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3D PRINTING Unit-1 1
3D PRINTING Unit-1 1
3D PRINTING Unit-1 1
printing technologies and applications. Liquid materials are used in SLA and Material Jetting,
UNIT-1 providing high precision and smooth surface finish. Solid materials, commonly used in FDM,
Syllabus offer versatility and a wide selection of thermoplastics for various applications. Wire-based
3D printing, known as WAAM, is primarily used for metal components, offering advantages
Unit-1.0 3D Printing Materials in terms of reduced waste and faster deposition rates. Powder materials are utilized in SLS
1.1 Various forms of 3D printing raw material-Liquid, Solid, Wire, Powder. and Binder Jetting, providing design freedom and versatility for complex geometries and a
wide range of materials. Each form of raw material has its unique benefits and limitations,
1.2 Popular FDM, SLA, SLS, Binder Jetting, Material Jetting and Direct Energy deposition 3D allowing users to choose the most suitable option based on their specific needs and project
printing materials. requirements. As 3D printing technology continues to evolve, we can expect further
1.3 Polymers, Metals, Non-Metals, Ceramics. advancements in the development of raw materials and their applications across industries.
1.5 Powder Preparation and their desired properties. 1.1 Various forms of 3D printing raw material-Liquid, Solid, Wire, Powder.
1.6 Choosing the Right 3D Printing Material on the basis of Performance Requirements and We will explore the four main forms of 3D printing raw materials: Liquid, Solid, Wire, and
Material Properties. Powder.
Properties: Liquid resins come in various formulations with different properties such as
flexibility, hardness, transparency, and color. They can create highly detailed and
smooth objects, but they may be brittle and less durable compared to other materials.
Fused Deposition Modeling (FDM) is one of the most popular 3D printing technologies, and 4. TPU (Thermoplastic Polyurethane):
it uses solid filament materials as its raw materials. Here are some common FDM printing
Properties: TPU is a flexible and elastic
materials, along with their properties and applications:
filament with rubber-like properties. It
1. PLA (Polylactic Acid): can withstand bending, stretching, and
compression. It comes in varying levels of
Properties: PLA is a biodegradable and
flexibility.
environmentally friendly material. It is easy
to print with, has low warping, and comes Applications: TPU is used for producing
in a variety of colors. It has good strength flexible parts such as phone cases, shoe
and is relatively rigid. soles, gaskets, and wearable devices.
3. Tough Resins:
Applications: Tough resins are used for Applications: Nylon is used for functional prototypes, complex parts, end-use
functional prototypes, snap-fit components, and parts subjected to mechanical products, automotive components, and consumer goods.
stress.
2. TPE (Thermoplastic Elastomer):
4. Biocompatible Resins:
Properties: TPE is a flexible and rubber-like material with good elasticity and shock
Properties: Biocompatible SLA resins are absorption. It is used for producing parts requiring a soft touch and impact
formulated to meet medical and dental industry resistance.
standards for biocompatibility. They are suitable
Applications: TPE is used for creating gaskets, seals, footwear components, and
for creating dental models, surgical guides, and
ergonomic grips.
custom medical devices.
3. TPU (Thermoplastic Polyurethane):
Applications: Used in the dental and medical fields
for applications requiring biocompatible materials. Properties: Similar to TPE, TPU is a flexible material with properties ranging from
soft to semi-rigid. It has good chemical resistance and durability.
5. Clear Resins:
Applications: TPU is used for producing flexible hinges, gaskets, seals, and
Properties: Clear SLA resins produce transparent
functional prototypes.
parts with optical clarity. They are often used for
creating lenses, light pipes, and clear prototypes. 4. PEEK (Polyether Ether Ketone):
Applications: Clear resins are used for Properties: PEEK is a high-performance engineering plastic with exceptional
applications where transparency and optical mechanical, thermal, and chemical resistance properties. It is suitable for
properties are critical, such as optics and demanding applications.
consumer electronics.
Applications: PEEK is used in aerospace, medical implants, automotive, and other 1. Sandstone (Gypsum):
industries for producing parts that require high strength, temperature resistance,
Properties: Sandstone is a brittle material that can produce detailed, full-color
and biocompatibility.
models. It's not particularly strong but is suitable for decorative and architectural
5. Metal Powders (e.g., Stainless Steel, Titanium, Aluminum): applications.
Properties: Metal SLS materials offer high strength, good thermal conductivity, Applications: Used for architectural models, figurines, and artistic sculptures.
and the ability to produce complex geometries. Different metals have varying
2. Metal Powders (Stainless Steel, Bronze, Inconel, etc.):
properties.
