36 The Activity Series-S

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36 the Activity Series-S ANSWERS

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1.Whichions,sodium(Na')ornitrate(NO,),aremorelikelytobethemissing"spectatorions"in
thebeakersofModel1?Explainyourreasoning.
NitrateionswillbespectatorionsinModei1.Thebeakersalreadycontainpositivelychargedions,so
negativelychargedionsarerequiredtokeepthesolutionselectricallyneutral.
2.ExaminethediagramsinModel1.
a.ListrwopiecesofevidencefromExperimentAinModel1thatindicateareactionhas
occurred.

Solidzincformedonthemetalstrip(theelectrode),andmagnesiumionsappearedinthesolution.
b.ListtwopiecesofevidencefromExperimentGinModel1thatindicatenoreactionoccurred.
Therewasnochangetothemetalstrip(theelectrode)ortotheionspeciesinthesolution.
3.CircletheletterbeloweachexperimentinModel1thatresultedinareaction.
a.Writeasinglereplacementreactionunderthebeakersineachexperimenttoillustratethe
reaction.Ignorethespectatorions.
SeeModel1.ExperimentsA,B,C,E,andFresultedinchemicalreactions.
b.Circlethespeciesineachofthereactantbeakersthatunderwentoxidation.
SeeModel1.
c.Drawanarrowfromonespeciesineachofthereactantbeakerstoanotherspeciesinthereac-
tantbeakertoshowhowtheelectronsweretransferredinthereaction.
4.FindthetwoexperimentsinModel1thatinvolvealuminumandmagnesium.
a.Willaluminumgiveitselectronstomagnesium?
No.
b.Willmagnesiumgiveitselectronstoaluminum?
Yes.
c.Whichmetal,aluminumormagnesium,isbetteratgivingupelectrons?
Magnesium.
5.FindthetwoexperimentsinModel1thatinvolvealuminumandcopper.
a.Willaluminumgiveitselectronstocopper?
Yes.
b.Willcoppergiveitselectronstoaluminum?
No.
c.Whichmetal,aluminumorcopper,isbetteratgivingupelectrons?
Aluminum.

6.Predictwhatmighthappenifyouputapieceofmetalinasolutionofitsownion(coppermetal
inaCu?*solutionormagnesiummetalinaMg?*solution).
Therewouldbenoreaction.

276 POGIL™™ActivitiesforHighSchoolChemistry

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ExtensionQuestions
14.Plumbersoftenusea"dielectricunion"jointtojoinpipesofdifferenttypes.Forexamplecopper
pipesinahousemightneedtobejoinedwithleadpipesinthemainwatersupply.Thedielectric
unionisaplasticjointwhichwillnotconductelectricity.Proposeanexplanationforwhyacop-
perpipecan'tsimplybeweldeddirectlytoaleadpipe.
Electronswouldflowfromtheleadpipetothecopperpipe,causingcorrosion.Theintegrityofthelead
pipewouldbecompromised.
15.Shipsandrecreationalboatsoftenhavelargechunksofzincattachedtotheirhullsinorderto
preventcorrosion(oxidation)ofthemetalpartsinthehullorengine.Thelatteraretypically
madeofironalloys.Explainwhyzincisagoodmetaltouseforthispurpose.
Theironintheenginecouldoxidizebygivingelectronstoionsinthewaterwheretheboatistravel-
ing.However,ifzincisnearby,itwillreactinsteadofironbecauseitismoreactivethaniron.
16.Shownbelowisanactivityseriesfornonmetalsthatrankstheabilityofdifferentnonmetalsto
acceptelectronsinaredoxreaction.
(Leastactive)P<S<I<Br<O<Cl<F(Mostactive)
Theactivityofchlorineandiodine,forexample,canbecomparedinthefollowingreactions.
CI,(g)+MgBr,(aq)→MgCl,(aq)+Br,(I)Willoccurspontaneously.
1(5)+2Naf(aq)→2Nal(aq)+Fig) WillNOToccurspontaneously.
Predictifthecombinationsofreactantsina-dwillresultinachemicalreaction.Ifareactionwill
occur,completeandbalancetheequation.
a.F,(g)+NaClaq)→CL,+2NaS
b.I,(s)+Br(aq)→Noreaction
c.ZnS(s)+0,(8)→8720+5,
d.C(g)+1-(aq)→1,+2Cl-

TheActivitySeries 279

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