System

Cveatec. pomets
com
sepha
C-pt2.
f= 42
9-9
>f=2’ f 0istoo
+2=
A
Distillate anyEmowm gas
frecdom ff be
(D)
ule Vola4ile
ore
the
DRgree
(Proviyoour)
dks Jiguid
f Recidaeeboiley
im
JA+BT ction
MatDiliion (onore)
ly.
e-dive
respe
fra
more Veladile
A:Velaile hore mole
feed Jess
R:
 Lflash Dis-tìlla tiom
Bemreme, ToluemeIo 'c)
(Kf= Soc) (BP- I then fed
up
headedvupoarizotio qapid.
feccd is nqkes
ubich DistIMa
8: An Eruimalor Jiuic mirn of Cbacieg n, called -flath -4io,
-hus
ß ae in Eoilh bricim alith ite, Yapoua
CoME)
o+ 4oo'k. A4 thie -lemþ Raou 14lr loo
J Mass ßolomce
pok fa, Assumig -that
f.: 120k Ovenall D
of ya:
ie valid. Jind -the value fed
A Component Ralamee
f. Í, H
=0tx)Eo+ ôX/2o

: Enrthaly
mole fraction of more Resioue
2! yolatile compomet
Now,
ic beimg flosh diss tiMed
mole o Toluene Jatm totat
chould mot
* ReJative Volail to or wps) precsae. The Ji2uid produet of RemTe me,
Mole fo of A Comtalen o e tham 3o
Mole fo 4 B/ Calceelate the anot0t emd the comsocitio
Mole fr ofA produ t 2-c.
2)
Mole fo ofB/1 () of topf the botlor

Sol Rasis ! 1hr

Jo= D+w
OMB! f= D+

|+ (oe-) Tolueme:
B
Ralasee of RenIen
 S
Shif

# Sleom DistiMatio,
As het le No flut
Jmnitcik
plso.
Used fo
J.Heat Sensitive
moteiol

Ha rodou
Steam kelbstamces
(Tuspemtime)
ration
3. Decolovi
oit.

* YocceuT distilation
n/tuve
Vaceum is used to boil the
scuve thus BP
Teadueing the prvfemb. oT favoa ble
by mormal eom
-Jo the
-t emt.
pharmo ceutieat in dustry
Differentiat Dictillatier
s Rotch /Rayleigh/
6214
idiMade)
O,odD
enole ef
A : Joitiol
L-dL feed of
-d! : fimol mee
fed ofteo At
Rsicue Joidial nole
fraetiem of
dD:finol moles of AY im feed
- d : fimol nole ef
fte At
vab generQted fed.
of p' jm
 S2
9(1-Xw)
16
2
FCI-IF)
MB) (0 30
2 o
Joe f= +Id! -ydl -ldr
04 CTp)a=
diom ra mole 2) t) from
ate. the im 'p' of
the bebimd
the Fimd 2). (o: ecidue moles
of to xdl D+ yd ld
collieted distillate
js
tillation dis Radeh ydb rdl: Ldr- -
st 4e amd
t stil.
hPfler IsB', of emole
comtoinimg
aoeqled
im
7n0Je 60 A00
) Vola (nore bima. p of o a of moles
nictue
Rolomce. Cembememt
p'
dbU) -dl
() J-
OMB
 Iy 0 402, 2. 429

' Balamee o90 }"48

4

Iw O 219

Now, comþoment
Bolamein9
02/9X9r p X25
0.45X ro
Q+ A fed of rokmol
of a nittue of Benlene
Cp 0- 681 Ars
and chlovobemEeme havin9 sr of the let
Volo4le hoe to botch dicilled. 2f 2r Fmole
f the colutio vasori sed amd Comdem ew) 4losp4
Meulti stoage fraefiamatiom
as Ae distllote. Calculote he Ceme of
-he a ccamtlotcd dictillote. ( 4.1 5s) nie-tuve
Bimay V: Vabotir
Chlero beIene: nore Vol. Rectificatiom/Fricbrent
f= So kanol Secliem

fecd Ven41
Hen
stibbim?
W= 2r kmol ( By oME) Secdiem

Jm N
Ho-l

2 2 Reslolae
W, H
(1-t)
9x
se oto yo joto har btka subseyi
haim
 MC- CObe Thile Methed Shit t

