = 15? 2s? 2p 35? 3p 3d? 4s? 4p 4q?4F255? Sp 65? TOUTES PARC FAIA (La) WHS Sy AH Cer aa STARE Pacer TERN (Ac) @ coats (Th) TBS SAS eT eT A RT SeRROMCH A RTT BATT BT 27 BB {JU"15-16] A TTR RR FROTT ERRE R 9 a Le HD MUTA CHA): (n — 2)F-™4(n — 1) dns? GIG n = 6,7 Ba BG Rera seres Gra ara Fae ter aTa OT PITA wal fr cy e we | tera am: HQ) Lig) | Nay) | Kas) | RbG7 | Css) SP TA fafa [cae [sree afc aka a 6 aR Be(4)_ | Mgci2) | ca(2o) | srs) | Ba(s6) | Ra(ss) sera | aenaca | seneta | oer arom | pe | ape 5 a Bos) | ala3)_| cay | _in@s) | m@1 | Nnc3) iva | sar ote [meer [ance farce am: c@ | sida) | ce@2) |_sn(so)_|_Pbis2y | F(a) © SP VA aT fer Se ia ari | SCaIS a No | PAS} A503) | sey | Bias) | NS é ar: VIA ° ra are e were | ATS < a: 0) _| sas | se@4 |_Te(S2) | Pog) | Lie) SF: VIIA Ca ay @ | sefefae | ape | aa am FO) | aay _| bres) | 1653) _| ates) | ts) f =F: VIIA a aT om ahr act rem | sree | | am: He) | Neco) | Arcs) | kro) | xe(s4) | Rn(86) | 09118) Gaease) (Ty 6 IA Li, Na, K, Rb, Cs, Fr Giger Ty 6 TA Be, Mg, Ca, Sr, Ba, Ra Gi) leo eee vies: 08-09, 014-15) |? = Cu, Ag, Au (iv) Zn-cnrots Ty 3 1B Zn, Cd, Hg. () Fe- nora ag 9 VII Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt (vi) ETC 4 VIIA F, Cl, Br (vii) Patter ter 6 0 He, Ne, Ar, Kr, Xe, Rn (viii) Faaer geet Cer 14 La Fife rie 14 (ix) OCCA 3 VIA ©, S, Se, Te, Po Bi \ 2 often eroren Page eT...‘WTA OF Oenkid nst yay ns? (Gy BIATESR ns? p> | (iv) DCRR ns? np* | Or (a= Dae ns? (vi) IR ATG (a= 1)d* ns? (ip Sem AVEREATG a ast npit (oii SRT GT (a— Dans? Gece ns? upé (He TSS) aioe erpyt err wa ares PTT ¢ — Beteng/ erry (Metalloid): [GST’21-22] i er or ae a or ae. B Si Ge As Sb Te At + WaT: DULG al oe ore Cu Ag Au + Reba 7 oT a Fe) erat (Ca) + afters ag: Set ort mC Ag Au Pt + FRE at ar e e Pb Na K Ca + Say: wer ore wet ret Ga Hg Ee [9U'14-15] & 6 SmaI: ear ae Fr Ga Cs Hg ‘Tera 27 30°C 285°C =40°C <= ARR ete RAET AT cae | —_1 2 1b 4 eo aw aa) qua) avay z Be, B c J ———. Mg BG saa araRCe Cora oars PAT CHIT Ctra MAS UH TR RT a TAT ACT > s-block OUCH CGM s! A SF 1 eae s? ROH BPH 2 > p-block GHC CHU s @ p orbital ax Remi Aaya AIC 10 AY VA HH MeN NSA AAT > d-block GTC CREM (n — 1)d 6 ns. FRRTRTA CaS o mee se oh cH > Eblock a RGM SP EAT 31 Example 01, CHAP SOARS Fite cll aa? Ans: d][JU"14-15}| (@ct (b) No (ur @Er Example-02. [Ar]4d*5s? Soran Ror RAB Ghat car aafige? [Ans: caren \ @ FRAT (&) BeRRER TT (© Patter @) sressaged OTe = Example-03, 141m rata orgs ffs A? [CU"12-13, 11-12, JU’10-11, RU*09-10, CU"08-09, CU"06-07) (Res RPT (}) eT (© areata oa @) mee RST Sol: (a); CRPTR Ora Berra Fear ST oer Hace OTE ATA Example-04. Gorm Gila corel @fafe aa? fAns: dj[JU"10-11] (@Li-Mg (b) Be—Al (©B-si @Be-B Example-05. Pftary aae PICA aR FET ef ors A HA? [Ans: d][JnU’10-11] Oe () at te rata ose apoE (© aera ae a Sera OTT Orr Example-06, fear gfeer iter 4a CHA? [Ans: b][JU"09-10] (Eu (b)Nb yo @Ce Example-07. 