Properties: Metal powders used in Binder Jetting can offer high strength, excellent
Applications: Metal SLS is used for producing functional prototypes, tooling,
thermal conductivity, and resistance to corrosion. The specific properties depend
aerospace components, medical implants, and customized parts for industrial
on the metal used.
applications.
Applications: Commonly used for producing metal parts for aerospace,
6. Ceramic Powders (e.g., Alumina, Zirconia):
automotive, and industrial applications.
Properties: Ceramic SLS materials offer high heat resistance, excellent electrical
3. Ceramic Powders (Alumina, Zirconia, etc.):
insulation, and chemical stability. They can have varying levels of hardness.
Properties: Ceramic materials are known for their high-temperature resistance,
Applications: Ceramic SLS is used for creating specialized components in
electrical insulation, and hardness. They can have various properties depending on
electronics, aerospace, medical, and other industries where high-temperature
the specific ceramic used.
stability is required.
Applications: Used for manufacturing ceramic components such as insulators,
7. Composite Materials (e.g., Carbon-Filled Nylon):
dental crowns, and intricate, custom-designed ceramic parts.
Properties: Composite SLS materials combine polymers with additives like carbon
4. Plastic Powders (Nylon, Polyamide, etc.):
fiber for enhanced mechanical properties, including strength and stiffness.
Properties: Plastic powders in Binder Jetting can offer a range of properties,
Applications: Used for producing lightweight but strong parts in aerospace,
including flexibility, durability, and impact resistance, depending on the material.
automotive, and sporting equipment industries.
Applications: Used for producing prototypes, intricate parts, and objects that
require specific plastic properties.
Binder Jetting 3D Printing materials:
5. Sand and Ceramic Composite Materials:
Binder Jetting is a 3D printing technology that uses a powder bed and a binder material to
Properties: These materials combine sand or ceramic powders with a binder to
create objects layer by layer. This process is often used for producing prototypes, intricate
create objects that are more durable than pure sandstone or ceramic prints.
parts, and objects with a range of materials. Here are some common materials used in
Binder Jetting 3D printing: Applications: Used in applications where a balance of strength and detail is
required, such as in custom sand casting molds for metal parts.
6. Glass Powder:
Applications: Used for producing glass art, decorative objects, and prototypes
requiring optical properties.
7. Food Materials: 2. Wax-like Materials:
Properties: Binder Jetting can be adapted to print food materials like chocolate, Properties: Wax-like materials are often used in investment casting processes.
sugar, and other edible substances. They can be melted away, leaving behind a void that can be filled with molten
metal.
Applications: Used in the culinary industry for creating custom-shaped chocolates,
cake decorations, and food prototypes. Applications: Wax-like materials in Material Jetting are commonly used for jewelry
making, dental crowns, and parts that will undergo investment casting.
3. Support Materials:
Material Jetting 3D Printing materials:
Properties: Material Jetting often employs separate support materials that can be
Material Jetting is a 3D printing technology that deposits droplets of photopolymer
easily removed after printing. These support materials are designed to work with
materials or wax-like materials layer by layer to create objects. It's known for its ability to
the main printing material.
produce high-resolution and highly detailed parts. Here are some common materials used in
Material Jetting 3D printing: Applications: Support materials are essential for creating complex and
overhanging geometries and can be used in a variety of applications, especially in
cases where intricate, high-detail parts are needed.
4. Multi-Material Printing:
Properties: Some Material Jetting systems allow for the simultaneous use of
multiple materials in a single print job. This enables the creation of objects with
varying properties and colors within a single part.
5. Full-Color Printing:
5. Polymer Powders:
Properties: Some DED systems are capable of using polymer powders, enabling
the creation of parts with different thermal and mechanical properties compared
to metals and ceramics.
Applications: Polymer DED is used for creating lightweight parts, tooling, and
prototypes in industries like aerospace and automotive.
6. Hybrid Materials:
Properties: In some cases, hybrid DED systems combine different materials, such
as metal and polymer, to create parts with unique properties.
Applications: DED with metal powders is used in industries such as aerospace, 1. Polymers:
automotive, and oil and gas for creating large and complex metal parts, repairing Definition: Polymers are large molecules made up of repeating subunits. They are
components, and adding wear-resistant coatings. characterized by their flexibility, lightweight nature, and diverse properties.