0f theoTetiealNo L/D

J.Comsamt molan
ovenloo rale -rog)
VEV,: V : Vy: V

R+l

y-m+ c Oheratimg Jime (utser)

9. Negligiblk heat Jost
s. ErrthalyIe comtomt Pmot chomge coit
-dhee comb0siem. D(*p. Xa)
Oforichtnent Seeien droight Jioe Aa sses toogh
Total Mass Ralamce (TMB)

(omkomet balomte Sectiom

Ln
Compomem t balemce
Ven+ Vm

fluz rotio: R:
Ln-l Vm
Use ef 0:0 as tuell as Assum ptlon (!)

tire Assumptio
L_
Operothg line (Letwer)
 7-W
= Hfy H

Jattea trough

Opevading (Ubc)
Cun ve

Lg) (Hy - Hy)

fCHy- Hv) = (ly- -
R+I
feed ine H- Hh
l-L4
Lotver Hy- HL
Okeraimg
Curve (100) Srterseciom boimt
here Hy -HL

feed Jme ahoog jnteseetom molar rate

Net ‘ in Jiuid
bojmt. Jeed floto rate

liguid in fd
=frocion of
V Volue af
feed
- gat. liuid
So4 Vafour
(olad Jiguid
5Sut headed
afowr
Fothalhy Batonte.
Com b. alom ee
fon nedifylag Section
-1
ab.
Ofor Saadurgted O for saturaded

)fe Cold 1ig.

So, n
stoihbimg tectio heated obour
Comp. balomce fom Ofor Super
Mix ture of L4V
( ) -(o)

op7a timg Jime

Nelet n fractieal for otoer
dato uphe operating Jime , than
fir: twith the
-the feed Jime t joim Aw Xw)
tue

(8) Datertedicm poit to get

lovo e openatimg
Jime.

er operatimg
J ine

R+1

Jime
rays Cue dn0w vertico f horizotot
for No. ofshown here the mo. 4 peak (4)i
Jinu ike
the theoretiead mo. f tra
3feed ones b/eo
 tab
3

f A methamo havimg e
Caps lock
A wE
S
Bk Dutta jndo a
*
to
methomel CCH,OH)
searatedoj
Araduet hovimg ge
botoms Jipuid
fecd comeg b/us ,th
js the fed trag -tray So, th
nethamol. The fecd ic at i'

here, R- s r DDeternine the No. of fseol

tRafhuse
-trays ind the No. of real
-ay fficiency is hon imd the feed
-tray jetitien.
84 0729
079
602
06
623
06 0304
0-365 8
09s8
O-2 6979
0665

04

Solut iom: fmrichmend Section

Jntercept:

(A Ne of 1deal rays : 6-S

 jom cf the cif-oieng
embenaturc
cemtrol
-hantiat Comdeteo Totot R Miminnn R
yefours
No.of : Mimimum
No.
Tray s( debemds om
tayste of traye)
(debmdt mfeplun
yu Comditiom (D:0)e Oo"y: fec fes lood
OTotal if Refu
Mimimum Restun vatio em Re boiler fec)
fired cott f Reflux
Relation b/u Ne. of trayE No. of toayt
Jes
) Min. mo. of Jime Rt4>
roy fixed eott Jes
)oeratimg (AL
ceytlead
fesem
abollsn tu)
het, ema
fen s ke En comtant
N+=Jog

4 lowem
eratimg cuve
tMimin tin
tott

tort
-broye)
* Mimines Refluc Ratie Condi4iom fixed cost 1)

Minirnn
CCam e beyend oplimm
As R
K (Mar)
er folaat
* Tray Lficiem ey
No. of theore tialatrays OF <loo +%
No ef Aethal a
overall Licient
tEHicieneie
hree voboumlou, The frete
Catyed by les
Murphe ereded
inefficient fo hold
the vabotur i8
heote
-the lhed em the ray berfoeratioru..
tartt -t leok threongh

otaim mpmt
est carriu the iguid
here
here twitk itvopour, leoim
to change cernptitien of
Dictillote.
t a po ind -Jakan avg
-he tray HA
Sove Ix: 7.12
be
goeater than oe
* Azeodrope
Dowmcone
A micture of Jiguid ubich has &oTDe
connpomenti , So Separa-)
Oflecdimg boilimg þoint for boththem.
-fiem is mot þesible
Jaleim
Otueir Emtroinment