4a Tafhicw Beyfrars (Te) CHA BUCMBTAA (0) ME TEA? [DU"07-08} (a) CBefrarcme core HRT TCATATTAR HCH RA RCRA CaP TTR (b) Gafrancra orem corr ae FRA ST SITE (© Gaftmcra oraniéera cor eA cetita eH BIE, (@) Gefen sree oor ao conta ca ICE Sol": (€); 132 Te sere 123 1 PA SATA OAT SH ALAN IHR (ceo 9 UIA Hee) Fey ones ALT fa Te aa 1 EE HE cetibm eH Example-08. Ficoa citecara 4m states wraea Pica a @ 20Ca ii) 27Co iii) 16S Civ) sCe Sol: () .oCa— 15? 25? 2p8 35? 3p 4s? GTM s-block aH EES 1 Cra 7d afesqaraR RRA TH 45?(ns?) « aPot A BAT 21 Sage TRE aA Carb eT (0) A fa, OTA HIN Shell HT ET NAT = 1a: 84 a a tao caren Fase NT.(ii) p00 ~ 15? 25? 2p 3s? 3pé 3d” 4s? Ce alok a erg, eee Noe SS A EEE NMEA SET ATH, (n— 1) d + ns a CHEB Bema = (4 — 1)d + 4s et CIB BORTRA = (3d7 + 452) at TS Rea = 9 GPF 9 BWI d-block ¥ group, VIIB ‘tre: 4% [4 1B coer Farerara, wee ore TAC PA 9 (iii) 4S — 1s? 2s? 2p 3s? 3p* Gm p FAA GOES! (ns + np) 2m GHB Revel = (36? + 3p!) ve cald ROMAN = 6 «SPT VIA SHAT 16, et: 3" (iv) sqCe — 1s? 2s? 2p® 35? 3p 3d! 4524p 4d!” 4f? 5s? Sp 6s? + Ge — block en wae wae dere rae SHB A MCA AL ARETE A + SPIE FEAT 3, [Flock A aT ATR ak seer TLE]; AT: 6 (Peoncert) (@ Group-t (1A) > retest Reeves Fora: ns > WOES citm: Li, Na, K, Rb, Cs, Fr > CS FA MY AT > weal TTS TREE At A TAL ats ef: SOE AT AT eA aA ACS ACAI FAT: LiCl, NaCl, KNOs; NazSOs, NasPOs, NaxCO3 ‘af: NaxCrO, > I, KaCreOr > FAM, KMnOu > Coren Gi) se conta Brace HAA (i) A: Tea THR A Ora BA Pree sist aT (iy) staan rer: aS ake Bora cas Frew aera BR TT (ov) HG: MATA aT Glas TCS TC AG GP TT [aufeara pNa(= 0.97) > pK(= 0.86)) [g/mL] BIR, Li, Na tae K ont OCH ATA sae TCS STOR (vi) tomar 6 gare: TTF eT Bea ACS AC BT tT (vii) Farr StS Paty ATT AT, AHH TATA STF eI apratie ef Group — 1A a CRTePraR se ace Firat ea la Beets ea SH, OTA A AT aT Ty (WR: 2Na + 2H,0 ~ 2Na0H + Hz! > C56 Rb GIEIa Op aa Me RPM HLA STOR MA AT Bret ertrerr a4 Na__| orate ar Ba | aot seem ae: K [aol Bb as a OT Ca__ | SoaworTT cam Sr | Babce nie Cicer ERR) Or mes = “fiom aera age eT.)Example-09. itera WoPer otihera aa eres MAT CTA ATA ARCS BRS Sat RE? (BUTEX’10-11] Sol": 1 HCI -a1 Example-10. PRAT atgrqe Aether BS af