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Paper / Subject Code: 89242 / Chemical Reaction Engineering-II

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1T00536 - T.E.(Chemical Engineering)(SEM-VI)(Choice Base Credit Grading System ) (R- 19) (C

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Scheme) / 89242 - Chemical Reaction Engineering-II

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QP CODE: 10042063 DATE: 13/12/2023

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Duration: 3 hours Total Marks:80

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N.B. (1) Question No.1 is compulsory.

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(2) Attempt any three questions from the remaining.

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(3) Assume suitable data wherever necessary with proper justification

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Q.1 a) Differentiate true density, apparent density and bulk density (05)

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b) Explain the step input experiment for the determination of RTD of the reactor (05)

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c) Draw the concentration profiles with all nomenclature for fast gas-liquid (05)

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reaction with low and high concentrations of liquid reactant.

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d) Differentiate the shrinking core model and progressive conversion model (05)

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Q.2 a) Develop conversion time relationship for spherical particles of unchanging size (10)
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using the Shrinking core model for the case when the chemical reaction is
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controlling resistance.
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Q.2. b) Develop a Langmuir-Hinshelwood type of rate equation for (10)

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𝐴+𝐵 ⇄𝑅+𝑆
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When the adsorption of B is rate controlling step.

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Q3. A reactor with a number of dividing baffles is to be used to carry out the (20)
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reaction
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A→ R, -rA = 0.05 CA mol/(l.min)

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The results of a pulse tracer test are given below:

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t, min 0 10 20 30 40 50 60 70
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C 35 38 40 40 39 37 36 35
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i) Calculate mean residence time

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ii) Find the conversion expected: (a) assuming plug flow, (b)
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assuming the tanks-in series model and (c) assuming mixed flow.
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42063 Page 1 of 3
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Paper / Subject Code: 89242 / Chemical Reaction Engineering-II

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A(g → l) + B(l) → R(l) , -rAl =kCACB

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in a packed bed. 85

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(i) Calculate the rate of reaction.
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(ii) Determine resistance offered by the main body of liquid at a point in the
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reactor where PA = 100 Pa and CB = 1 mol/m³ liquid.
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Data : k= 10 m3 liquid/(mol.h)
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HA = 105 (Pa.m3 liquid)/mol

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kAg a = 0.10 mol/ (h.m3 of reactor. Pa)

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kAl a = 100 m3 liquid/(m3 reactor.h)
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fl =0.01 m3 liquid/m3 reactor

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a = 100 m2/m3 reactor

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ƊAl = ƊBl = 10-6 m2/h

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For MH< 0.02, we have an infinitely slow reaction.

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b) Calculate the time required to burn to completion spherical particles of (06)
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graphite (radius 5 mm, bulk density 2.2 g/cc) in an 8% oxygen stream at
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900oC and 1 atm. Assume gas film resistance to be negligible. Surface

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reaction rate constant = k” = 20 cm/s

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Q.5 An active carbon catalyses the oxidation of NO according to the following rate. (20)
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𝑝𝑁𝑂2 . 𝑝𝑂2 𝑚𝑜𝑙

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−𝑟′ = ,
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[𝑘 + 𝑘1 𝑝𝑁𝑂2 + 𝑘2 𝑝𝑁𝑂 ] 𝑔𝑚 𝑐𝑎𝑡𝑎𝑙𝑦𝑠𝑡. ℎ
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Pressure is in atm, k1 – 0.001352 , k2 – 4.812, k – 0.0001619

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Find the volume of a reactor for converting 50 MT /day of NO to NO2 when

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using an air -NO mixture containing 15 mole% of NO. The conversion of NO

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is 90%. The bulk specific gravity of the catalyst is 0.48, and the total pressure
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is 3 atm.
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42063 Page 2 of 3
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particles. Also find out solid hold up in the bed.

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Paper / Subject Code: 89242 / Chemical Reaction Engineering-II

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using a 1000 kg/h feed consisting of equal amounts of 2 mm and 1 mm
solids in a fluidised bed reactor operating with the same environment as before,
controlling. The solids remain unchanged in size during the reaction. Find the
product in 5 min according to the SCM with the chemical reaction step as rate

mean residence time of solids needed to achieve the same mean conversion of

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Q6. a) In a uniform gas environment, 4 mm solid particles are 87.5% converted to the (10)

Q6.b) Discuss the reactors used for carrying out Solid Fluid Noncatalytic reactions . (10)

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