SRI CHAITANYA IIT ACADEMY, INDIA 27-04-2024_Sr.

C-120_Jee-Mains_ WTM-31_KEY & Sol’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur – Hyderabad
Sec: Sr. C-120 Jee Main Date: 27-04-24
Time: 09.30Am to 12.30Noon WTM-31 Max. Marks: 300

KEY SHEET

PHYSICS
1) 4 2) 2 3) 2 4) 4 5) 1
6) 2 7) 1 8) 2 9) 2 10) 3
11) 1 12) 1 13) 3 14) 3 15) 2
16) 1 17) 3 18) 3 19) 1 20) 4
21) 1 22) 9 23) 25 24) 5 25) 3
26) 26 27) 9 28) 4 29) 152 30) 6

CHEMISTRY
31) 2 32) 1 33) 3 34) 3 35) 2
36) 3 37) 4 38) 1 39) 2 40) 4
41) 1 42) 3 43) 1 44) 2 45) 2
46) 3 47) 3 48) 2 49) 2 50) 1
51) 1 52) 5 53) 3 54) 1 55) 4
56) 5 57) 3 58) 1 59) 6 60) 36

MATHEMATICS
61) 2 62) 1 63) 3 64) 4 65) 1
66) 3 67) 4 68) 1 69) 1 70) 3
71) 3 72) 1 73) 2 74) 4 75) 2
76) 3 77) 2 78) 3 79) 1 80) 2
81) 1680 82) 14 83) 5 84) 120 85) 31
86) 360 87) 36 88) 30 89) 1 90) 64

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 SRI CHAITANYA IIT ACADEMY, INDIA 27-04-2024_Sr. C-120_Jee-Mains_ WTM-31_KEY & Sol’S

SOLUTIONS
PHYSICS
v
1. v  n   1  100cm
n
 3 5
Resonating lengths are  , , ..........
4 4 4
2. I  density
Density of CO2 is more than the density of air.
V V
3. nopen  nclosed 
2l 4l
4. Conceptual
2 nVs
5. Number of beats 
V
 V 
6. f1  f  
 V  Vs 
 V   2V2
7.  mix  1 1
V1  V2
c22
2 V  2V2
1 1 1 c22 c12 1 cmax 2
Velocity of sound   2  mix  
 c 2 c12 V1  V2 c2  max
8. Conceptual
V
9. n e  0.6 r
2  l  2e 
10. Ar  A cos k x
3rd overtone is 4th harmonic
4 l
l 
2 2
 
 2  l  2 l  A
Ar  A cos  x and x   A cos  =
   16 l 16  2
 
 2 
11. In resonance column, first resonance occurs at

l1  x  ........(1)
4
Second resonance occurs at
3
l2  x  ........(2)
4
Now, for third resonance depth
5 5
l3  x   l3   x ........(3)
4 4

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 SRI CHAITANYA IIT ACADEMY, INDIA 27-04-2024_Sr. C-120_Jee-Mains_ WTM-31_KEY & Sol’S

From (1) , (2) and (3),

 l3  5  l1  x   x  5l1  4 x
 l3  5  22.7  4 1.05  117.7cm
V
12. n p1l 1  pl 1.5 pl1  p  25 10 2
4l 1
3V V V
13.   55 nc 
4l 2l 4l
V V n1 l2 33
14. n1  n2  7  7  
4l1 4l2 n2 l1 32
15 n1  n  8  1
n  n2  8   2 
By adding (1) & (2) n1  n2  16
k k
  16 1  n1  8  n
l1 l2
 l l  k
k  2 1   16 8  n
 l1l2  l1
16. Source is moving forwards the observer. Wavelength of sound waves decreases, frequency
will increase.
17. Conceptual
h h 0
18.  1   1 
m 2V0 2
e 2 E 02 t 2
2  eE t 
2
1
V V   0 
0 0
 m  2 m 2V02

19. Conceptual
dv
20. F  kr
dx
mv 2
 kr  1
r
nh
L  mvr 
2
2
 nh 
m 
From (1)   2 mr   kr
r
r n
Energy E  U  K  n
1 T V 1 T  8 3V
21.   1    2
2l  4lc 2l  4lc
Divide (1) & (2) get