heontomer : helk: the oVe flovone iguid Joe'e) (8)

by trovidimg ferms Preotrese

thid cob
-fere eparatiom amoter
to ctìllatiom
-omet s added

Jlovo e cuch that rag force af iqid hemteme (onisci ble tuith ethame/) I
tecomes greater thor graviBatiomal foree - Kenzeme /Cyclo
drep tuise
tubile al's tillatie.
Ic oddd
No ploforatiem figuid hotpng ittllate: hamol Bemrerme
Do nermal
Reridue i Water dietillatlom
stopt haoe only
Bemteme.
 Gaps lock
A

Pochon Savavit Methed

Fzeotrote J+ve deviadion Feom)
Mim/mum
Soilimg Ceordege)

molar
tamt
DNo comg
Llowrate
dapends cafom
fnthaAy
T
O
mn timg in
doionsasd Seetien
direeto Rectifyimy
H m
H
Maimum Boiirg Are otrope ve deriadien compeeyit balaoce (A)

Lm

balance
fothalky
heat eleased
Curve
(Hs) ber cenit
JictlMote
[Read fren &k Dutto
 F)
HL
HE
amd
Methed
t fonchet * eidimg con
HL
19/es/24
DM,
)Zi2ne (
Hn) (o,
t+ oimti for cote Qiila
-H Hv O,) (h,
Slobe
J+R 1)
(Line
Safose
HbHL,o O' V and Hy.m)
+D Lo Lo Ymt! T,-
Lo O'Hy,m+!
HL,m O,'-
H
1
hare,
-O,' HL,n
D (9) Fym+
ta) D(b, ,to TMBp'oom fet
get
A
lock Cops
 Zm

Hym+
H ie Jione HL,m
Hv
Ht,n
No. of

-rog im Aoimt1

Goifhimg saelion feetityiny

Qetio. Lime(1)
slobe =

Consicler
beiti: (ILm, Ma)
Comb baloste (A)
Limet2)
klope:
thay
Limmo l) is baro1el to Lie (2). bt
So. baint ao ( ,S) So
Comnom
haye
Co-liea
(Iem He,m)
(Im, Hi m) amd
fregy Ralomee 1Vm (Ym1 Hum+t), Lm
imear
WCIN Oo!) are co-ll
demotes a ficlitious glveom
-’ CovceTtratiom
of
XH

(Lom- Veri)
Graph wil look ke
Hy

-H
demotes
imtermRdiode boimt F(F, Hs)
compositiom
the
ktate of feed in teng of
tha
Emthalby:
No. ef ideol treys
+ To detemime
assune hat the
coDceTrotiom,
distillote
te flow rates of te
enthaies eu ase- eflut ratio
the botom boduet
Sufficlet dataame sAhlied
QTe 9iven (om f these 2uamtthee by
-for -he caleulatiom balamte.
naterial p Erme9
Qe o cated e

(3)
F(F, Hp) is to be Jo cated.
feed þoimt Edented to oeet the
1 E is joimed g
Mho) at the
yerdical one tough (Th
point W'.
either
Comsttsetie of stages om af froceed Orer ba
from ' or from the feedhamgec Jie is cratred.
Jo Ae dome afte
chogeover is
at obieh the
The ay wl be the fead ay. Conttrutia
mode that other bont is reached.
Aoreds iu te
 A

methac to find.
Solve
olutio
No. cf
ielecl oaysJdaaltroys) ! e eed omly
x 12 = 9
11':
þer mim - a y So
t ro 9m mela (As O
bt have 9
Kenzeme (move Velatile)
atisfoctoy.
nh
mtyatueve = 92
9T4,
ligeuid Egui2ihoia
eguilikia
bimeycae mmetho
92
Node dy Cont. tep. strair
*Cchy toe tse
(simn)laly) Ligid Ftroetio (LLE)
+ Liguid- krocene/Ether kE + Nicoti
Cem refiom
fo mole
of ot.frattion Wshaking,
-Sohe fraetio. LJoter
Sahant
Veg
Nicotim
doas fesd tine
Nicoti
(Eztaet phoe)
/E + N Ctokte b phaj
91lasleu Jeed (F)
a methgmm6k INicofim ate
oeomple 2ri feed: Joce kg /hr f (Raffimate bhase)
ot it bubble boint todvemt (:)
(k/EY [sete leam bhajeJ
Nieotim sadte-C
Ne f plades : )2 lodes
then After Kmi late
boe have p?. k/E Raffiate (R)
then twe fatract (E)

