SAFETY DATA SHEET

Date: February 28, 2019.

SECTION 1 Identification of the Substance / Mixture and of the Company / Undertaking
Product
Product name: Tanoi Paste EX
Product Description: Mineral Oil and Additives
Intended Use: Metalworking Tapping Paste (Non water soluble oil)
Company Identification
Supplier: SHINCOOL Company Limited
89 Nakashiota, Narumi-cho, Midori-ku, Nagoya, Aichi 458-0801, Japan
Telephone no.: +81-52-623-5667
FAX no.: +81-52-623-8705
e-mail address: shincool@mc.ccnw.co,jp
SECTION
SECTION 2 Hazards Identification
Classification and labeling according to Regulation (EC) 1272/2008(CLP)
Signal word: Danger
Classification: ACUTE TOXICITY: INHALATION - Category 5
SKIN IRRITATION CORROSIVE - Category 3
Eye Effects - Category 2
Cell Mutagenicity - Category 2
Target Organ Systemic Toxicity: Single Exposure - Category 2 (Lung, Respiratory tract)
Target Organ Systemic Toxicity: Repeated Exposure - Category 1 (Lung, Skin)
Aspiration Toxicity - Category 1
Hazard symbol or Symbols:

Hazard statements:
Toxic if inhaled
Mild skin irritation
Eye irritation
Suspected genetic disorder
Risk of organ failure(Lung)
Precautionary statements
Prevention: Wear protective gloves. Wear protective clothing. Use only in a well-ventilated area.
Avoid release to the environment. Do not breathe dust. Do not eat, drink or smoke when
using this product. Wash hands thoroughly after handling.
Response: Collect spillage. Immediately call a POISON CENTER or doctor/physician.
IF SWALLOWED: Rinse mouth.
IF ON SKIN: Remove/Take off immediately all contaminated clothing. Wash with plenty
of soap and water. Wash contaminated clothing before reuse.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
Storage: Store in a well-ventilated place. Keep cool. Store locked up.
Disposal: Dispose of contents and container in accordance with all local, regional, national and
international regulations.
SECTION 3 Composition/Information
Composition/Information on Ingredients
Description of the product ：Mixture
type
Ingredient name % CAS number
Mineral Oil １５ – ２ 72623-86-0
Lubricant Additives ８５ – ９８ Confidential
Hazardous components
No dangerous ingredients according to Regulation (EC) No. 1907/2006

