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Corrosion Its Control
Corrosion Its Control
Corrosion Its Control
Syllabus:
Corrosion – Introduction
Chemical Corrosion Before Corrosion After Corrosion
Electrochemical Corrosion
Galvanic Corrosion
Differential aeration Corrosion
Stress Corrosion
Soil (Microbial) Corrosion
Factors influencing Corrosion
By Nature of Metal
By Nature of Environment
Corrosion Control
Selection of Materials
Design Principles
Cathodic Protection
Sacrificial Anodic Protection
Corrosion Inhibitors
Factors Influencing Corrosion Galvanic series:
EMF series does not account for
Extent of Corrosion depends mainly on, the Corrosion of all metals &
alloys. So, a more practical
➢ Nature of the metal series, called galvanic series is
➢ Nature of the environment prepared.
Large Cathode
(Steel) Small Anode
(Aluminium)
e-n flow
If cathodic area is larger, the demand for electrons will be more and
this results in the increase of rate of oxidation of metal at anode. i.e,
high rate of corrosion at anode.
Factors Influencing Corrosion
Purity of the metal:
Impurities present in a metal create heterogeneity and thus
galvanic cells are set up with distinct anodic and cathodic areas in
the metal.
Eg:- Impurities like Pb, Fe, etc. in Zn lead to the formation of tiny
electrochemical cells at the exposed part of the impurity and the
corrosion of Zn around the impurity takes place.
Factors Influencing Corrosion
Physical state of the metal:
Temperature:
Humidity :
Iron
Important Design Principles:
Stainless steel
The contact of two bolt & nut
dissimilar metals in the
presence of the corroding
solution should always be Iron
avoided, otherwise the
more active metal will act
as anode and corrosion
will be localized.
Corrosion Control
e-n flow
e-n flow
Initially Then..
At Seashore… Finally
RUSTY SHIP
RUSTY SHIP WRECK
RUSTY ANCHORS
Corrosion Control
Impressed current cathodic protection:
(+) (–)
DC
Back fill
Buried pipe
Corrosion Inhibitors:
Substance which on addition in small quantities to the corrosive
environment reduces the corrosion of metal is called inhibitors.
Anodic inhibitors:
Chemicals like chromates, phosphates, tungstates, when added to
corrosive environment produces sparingly soluble compounds by
reacting with metal ions (produced because of corrosion).
Deaeration
Presence of more O2 is
harmful and it increases the
corrosion rate. Dissolved
oxygen can be removed by
deaeration using mechanical
agitation.
mechanical agitator
Corrosion Control
Deactivation
Removal of oxygen can be attained also by adding chemicals like
Na2SO3, hydrazine etc.,
2Na 2SO3 + O2 ⎯⎯
→ 2Na 2SO4
N2 H4 + O2 ⎯⎯
→ N2 + 2H2O
Corrosion Control
Dehumidification