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 SRI CHAITANYA IIT ACADEMY, INDIA 27-04-2024_Sr. C-120_Jee-Mains_ WTM-31_KEY & Sol’S

hc hc
22. ev    1
 0
v hc hc
e     2
4 3 0
By dividing (1) & (2) we get

V V V
23. n0  nc  n
2l0 4lc 4  l0  lc 
1 1 1  4
24.  R     
 1 4  3R
1 1 1
3rd line of Paschen  R  2  2 
1 3 6 
1  1 1
2nd line of Balmer  R 2  2 
2 2 4 
kze2    
25. b cot   b  cot  
E 2 2
26. E  4  7.6   4 1.1
1 1
27. t N  N 0 e  t t
1  2 25  16
3V 2V P
28.  V
4lc 2lo d
29. S n  S1   n  1 d 2 S1  S1  19  4 S1  19  4 S 20  2 19  4
V 340
30. n   100 n : n1 : n2 :.........  1: 3 : 5 : ..........
4l 4  85  102

CHEMISTRY
31. Inter halogen compounds are dia magnetic
Inter halogen compounds are more reactive than halogens except F2
32. F2 strong oxidising agent it oxidises Cl  to Cl2
33. Conceptual
34. Cl2  Br2  F2  I 2
35. 3Cl2  6 NaOH  5 NaCl  3H 2O  NaClO3
36. ClF5  colourless liquid  square pyramidal
37. Cl2O7  H 2O  2 HClO4
38. 3 parts of con. HCl and 1 part of con. HNO3
39. ClO4 has 4 bond pairs and zero lone pair. Hence shape is tetrahedral.
40. Due to large size
41. Cu  H 2O  4  SO4 .H 2O

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 SRI CHAITANYA IIT ACADEMY, INDIA 27-04-2024_Sr. C-120_Jee-Mains_ WTM-31_KEY & Sol’S

42. The complex show geometrical isomerisam

43. SCN  and NO2 are ambidentate ligands. [mabed] shows 3 isomers, 2-cis and 1-trans
44. K 2  Ni  CN  4 
45. Ma3b3 type
46.  M  AA 3  type
47.  M  AA 2 a2  type
3
48. In  FeF6   Sp 3 d 2 hybridisation.
Fe 3 has 5 unpaired electrons
49. Tetra carbonyl nickel (O)
2
50.  Ni  NH 3 6   Sp 3d 2
51. IF5  1 IF7  0
52. Conceptual
53. Conceptual
54. S2 only paramagnetic
55. 2 I 2  9O3  I 4O9  9O2
56. Counter ion chlorines only precipitated.
57. Conceptual
58. Cu  H 2O  4  SO4 .H 2O
59. Conceptual
60. 27  3  2  6   36

MATHS
61. The words starting with E = 360
The words starting with GE = 60
The words starting with GN = 60
The words starting with GTE = 24
The words starting with GTN = 24
The words starting with GTT = 24
GTWENTY = 1
 Total = 553

2 3 20
6  6 20  1
62. 6  6  6  .....  6 
5
 1 1 1 1 
63. 5  4! 1       45
 1! 2! 3! 4!
3
64. Each ring can be rotated in 9-ways, so that total no of ways is  9  9  9  9
65. Case- I : E is to the immediate right of A
The seat next to E (on right side) can be filled in 2-ways
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 SRI CHAITANYA IIT ACADEMY, INDIA 27-04-2024_Sr. C-120_Jee-Mains_ WTM-31_KEY & Sol’S

i.e., either D or F
remaining 3-seats can be filled in 3! Ways
Total no. of ways = 2  3!  12
Case- II : F is to the immediate right of A number of ways E can be filled = 3-ways
[ E can’t occupy seat on left of A as there will be no Space for D]
Number of ways for D = 1 ways
Remaining seats can be filled in 2 –ways.
 Total number of ways  3  1  2  6
 required total number of ways  12  6  18
66. We have 0,1,2,3,4,5,6,7,8,9,
There are 16 last two digit numbers that are divisible by 4 without using zero. So, total
number of such
10 Digit numbers  7  7!  16
Again, there are 6 last two digits numbers that are divisible by 4 with using zero. So, total
number of such
10-digit Numbers  8!  6
 required no. of ways  7  8! 2  8! 6  7  8! 2  8! 6  20  8!
Similarly, six digit numbers = 5  5  4  3  2  1  600
Five digit numbers = 5  5  4  3  2  600
Four digit numbers = 5  5  4  3  300
Three digit numbers  5  5  4  100
Two digit numbers  5  5  25
One digit numbers = 5
 Total =1630
67. R will sit on seat – 1 and Q will sit somewhere to the right of P.
These are three ways
i) P on 2, so Q can be seated on 3,4 or 5 and the remaining can be seated on two chairs in 2-
ways
ii) P on 2, so Q can be seated on 4 or 5
iii) P on 4, so Q will be on 5
 Total no of ways = 6+4+2 = 12
68. 
n  AC  B C   n  A  B 
C
  n S   n A  B
6 6
69. a) Number of onto functions  36  3C  3  1  3C  3  2   540
1 2