Japanese Composition Information

Industrial Safety and Health Law: Article 57, Chemical substances to be labeled: None.
Industrial Safety and Health Law: Article 57-2, Chemical substances to be notified:
Name ISHL Ordinance Number
Mineral Oil 168
ISHL Enforcement Order, Table 3-1, Manufacturing Permit Chemical Substances: None.
PRTR Class 1 Designated Chemical Substances: None.
PRTR Class 2 Designated Chemical Substances: None.
PDSCL Chemical Substances: None.
Note: This law and regulatory information are Japanese law and regulatory information. When used outside
Japan, please follow the law and regulations to your country.
SECTION 4 First Aid Measures
First-
First-aid measures
Inhalation:
Get medical attention immediately. Move exposed person to fresh air. Keep person warm and
at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing such
as collar, tie, belt or waistband. Incase of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Skin contact:
Get medical attention immediately. Wash contact areas with soap and water. If product is
injected into or under the skin, or into any part of the body, regardless of the appearance of the
wound or its size, the individual should be evaluated immediately by a physician as a surgical
emergency. Even though initial symptoms from high pressure injection may be minimal or
absent, early surgical treatment within the first few hours may significantly reduce the
ultimate extent of injury.
Eye contact:
Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally
lifting the upper and lower eyelids. Remove any contact lenses. Continue to rinse for at least
15 minutes.
Ingestion First aid is normally not required. Seek medical attention if discomfort occurs.
See section 11 for more detailed information on health effects and symptoms.
SECTION 5 Fire Fighting Measures
Extinguishing media
Appropriate Extinguishing Media:
Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Inappropriate Extinguishing Media:
Straight Streams of Water.
Special exposure hazards:
No specific fire or explosion hazard.
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is
a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous Combustion products:
Smoke, Fume, Sulfur oxides, Oxide of carbon. Incomplete combustion products.
SECTION 6 Accidental Release Measures
Notification procedures:
In the event of a spill or accidental release, notify relevant authorities in accordance with all
applicable regulations.
Spill Management:
Land Spill:
Stop leak if you can do it without risk. Recover by pumping or with suitable absorbent.
Water Spill:
Spill
Stop leak if you can do it without risk. Confine the spill immediately with booms. Remove
from the surface by skimming or with suitable absorbents. Seek the advice of a specialist
before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this
material; however, geographic conditions, wind, temperature, (and in the case of a water spill)
wave and current direction and speed may greatly influence the appropriate action to be
taken. For this reason, local experts should be consulted.
Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills:
Dike far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.
SECTION 7 Handling and Storage
Handling: Put on appropriate personal protective equipment (see section 8). Eating, drinking and
smoking be prohibited in areas where this material is handled, stored and processed. Workers
should wash hands and face before eating, drinking and smoking. Do not get in eyes or on
skin or clothing. Do not ingest. Avoid release to the environment. Refer to special
instructions/safety data sheet. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Empty
containers retain product residue and can be hazardous. Do not reuse container.
Storage: Store in accordance with local regulation. Store in original container protected from direct
sunlight in a dry, cool and well ventilated area, away from incompatible materials (see section
10) and food and drink. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabelled containers. Use appropriate containment to avoid
environmental contamination.
SECTION 8 Exposure Controls / Personal Protection
Exposure limits/ standards for materials that can be formed when handling this product:
When mists/ aerosols can occur, the following are recommended:
5 mg/m3 - ACGIH TLV.
10mg/m3 - ACGIH STEL
Biological limits
No biological limits allocated.
Note: Limits/ standards shown for guidance only. Follow applicable regulations.
Engineering Controls
The level of protection and types of controls necessary will vary depending upon potential
exposure conditions. Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. Use
explosion-proof ventilation equipment.
Personal Protection
Personal protective equipment selections vary based on potential exposure conditions such as
applications, handling practices, concentration and ventilation. Information on the selection of
protective equipment for use with this material, as provided below, is based upon intended,
normal usage.
Respiratory Protection:
If engineering controls do not maintain airborne contaminant concentrations at a level which
is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if
applicable. Types of respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation.
Particulate air-purifying respirator approved for dust / oil mist is recommended.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive
pressure mode. Supplied air respirators with an escape bottle may be appropriate when
oxygen levels are inadequate, gas/vapor warning properties are poor, or if air purifying filter
capacity/rating may be exceeded.
Hand Protection:
Any specific glove information provided is based on published literature and glove
manufacturer data. Work conditions can greatly effect glove durability; inspect and replace
worn or damaged gloves. The types of gloves to be considered for this material include:
If prolonged or repeated contact is likely. Chemical-resistant gloves are recommended. If
contact with forearms is likely, wear gauntlet-style gloves.
 Eye Protection:
If contact is likely, safety glasses with side shields are recommended. Chemical type goggles
should be worn during misting operations.
Skin and Body Protection:
Any specific clothing information provided is based on published literature or manufacturer
data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with
good industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures:
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. Discard contaminated clothing and footwear that cannot
be cleaned. Practice good housekeeping.
Environmental Controls
Emissions from ventilation or work process equipment should be checked to ensure they
comply with the requirements of environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.
SECTION 9 Physical and Chemical Properties
General
General Information
Physical State: Paste
Color: Light yellow
Odor: Characteristic
Odor Threshold: N/D
Important Health, Safety, and Environmental Information
Specific Gravity : N/D
Density:
Density: N/D
Flash Point [Method]: over 200℃ ( ASTM D92)
Flammable
Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 (Estimate)
Autoignition Temperature: N/D
Boiling Point / Range: > 250℃ (482F) (Initial Boiling Point)
Vapor Density (Air = 1): N/D
Vapor Pressure: N/D
Evaporation Rate (n-
(n-butyl acetate = 1): N/D
pH: N/A
Log Pow (n-
(n-Octanol/Water Partition Coefficient): N/D
 Solubility in Water: Insoluble
Kinematic Viscosity: N/A
Oxidizing Properties: See Sections 3, 15, 16.
Other Information
Freezing Point: N/D
Melting Point: over ４５ ℃
Pour Point: N/D
DMSO Extract (mineral oil only), IP-
IP-346: < 3 %wt
SECTION 10 Stability and Reactivity
Stability: Material is stable under normal conditions.
Conditions to Avoid:
Excessive heat. High energy sources of ignition.
Materials to Avoid:
Strong oxidizers
Hazardous Decomposition Products:
Material does not decompose at ambient temperatures.
Possibility of Hazardous Reactions:
Hazardous polymerization will not occur.
SECTION 11 Toxicological Information
Acute Toxicity
Route Test Result Species Category
Oral LD50 >5000mg/kg Computationally Not Classified
Skin LD50 >5000mg/kg Computationally Not Classified
Inhalation (Mist) LD50 15.57mg/kg Computationally Category 5
Skin Corrosion/Irritation
Possibility of mild skin irritation. Category 3
Serious Eye Damage/Eye Irritation
Possibility of mild eye irritation. Category 2
Respiratory or Skin Sensitization
Respiratory Sensitization: No Data.
Skin Sensitization: From several guinea pigs test, there is no result in sensitization. Not
classified.
Germ Cell Mutagenicity
There was an increase of abnormal cells at cytogenetic test in rats and the increase in
chromosome abnormalities in peripheral blood lymphocytes in the body of the person who
ingested. Category 2
 Carcinogenicity
Highly refined oils, IARC classified according to the outside category.
Reproductive Toxicology
No Data.
Target Organ Systemic Toxicity - Single Exposure
Possibility of acute abnormalities to lung and respiratory tract. Category 1
(Lung, Respiratory tract)
tract)
Target Organ Systemic
Systemic Toxicity - Repeated Exposure
Some people who have undergone years of exposure, have been reported to lung fibrosis and
lipid granuloma of the lung. And Epidemiological survey, by occupational exposure to cutting
oils has been reported the occurrence of severe folliculitis. Category 1(Lung, Skin)
Aspiration Toxicity
The aspiration of mineral oil to the lungs has been reported to cause chemical pneumonia and
oil pneumonia. Category 1
Note: Toxicity information is based on mineral oil toxicity information For other additives, there is no useful
information at this time
SECTION 12 Ecological Information
The information given is based on data available for the material, the components of the material, and
similar materials.
Ecotoxicity
Material -- Not expected to be harmful to aquatic organisms.
Mobility
Base oil component -Low solubility and floats and is expected to migrate from water to the land.
Expected to partition to sediment and wastewater solids.
Persistence and Degradability
Biodegradation:
Base oil component - This material is not expected to be readily biodegradable.

