Chapter # 04 & 08 (Chemistry 11th ) Total Marks:30

Q # 01 = Answer the following questions?

1. Find the value of “a” and “b” in Van der Wall’s equation. (03)

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

2. The density of air at 161.325kPa and 298.15k is 1.59g dm -3. Assuming that the air behaves as an ideal gas, calculate its
molar mass. (03)

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

Engr. Tariq Mahmood (03215259599) Page 1

Chapter # 04 & 08 (Chemistry 11th ) Total Marks:30
3. Define Joule’s Thomson effect and grham’s law of diffusion. (03)

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ______________________________________________

4. Write two units of ideal gas constant. (01)

_________________________________________________________________________________________________

_________________________________________________________________________________________________

5. With the help of kinetic molecular theory show that k.E is proportional to temperature. (04)

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

________________________________________________________________________________________________

6. Explain curdling of milk with lemon juice (03)

Engr. Tariq Mahmood (03215259599) Page 2

Chapter # 04 & 08 (Chemistry 11th ) Total Marks:30
_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

7. Define pKa and hydrolysis.(3)

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

________________________________________________ ________________________________________________

8. Classify each of the following as Bronsted acid or Bronsted base (a) (b) HBr (c) CH3COO-1 (03)

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

9. Calculate the pH of formic acid sodium format buffer solution containing 1 mole of each component. (04)

Engr. Tariq Mahmood (03215259599) Page 3

Chapter # 04 & 08 (Chemistry 11th ) Total Marks:30
_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

10. An aqueous solution contains 1 ×10-9 moles/dm3 of hydronium ions. Calculate the pOH of these solutions. (03)

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

_________________________________________________________________________________________________

Engr. Tariq Mahmood (03215259599) Page 4