a aca fre: [{CUET’0S-06; RUET’07-08; BUTEX"03-04] . Bu SAP () onféare oF oP CD area (6) cafe Sor) Baer (@) COMA SH C)ach @) Was (EASA Group-2 (IIA) > SESS Ge: Be, Mg, Ca, Sr, Ba, Ra TANF YORE MG TA A OI TS START S911 a TA Et ‘arena Sera FOPT: ns? Be waa fOShn wtatrreae 1757 kj mol-* > Be @ Mg Sw s Hwa wee ct rat dbo alee ao BE CA cote ef BP-2 AIDA FATT HITS PH Fat: vvvy M MSO, 4 MCOs. M(H) Be | RRR aM a eM RTT Bara | eo aaa aM hea BeTST ae RT a ari ata | wrayer ey] [ turrergfa] a Sr Ba waits ret LE) LE= Lattice Enthalpy S.E= Solution Enthalpy #0 Saal ‘Se Art Bian) er Os raat FaRpes, Ao aC + wat AAMT = RO aA, = LE+SE=HE>S.E=H.E-LE > marge : > BTS ar ORE WAR OHE TAR Gi) LE WSFA BITSTS OS FR ACA @) LE Wo aged Tae BS BH A! SF-2 GI SOF” 6 CO} FATTER CHE OTA TT TO arc Bria cece cos fAcs ASR WT, SSE ALE TAR BPI CTS AIC (LLB a HIT COWA BORAT ATER VAAN WOR TS BrTOTA aH aT BeSO, > MgSO, > CaSO, > SrSO, > BaSO, BeCO; > MgCO; > CaCO; > SrCO; > BaCO, SHORT aFet-2 eas OH araLs A CHAT GAR TR SPLOT BH Cole FICE HCH. Beat BENICIA AT BEAT LE BP CHS eH VOM MACS BIATOTA GPA FHM RA- Be(OH), < Mg(OH), < Ca(OH), < Sr(OH)2 < Ba(OH); Ae ATOR COTE PAGE TIO.+ aPTEATe eof: PIA x trae wea nf ee FARE ea A BR A MgO + H,0 > Mg(OH)21 Mg ater sna ace fafiem ea AT! FEAR, ak GaRSETR HA aay ak CT ATPL (Ca, Mg) Bifbrw Bafa evra ST, E118 seo Serre yORTT MTg AT ‘roup-13 (IITA) ‘SBE Nm: B, Al, Ga, In, TI, Nh ‘aerators Faeota: ns?npt 6 SPC I UT ae ATCT AT AR TOTAL wT IAA SF AT A ae af: @ aera APR Ta ART +3 ae ToT HATO wR: B > AL > Ga?* > In** > THY (i) OTE STH TS CRIS eH, AACA At TAA SATTT SS ACG | ii) onraarace sreegt gfiea Fe BC aT SAG, AACA HHNG @ Bree GTA ACG B20; ¥RR Al,O; Bowtt: ‘SHY: Mz0, + 6HCI + MCI; + 3H,0 cwIsty: Mz03 + 2NaOH ~ 2NaMO, + H,0 [481 M = B, Al] > BBE AM: C,Si, Ge, Sn, Pb, FI > ahaa Bera fort: ns*np? > aE > WHT: Si, Ge > 91g: Sn,Pb > VA GPR afar h cer aI Maw Care ef: (can ofces ara ACA ergo (i) MP gan MR BR HCA BTA ART COMA CA Me gat fee EH Ge < Sn?*< Pb iat M* ia BT Ge" > Sn**> Po (Giiy ores eet Bas ATCA TC aA TATA PSs, We WEST AT ate atse ely Pe MT iv) RES TTR AAT AGT CH SPATE ROVE PT TT AT | ACR Pb, Ph ot AAT > Sn HATE! PbO; AR SnO, Berit: ‘HAG: MO; + 2NaOH > NazMO; +120 THING: MO, + 4HCI > MCl, +H0 [Ith, M = Pb, Sn] aR Hever CURIE A Wa (MCI,), WA Sn Ae Ph BPR (MCI) Beery ace ater FG, Sale ASA WS Phi, ASA A! 3 ARTS ETT FRET AO¢- SBYS ANN, P, As, Sb, Biaae Mc SF1-15 G8 COTATICS (N, PAS, Sb, Bi) FRRBICER (Phictogen) citer aor Freebies wd TTATHAA ea 9 ATTN Tea oT A RCH FTTH AT RCT Aare Ber FOP: