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URANIUM MINERALIZATION IN THE Rhyoloite Basalt of Dongarghar Granite
URANIUM MINERALIZATION IN THE Rhyoloite Basalt of Dongarghar Granite
URANIUM MINERALIZATION IN THE Rhyoloite Basalt of Dongarghar Granite
S. N. SINGH, P. KRISHNAMURTHY,
T. M. MAHADEVAN
Atomic Minerals Division,
Department o f Atomic Energy,
Nagpur, India
Abstract
URANIUM MINERALIZATION IN THE RHYOLITE-BASALT PROVINCE OF THE
DONGARGARH SUPERGROUP, CENTRAL INDIA.
The Dongargarh uranium province, comprising a major volcano-plutonic complex with
relatively minor sedimentary units, evolved during the Lower Proterozoic over a time span
o f 2500 to 2200 Ma in a major north-south trending intracontinental rift zone. A continental
bimodal tholeiitic rhyolite-basalt suite and the associated epizonal potassic granites character
ize the complex. Repeated upthrust emplacement o f the granite plutons probably resulted in
the tight folding and shearing o f the effusive sequence and the associated sediments. Uranium
mineralization is hosted in sheared metabasic and meta-acid volcanic sequences and shows a
spatial preference for their contacts. It is suggested that hydrothermal fluids generated during
the prolonged acid magmatism in the area were enriched in uranium during their migration
to favourable lithostructural locales in the basic and acid volcanics, leading to the formation
o f major ore bodies. Uranium metallogeny and possibly also copper and molybdenum forma
tion in the region ensued during the time span o f 2200-1400 Ma. The thermal episodes indi
cated by K -A r mineral ages and the presence o f sedimentary type uranium mineralization in
the overlying Khairagarh sequence limit the age further to a period o f 1600-1400 Ma. This
is in conformity with the age o f uranium mineralization events in the Singhbhum uranium
province lying far to the east o f the area and separated from it by the rather extensive younger
Upper Proterozoic Chattisgarh Supergroup cover.
INTRODUCTION
399
400 SINGH et al.
LEGEND MINERALIZATION
■ FLUORITE 9 RARSQM
1 (HANDDONGM
a THANEWA5NA
n SHOT
CMLMGHAT SEMES • URANIUM tt TANBEKHAN
2 RARSORI 13 T H A IIT O U
DOMARGARH GRAM tt 3 BAGMMACN
BA SK EFFUSffES 4 JANGAIRUR * C u -P b
RHYOIITE
S mandamtola U KARANTARA
4 BOOAl
ACu ■ Mo
M JAREGAON
7 HALAMJKHAMO
i rular
in the Rajnandgaon district and the copper deposits o f Malanjkhand and Pular-
Parsori exemplify the latter. The uranium deposits have special features not shared
by any other o f the known deposits in the world and their genesis is, therefore, o f
particular interest. The characteristics o f these deposits and a tentative model o f their
genesis are presented in this paper, which could constitute the basis for the search
for uranium deposits in similar settings in other areas.
GEOLOGICAL HISTORY
Radiometric surveys carried out in the Rajnandgaon district during the field
season 1972-1973 revealed a unique radioactive anomaly in the quartz-homblende-
biotite (amphibolite) rock around Bodal village (20°39' N , 8 0 ° 4 5 '4 0 ' E), located
66 km south o f Rajnandgaon, the nearest railhead on the Bombay-Howrah railway
line [1]. Subsequent field investigations led to the discovery o f significant radioac
tive anomalies in sheared quartz porphyry outcrops about 8 km NNW o f Bodal near
Bhandaritola village (20°42'00" N , 80°41 '3 0 ' E) [2]. Geological mapping, radon
emanometry and ground and airborne geophysical surveys followed by drilling and
exploratory mining have helped in identifying uranium resources in the area [3].
Uranium mineralization o f relatively low tenor and extent has also been located in
metarhyolites in Parsori, Baghnadi and Jangalpur and in a younger sequence o f sedi
ments in the northwestern part o f the area [4],
REGIONAL GEOLOGY
The most prominent geological feature o f the area is the Dongargarh granite
complex o f batholithic dimensions (Fig. 1). It is bounded to the east by rocks o f the
Sakoli Group and the overlying Dongargarh Supergroup which are covered further
to the east by the large Chattisgarh Basin. To the north o f the Dongargarh granite
complex are the formations o f the Sausar, Sakoli and Chilpighat Groups and to the
west, the Sakoli Group. The Dongargarh granites are believed to be intruded into
the volcano-sedimentary complexes surrounding them. Recent age determinations,
however, have revealed that the acid volcanic rocks o f the Dongargarh Supergroup
are temporally related to the Dongargarh granites and, therefore, represent only the
effusive phase o f the granites (Table I).
