Credit Cod and

Course name
hour. No.
ACHM
3 Physical Chemistry II
343
HOMEWORK -6
Mark = 10

1- Calculate the Ionic Mobilities of theses ions:

SO42- , Cl- , Mg2+ and OH-

2- Calculate the molar conductivities (), -1cm2 mol-1 of Mg(OH)2 at 25C , if

the molar conductivities(),-1cm2 mol-1 of NaNO3=121.65 , NaOH =249.2 and
Mg(NO3)2=249.02.

3- Calculate the transport numbers of positive ion if the current pass through the
electrolyte is 0.23A and the current carried by negative ion is about 0.170A.

4- Using the data in the Table below : Ionic Mobilities, calculate the molar conductivity
of following ions:

a.Ba2+

b. Br-

c. Zn2+

d. H+

5- Conductivity of 0.000241M acetic acid is 7.896x10-5 -1cm-1, if (o) = 390.5

Scm2/mol, calculate the value of the acid dissociation constant Ka?
Cation (cm2 V-1 s-1) Anion (cm2 V-1 s-1) Cation  + Anion -

H+ 36.23 x10-4 OH- 20.64 x10-4 H+ 349.8 OH- 199.1

Na+ 5.19 x10-4 Cl- 7.91 x10-4 Na+ 50.10 F- 55.40

K+ 7.62 x10-4 Br- 8.09 x10-4 K+ 73.50 Cl- 76.35

Zn2+ 1.094 x10-3 SO42- 1.658 x10-3 Cs+ 77.26 NO3- 71.46

Ba2+ 1.32 x10-3 NO3- 7.4 x10-4 Ba2+ 127.26 Acetate 40.90

Mg2+ 106.10 SO42- 160.0

Table (1)
Table (2)
 6- What fraction of the total current is carried by Cl- when current flows through

an aqueous solution of NaCI at 25°C? (according to Table 1)

7- The limiting molar conductivities of NaI, NaCH3CO2 and Mg(CH3CO2)2 are 12.69 mS
m2 mol-1, 9.10 mS m2 mol-1, and 18.78 mS m2 mol-1, respectively (all at 25°C). What is the
limiting molar conductivity of MgI2 at this temperature?

8- After correction for the water conductivity, the conductivity of a saturated aqueous
solution of AgCl at 25°C was found to be 0.1887 mS m-1. What is the solubility of silver
chloride at this temperature?