anim Can aao be

sed
Knint get Renio.
 (4e/ta)
(T:/Xa)
riengular Diagrem
fretract phae(E)
Salude
offimaf phae (K)
Salvemt
(Rofnak Setle
aten)
Jelvamt
TMB, f+S= E+R= M (say)
tomnb. bolam ce, (e)
Lquilateal -tiemgutor Diagram
MN, MA, + MN, =Cr
MN F+S
CT

MN B
CT
JeokA MNg
CT S

*focors affeedig LIE

Tenn parefuee ‘, ni scibili 4y ‘
OYisoousity of sodvent
olte
Viacousity 1. fousen eomiuenkdiom 1
Sunfotk -leniond Tent , sraadnss ‘
cam fine Solvemt
 Eilotrol briomgulor Sydeor
c(lee)
2 B
Ac fima hag mog'
le
AR imne hat mo
çete C

(/eoe) (0e
to.A 1t. A

Note

foude cone
cakntate Caie comc
teletivity(8)
Solte cemc

Corier comc /Raffimk

-fimd tomemg throgh

heregoash
fem grosh harltet
 t stag heratiem
TME.
9
solte alamce
S Ter + S Yee= M, XcM,
S S2
CM,
:+k O: 202
TMB : f +S, =M,
Jodute Balomta : eg t S, te, M, TcM.

tee, Xer,
M
btaimed

, +f M of TMA +
M
Sodute kelame.
+ &ICe,: M XCy,

onikarly de for ott them esat the

o610412
4

9
Total

(2636 *q) af SoLute eteted

Net
Yeg:002 406-2 - 7 = 918:4 kg
A-ate
BeKane
 * (osmder Curont fadractiem
Jeed ()
Ldeal
k
*Solid- Lipuid fotractiom
Ry - ) Overtos
TM8, f 4S: M,: E, (Soldet
Solyemt)
Sedde
Balamee

haradlel to e Jime o
RSovemt - ercome (He ae) Ltmder (low
(fmet Solid/laku
4 Selutel t Sohent
Je
Jolid
rent, forb
Solvnt boilimg þoint
cheat. mom- toxic, Jow
E,-f: S- kN A Aular
Cooralimate Systen
DEight overfloo
foacdion f conþomemt cemale flow
TMB: K-! +S= Eh + R fraction of com pememt
Em Rm-= N-S= A
olute

S= 2soo kg/k tundeew) (X VA Xe)

Xcgs4r Solvent
 Caps

Unolerftoo
0397o
t
0149o
O444 o2420o

(orcler flou (loo kg solm)

O:328
O:299 O0296
O281 O0496
* fomcho Sovamd diagron 0.2r1
timdenflus
Xe
in mderflow
0) Aular diogram
A-free batia f- Jooo kg
Ovefleo
trrough.
M

Xe, Ye
TMB)
f+S= M- L4y
Jolte
to ti
Aumclerfle
Y= Mau fractiom c
1: Ma of Roid Sodute (e) Balamce
A-free bauin
A M

Cveeflo
O
Nors.
JMB L4Ve M= 2reo v(Cy: O14)

fd (F),
Leg

Unole ftous(
1=1921 kg V l2v9 k
 Balante
A) ( idSol
0+195 B+C /69r M'=9+
600= 1
=1 (95 So.
ohy is had
balamce Selid 5o 2
olheed. becomtOgaimSo /49 O 149 O:
o-090
C=19c Ye
tohat Lolomce olA do
if J95
o1s fatvactd 4=12 9
line Tie
foaction TMA
l29g:4 v'=
kg oil M
(Ye:')
kgf96-6 l= L'
Ralamte
A
Sovamt fomehen G)
TM
(PS oom piag
D)
k
69
Valnel
 Cocrmte Cunent SLX

Lm'

(x,Z)
1
B+C
SCo,o)

TBM. M.= LN+ ad Fs= M,L

Sobjd Balance,
FI'+ S, ze'= M,' IM
fEpl+ S, Es'