The formations in the area have an Early to Upper Proterozoic age, the Don
gargarh granite ages being suggestive o f prolonged acid magmatic activity spanning
the time range o f 2500 to 2200 Ma. The regional stratigraphy and the sequences
exposed in the Bodal-Bhandaritola area are presented in Table II.
TABLE I. RADIOMETRIC AGE DATA ON ROCK TYPES OF THE DONGARGARH URANIUM PROVINCE
Metarhyolite 8 2503 ± 35 Whole rock 0.703 50 ± 0.001 69 J.N. Gupta Effusive phase o f
(Bodal area) Rb-Sr (unpublished) Dongargarh
granite
SIN G H et *1.
570 Ma
Upper Chattisgarh Raipur Group, Not represented
Proterozoic Supergroup Chandrapur Group
900 Ma -----------------------------------Khairagarh O r o g e n y ------------------------------------------------------------ ----------— ■-----;---------
SINGH et al.
Note: The age o f the older unconformity is modified on the basis o f data presented in Table I.
406 SINGH et al.
I l l i «k<*
I I I I - 1 I .... l l I
* sulphide
° MIHERAIIZATKM
• URANIUM
{S a SHEARS
, - ' F FAULT
f
FOLIATION WITH U P
CONTACT WITH U P
E3 SILICIFED FAULT
ROCK/OUARTZ VEIN
J '' DOLERITE
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lE 3
GABBRO
DTKE
m DOHGARGARH GRANITE
t r - m METARHYOLITE
L l - J PORPHTRY-IHANG MALI)
R R ULTRABASK ROCK
B R U AMPHIBOLITE
METAWHVOLITE ANO
llxi) RHYOLITE-PORPHYRY
(FOOT WALL)
BANDED HAEMATITE
QEJ QUARTZITE
I I PHYLLITIC SHALE
FIG. 2. General geological map o f Bodal and adjoining areas based on photogeological
interpretations [8] and geological mapping [9, 10].
Local geology
STRUCTURE
The rocks o f the area have been tightly folded, with the major set o f folds hav
ing the axial plane trending roughly N -S with both limbs showing steep dips. Small
disharmonic folds with axes plunging at 20° to 40° towards the NW are common.
Cross-folding results in easterly swings in the strike in some areas, for example west
o f Karmatara (Fig. 2).
The sequence o f acid-basic-acid metavolcanics in Bodal, bounded by Sakoli
shales on either side, represents a major syncline, the core o f which exposes the
metabasic formations, now represented by the amphibole-biotite-quartz rocks (a
type o f orthoamphibolite). The mineralized metabasic rocks are exposed along the
core o f a syncline, bounded to the east by a large mass o f intrusive gabbro and to
the west by the Dongargarh granite.
Two major shears are noticed in the area — the Bodal shear striking N 40°W -
S40°E and the Bhandaritola shear striking N 15°E -S15°W . There are a number o f
faults that traverse the area striking N -S , as well as ENE-WSW and NW -SE.
PETROGRAPHY
Basic volcanics
The metabasic rocks o f the area are generally massive but exhibit a discernible
foliation due to elongation o f prisms o f hornblende and flakes o f biotite in places.
They show many relict igneous textures such as those o f porphyritic and amygdaloi-
dal types. They have a metamorphic overprint resulting in crude foliation, microfrac
tures and late stage slip planes. Coarsening o f the fabric is evident particularly along
the sheared zones.
A d d volcanics
The acid volcanics o f the area comprise strongly porphyritic to fine grained
types, characterized by flow layers in many exposures. At several places the
metarhyolites show foliated fabric. The porphyritic varieties consist o f large
phenocrysts and augen o f orthoclase, acid plagioclase and bluish quartz with minor
amounts o f biotite, chlorite and sericite in the groundmass. The main accessories are
zircon, apatite, sphene and uraninite. The quartz porphyries bordering the
Dongargarh granites at Bhandaritola, which host part o f the uranium mineralization,
have structures and textures akin to those described as ‘protoclastic’ [11-13]. The
presence o f protoclastic rocks is characteristic o f die epizonal environment o f
emplacement o f the Dongargarh granite plutons. The relatively less metamorphosed
nature o f these acid volcanics contrasts with die metamorphic features o f the basic
rocks.
408 SINGH et al.
Dongargarh granites
The Dongargarh granites near Bhandaritola are mostly coarse grained and in
places porphyritic. They are feebly foliated and comprise quartz, orthoclase,
microperthite with minor amounts o f hornblende and biotite. Zircon and epidote
occur as accessories.