2. Ceramic Powders: Properties: Polymers used in 3D printing can vary widely in terms of flexibility,
Properties: Ceramic powders are used in DED to create parts with excellent strength, heat resistance, and other properties.
thermal and electrical insulating properties, as well as high-temperature Applications: Polymers are commonly used in 3D printing for producing prototypes,
resistance. Examples include alumina and zirconia. consumer goods, medical devices, and more.
Applications: Ceramic DED is used in applications like manufacturing ceramic Examples of polymer 3D printing materials:
components for electronic devices, aerospace, and advanced ceramics.
a) PLA (Polylactic Acid): Biodegradable, easy to print, used for prototyping.
3. Metal Wire:
b) ABS (Acrylonitrile Butadiene Styrene): Durable, impact-resistant, used for
Properties: Metal wire is fed into the DED system and melted onto the substrate. functional parts.
This process can be more cost-effective than using metal powders.
c) PETG (Polyethylene Terephthalate Glycol): Combines the best of PLA and ABS
Applications: Metal wire DED is used in industries requiring large metal parts, such properties.
as shipbuilding and construction.
d) TPU (Thermoplastic Polyurethane): Flexible and elastic, used for soft parts.
4. Ceramic Wire:
e) Nylon: Strong, durable, used for functional and mechanical parts.
Properties: Similar to metal wire, ceramic wire can be used in DED to produce
ceramic components with specific properties.
2. Metals: Examples of ceramic 3D printing materials:
Definition: Metals are solid materials with high electrical and thermal conductivity, a) Alumina: High mechanical strength and electrical insulating properties.
often malleable and ductile.
b) Zirconia: High toughness and resistance to cracking.
Properties: Metal 3D printing materials offer high strength, excellent thermal and
c) Silicon Carbide: Extremely high thermal conductivity and hardness.
electrical conductivity, and a range of other properties depending on the alloy.
b) Titanium: High strength-to-weight ratio, biocompatible, used in aerospace and a) Biodegradable and environmentally friendly.
medical.
b) Easy to print, making it ideal for beginners.
c) Aluminum: Lightweight, good thermal conductivity, used in automotive and
c) Relatively low melting point, around 180-220°C.
aerospace.
d) Generally rigid and somewhat brittle.
3. Non-Metals:
e) Available in a wide range of colors and formulations.
Definition: Non-metals encompass a wide range of materials that do not exhibit
metallic properties. Applications:
Properties: Non-metal 3D printing materials can include composites, ceramics, and a) Prototyping and hobbyist projects.
other materials with unique properties.
b) Decorative items and figurines.
Applications: Non-metal materials are used in specialized applications where metal
c) Educational purposes.
properties are not required.
d) Packaging materials.
Examples of non-metal 3D printing materials:
2. ABS (Acrylonitrile Butadiene Styrene):
a) Carbon Fiber Reinforced Polymers: Lightweight and strong, used in aerospace and
sports equipment. Properties:
b) Glass-Filled Nylon: Enhanced strength, used for engineering parts. a) Tough and impact-resistant.
c) Wood and Metal Composites: Used for aesthetic and artistic applications. b) Higher melting point, typically around 210-240°C.
Definition: Ceramics are inorganic, non-metallic materials that are typically brittle d) Excellent layer adhesion.
and have high heat resistance. Applications:
Properties: Ceramic 3D printing materials can have excellent thermal and electrical a) Functional parts in automotive and consumer electronics.
insulating properties, as well as high-temperature resistance.
b) Enclosures and casings.
Applications: Ceramic 3D printing is used in aerospace, electronics, and applications
requiring high-temperature resistance and precision. c) Durable prototypes.
d) LEGO bricks are made from ABS. Powder Preparation:
3. PETG (Polyethylene Terephthalate Glycol): 1. Particle Size Distribution: The powder particles should have a consistent size
distribution to ensure uniform packing and sintering during the printing process.
Properties:
2. Powder Shape: Spherical or near-spherical particles are preferred as they allow for
a) Combines the ease of printing of PLA with some properties of ABS.
better flowability and packing density, reducing the chances of defects.
b) Good layer adhesion.