SECTION 13 Disposal Considerations

Disposal Method:
Disposal recommendations based on material as supplied. Disposal must be in accordance
with current applicable laws and regulations, and material characteristics at time of disposal.
Disposal Recommendations:
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by
supervised incineration at very high temperatures to prevent formation of undesirable
combustion products.
 Empty Container Warning Empty Container Warning:
Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean
containers without proper instructions. Empty drums should be completely drained and safely
stored until appropriately reconditioned or disposed. Empty containers should be taken for
recycling, recovery, or disposal through suitably qualified or licensed contractor and in
accordance with governmental regulations.
DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF
IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 Transport Information
UN Number - UN Classification:
Classification:
Not applicable
LAND – Precautionary Transportation Measures & Conditions:
Do not co-land together with dangerous substances categorized in Fire Cat. 1 and/or 6, and/or
High pressure Gases.
NOTE: Comply with applicable laws and regulations.
SEA (IMDG):
Not Regulated for Sea Transport according to IMDG-Code.
AIR (IATA):
Not Regulated for Air Transport.

SECTION 15 Regulatory Information

regulations..
Regulatory status and applicable laws and regulations
Complies with the following national/ regional chemical inventory requirements:
AICS, DSL, KECI, PICCS, IECSC, ENCS, TSCA, EINECS
National Laws and Regulations:
Chemical Substances Law: Existing Chemicals
Fire Service Law: N/A
ISHL: Notified Substances
Maritime Pollution Prevention Law: Regulated
Pollutant Release and Transfer Register (PRTR): not applicable
Sewage Water Law: Mineral oil (5mg/l max.)
Waste Treatment Law: Controlled Industrial Waste
Water Pollutant Control Law: Effluent Regulation (5mg/l max.)
Note: This regulatory information are Japanese regulatory information. When used outside Japan, pleas
please
e
follow the regulations in your country.
SECTION 16 Other Information
N/D = Not Determined, N/A = Not applicable
This Safety Data Sheet Contains the Following Revisions:
Update made in accordance with implementation of GHS requirements.

Notice to Reader
To the best of knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.