METAMORPHISM
The shales and phyllites o f the Sakoli Group and the metarhyolites have
registered a very low grade o f metamorphism, not exceeding the impress o f the
greenschist facies. Though metabasic rocks in the area preserve many primary igne
ous features, assemblages o f hornblende ± oligoclase and hornblende + andesine
indicate metamorphism under the epidote amphibolite and amphibolite facies [14].
This higher metamorphic impress could possibly be due to diaphthoretic changes
brought about by introduction o f water into these rocks under conditions o f shearing
and low temperatures, the metamorphic facies being influenced by the low water
vapour pressures. As is well known, basic rocks respond to such changes more than
acidic and sedimentary rocks like shales and phyllites, since the metamorphic
changes are from high temperature assemblages to lower temperature assemblages.
Regionally, therefore, the degree o f metamorphism is that o f the greenschist facies
or even lower, and locally, especially in basic rocks, a higher metamorphic facies
is seen.
A clue to the tectonic environment o f evolution o f the rocks o f the area may
be obtained from die petrochemistry o f die volcanic rocks. The metabasic rocks have
a chemistry akin to those o f subalkaline tholeiite and basaltic andesite. There is a
large silica gap between diem and die associated rhyolites, emphasizing the bimodal
nature o f the association (Figs 3 and 4). This suggests continental affinities and is
in keeping with their Early to Middle Proterozoic age. The epizonal and potassic
character o f the granites and the relative preponderance o f rhyolites over basalts also
IAEA-TC-542/24 409
0-0 □
7>0
ALKALINE ROCKS,
x "
0-0
so * • o • O
gZO 3 O
4.0 ■ Z o o
5 <?’ •
oo SUB A L K A LIN E
AO TH O LE IITIC ROCKS
o °o +
CM>0 *4
+
o 2-0
£ A
2 A
1-0
BASALTS — ♦ B A S A L T IC — < -A N O € S IT E S —
ANOESITES
--------------- -- S1O2 (W t% )
FIG. 3. Na2 O + K 2 O versus SiO2 diagram o f the metabasic rocks and metarhyolites o f the
Bodal-Bhandaritola area [15, 16].
Number of
U Th K
samples
Metarhyolites and
quartz porphyries 11 5.8 30.2 4.20
Dongargarh granites 24 5.8 30.8 4.07
Metabasic rocks 43 2.0 6.3 0.92
Sakoli shales 3 5.3 16.4 2.98
confirm such a continental set-up. It is, therefore, suggested that the development
o f the Dongargarh Supergroup was possibly heralded by rifting o f the crust in the
beginning o f the Early Proterozoic and was followed by acid and basic volcanism
and synchronous granite emplacement.
Abundances o f U , Th and K in the granites, the acid and basic volcanic rocks
o f the Dongargarh Supergroup and the Sakoli shales are presented in Table m . It
may be seen that the U and Th contents in the acidic rocks are higher than crustal
averages.
The radiometric age data based on total rock Rb-Sr isochrons, K-Ar mineral
ages and Rb-Sr mineral ages are presented in Table I.
It may be seen that the Dongargarh granite complex has a large time span o f
emplacement and crystallization, covering the period 2500 to 2200 Ma; the different
phases have their temporal equivalents in the acid eftusives.
The mineral ages are suggestive o f a broad time band o f 1700-1400 Ma, when
there was a pronounced thermal event [6].
The initial Sr ratios for the Dongargarh granite and the rhyolites are signifi
cantly low and point to a derivation from the upper mantle or lower crust.
IAEA-TC-542/24 411
URANIUM MINERALIZATION
Mode of occurrence
In the Bodal ores, pitchblende and uraninite form fine veins and dissemina
tions. Radioluxography and solid state neutron track detection studies reveal that
pitchblende and uraninite occur in. microfractures without any mineralogical
preference, thereby confirming their epigenetic nature [18], However, development
o f high grade ores (0.38% U 3 O8 ) is confined to metabasics containing iron rich
hornblende and opaque oxides [19]. This could be due to the geochemical influence
o f F e 2 + /F e 3 + ratios in the amphiboles in localizing mineralization.
Pyrrhotite, pyrite and marcasite are the common sulphide minerals. Minor
amounts o f chalcopyrite, molybdenite, galena and polydymite (a N i-C o sulphide
mineral) are also present. The content o f Cu, Ni, Zn and Mo in the Bodal and
Bhandaritola ores is shown in Table IV.
Ilmenite with an alteration halo o f microcrystalline anatase is present [20]. The
presence o f fine grains o f electrum is also suspected [21]. The ore zone contains en
echelon veins o f bluish quartz a few metres in length and up to half a metre thick.