ns*np? 4 Teatro: 34 aRchicerma yf weTEH BIE: () ARRTTS FRE com we (i) ATRCRTCOR (CRATE CHP) « srctiices fea wecEH utce: Opratis diye cis Git) Fen SIE + SPs fea wetcer: @ "184 Sb (ii) a-Sb Git) Re-wae Sb + RICH WCET TS RAB: (i) CTS TEST (Pa) i) CRS wHrHAT (P,) (ii) FIT PRIM (P,) CTS PARA 6 OURS TRACTS MRS HTT: FART CUR: CO, TN, STO Wey 250°C | PikeT oscar GIRS TRAITS 550°C Bema See UPRTET 6 ICE ererarer Cofeere one | wae oie ener IMT Beem, SAL GT THIET RRS Bae FIM fee rea Beem at | hear ea ofS BTA Been Vt fee BEAT, (P,) 250% by ssorc CAO ERT (Px) Sa eee AAMT) | RCP) ees wrest Im (P) > cro WHEAT (P,) N20 +1 aia Face) NO +2 FR nr Rater) N203 +3 ler acta waa mld (Re NOp,N204 +4 aarp erate) N205 +5 ARR Cortera TIE (RE ’ BEXS AM: O, S, Se, Te, Po wae Lv 4-16 Tera aRracaa Beers FATT: ns?*np* SACO 9 HRA ety, Tce we CoePAATN ITUT aee CCITT MTR CAPES TATE 8 ots Tee HITTER aT TARE Beer Get WTS: aFSCER an AE HITE FAATATA- 02 AR Os; 302 2, ec eeesAPTS HCE: © Weta Tree ©) afte / ROMS Joc HTT (ey weanftie / aan FRrercatbe/ p aterers Gi) Serr ere: %) eos aaa aera (y) (8) 5 rT (iy aera: (FURST TEA) (@ FAB aA (H) * sage cin: F(9), CI(17), Br(35), 1(53), At(BS), Ts (117) MOTACH AUR TITICAT SF AT RITCHTICRE ICT re FTE aa, Bevis src ee cx ae NRT TA CG GA, ca, EMC MA OT | STR FRAY TC, SO ET ATEN EA | © Ree ep rarer se orf Fer UTS a TAT ila HTEMAT aT SaIA |AAT (bromas whe) eR, ST reer fy ever aT ATATAT WIE COA ATOM FETS AI © STICOA coaftrr at arpfore omen am aT Bye wx Roca crf emt 13 wT GACe GrIICAA RF 20 BR ITCH Horst Xo. ea ee SH BP ATC ATC SHIA TETT eT le MTL HR CAT ATT A aE Batt Oar aes SICMTEAS Mem TATA AMA) ATTA CASS WHATS MA: F > Cl > Br> 1 TSE WS AP Ba ARS SHA TOH AA BS BT Group-18 (Fafa *5M) MATS SA: 4 ARTA SA: 39.9 ATA SA: 83.8 wa (fair ATA): 3a ordicaa | Sag Corde onal): oF oritcaa | SaErT (tae iA: of orice “aR amet (18 FC) arse sera cas Genie: Ae“ “Helios” | *tcva Benfe: de “Argos” | arora Bente: Mela “Krypton” arora 4 3 _arcara ert ar FART AIRE: OS amr wag 2 (A) AAW: 19.94 AERA: 40 Bereta RT: 1s? "Bere FAUT: [Ne] 3s? 3p eras rs: [Ar]sd'4s?4p® ROG FAR ACA Ae MH Neon x A HE AGA; CHA MAT ANE 1 Xenos US Ua TE GITH, GEA a0ATE Radium S| co faftipm since cite aA: @ Beafere orate ctr oA: Fa AC FAT Hyg SUT BRE HgHere vo ao MATH soora Beier Bea Reras aPL CT ‘ORFS WA WHe "19S i AIG PtsHe, PdHe, BiHe, FeHe, FeAri SATE ACA BHA aT PTAA AY AM, AIR CATE CA (absorption Compounds); ena SBA cAI (Interstitial Compound) #1 1 1 uals s 8 rf] 1922.81, [4 |] He (eft) He (Creftre) aan Ne ites aren Page wT. |