3. Surface Characteristics: The powder surface should be free of contaminants,
c) Moderate flexibility and impact resistance. oxidation, or impurities that could affect the sintering process or mechanical
properties of the final part.
d) Melting point around 220-260°C.
4. Flowability: Good flow properties are essential for uniform powder distribution in
Applications:
the build chamber and proper layer deposition.
a) Functional parts requiring strength and durability.
5. Drying and Debinding: Some powders might need to undergo drying or debinding
b) Transparent or translucent items. processes to remove moisture or any organic binders, respectively.
c) Food-safe containers. Desired Properties of 3D Printing Powders:
d) Mechanical components. 1. Sinterability: The powder should sinter well under the energy source (laser or
electron beam) used in the 3D printing process, leading to strong bonding between
4. TPU (Thermoplastic Polyurethane):
particles.
Properties:
2. Melting Point: The powder's melting point or sintering temperature should be
a) Highly flexible and elastic. appropriate for the specific 3D printing process without causing excessive thermal
b) Good resistance to abrasion and impact. degradation.
c) Melting point around 200-230°C. 3. Thermal Conductivity: Powders with good thermal conductivity are essential for
efficient energy absorption during the sintering process.
d) Available in various hardness levels.
4. Chemical Composition: The chemical composition of the powder must match the
Applications: desired material properties, allowing for the production of parts with the required
a) Phone cases and protective gear. mechanical, thermal, and chemical characteristics.
b) Gaskets and seals. 5. Density: Higher powder density leads to better packing and improved mechanical
properties in the final part.
c) Flexible and stretchable prototypes.
6. Powder Purity: The powder should be free from impurities that could weaken the
d) Shoe soles and sportswear material's properties or introduce defects in the printed part.
1.5 Powder Preparation and their desired properties. 7. Particle Adhesion: Powder particles should have enough adhesion to each other to
Powder preparation is a crucial step in powder-based 3D printing processes, such as maintain their shape during handling, transport, and printing.
Selective Laser Sintering (SLS) and Electron Beam Melting (EBM). The quality and properties 8. Reusability: Some powder-based processes allow for the recycling of unused or
of the powder material play a significant role in the final printed part's characteristics. Here excess powder, so powders should maintain their properties through multiple cycles.
are some key aspects of powder preparation and the desired properties of 3D printing
powders: 9. Size and Shape Control: Consistent particle size and shape contribute to uniform
packing and layer quality during printing.
10. Powder Handling: Ease of handling and processing during loading, spreading, and 6. Electrical Properties: Understand electrical conductivity, dielectric strength, and
recycling is important for efficient operation. other relevant electrical properties.
Choosing the right 3D printing material based on performance requirements and material 1. Material Databases: Utilize online material databases and resources provided by
properties involves a systematic approach to ensure the desired outcomes of your project. manufacturers to compare properties side by side.
Here's a comprehensive guide:
2. Material Compatibility: Ensure the selected material is compatible with your 3D
Step 1: Define Performance Requirements: printer and its specifications.
1. Mechanical Properties: Determine the required strength, stiffness, and impact Step 4: Evaluate Trade-offs:
resistance for your part. Consider factors like load-bearing capacity and potential
1. Performance vs. Cost: Consider the balance between the desired performance and
mechanical stress.
the cost of the material.
2. Thermal Properties: Identify the temperature range your part will experience.
2. Ease of Printing: Evaluate how well the material works with your 3D printer,
Consider factors like heat resistance, thermal expansion, and conductivity.
including considerations like bed adhesion and nozzle temperature.
3. Chemical Compatibility: Understand the chemicals or substances your part will
3. Availability: Check the availability of the chosen material in your region and its lead
come into contact with and choose a material that is chemically resistant.
times.
4. Electrical Properties: Determine if your part needs to conduct electricity, insulate, or
Step 5: Test and Validate:
have specific electrical characteristics.
1. Prototyping: Create prototypes using the shortlisted materials to test their actual
5. Durability: Evaluate whether your part needs to withstand repetitive stress, fatigue,
performance under relevant conditions.
or wear over time.
2. Functional Testing: Subject prototypes to real-world conditions to validate their
6. Aesthetic Requirements: Consider factors such as color, surface finish, transparency,
performance against your defined requirements.
and texture.
3. Iterate if Necessary: If the initial material choice doesn't meet expectations, iterate
Step 2: Research Material Properties:
the process with new options.
1. Material Categories: Understand the properties and limitations of polymers, metals,
ceramics, and composites.