b) If f  ai   bi , then pre-image a1 , a2 , a3 cannot be assigned images b1 , b2 , b3 respectively.

Hence each of can be assigned images in 2-ways, can be assigned images in 3 ways each.
Hence no of functions = 216.
c) Total no of functions = 39
d) No. of into functions 39  540  189
b c b c
70.  n  r  1,  n  r    1
a b a b
71. We write all the numbers from 0 to 999 as 3-digit numbers

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 SRI CHAITANYA IIT ACADEMY, INDIA 27-04-2024_Sr. C-120_Jee-Mains_ WTM-31_KEY & Sol’S

000, 001, 002, 003……..998,999 and writing these in reverse

999,998,997,996……..001,000
Adding all these we get 999,999,999,………999
Now the sum of the digits of the 1000
27000
Numbers from 0 to 999 is   13500
2
Now delete 0 and add 1000 to the list of 1000 numbers then N=13501
72. The first entry is a letter. The other entries are letters or digits,
4
so the desired number is   26  36r
r 0

26

35
 365  1

2 1012 
 42024   4   1012
  1  15   15k  1  1
73.     
 15   15   15   15  15
6 6
74.   
x  x 2  1  x  x2  1   26 C0
2
x 6  6C2 x 4  x 2  1  6C4 x 2  x 2  1  6C6  x 2  1
3

 2
75.  x  1 x  3   x  3 x  3  4  x  3  x  
 4
  x  3  0  x  3
And  x  1   x  1  4x  2
Squaring on both sides
2  x  1 x  3  2 x  4
7
x  not in domain
6
th
n
76. Since, n is even, these for   1 term is the middle term
2 
n
n
 1 2
Tn  nCn  x 
2 2
   924 x
6

2
1
2
x
 
n
 x 2  x6
 n  12
77. Put x 2  1  y and simplify
78. S1  6, S 2  14, S3  36
S12  S 2 S  S  P   S3
 P1   S1  6 , P2   11 and P3  1 2 2  6
2 3
Newtons formula is S4  PS 1 3  P2 S 2  P3 S1  0

79. 0  y  x  2 y  x  y, y, x, 2 x  y
yx
Median   10  x  y  20
2

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 SRI CHAITANYA IIT ACADEMY, INDIA 27-04-2024_Sr. C-120_Jee-Mains_ WTM-31_KEY & Sol’S

And range   2 x  y    x  y   28  x  2 y  28
By solving we get x  12, y  8
80.  9
4x
Let a student obtains x  marks out of 75. Then his marks out of 100 is
3
4
Each observation is multiplied by
3
4
New S.D    9  12
3
  2  144

81. Letters of the word NALGONDA are A,A,N,N,L,G,O,D

8 P5
No. of ways of arranging A,A,N,N,L in 8 gaps =  1680
2!2!
And in the remaining 3-gaps G,O,D can be arranged in 1-way in specified order
Total  1680  1  1680
82.
 n  1!   n  5!  3  n  14
 n  4! n! 2
83. Formula based
84. nPr  5P4  5!  120
85. 4! 3! 1  31
6!
86.  360
2!
87. -1,1,2 in principal diagonal  3!  6
-1,1,2 above principal diagonal  3!  6
-1,1,2 below principal diagonal = 1way
Total  6  6  1  36
7!
88. x ( out of 7 different letters of FORTUNE, 3-vowels O,U,E have specified order)
3!
7! 7! x y
Similarly y  & z    30
4! 3!4! z
89. Conceptual
90. S n  S n 1  8S n  2 and
 S15  S14  S16  S15   8S13  8S14  64
S13 S14 S13  S14

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