Stringers o f quartz and occasional adularia veins are also present. They in places
contain sulphide minerals such as pyrite, pyrrhotite and chalcopyrite and pentlandite.
Interestingly, the ore bodies contain fine spheroidal aggregates o f graphite,
associated with the gangue [20]'. The graphite could be a primary mineral and may
412 SINGH et al.
Pyrite and pyrrhotite samples from Bodal ore zones have given values o f
+ 1 .8 7 to + 1 .9 4 per mille. The small spread o f 6 M S values near 0 o/ o o is sug
gestive o f a magmatic origin o f the sulphur (Table V).
IAEA-TC-542/24 413
ILMENITE
PYRRHOTITE
PYRITE
CHALCOPYRITE
PITCHBLENOE
(a )
(18) (b)
FIG. 6. Semivariogram o f Bodal deposit (a) accumulation and (b) thickness [22],
414
TABLE VI. GEOLOGICAL EVOLUTION OF THE DONGARGARH URANIUM PROVINCE
Upper Proterozoic Formation o f Chattisgarh sedimentary basin
Closing o f Khairagarh Orogeny
Middle Proterozoic Continued basic volcanism
Sedimentary type uranium mineralization
Deposition o f arkose, conglomerates and tuffs
with rhyolitic provenance
SINGH et al.
Subsidence and formation o f basins o f sedimentation
Hydrothermal activity and uranium mineralization
Onset o f crustal adjustments and shearing
Continued emplacement o f Dongargarh granites
Eruption o f subalkaline tholeiitic basalts
Early Proterozoic Minor sedimentation (tuffs and clays)
Eruption o f rhyolites and emplacement o f
Dongargarh granites
Rifting o f crust and formation o f basins o f deposition
Late Archaean Evolution o f Sakoli and the older Amgaon Groups
IAEA-TC-542/24 415
The variogram models (E-W direction) for die variables thickness and
accumulation are presented in Fig. 6. The modelling has revealed that both the thick
ness o f the ore bands and the accumulation (grade and thickness) can be regarded
as regionalized variables. They have spatial variability which can be modelled by a
spherical variogram. The model shows that the random functions (i.e. uranium
mineralization) can be considered as a composite o f random (noise) fluctuations and
a spatial structure. The nugget effect accounts for 35% o f the total variability. The
remaining 65% is accounted for by a well defined spatial correlation. At least for
the E-W direction the continuity is established for about 150 m (range) and beyond
this range the variables become independent [22].
DISCUSSION
(7) The hydrothermal fluids were generated during the magmatic activity in the
region. The sulphur isotope data lend support to such a view. These fluids pos
sibly took up much o f the uranium during their sojourn through the uranium
rich acid rocks along their pathways to specific lithostructural locales.
(8) It is possible that the Dongargarh granites and rhyolites themselves could have
contributed uranium to these circulating fluids, though not necessarily close to
the existing pre zones.
(9) H ie xenoliths o f rhyolites in the mineralized basic rocks also could have con
tributed some uranium into the system, though such additions may not be
significant.
(10) The time o f uranium mineralization could be around 1600 Ma, considering the
closure o f the Dongargarh magmatism to be around 2200 Ma and the begin
ning o f the Khairagarh sedimentation around 1600-1400 Ma [6]. The presence
o f sedimentary type uranium concentrations in the Borthalao conglomerates
and their equivalents bears testimony to the presence o f uranium rich zones in
the older provenance rocks o f the Nandgaon Group. The indication o f a
pronounced thermal event by numerous mineral ages between 1700 and
1400 Ma also supports an age o f mineralization falling in this time bracket.
(11) This postulated age will have to be confirmed by the U -Pb dates o f the ura
ninites from Bodal. If is, however, tempting to correlate this age with the date
o f uranium mineralization in the Singhbhum uranium province o f Bihar, which
has been dated at 1478 ± 14 Ma [23]. The two belts are separated by the large
Chattisgarh Basin o f Late Proterozoic to Lower Palaeozoic age.
ACKNOWLEDGEMENTS
The data presented in this paper have been generated as a result o f field investi
gations carried out over more than a decade by a large number o f geologists o f the
Atomic Minerals Division. The authors wish to express their deep gratitude to many
o f these geologists with whom they have had discussions from time to time. The
geochronological data presented in this paper have been communicated by J.N.
Gupta, petrological data by H.M . Verma and Dhana Raju and statistical data by G.
Viswanathan, scientists o f the Atomic Minerals Division.
IAEA-TC-542/24 417
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418 SINGH et al.
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DISCUSSION